CN105936751A - Artificial board with good flame retardant effect - Google Patents
Artificial board with good flame retardant effect Download PDFInfo
- Publication number
- CN105936751A CN105936751A CN201610403348.4A CN201610403348A CN105936751A CN 105936751 A CN105936751 A CN 105936751A CN 201610403348 A CN201610403348 A CN 201610403348A CN 105936751 A CN105936751 A CN 105936751A
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- Prior art keywords
- powder
- artificial board
- adhesive
- prepared
- good flame
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses an artificial board with good flame retardant effect. The artificial board is prepared from the following raw materials by weight part: 50-60 of wood flour, 2-6 of hydrotalcite powder, 1-3 of perlite powder, 3-8 of antimony trioxide, 0.4-0.6 of glass fibre, 3-5 of modified compound powder, and 10-20 of an adhesive. The artificial board provided by the invention contains natural adhesive, does not contain formaldehyde, and is safe and pollution-free. The obtained artificial board contains hydrotalcite powder, perlite powder, antimony trioxide, glass fibre and other flame retardant components. And according to the invention, artificial boards with the characteristics of zero formaldehyde release, good static bending strength, good thermal stability and fire resistance can be prepared.
Description
Technical field
The present invention relates to technical field of artificial boards, particularly relate to the artificial board of a kind of good flame retardation effect.
Background technology
Wood-based plate, as the term suggests, it is simply that utilize the leftover bits that timber produces in the course of processing, add chemical adhesive
The sheet material being fabricated to.Artificial board kind is a lot, and conventional has particieboard, medium-density plate, core-board (lumber core), gluing
Plate, and the decoration type wood-based plate such as PLASTIC LAMINATED.Because they have the most different features, it is applied to different Furniture manufacture necks
Territory.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that, the artificial board of a kind of good flame retardation effect.
The present invention is achieved by the following technical solutions:
A kind of artificial board of good flame retardation effect, it is to be prepared by the raw material of following weight parts:
Wood powder 50-60, hydrotalcite powder 2-6, crushed crude pearlite 1-3, antimony oxide 3-8, glass fibre 0.4-0.6, modification compound
Powder 3-5, adhesive 10-20;
Modified compounding powder is prepared by the raw material of following weight parts:
Montmorillonite 10-15, bentonite 3-5, sodium lauryl sulphate 0.3-0.8, Cetyltrimethylammonium bromide 0.1-0.3,
Silane coupling agent KH550 1-2, methanol 5-6;
Described adhesive is prepared by the raw material of following weight parts:
Tapioca 10-20, brown sugar 1-2, carbamide 1-2, C5 Petropols 3-5, Radix Acaciae senegalis 1-4, epoxidized linseed oil 1-2,
Trimethylmethoxysilane 1-3, sodium propionate 0.3-0.5, calcium propionate 0.3-0.4.
The artificial board of described a kind of good flame retardation effect, preparation method comprises the following steps:
(1) wood powder dry, pulverize, then with modification compound powder mix sheet material powder is standby;
(2) after each raw material blending of adhesive, add appropriate amount of deionized water, at 30-35 DEG C, stir 20-30min, obtain adhesive standby
With;
(3) sheet material powder, adhesive mix homogeneously, adds in mould, in hot press after compacting, is heating and curing, to obtain final product.
The artificial board of described a kind of good flame retardation effect, described modification compounds powder, preparation method thereof and comprises the following steps:
(1), after montmorillonite, bentonite being mixed with methanol, remove supernatant after being centrifuged, obtain pasty state compound;
(2) sodium lauryl sulphate, Cetyltrimethylammonium bromide, Silane coupling agent KH550 and appropriate amount of deionized water solution
Mixing, and dispersed with stirring, obtain compounding aqueous solution;
(3) being mixed with compounding aqueous solution by pasty state compound, adjust pH value to 3-5,12-24h is reacted in stirring at room temperature;
(4) product obtained in step (3) is centrifuged, washs with toluene, air-dry under room temperature and get final product.
The invention have the advantage that (1) present invention contains natural glue, without formaldehyde, safety non-pollution;Gained wood-based plate
Material contains the flame-retardant compositions such as hydrotalcite powder, crushed crude pearlite, antimony oxide, glass fibre, can be prepared by the present invention and possess
Formaldehydeless release, good MOR, heat stability and the wood-based plate of fire resistance;
(2) organic compound intercalation of mineral powder can be in the case of keeping mineral mother crystal structure constant so that it is interlamellar spacing is big
The raising of amplitude, thus reach the effect delaminated, reduce the thickness of layer mineral, expand radius-thickness ratio, increasing specific surface area, answered
Use on artificial board, help speed up sheet material powder and adhesive bonding consistency, improve intensity.
Detailed description of the invention
A kind of artificial board of good flame retardation effect, it is to be prepared by the raw material of following weight parts:
Wood powder 50, hydrotalcite powder 2, crushed crude pearlite 1, antimony oxide 3, glass fibre 0.4, modified compounding powder 3, adhesive 10;
Modified compounding powder is prepared by the raw material of following weight parts:
Montmorillonite 10, bentonite 3, sodium lauryl sulphate 0.3, Cetyltrimethylammonium bromide 0.1, silane coupler
KH550 1, methanol 5;
Described adhesive is prepared by the raw material of following weight parts:
Tapioca 10, brown sugar 1, carbamide 1, C5 Petropols 3, Radix Acaciae senegalis 1, epoxidized linseed oil 1, trimethyl methoxy silicon
Alkane 1, sodium propionate 0.3, calcium propionate 0.3.
The artificial board of described a kind of good flame retardation effect, preparation method comprises the following steps:
(1) wood powder dry, pulverize, then with modification compound powder mix sheet material powder is standby;
(2) after each raw material blending of adhesive, add appropriate amount of deionized water, at 30 DEG C, stir 20min, obtain adhesive standby;
(3) sheet material powder, adhesive mix homogeneously, adds in mould, in hot press after compacting, is heating and curing, to obtain final product.
The artificial board of described a kind of good flame retardation effect, described modification compounds powder, preparation method thereof and comprises the following steps:
(1), after montmorillonite, bentonite being mixed with methanol, remove supernatant after being centrifuged, obtain pasty state compound;
(2) sodium lauryl sulphate, Cetyltrimethylammonium bromide, Silane coupling agent KH550 and appropriate amount of deionized water solution
Mixing, and dispersed with stirring, obtain compounding aqueous solution;
(3) being mixed with compounding aqueous solution by pasty state compound, adjust pH value to 3,12h is reacted in stirring at room temperature;
(4) product obtained in step (3) is centrifuged, washs with toluene, air-dry under room temperature and get final product.
Prepared artificial board is carried out performance test, and test result is:
The MOR recording the wood-based plate that this example obtains according to the three-point bending method of GB/T 17,657 2013 regulation is
15-17MPa。
Claims (3)
1. the artificial board of a good flame retardation effect, it is characterised in that: it is to be prepared by the raw material of following weight parts:
Wood powder 50-60, hydrotalcite powder 2-6, crushed crude pearlite 1-3, antimony oxide 3-8, glass fibre 0.4-0.6, modification compound
Powder 3-5, adhesive 10-20;
Modified compounding powder is prepared by the raw material of following weight parts:
Montmorillonite 10-15, bentonite 3-5, sodium lauryl sulphate 0.3-0.8, Cetyltrimethylammonium bromide 0.1-0.3,
Silane coupling agent KH550 1-2, methanol 5-6;
Described adhesive is prepared by the raw material of following weight parts:
Tapioca 10-20, brown sugar 1-2, carbamide 1-2, C5 Petropols 3-5, Radix Acaciae senegalis 1-4, epoxidized linseed oil 1-2,
Trimethylmethoxysilane 1-3, sodium propionate 0.3-0.5, calcium propionate 0.3-0.4.
The artificial board of a kind of good flame retardation effect the most according to claim 1, it is characterised in that: preparation method includes following
Step:
(1) wood powder dry, pulverize, then with modification compound powder mix sheet material powder is standby;
(2) after each raw material blending of adhesive, add appropriate amount of deionized water, at 30-35 DEG C, stir 20-30min, obtain adhesive standby
With;
(3) sheet material powder, adhesive mix homogeneously, adds in mould, in hot press after compacting, is heating and curing, to obtain final product.
The artificial board of a kind of good flame retardation effect the most according to claim 1, it is characterised in that: described modification compounds powder
Preparation method comprises the following steps:
(1), after montmorillonite, bentonite being mixed with methanol, remove supernatant after being centrifuged, obtain pasty state compound;
(2) sodium lauryl sulphate, Cetyltrimethylammonium bromide, Silane coupling agent KH550 and appropriate amount of deionized water solution
Mixing, and dispersed with stirring, obtain compounding aqueous solution;
(3) being mixed with compounding aqueous solution by pasty state compound, adjust pH value to 3-5,12-24h is reacted in stirring at room temperature;
(4) product obtained in step (3) is centrifuged, washs with toluene, air-dry under room temperature and get final product.
Priority Applications (1)
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CN201610403348.4A CN105936751A (en) | 2016-06-07 | 2016-06-07 | Artificial board with good flame retardant effect |
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CN201610403348.4A CN105936751A (en) | 2016-06-07 | 2016-06-07 | Artificial board with good flame retardant effect |
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CN201610403348.4A Withdrawn CN105936751A (en) | 2016-06-07 | 2016-06-07 | Artificial board with good flame retardant effect |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106891413A (en) * | 2017-03-07 | 2017-06-27 | 温汉明 | Color wood powder compression molding high density insulation board technique |
CN108890847A (en) * | 2018-06-29 | 2018-11-27 | 广西浙缘农业科技有限公司 | A kind of preparation process of manioc waste base wood-based plate |
CN109629789A (en) * | 2018-11-19 | 2019-04-16 | 温州丰成建设有限公司 | Floor panel structure is built in a kind of sound-absorbing room |
CN109749200A (en) * | 2018-12-29 | 2019-05-14 | 安徽天康(集团)股份有限公司 | A kind of middle-high voltage power cable |
CN110003829A (en) * | 2019-03-27 | 2019-07-12 | 莒县中邦新能源有限公司 | A kind of preparation method of environment-friendly modified urea-formaldehyde resin adhesive |
CN114311213A (en) * | 2022-02-08 | 2022-04-12 | 福人集团森林工业有限公司 | Process for manufacturing bamboo shaving board with flat surface and oriented structure and paving machine |
CN116408859A (en) * | 2023-06-09 | 2023-07-11 | 潍坊万丰新材料科技有限公司 | Flame retardant composition and application thereof in anti-corrosion flame-retardant wood |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1422905A (en) * | 2001-12-05 | 2003-06-11 | 叶科尼亚有限责任公司 | Preparation method for formed articles capable of biological degradation |
CN105061924A (en) * | 2015-07-28 | 2015-11-18 | 苏州市相城区明达复合材料厂 | Montmorillonite modified wood-plastic composite material plate |
-
2016
- 2016-06-07 CN CN201610403348.4A patent/CN105936751A/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1422905A (en) * | 2001-12-05 | 2003-06-11 | 叶科尼亚有限责任公司 | Preparation method for formed articles capable of biological degradation |
CN105061924A (en) * | 2015-07-28 | 2015-11-18 | 苏州市相城区明达复合材料厂 | Montmorillonite modified wood-plastic composite material plate |
Non-Patent Citations (1)
Title |
---|
郑水林等: "《粉体表面改性》", 30 September 2011, 中国建材工业出版社 * |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106891413A (en) * | 2017-03-07 | 2017-06-27 | 温汉明 | Color wood powder compression molding high density insulation board technique |
CN108890847A (en) * | 2018-06-29 | 2018-11-27 | 广西浙缘农业科技有限公司 | A kind of preparation process of manioc waste base wood-based plate |
CN109629789A (en) * | 2018-11-19 | 2019-04-16 | 温州丰成建设有限公司 | Floor panel structure is built in a kind of sound-absorbing room |
CN109749200A (en) * | 2018-12-29 | 2019-05-14 | 安徽天康(集团)股份有限公司 | A kind of middle-high voltage power cable |
CN110003829A (en) * | 2019-03-27 | 2019-07-12 | 莒县中邦新能源有限公司 | A kind of preparation method of environment-friendly modified urea-formaldehyde resin adhesive |
CN110003829B (en) * | 2019-03-27 | 2020-04-14 | 莒县中邦新能源有限公司 | Preparation method of environment-friendly modified urea-formaldehyde resin adhesive |
CN114311213A (en) * | 2022-02-08 | 2022-04-12 | 福人集团森林工业有限公司 | Process for manufacturing bamboo shaving board with flat surface and oriented structure and paving machine |
CN116408859A (en) * | 2023-06-09 | 2023-07-11 | 潍坊万丰新材料科技有限公司 | Flame retardant composition and application thereof in anti-corrosion flame-retardant wood |
CN116408859B (en) * | 2023-06-09 | 2023-08-11 | 潍坊万丰新材料科技有限公司 | Flame retardant composition and application thereof in anti-corrosion flame-retardant wood |
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Application publication date: 20160914 |