CN105928989B - Humidity sensor and its correction of temperature drift method based on the huge piezo-resistive arrangement of π type - Google Patents

Humidity sensor and its correction of temperature drift method based on the huge piezo-resistive arrangement of π type Download PDF

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CN105928989B
CN105928989B CN201610567744.0A CN201610567744A CN105928989B CN 105928989 B CN105928989 B CN 105928989B CN 201610567744 A CN201610567744 A CN 201610567744A CN 105928989 B CN105928989 B CN 105928989B
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CN105928989A (en
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张加宏
沈雷
刘进
冒晓莉
顾芳
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Nanjing Ruifico Electromechanical Technology Co ltd
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Nanjing University of Information Science and Technology
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Abstract

The present invention provides a kind of humidity sensor based on the huge piezo-resistive arrangement of π type, including 4 data collectors, data conversion integrated layer and filter screen, 4 data collector point two rows are distributed on data conversion integrated layer, the filter screen is placed on the detection zone of the data collector, and the data conversion integrated layer includes the very color liquid crystal display of four-point resistance measurement circuit, CS1180 analog-digital converter, STM32F407 single-chip microcontroller and TFT;4 data collectors give collected data to CS1180 analog-digital converter by four-point resistance measurement amount of circuitry circuit transmission, it exports after the conversion of CS1180 analog-digital converter to STM32F407 single-chip microcontroller, the very color liquid crystal display of TFT is sent to by STM32F407 single-chip microcontroller, in the very color liquid crystal display screen display of TFT;In addition, the present invention also provides the correction of temperature drift methods of humidity sensor.

Description

基于π型巨压阻结构的湿度传感器及其温漂修正方法Humidity sensor based on π-type giant piezoresistive structure and its temperature drift correction method

技术领域technical field

本发明涉及一种基于π型巨压阻结构的湿度传感器及其温漂修正方法,属于微纳机电系统传感器技术领域。The invention relates to a humidity sensor based on a π-type giant piezoresistive structure and a temperature drift correction method thereof, belonging to the technical field of micro-nano electromechanical system sensors.

背景技术Background technique

从上世纪80年代以来随着MEMS(微机电系统)技术的快速发展,越来越多的MEMS器件被广泛应用于工农业、航空航天、气象环境、国防军事等各个领域。而近些年来随着微探针与微流计等器件的研制成功,数量众多的MEMS器件进入了化学分析、大气检测、和温湿度检测等领域。然而,目前的湿度传感器由于器件本身结构限制,无法实现实时高精度、高灵敏度、高可靠性的湿度测量。Since the 1980s, with the rapid development of MEMS (micro-electromechanical systems) technology, more and more MEMS devices have been widely used in various fields such as industry and agriculture, aerospace, meteorological environment, national defense and military affairs. In recent years, with the successful development of devices such as microprobes and microflow meters, a large number of MEMS devices have entered the fields of chemical analysis, atmospheric detection, and temperature and humidity detection. However, the current humidity sensor cannot achieve real-time high-precision, high-sensitivity, and high-reliability humidity measurement due to the structural limitations of the device itself.

传统的湿度传感器大多采用电阻或者电容式的湿敏元件对空气中的水蒸气浓度进行检测,但是由于水和高分子聚合物的介电常数随温度的改变是不同步的,容易产生温漂,同时容易受到光照的影响,所以在很难实现对微小湿度变化的高精度,高灵敏度测量。因此需要对温度的影响和低灵敏度现状进行处理。Most traditional humidity sensors use resistive or capacitive humidity sensors to detect the concentration of water vapor in the air. However, since the dielectric constant of water and polymers changes asynchronously with temperature, it is easy to cause temperature drift. At the same time, it is easily affected by light, so it is difficult to achieve high-precision and high-sensitivity measurement of small humidity changes. Therefore, it is necessary to deal with the influence of temperature and the status quo of low sensitivity.

发明内容Contents of the invention

本发明 为了解决现有技术中存在的上述缺陷和不足,提供了一种基于π型巨压阻结构的湿度传感器及其温漂修正方法,该湿度传感器的压阻系数与应变系数均数量级地增加,极大地高了传感器的灵敏度,可以有效地捕捉空气中微小的湿度变化,拓展测量量程。In order to solve the above-mentioned defects and deficiencies in the prior art, the present invention provides a humidity sensor based on a π-type giant piezoresistive structure and its temperature drift correction method. The piezoresistive coefficient and gauge coefficient of the humidity sensor both increase by orders of magnitude , which greatly increases the sensitivity of the sensor, can effectively capture small humidity changes in the air, and expand the measurement range.

为解决上述技术问题,本发明 提供一种基于π型巨压阻结构的湿度传感器,包括4个数据采集器、数据转换集成层和过滤网,4 个所述数据采集器分两排分布在数据转换集成层上,所述过滤网置于所述数据采集器的检测区上,所述数据转换集成层包括四点电阻测量电路、CS1180模数转换器、STM32F407单片机和TFT真彩液晶显示屏;4个数据采集器将采集到的数据通过四点电阻测量电路传输给 CS1180模数转换器,CS1180模数转换器转换后输出至STM32F407 单片机,由STM32F407单片机发送至TFT真彩液晶显示屏,在TFT 真彩液晶显示屏上显示;In order to solve the above technical problems, the present invention provides a humidity sensor based on a π-type giant piezoresistive structure, including 4 data collectors, a data conversion integration layer and a filter screen, and the 4 data collectors are distributed in two rows in the data On the conversion integration layer, the filter screen is placed on the detection area of the data collector, and the data conversion integration layer includes a four-point resistance measurement circuit, a CS1180 analog-to-digital converter, a STM32F407 single-chip microcomputer and a TFT true-color liquid crystal display; The 4 data collectors transmit the collected data to the CS1180 analog-to-digital converter through the four-point resistance measurement circuit, and the CS1180 analog-to-digital converter converts and outputs to the STM32F407 microcontroller, which is sent to the TFT true-color LCD display by the STM32F407 microcontroller. Displayed on the true color LCD screen;

所述数据采集器包括基底、应力层、检测区和π型巨压阻结构,所述应力层置于所述基底上,所述检测区和π型巨压阻结构分布在所述应力层上,其中,检测区置于所述应力层的中心,π型巨压阻结构为两个,分布置于所述检测区的两侧且位于所述应力层边缘处,两个所述π型巨压阻结构通过金属铝材质的连接线串联,并由一个恒流源供电;所述π型巨压阻结构包括硅结构区、锗结构区和金结构区,其中硅结构区为两段,分布置于所述锗结构区的两端,所述金结构区置于所述硅结构区、锗结构区的同一侧,且所述金结构区的长度等于两段硅结构区和锗结构区的长度之和,所述硅结构区和所述锗结构区的交界处为硅-锗异质结,所述金结构区和所述硅结构区、锗结构区的交界处为金-硅-锗异质结;所述锗结构区的另一侧设有电位监测点;所述π型巨压阻结构的一侧设有温度传感器,用于实时检测环境温度。The data collector includes a substrate, a stress layer, a detection area and a π-type giant piezoresistive structure, the stress layer is placed on the substrate, and the detection area and the π-type giant piezoresistive structure are distributed on the stress layer , wherein the detection area is placed in the center of the stress layer, there are two π-type giant piezoresistive structures, distributed on both sides of the detection area and at the edge of the stress layer, and the two π-type giant piezoresistive structures The piezoresistive structure is connected in series through a connecting line made of metal aluminum, and powered by a constant current source; the π-type giant piezoresistive structure includes a silicon structure area, a germanium structure area and a gold structure area, wherein the silicon structure area is divided into two sections, divided into Arranged at both ends of the germanium structure region, the gold structure region is placed on the same side of the silicon structure region and the germanium structure region, and the length of the gold structure region is equal to the length of the two silicon structure regions and the germanium structure region The sum of the lengths, the junction of the silicon structure region and the germanium structure region is a silicon-germanium heterojunction, and the junction of the gold structure region and the silicon structure region and germanium structure region is gold-silicon-germanium Heterojunction; the other side of the germanium structure region is provided with a potential monitoring point; one side of the π-type giant piezoresistive structure is provided with a temperature sensor for real-time detection of ambient temperature.

进一步,所述应力层与所述基底之间设有单晶硅材质的固体支撑结构,用于防止应力层因压力过大而破裂。Further, a solid support structure made of monocrystalline silicon is provided between the stress layer and the substrate to prevent the stress layer from being ruptured due to excessive pressure.

进一步,所述应力层和所述固体支撑结构之间设有加热装置,所述加热装置为多晶硅电阻丝。Further, a heating device is provided between the stress layer and the solid support structure, and the heating device is a polysilicon resistance wire.

进一步,所述数据采集器还包括两个尺寸、组成材料均与π型巨压阻结构相同的共模信号补偿结构,两个所述共模信号补偿结构位于所述检测区的两端且位于所述应力层边缘处,与两个所述π型巨压阻结构形成方形结构,所述共模信号补偿结构与所述π型巨压阻结构通过金属铝材质的连接线串联,并由同一个恒流源供电。Further, the data collector also includes two common-mode signal compensation structures with the same size and composition materials as the π-type giant piezoresistive structure, and the two common-mode signal compensation structures are located at both ends of the detection area and located at At the edge of the stress layer, a square structure is formed with the two π-type giant piezoresistive structures, and the common-mode signal compensation structure is connected in series with the π-type giant piezoresistive structure through a connecting line made of metal aluminum, and is connected by the same powered by a constant current source.

进一步,所述π型巨压阻结构的周围设有U形应力增强结构;所述应力增强结构为采用RIE刻蚀技术刻蚀在应力层上的槽状结构。Further, a U-shaped stress enhancement structure is provided around the π-type giant piezoresistive structure; the stress enhancement structure is a groove-shaped structure etched on the stress layer by RIE etching technology.

进一步,所述基底的材质为玻璃,应力层的材质为二氧化硅,检测区的材质为聚酰亚胺。Further, the material of the substrate is glass, the material of the stress layer is silicon dioxide, and the material of the detection area is polyimide.

进一步,所述四点电阻测量电路与所述的CS1180模数转换器之间设有依次相连的多路选择器和放大滤波电路;所述放大滤波电路包括由电阻R1、R2、R3、R4与放大器AD620构成的第一级放大电路,由电阻R5和电容C1、电阻R7和电容C2构成的二阶RC低通滤波器。Further, between the four-point resistance measurement circuit and the CS1180 analog-to-digital converter, a multiplexer and an amplification filter circuit connected in sequence are provided; the amplification filter circuit includes resistors R1, R2, R3, R4 and The first-stage amplifying circuit composed of amplifier AD620 is a second-order RC low-pass filter composed of resistor R5 and capacitor C1, resistor R7 and capacitor C2.

进一步,所述硅-锗异质结的尺寸为(60-70)μm*5μm*(50-150)nm,金-硅-锗异质结的尺寸为(60-70)μm*(35-50)μm*(50-150)nm。Further, the size of the silicon-germanium heterojunction is (60-70) μm*5 μm*(50-150) nm, and the size of the gold-silicon-germanium heterojunction is (60-70) μm*(35- 50)μm*(50-150)nm.

进一步,所述金结构区与所述硅结构区、锗结构区之间设有钛结构区,用于固定金结构区,所述钛结构区的长度与所述金结构区的长度相等。Further, a titanium structure area is provided between the gold structure area, the silicon structure area and the germanium structure area for fixing the gold structure area, and the length of the titanium structure area is equal to the length of the gold structure area.

本发明还提供了一种基于π型巨压阻结构的湿度传感器的温漂修正方法,其特征在于:STM32F407单片机利用二次曲面拟合函数 H标准=f(V,T)对温漂的影响进行实时补偿修正,所述二次曲面拟合函数H标准=f(V,T)的获得方法包括以下步骤:The present invention also provides a temperature drift correction method for a humidity sensor based on a π-type giant piezoresistive structure, which is characterized in that: the STM32F407 single-chip microcomputer utilizes the quadratic surface fitting function H standard = f (V, T) to influence the temperature drift Carry out real-time compensation correction, the obtaining method of described quadratic surface fitting function H standard =f (V, T) comprises the following steps:

步骤一,将湿度传感器放入恒温恒湿试验箱内,确定温度T=20 度时的湿度作为标准湿度H标准,然后调节试验箱内的温度,调节范围为-20-60度,步长为10度,得到不同温度下湿度传感器的输出电压值V(T);Step 1, put the humidity sensor into the constant temperature and humidity test chamber, determine the humidity when the temperature T = 20 degrees as the standard humidity H standard , and then adjust the temperature in the test chamber, the adjustment range is -20-60 degrees, and the step size is 10 degrees, get the output voltage value V(T) of the humidity sensor at different temperatures;

步骤二,改变标准湿度H标准,重复步骤一,得到不同温度和不同湿度下的湿度传感器的输出电压值V(H标准,T),将湿度传感器的输出电压值V和温度值T作为待构建的标准湿度曲面方程H标准=(V, T)的输入变量,因此在分析湿度时可以兼顾温度因素的影响;Step 2, change the standard humidity H standard , repeat step 1, obtain the output voltage value V (H standard , T) of the humidity sensor under different temperatures and different humidity, and use the output voltage value V and temperature value T of the humidity sensor as the to-be-built The input variable of the standard humidity surface equation H standard = (V, T), so the influence of the temperature factor can be taken into account when analyzing the humidity;

步骤三,利用上述实验测量的用于构建曲面方程H标准=(V,T)的离散数据进行二次曲面拟合,并采用最小二乘方法确定二次曲面拟合函数H标准=f(V,T)中自变量V和T的系数,从而确定二次曲面拟合函数H标准=f(V,T)。Step 3, using the discrete data for constructing the surface equation H standard =(V, T) measured by the above experiment to carry out quadratic surface fitting, and adopting the least squares method to determine the quadratic surface fitting function H standard =f(V , T) in the coefficients of the independent variables V and T, so as to determine the quadratic surface fitting function H standard = f (V, T).

本发明 所达到的有益技术效果:本发明提供一种基于π型巨压阻结构的湿度传感器,该传感器的实现原理为:环境中的水汽分子透过过滤网滤去杂质后,被综合性能最佳的有机高分子材料聚酰亚胺吸收,由于聚酰亚胺的优异性能,以及过滤网的过滤作用,能够实现在恶劣环境下的湿度检测工作,拓展了本湿度传感器的使用范围。同时该传感器的数据采集器采用具有两个硅-锗异质结和一个金-硅-锗异质结组成的π型巨压阻结构,以及在π型巨压阻结构周围通过RIE 刻蚀制作的应力增强结构,能够使湿度传感器的压阻系数与应变系数均有数量级地增加,通过两种异质结结合使用,π型巨压阻结构能够同时沿横向和纵向的放大应力,在相同应力条件下产生更大的电阻阻值变化,从根本上提高湿度传感器的灵敏度;采用两个共模信号补偿结构能够保证该湿度传感器的压力传感结构在复杂外界环境下的测量精度;为了防止应力层在极限工作状态下因应力过大而破裂,本湿度传感器在应力层下方设有单晶硅构成的固体支撑结构,为应力层在极限工作条件下提供保护,使本湿度传感器的测量范围和使用场合都得到扩展;另外,该传感器采用四点电阻测量方法以及信号的放大、滤波调理电路,可得到较为精准的信号,削弱噪声等外界因素对检测结果的影响,可以达到高精度、稳定测量的效果。采用4个数据采集器获取数据后再取平均值可以提高系统的测量精度和稳定性。本发明提供的湿度传感器的温漂修正方法可以有效提高检测的准确度,避免温度对湿度测量产生的影响。Beneficial technical effects achieved by the present invention: the present invention provides a humidity sensor based on a π-type giant piezoresistive structure. The best organic polymer material polyimide absorbs. Due to the excellent performance of polyimide and the filtering effect of the filter, it can realize the humidity detection work in harsh environments and expand the use range of this humidity sensor. At the same time, the data collector of the sensor adopts a π-type giant piezoresistive structure composed of two silicon-germanium heterojunctions and a gold-silicon-germanium heterojunction, and is fabricated by RIE etching around the π-type giant piezoresistive structure. The stress-enhanced structure can increase the piezoresistive coefficient and gauge coefficient of the humidity sensor by an order of magnitude. Through the combination of two heterojunctions, the π-type giant piezoresistive structure can simultaneously amplify the stress in the horizontal and vertical directions. Larger resistance resistance changes under certain conditions, which fundamentally improves the sensitivity of the humidity sensor; the use of two common-mode signal compensation structures can ensure the measurement accuracy of the pressure sensing structure of the humidity sensor in complex external environments; in order to prevent stress The layer is broken due to excessive stress under the extreme working condition. The humidity sensor is equipped with a solid support structure made of monocrystalline silicon under the stress layer to provide protection for the stress layer under the extreme working conditions, so that the measurement range of the humidity sensor and The application occasions have been expanded; in addition, the sensor adopts the four-point resistance measurement method and the signal amplification and filter conditioning circuit, which can obtain more accurate signals, weaken the influence of external factors such as noise on the detection results, and achieve high precision and stable measurement Effect. The measurement accuracy and stability of the system can be improved by using 4 data collectors to obtain the data and taking the average value. The temperature drift correction method of the humidity sensor provided by the invention can effectively improve the accuracy of detection and avoid the influence of temperature on humidity measurement.

附图说明Description of drawings

图1本发明之数据采集器结构示意图;The structural representation of the data collector of the present invention of Fig. 1;

图2本发明之π型巨压阻结构的结构示意图;The structural representation of the π-type giant piezoresistive structure of Fig. 2 of the present invention;

图3本发明之整体结构示意图;The overall structure schematic diagram of Fig. 3 the present invention;

图4本发明之放大滤波电路图;The amplification filter circuit diagram of Fig. 4 of the present invention;

图5本发明之湿度传感器工作流程示意图;Fig. 5 schematic diagram of the working process of the humidity sensor of the present invention;

图6本发明之湿度传感器温漂修正方法示意图。FIG. 6 is a schematic diagram of a method for correcting temperature drift of a humidity sensor according to the present invention.

其中:1基底;2检测区;3应力增强结构;4应力层;5π型巨压阻结构;6共模信号补偿结构;7固体支撑结构;8硅结构区;9锗结构区;10钛结构区;11金结构区;12硅-锗异质结;13金-硅-锗异质结;14加热装置;15温度传感器;16电位测量点;17数据采集器; 18数据转换集成层;19过滤网。Among them: 1 substrate; 2 detection area; 3 stress enhancement structure; 4 stress layer; 5π type giant piezoresistive structure; 6 common mode signal compensation structure; 7 solid support structure; 8 silicon structure area; 11 gold structure area; 12 silicon-germanium heterojunction; 13 gold-silicon-germanium heterojunction; 14 heating device; 15 temperature sensor; 16 potential measurement point; 17 data collector; 18 data conversion integration layer; 19 Filter.

具体实施方式Detailed ways

下面结合附图对本发明 作进一步描述。以下实施例仅用于更加清楚地说明本发明 的技术方案,而不能以此来限制本发明的保护范围。The present invention will be further described below in conjunction with accompanying drawing. The following examples are only used to more clearly illustrate the technical scheme of the present invention, and cannot limit the protection scope of the present invention with this.

如图1-5所示,本发明 提供一种基于π型巨压阻结构的湿度传感器,包括4个数据采集器17、数据转换集成层18和过滤网19, 4个所述数据采集器17分两排分布在数据转换集成层18上,所述过滤网19置于所述数据采集器17的检测区2上,所述数据转换集成层 18包括四点电阻测量电路、CS1180模数转换器、STM32F407单片机和TFT真彩液晶显示屏;4个数据采集器将采集到的数据通过四点电阻测量电路传输给CS1180模数转换器,CS1180模数转换器转换后输出至STM32F407单片机,由STM32F407单片机发送至TFT真彩液晶显示屏,在TFT真彩液晶显示屏上显示;As shown in Figures 1-5, the present invention provides a humidity sensor based on π-type giant piezoresistive structure, including 4 data collectors 17, data conversion integration layer 18 and filter screen 19, 4 said data collectors 17 Distributed in two rows on the data conversion integration layer 18, the filter screen 19 is placed on the detection area 2 of the data collector 17, and the data conversion integration layer 18 includes a four-point resistance measurement circuit, a CS1180 analog-to-digital converter , STM32F407 single-chip microcomputer and TFT true-color LCD display; 4 data collectors transmit the collected data to the CS1180 analog-to-digital converter through the four-point resistance measurement circuit, and the CS1180 analog-to-digital converter is converted and output to the STM32F407 single-chip microcomputer, which is controlled by the STM32F407 single-chip microcomputer Send to the TFT true color LCD display, and display on the TFT true color LCD display;

所述数据采集器17包括基底1、应力层4、检测区2和π型巨压阻结构5,所述应力层4置于所述基底1上,所述检测区2和π型巨压阻结构5分布在所述应力层4上,其中,检测区2置于所述应力层 4的中心,π型巨压阻结构5为两个,分别为C1,C2,分布置于所述检测区2的两侧且位于所述应力层4边缘处,两个所述π型巨压阻结构5通过金属铝材质的连接线串联,并由一个恒流源供电,恒流源在提供稳定电流的同时减少因电源不同造成的测量误差;所述π型巨压阻结构5包括硅结构区8、锗结构区9和金结构区11,其中硅结构区8为两段,分布置于所述锗结构区9的两端,所述金结构区11置于所述硅结构区8、锗结构区9的同一侧,且所述金结构区11的长度等于两段硅结构区8和锗结构区9的长度之和,所述硅结构区8和所述锗结构区9的交界处为硅-锗异质结12,所述金结构区11和所述硅结构区8、锗结构区9的交界处为金-硅-锗异质结13,其中两个硅 -锗异质结12相互平行,且与金-硅-锗异质结13垂直,从而形成π结构,称为π型巨压阻结构5;所述锗结构区9的另一侧设有电位监测点6;所述π型巨压阻结构5的一侧设有温度传感器15,用于实时检测环境温度。The data collector 17 includes a substrate 1, a stress layer 4, a detection region 2 and a π-type giant piezoresistive structure 5, the stress layer 4 is placed on the substrate 1, and the detection region 2 and the π-type giant piezoresistive structure 5 The structure 5 is distributed on the stress layer 4, wherein the detection area 2 is placed in the center of the stress layer 4, and there are two π-type giant piezoresistive structures 5, respectively C1 and C2, distributed in the detection area 2 and at the edge of the stress layer 4, the two π-type giant piezoresistive structures 5 are connected in series through connecting wires made of aluminum, and powered by a constant current source, which provides stable current At the same time, the measurement error caused by different power sources is reduced; the π-type giant piezoresistive structure 5 includes a silicon structure region 8, a germanium structure region 9 and a gold structure region 11, wherein the silicon structure region 8 is divided into two sections, and is distributed in the germanium structure region. The two ends of the structural region 9, the gold structural region 11 is placed on the same side of the silicon structural region 8 and the germanium structural region 9, and the length of the gold structural region 11 is equal to two sections of the silicon structural region 8 and the germanium structural region 9, the junction of the silicon structure region 8 and the germanium structure region 9 is a silicon-germanium heterojunction 12, the gold structure region 11 and the silicon structure region 8, germanium structure region 9 The junction is a gold-silicon-germanium heterojunction 13, in which two silicon-germanium heterojunctions 12 are parallel to each other and perpendicular to the gold-silicon-germanium heterojunction 13, thus forming a π structure, called π-type giant pressure resistance structure 5; the other side of the germanium structure region 9 is provided with a potential monitoring point 6; one side of the π-type giant piezoresistive structure 5 is provided with a temperature sensor 15 for real-time detection of ambient temperature.

所述基底1的材质为玻璃,应力层4的材质为二氧化硅,检测区 2的材质为聚酰亚胺,能够实现复杂环境下的湿度检测。The material of the substrate 1 is glass, the material of the stress layer 4 is silicon dioxide, and the material of the detection area 2 is polyimide, which can realize humidity detection in complex environments.

为了防止应力层4在极限工作状态下因压力过大而破裂,所述应力层4与所述基底1之间设有单晶硅材质的固体支撑结构7,为应力层4在极限工作条件下提供保护。所述应力层4和所述固体支撑结构 7之间设有加热装置14,所述加热装置为多晶硅电阻丝。In order to prevent the stress layer 4 from being broken due to excessive pressure under the extreme working condition, a solid support structure 7 made of monocrystalline silicon is provided between the stress layer 4 and the substrate 1, so that the stress layer 4 can withstand the extreme working conditions. Provide protection. A heating device 14 is provided between the stress layer 4 and the solid support structure 7, and the heating device is a polysilicon resistance wire.

所述π型巨压阻结构5的周围设有U形应力增强结构3;所述应力增强结构3为采用RIE刻蚀技术刻蚀在应力层上的槽状结构,应力更加集中,使应力变化产生的形变更加明显。A U-shaped stress enhancement structure 3 is provided around the π-type giant piezoresistive structure 5; the stress enhancement structure 3 is a groove-shaped structure etched on the stress layer by RIE etching technology, and the stress is more concentrated, so that the stress changes The resulting deformation is more obvious.

所述数据采集器17还包括两个尺寸、组成材料均与π型巨压阻结构相同的共模信号补偿结构6,分别为C3,C4,两个所述共模信号补偿结构6位于所述检测区2的两端且位于所述应力层4边缘处,与两个所述π型巨压阻结构5形成方形结构,所述共模信号补偿结构 6与所述π型巨压阻结构5通过金属铝材质的连接线串联,并由同一个恒流源供电。The data collector 17 also includes two common-mode signal compensation structures 6 with the same size and composition materials as the π-type giant piezoresistive structure, respectively C3 and C4, and the two common-mode signal compensation structures 6 are located in the Both ends of the detection area 2 are located at the edge of the stress layer 4, forming a square structure with the two π-type giant piezoresistive structures 5, and the common-mode signal compensation structure 6 and the π-type giant piezoresistive structure 5 Connecting wires made of metal aluminum are connected in series and powered by the same constant current source.

试验表明,π型巨压阻结构5的尺寸极大地影响了巨压阻结构的压阻与应变系数,本发明中,所述硅-锗异质结的尺寸为(60-70)μm *5μm*(50-150)nm,金-硅-锗异质结的尺寸为(60-70)μm *(35-50)μm*(50-150)nm。Tests have shown that the size of the π-type giant piezoresistive structure 5 greatly affects the piezoresistivity and gauge factor of the giant piezoresistive structure. In the present invention, the size of the silicon-germanium heterojunction is (60-70) μm*5 μm *(50-150)nm, the size of the gold-silicon-germanium heterojunction is (60-70)μm*(35-50)μm*(50-150)nm.

所述金结构区11与所述硅结构区8、锗结构区9之间设有钛结构区10,用于固定金结构区11,所述钛结构区10的长度与所述金结构区11的长度相等。A titanium structure region 10 is arranged between the gold structure region 11 and the silicon structure region 8 and the germanium structure region 9 for fixing the gold structure region 11, and the length of the titanium structure region 10 is the same as that of the gold structure region 11. are equal in length.

所述四点电阻测量电路与所述的CS1180模数转换器之间设有依次相连的多路选择器和放大滤波电路;所述放大滤波电路包括由电阻 R1、R2、R3、R4与放大器AD620构成的第一级放大电路,由电阻 R5和电容C1、电阻R7和电容C2构成的二阶RC低通滤波器。Between said four-point resistance measurement circuit and said CS1180 analog-to-digital converter, a multiplexer and an amplifying filter circuit connected in sequence are provided; said amplifying and filtering circuit comprises resistors R1, R2, R3, R4 and amplifier AD620 The first-stage amplifying circuit constituted is a second-order RC low-pass filter composed of resistor R5 and capacitor C1, resistor R7 and capacitor C2.

本发明提供的数据采集器17的工作原理:湿度检测区表面覆盖一层过滤网19,将周围环境中除水分以外的其他杂质颗粒过滤,只对空气中水分进行吸收,吸收空气中的水分后π型巨压阻结构5质量发生改变并产生应力,应力通过应力增强结构进行增强,增强后的应力进一步导致π型巨压阻结构5表面尤其是其根部区域产生较大应力,该应力导致π型巨压阻结构5的硅-锗异质结12和金-硅-锗异质结13产生巨压阻效应,即增强后的应力调整了硅-锗异质结12和金- 硅-锗异质结13的势垒高度,使电子通过的数量发生巨大改变,从而使电阻发生数量级的巨变。相对于传统湿度传感器通过电阻电容变化来检测湿度变化,本湿度传感器先通过将湿度变化转变为应力变化,然后通过应力增强并采用在相同应力条件下能够产生更为明显电阻阻值变化的π型巨压阻结构,从而本发明从传感结构上显著提高了湿度传感器的灵敏度,拓宽了其量程范围。The working principle of the data collector 17 provided by the present invention: the surface of the humidity detection area is covered with a layer of filter screen 19, which filters other impurity particles in the surrounding environment except moisture, and only absorbs moisture in the air. The quality of the π-type giant piezoresistive structure 5 changes and generates stress, and the stress is enhanced by the stress-enhancing structure, and the enhanced stress further leads to greater stress on the surface of the π-type giant piezoresistive structure 5, especially in the root region, which leads to π The silicon-germanium heterojunction 12 and the gold-silicon-germanium heterojunction 13 of the type giant piezoresistive structure 5 produce a giant piezoresistive effect, that is, the stress after the enhancement adjusts the silicon-germanium heterojunction 12 and the gold-silicon-germanium heterojunction 12 The height of the potential barrier of the heterojunction 13 greatly changes the number of electrons passing through, so that the resistance undergoes an order of magnitude change. Compared with traditional humidity sensors that detect humidity changes through resistance and capacitance changes, this humidity sensor first converts humidity changes into stress changes, and then enhances the stress and adopts a π-type that can produce more obvious resistance changes under the same stress conditions. The giant piezoresistive structure, so that the invention significantly improves the sensitivity of the humidity sensor from the sensing structure and widens its measuring range.

实施例Example

传统的体硅压阻结构的应变灵敏度系数一般在50-100之间,且易受环境温度的影响。为了说明本发明提供的湿度传感器的技术效果,采用四点弯曲测试装置在-20-60度温度范围内对本发明提出的π型巨压阻结构的应变灵敏度系数进行了测量,测试结果表明:π型巨压阻结构的应变灵敏度系数可以达到1000以上,同时,考察了硅- 锗异质结和金-硅-锗异质结尺寸的变化对应变灵敏度系数的影响,当硅-锗异质结长度为5μm时,应变灵敏度系数数量级巨变,可以达到 3000。另外,温度对π型巨压阻结构的应变灵敏度影响也比较显著,温漂误差达到了3%FS-5%FS。The strain sensitivity coefficient of the traditional bulk silicon piezoresistive structure is generally between 50-100, and is easily affected by the ambient temperature. In order to illustrate the technical effect of the humidity sensor provided by the present invention, the strain sensitivity coefficient of the π-type giant piezoresistive structure proposed by the present invention is measured in the temperature range of -20-60 degrees by using a four-point bending test device, and the test results show that: π The strain sensitivity coefficient of the large piezoresistive structure can reach more than 1000. At the same time, the influence of the size change of the silicon-germanium heterojunction and the gold-silicon-germanium heterojunction on the strain sensitivity coefficient is investigated. When the silicon-germanium heterojunction When the length is 5 μm, the strain sensitivity coefficient changes greatly in magnitude and can reach 3000. In addition, the influence of temperature on the strain sensitivity of the π-type giant piezoresistive structure is also significant, and the temperature drift error reaches 3%FS-5%FS.

由于湿度测量所处的环境复杂,环境温度不是恒定不变的,并且湿度传感器是由半导体材料制作的,所以极易受到温度的影响。考虑到环境温度会对传感器湿度测量带来不小的误差,因此,本发明提供了一种基于π型巨压阻结构的湿度传感器的温漂修正方法,该方法为:STM32F407单片机利用二次曲面拟合函数H标准=f(V,T)对温漂的影响进行实时补偿修正,所述二次曲面拟合函数H标准=f(V,T)的获得方法包括以下步骤:Due to the complex environment in which the humidity is measured, the ambient temperature is not constant, and the humidity sensor is made of semiconductor materials, so it is very susceptible to the influence of temperature. Considering that the ambient temperature will bring considerable errors to the humidity measurement of the sensor, the present invention provides a method for correcting temperature drift of the humidity sensor based on the π-type giant piezoresistive structure. The method is as follows: STM32F407 single-chip The fitting function H standard =f(V, T) performs real-time compensation and correction on the influence of temperature drift, and the method for obtaining the quadratic surface fitting function H standard =f(V, T) includes the following steps:

步骤一,将湿度传感器放入恒温恒湿试验箱内,确定温度T=20 度时的湿度作为标准湿度H标准,然后调节试验箱内的温度,调节范围为-20-60度,步长为10度,得到不同温度下湿度传感器的输出电压值V(T);Step 1, put the humidity sensor into the constant temperature and humidity test chamber, determine the humidity when the temperature T = 20 degrees as the standard humidity H standard , and then adjust the temperature in the test chamber, the adjustment range is -20-60 degrees, and the step size is 10 degrees, get the output voltage value V(T) of the humidity sensor at different temperatures;

步骤二,改变标准湿度H标准,重复步骤一,得到不同温度和不同湿度下的湿度传感器的输出电压值V(H标准,T),将湿度传感器的输出电压值V和温度值T作为待构建的标准湿度曲面方程H标准=(V, T)的输入变量,因此在分析湿度时可以兼顾温度因素的影响;Step 2, change the standard humidity H standard , repeat step 1, obtain the output voltage value V (H standard , T) of the humidity sensor under different temperatures and different humidity, and use the output voltage value V and temperature value T of the humidity sensor as the to-be-built The input variable of the standard humidity surface equation H standard = (V, T), so the influence of the temperature factor can be taken into account when analyzing the humidity;

步骤三,如图6所示,利用上述实验测量的用于构建H标准=(V, T)曲面方程的离散数据进行二次曲面拟合,并采用最小二乘方法确定二次曲面拟合函数H标准=f(V,T)中自变量V和T的系数,从而确定二次曲面拟合函数H标准=f(V,T)。采用最小二乘方法确定二次曲面拟合函数的系数,可以使采用二次曲面拟合函数H标准=f(V,T)计算的湿度值和标准湿度值H标准之间的误差最小。Step 3, as shown in Figure 6, use the discrete data for constructing the H standard =(V, T) surface equation measured by the above experiment to carry out quadratic surface fitting, and adopt the least squares method to determine the quadratic surface fitting function H standard = the coefficients of the independent variables V and T in f(V, T), so as to determine the quadratic surface fitting function H standard = f(V, T). Using the least squares method to determine the coefficients of the quadratic surface fitting function can minimize the error between the humidity value calculated using the quadratic surface fitting function Hstandard =f(V, T) and the standard humidity value Hstandard.

该二次曲面拟合函数H标准=f(V,T)是传感器的被测湿度、环境温度和输出电压之间的曲面拟合数学预测模型,在获取了传感器输出电压和环境温度后可方便地计算出被测湿度值。该二次曲面拟合函数H标准=f(V,T)包含了温度T,通过建立温度和湿度之间的非线性映射关系去除温漂影响,实现温度补偿。将该二次曲面拟合函数移植到 STM32单片机可以进行实时温度漂移补偿修正。The quadratic surface fitting function H standard = f (V, T) is the surface fitting mathematical prediction model between the measured humidity of the sensor, the ambient temperature and the output voltage, and can be conveniently obtained after the sensor output voltage and the ambient temperature Calculate the measured humidity value accurately. The quadratic surface fitting function Hstandard =f(V,T) includes the temperature T, and the influence of temperature drift is removed by establishing a nonlinear mapping relationship between temperature and humidity to realize temperature compensation. Transplanting the quadratic surface fitting function to the STM32 microcontroller can perform real-time temperature drift compensation correction.

以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明技术原理的前提下,还可以做出若干改进和变形,这些改进和变形也应视为本发明的保护范围。The above is only a preferred embodiment of the present invention, it should be pointed out that for those of ordinary skill in the art, without departing from the technical principle of the present invention, some improvements and modifications can also be made. It should also be regarded as the protection scope of the present invention.

Claims (10)

1.基于π型巨压阻结构的湿度传感器,其特征在于:包括4个数据采集器、数据转换集成层和过滤网,4个所述数据采集器分两排分布在数据转换集成层上,所述过滤网置于所述数据采集器的检测区上,所述数据转换集成层包括四点电阻测量电路、CS1180模数转换器、STM32F407单片机和TFT真彩液晶显示屏;4个数据采集器将采集到的数据通过四点电阻测量电路传输给CS1180模数转换器,CS1180模数转换器转换后输出至STM32F407单片机,由STM32F407单片机发送至TFT真彩液晶显示屏,在TFT真彩液晶显示屏上显示;1. Based on the humidity sensor of π type giant piezoresistive structure, it is characterized in that: comprise 4 data collectors, data conversion integrated layer and filter screen, 4 described data collectors are divided into two rows and are distributed on the data conversion integrated layer, The filter screen is placed on the detection area of the data collector, and the data conversion integrated layer includes a four-point resistance measurement circuit, a CS1180 analog-to-digital converter, a STM32F407 single-chip microcomputer and a TFT true-color liquid crystal display; 4 data collectors The collected data is transmitted to the CS1180 analog-to-digital converter through the four-point resistance measurement circuit. After conversion, the CS1180 analog-to-digital converter is output to the STM32F407 single-chip microcomputer, and the STM32F407 single-chip microcomputer sends it to the TFT true-color LCD display. On the TFT true-color LCD display on display; 所述数据采集器包括基底、应力层、检测区和π型巨压阻结构,所述应力层置于所述基底上,所述检测区和π型巨压阻结构分布在所述应力层上,其中,检测区置于所述应力层的中心,π型巨压阻结构为两个,分布置于所述检测区的两侧且位于所述应力层边缘处,两个所述π型巨压阻结构通过金属铝材质的连接线串联,并由一个恒流源供电;所述π型巨压阻结构包括硅结构区、锗结构区和金结构区,其中硅结构区为两段,分布置于所述锗结构区的两端,所述金结构区置于所述硅结构区、锗结构区的同一侧,且所述金结构区的长度等于两段硅结构区和锗结构区的长度之和,所述硅结构区和所述锗结构区的交界处为硅-锗异质结,所述金结构区和所述硅结构区、锗结构区的交界处为金-硅-锗异质结;所述锗结构区的另一侧设有电位监测点;所述π型巨压阻结构的一侧设有温度传感器,用于实时检测环境温度。The data collector includes a substrate, a stress layer, a detection area and a π-type giant piezoresistive structure, the stress layer is placed on the substrate, and the detection area and the π-type giant piezoresistive structure are distributed on the stress layer , wherein the detection area is placed in the center of the stress layer, there are two π-type giant piezoresistive structures, distributed on both sides of the detection area and at the edge of the stress layer, and the two π-type giant piezoresistive structures The piezoresistive structure is connected in series through a connecting line made of metal aluminum, and powered by a constant current source; the π-type giant piezoresistive structure includes a silicon structure area, a germanium structure area and a gold structure area, wherein the silicon structure area is divided into two sections, divided into Arranged at both ends of the germanium structure region, the gold structure region is placed on the same side of the silicon structure region and the germanium structure region, and the length of the gold structure region is equal to the length of the two silicon structure regions and the germanium structure region The sum of the lengths, the junction of the silicon structure region and the germanium structure region is a silicon-germanium heterojunction, and the junction of the gold structure region and the silicon structure region and germanium structure region is gold-silicon-germanium Heterojunction; the other side of the germanium structure region is provided with a potential monitoring point; one side of the π-type giant piezoresistive structure is provided with a temperature sensor for real-time detection of ambient temperature. 2.根据权利要求1所述的基于π型巨压阻结构的湿度传感器,其特征在于:所述应力层与所述基底之间设有单晶硅材质的固体支撑结构,用于防止应力层因压力过大而破裂。2. The humidity sensor based on the π-type giant piezoresistive structure according to claim 1, characterized in that: a solid support structure of monocrystalline silicon is provided between the stress layer and the substrate to prevent the stress layer from Rupture due to excessive pressure. 3.根据权利要求2所述的基于π型巨压阻结构的湿度传感器,其特征在于:所述应力层和所述固体支撑结构之间设有加热装置,所述加热装置为多晶硅电阻丝。3. The humidity sensor based on the π-type giant piezoresistive structure according to claim 2, characterized in that: a heating device is provided between the stress layer and the solid support structure, and the heating device is a polysilicon resistance wire. 4.根据权利要求1所述的基于π型巨压阻结构的湿度传感器,其特征在于:所述数据采集器还包括两个尺寸、组成材料均与π型巨压阻结构相同的共模信号补偿结构,两个所述共模信号补偿结构位于所述检测区的两端且位于所述应力层边缘处,与两个所述π型巨压阻结构形成方形结构,所述共模信号补偿结构与所述π型巨压阻结构通过金属铝材质的连接线串联,并由同一个恒流源供电。4. The humidity sensor based on the π-type giant piezoresistive structure according to claim 1, characterized in that: the data collector also includes two common-mode signal signals of the same size and composition materials as the π-type giant piezoresistive structure A compensation structure, the two common-mode signal compensation structures are located at both ends of the detection area and at the edge of the stress layer, forming a square structure with the two π-type giant piezoresistive structures, and the common-mode signal compensation The structure is connected in series with the π-type giant piezoresistive structure through a connecting line made of metal aluminum, and powered by the same constant current source. 5.根据权利要求1所述的基于π型巨压阻结构的湿度传感器,其特征在于:所述π型巨压阻结构的周围设有U形应力增强结构;所述应力增强结构为采用RIE刻蚀技术刻蚀在应力层上的槽状结构。5. The humidity sensor based on the π-type giant piezoresistive structure according to claim 1, characterized in that: the surrounding of the π-type giant piezoresistive structure is provided with a U-shaped stress enhancement structure; the stress enhancement structure adopts RIE Etching technology etches groove-like structures on the stress layer. 6.根据权利要求1所述的基于π型巨压阻结构的湿度传感器,其特征在于:所述基底的材质为玻璃,应力层的材质为二氧化硅,检测区的材质为聚酰亚胺。6. The humidity sensor based on the π-type giant piezoresistive structure according to claim 1, characterized in that: the material of the substrate is glass, the material of the stress layer is silicon dioxide, and the material of the detection area is polyimide . 7.根据权利要求1所述的基于π型巨压阻结构的湿度传感器,其特征在于:所述四点电阻测量电路与所述的CS1180模数转换器之间设有依次相连的多路选择器和放大滤波电路;所述放大滤波电路包括由电阻R1、R2、R3、R4与放大器AD620构成的第一级放大电路,由电阻R5和电容C1、电阻R7和电容C2构成的二阶RC低通滤波器。7. The humidity sensor based on the π-type giant piezoresistive structure according to claim 1, characterized in that: between the four-point resistance measurement circuit and the CS1180 analog-to-digital converter, there are sequentially connected multiplexers amplifier and amplifying and filtering circuit; the amplifying and filtering circuit includes a first-stage amplifying circuit composed of resistors R1, R2, R3, R4 and amplifier AD620, and a second-order RC low composed of resistor R5 and capacitor C1, resistor R7 and capacitor C2 pass filter. 8.根据权利要求1所述的基于π型巨压阻结构的湿度传感器,其特征在于:所述硅-锗异质结的尺寸为(60-70)μm*5μm*(50-150)nm,金-硅-锗异质结的尺寸为(60-70)μm*(35-50)μm*(50-150)nm。8. The humidity sensor based on the π-type giant piezoresistive structure according to claim 1, characterized in that: the size of the silicon-germanium heterojunction is (60-70) μm*5 μm*(50-150) nm , the size of the gold-silicon-germanium heterojunction is (60-70) μm*(35-50) μm*(50-150) nm. 9.根据权利要求1所述的基于π型巨压阻结构的湿度传感器,其特征在于:所述金结构区与所述硅结构区、锗结构区之间设有钛结构区,用于固定金结构区,所述钛结构区的长度与所述金结构区的长度相等。9. The humidity sensor based on the π-type giant piezoresistive structure according to claim 1, characterized in that: a titanium structure area is provided between the gold structure area, the silicon structure area, and the germanium structure area for fixing The gold structure region, the length of the titanium structure region is equal to the length of the gold structure region. 10.根据权利要求1-9任一项所述的基于π型巨压阻结构的湿度传感器的温漂修正方法,其特征在于:STM32F407单片机利用二次曲面拟合函数H标准=f(V,T)对温漂的影响进行实时补偿修正,所述二次曲面拟合函数H标准=f(V,T)的获得方法包括以下步骤:10. The temperature drift correction method based on the humidity sensor of π-type giant piezoresistive structure according to any one of claims 1-9, characterized in that: STM32F407 single-chip microcomputer utilizes quadratic surface fitting function H standard =f(V, T) real-time compensation correction is carried out to the influence of temperature drift, and the obtaining method of described quadratic surface fitting function H standard =f (V, T) comprises the following steps: 步骤一,将湿度传感器放入恒温恒湿试验箱内,确定温度T=20度时的湿度作为标准湿度H标准,然后调节试验箱内的温度,调节范围为-20-60度,步长为10度,得到不同温度下湿度传感器的输出电压值V(T);Step 1, put the humidity sensor into the constant temperature and humidity test chamber, determine the humidity when the temperature T = 20 degrees as the standard humidity H standard , and then adjust the temperature in the test chamber, the adjustment range is -20-60 degrees, and the step size is 10 degrees, get the output voltage value V(T) of the humidity sensor at different temperatures; 步骤二,改变标准湿度H标准,重复步骤一,得到不同温度和不同湿度下的湿度传感器的输出电压值V(H标准,T),将湿度传感器的输出电压值V和温度值T作为待构建的标准湿度曲面方程H标准=(V,T)的输入变量,因此在分析湿度时可以兼顾温度因素的影响;Step 2, change the standard humidity H standard , repeat step 1, obtain the output voltage value V (H standard , T) of the humidity sensor under different temperatures and different humidity, and use the output voltage value V and temperature value T of the humidity sensor as the to-be-built The input variable of the standard humidity surface equation H standard = (V, T), so the influence of the temperature factor can be taken into account when analyzing the humidity; 步骤三,利用上述实验测量的用于构建曲面方程H标准=(V,T)的离散数据进行二次曲面拟合,并采用最小二乘方法确定二次曲面拟合函数H标准=f(V,T)中自变量V和T的系数,从而确定二次曲面拟合函数H标准=f(V,T)。Step 3, use the discrete data for constructing the surface equation H standard =(V, T) of above-mentioned experimental measurement to carry out quadratic surface fitting, and adopt least squares method to determine quadratic surface fitting function H standard =f(V , T) in the coefficients of the independent variables V and T, so as to determine the quadratic surface fitting function H standard = f (V, T).
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