CN105925749A - High-nodularity nodulizer for nodular cast iron - Google Patents
High-nodularity nodulizer for nodular cast iron Download PDFInfo
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- CN105925749A CN105925749A CN201610357795.0A CN201610357795A CN105925749A CN 105925749 A CN105925749 A CN 105925749A CN 201610357795 A CN201610357795 A CN 201610357795A CN 105925749 A CN105925749 A CN 105925749A
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- cast iron
- nodulizer
- nodular cast
- nodulizing
- oxide
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/10—Making spheroidal graphite cast-iron
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/08—Making cast-iron alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Mold Materials And Core Materials (AREA)
Abstract
The invention discloses a high-nodularity nodulizer for nodular cast iron. The nodulizer is prepared from the following components in percentage by weight: 16% of Mg and Si, 3.0% of Re, 2.1% of Ca, 2.0% of Ba, 0.05% of Bi, 0.09% of Ti, 0.3% of Al, 1.0% of rare earth and Fe in balancing amount. The nodulizer prepared according to the invention adopts rare earth made from yttria, gadolinium oxide, holmium oxide and cerium oxide, so that the nodulizer is greatly enhanced in molten iron purification capacity, nodulizing capacity, nodulizing degeneration resistance and graphite distortion resistance, has a little chilling tendency, can refine a matrix structure, can prevent a resulfurization phenomenon, has high boiling point, can inhibit interference of anti-nodulizing elements, can improve the impact toughness of the nodular cast iron, can also improve the nodularity and the quality of a casting and has the characteristics of energy saving and pollution prevention; the nodulizer can effectively inhibit a nodulizing degeneration phenomenon of the nodular cast iron and meanwhile can accurately control the nodulizing reaction time; and owing to a synergistic effect of the added elements, the strength, hardness and heat resistance of the alloy can be effectively improved, and the nodularity can be greatly improved.
Description
Technical field
The present invention relates to molding sand and make field, particularly relate to the Nodulizing agent for nodular cast iron of a kind of high Oxygen potential.
Background technology
The nodulizer of production and selling generally Re3Mg7-9 or Re5Mg7-9 in the market.Rare earth and content of magnesium are higher.There is problems in that the production cost of nodulizer is higher；Abnormal nodularizing makes mechanical property drastically decline, it is impossible to reaching corresponding index, wherein major reason is exactly
The residual quantity of magnesium and rare earth content is not enough；The severity of molten iron boiling when spheroidising, and with high light and magnesium steam potential safety hazard, skin and eye irritation to people are big, and temperature fall is big simultaneously, and foundry goods can be made the defects such as pore, cold shut, underpriming occur；The absorptivity of magnesium is declined by molten iron, molten iron to the absorption of magnesium typically when 4-6% absorptivity reach 70%, along with the absorptivity of magnesium is begun to decline by the molten iron that increases of magnesium, when reaching 8%, absorptivity only has 50%, only has 45% when 9%.
Because the defect that above-mentioned existing nodulizer and production method thereof exist, the present inventor manufactures practical experience abundant for many years and professional knowledge based on being engaged in this type of product design, and coordinates the utilization of scientific principle, the most in addition research and innovation, to founding a kind of nodulizer so that it is have more practicality.Through constantly research, design, and after repeatedly studying sample and improving, finally create the present invention having practical value.
Summary of the invention
It is an object of the invention to provide the Nodulizing agent for nodular cast iron of a kind of high Oxygen potential.
The present invention is achieved through the following technical solutions:
A kind of Nodulizing agent for nodular cast iron of high Oxygen potential, it is made up of following component by weight percentage, Mg+Si 16%, Re3.0%, Ca2.1%, Ba2.0%, Bi0.05%, Ti0.09%, Al0.3%, rare earth 1.0%, Ni1.0%, Mn0.03%, SiC0.1%, remaining is Fe；
In described Mg+Si16%, the desirable scope of percentage by weight of Mg is 5.8-6.2%, and the desirable scope of percentage by weight of described Si is 9.8-10.2%, Mg and Si weight percent content and keeps definite value 16%；
Described rare earth is made up of following component in percentage terms: yittrium oxide 20%, gadolinium oxide 35%, holimium oxide 25%, cerium oxide 20%；
Described SiC is nano SiC, and granularity is 25-28nm.
Further, the particle diameter of described Nodulizing agent for nodular cast iron is 4.2-4.4mm.
Further, proportioning when described Nodulizing agent for nodular cast iron uses is pressed 1-1.2 kilogram/and is added.
The preparation method of the Nodulizing agent for nodular cast iron of a kind of high Oxygen potential, is made up of following making step:
1) raw material is chosen by each element weight percent；
2) by 1) material that takes joins and carries out melting in electric induction furnace；
3) come out of the stove when temperature reaches 1200 DEG C ~ 1300 DEG C, aluminium alloy is poured in the wharve of airtight multilayer and be cooled to room temperature；
4) by 3) aluminium alloy that cools down is crushed to required particle diameter, is processed into final package packing.
Silicon is extremely strong graphite element, and addition is too low easily to be occurred when molten alloy spraying stove phenomenon, and a lot of manufacturers all occur because spray stove causes casualties accident.The too high not only added cost of addition, and there will be alloy structure and loosen, component segregation.The present invention by silicon in nodulizer and magnesium content done big component analysis and experiment, find when magnesium and silicon content and account for nodulizer quality 16% time, can significantly improve the performance of nodulizer, improve Oxygen potential, the tensile strength obtaining high-toughness ductile iron under as cast condition brings up to 478.4 MPa, makes the absorptivity of magnesium be brought up to 87.57% by the 48.67% of conventional nodulizer.
The present invention is by the rare earth adding 1.0% in nodulizer, and rare earth is made up of yittrium oxide 20%, gadolinium oxide 35%, holimium oxide 25%, cerium oxide 20%, so that the nodulizer made has obtained great reinforcement in purifying molten iron, nodularization, anti-decaying spheroidisation, anti-graphite morphology ability, chilling tendency is little, matrix can be refined, and it is possible to prevent reversion phenomenon, boiling point is high, tension-active element can be suppressed to disturb, the impact flexibility of magnesium iron can be improved, Oxygen potential can also be improved, improve the quality of foundry goods.
Calcium is the deficiency that strong graphite element can effectively make up rare earth and magnesium, suppresses the boiling of magnesium simultaneously.But the solubility that calcium is in molten iron is limited, low weak effect, high occur inverted chill phenomenon on the contrary, the addition that the present invention determines calcium by great many of experiments coordinates a certain amount of aluminium of interpolation and titanium, not only increase calcium effect originally, also avoid the appearance of inverted chill phenomenon, tensile strength, toughness and the dynamic property of spheroidal graphite cast-iron is had great castering action.Barium be strong graphite element can purifying molten iron, the effect such as delayed involution.Barium forms the diaphragm of thin layer and prevents sulphur, oxygen secondary from entering molten iron on molten iron surface.Bismuth is strong graphite element, adds and magnesium iron can be made when eutectoid reaction in right amount to form a large amount of or whole ferrite matrix, refine graphite nodule, increase the number of graphite simultaneously.Foundry goods tensile strength and elongation percentage is made to be greatly enhanced.
By the coordinated effect of manganese, nickel, nanometer silicon carbide and titanium, it is possible to prevent nodulizer from floating to molten iron surface and be burned off, favourable nodularization, it is possible to increase the molten iron absorptivity to magnesium；Purifying molten iron can also be realized, increase graphite nuclei calculation, promotion graphitization, prolongation decaying spheroidisation time, promote forming core thinning microstructure etc. effect, be conducive to improving the comprehensive mechanical performance of nodular iron casting.
The invention has the beneficial effects as follows, compared with prior art:
The nodulizer that the present invention prepares uses the rare earth being made up of yittrium oxide, gadolinium oxide, holimium oxide, cerium oxide, so that the nodulizer made has obtained great reinforcement in purifying molten iron, nodularization, anti-decaying spheroidisation, anti-graphite morphology ability, chilling tendency is little, can refine matrix, and be possible to prevent reversion phenomenon, boiling point is high, tension-active element can be suppressed to disturb, the impact flexibility of magnesium iron can be improved, Oxygen potential can also be improved, improve the quality of foundry goods, there is feature energy-conservation, antipollution；" decaying spheroidisation " phenomenon of magnesium iron can be effectively suppressed, the spheroidizing reacion time can be accurately controlled simultaneously；The synergy that coordinates of each addition element can be effectively improved the intensity of alloy, hardness and heat resistance, it is possible to Oxygen potential is greatly improved；Have that energy consumption is low, it is little to pollute, production cost is low feature.
Detailed description of the invention
A kind of Nodulizing agent for nodular cast iron of high Oxygen potential, it is made up of following component by weight percentage, Mg+Si 16%, Re3.0%, Ca2.1%, Ba2.0%, Bi0.05%, Ti0.09%, Al0.3%, rare earth 1.0%, Ni1.0%, Mn0.03%, SiC0.1%, remaining is Fe；
In described Mg+Si16%, the desirable scope of percentage by weight of Mg is 5.8-6.2%, and the desirable scope of percentage by weight of described Si is 9.8-10.2%, Mg and Si weight percent content and keeps definite value 16%；
Described rare earth is made up of following component in percentage terms: yittrium oxide 20%, gadolinium oxide 35%, holimium oxide 25%, cerium oxide 20%；
Described SiC is nano SiC, and granularity is 25-28nm.
Further, the particle diameter of described Nodulizing agent for nodular cast iron is 4.2-4.4mm.
Further, proportioning when described Nodulizing agent for nodular cast iron uses is pressed 1-1.2 kilogram/and is added.
The preparation method of the Nodulizing agent for nodular cast iron of a kind of high Oxygen potential, is made up of following making step:
1) raw material is chosen by each element weight percent；
2) by 1) material that takes joins and carries out melting in electric induction furnace；
3) come out of the stove when temperature reaches 1200 DEG C ~ 1300 DEG C, aluminium alloy is poured in the wharve of airtight multilayer and be cooled to room temperature；
4) by 3) aluminium alloy that cools down is crushed to required particle diameter, is processed into final package packing.
Comparative example 1: nodulizer QRMg6Re5:Mg6%, Si 8%, Re5%, Ca0.8%, Mn1.6%, Ti1%, Al0.5%, remaining is Fe；
Comparative example 2: nodulizer: Mg5, Si 11%, Re3.0%, Ca2.1%, Ba2.0%, Bi0.05%, Ti0.09%, Al0.3%, rare earth 1.0%, Ni1.0%, Mn0.03%, SiC0.1%, remaining is Fe；Described rare earth is made up of following component in percentage terms: yittrium oxide 20%, gadolinium oxide 35%, holimium oxide 25%, cerium oxide 20%；
Comparative example 3: nodulizer: Mg+Si 16%, Re3.0%, Ca2.1%, Ba2.0%, Al0.3%, rare earth 1.0%, Ni1.0%, Mn0.03%, remaining be Fe；Described rare earth is made up of following component in percentage terms: yittrium oxide 20%, gadolinium oxide 35%, holimium oxide 25%, cerium oxide 20%；The desirable scope of percentage by weight of Mg is 5.8-6.2%, and the desirable scope of percentage by weight of described Si is 9.8-10.2%；
Comparative example 4: nodulizer: Mg+Si 16%, Re3.0%, Ca2.1%, Ba2.0%, Bi0.05%, Ti0.09%, Al0.3%, rare earth 1.0%, Ni1.0%, Mn0.03%, SiC0.1%, remaining is Fe；Described rare earth is yittrium oxide；The desirable scope of percentage by weight of Mg is 5.8-6.2%, and the desirable scope of percentage by weight of described Si is 9.8-10.2%；
Nodulizer of the present invention and comparative example nodulizer are administered contrast:
| Oxygen potential % | Remaining magnesium % | Residual Re % | Spheroidal graphite cast-iron tensile strength MPa | Foundry returns proportioning % | |
| The present invention | 98 | 0.060 | 0.0087 | 499.7 | 85 |
| Comparative example 1 | 92 | 0.041 | 0.0054 | 452 | 73 |
| Comparative example 2 | 94 | 0.055 | 0.0075 | 478 | 77 |
| Comparative example 3 | 92 | 0.042 | 0.0066 | 464 | 75 |
| Comparative example 4 | 95 | 0.056 | 0.0064 | 478 | 78 |
Table 1
As can be seen from Table 1, the present invention and the contrast of comparative example 2, it appeared that, although the content of magnesium and silicon and reached 16% still in comparative example 2, its each content beyond the scope that present invention provide that, cause the nodulizer performance made significantly to decline, contrast by the present invention Yu comparative example 3, it is found that lack some element, the performance of the nodulizer made significantly declines；Being contrasted with comparative example 4 by the present invention, it is found that be used alone the nodulizer that yittrium oxide is made, performance is substantially not as the present invention；Contrasted with comparative example 1 by the present invention, it appeared that, the present invention has raising greatly to spheroidal graphite cast-iron Oxygen potential, its remaining magnesium after spheroidizing reacion, residual Re and foundry returns proportioning are all significantly improved, solving the affected problem of mechanical property caused by remaining magnesium and residual Re deficiency etc., improve nodularization effect and the mechanical performance of spheroidal graphite cast-iron, economic benefit is obvious.
Claims (4)
1. the Nodulizing agent for nodular cast iron of a high Oxygen potential, it is characterized in that, being made up of following component by weight percentage, Mg+Si 16%, Re3.0%, Ca2.1%, Ba2.0%, Bi0.05%, Ti0.09%, Al0.3%, rare earth 1.0%, Ni1.0%, Mn0.03%, SiC0.1%, remaining is Fe；
In described Mg+Si16%, the desirable scope of percentage by weight of Mg is 5.8-6.2%, and the desirable scope of percentage by weight of described Si is 9.8-10.2%, Mg and Si weight percent content and keeps definite value 16%；
Described rare earth is made up of following component in percentage terms: yittrium oxide 20%, gadolinium oxide 35%, holimium oxide 25%, cerium oxide 20%；
Described SiC is nano SiC, and granularity is 25-28nm.
The Nodulizing agent for nodular cast iron of a kind of high Oxygen potential the most according to claim 1, it is characterised in that the particle diameter of described Nodulizing agent for nodular cast iron is 4.2-4.4mm.
The Nodulizing agent for nodular cast iron of a kind of high Oxygen potential the most according to claim 1, it is characterised in that proportioning when described Nodulizing agent for nodular cast iron uses is pressed 1-1.2 kilogram/and added.
4. according to the preparation method of the Nodulizing agent for nodular cast iron of a kind of high Oxygen potential described in claim 1-3, it is characterised in that be made up of following making step:
1) raw material is chosen by each element weight percent；
2) by 1) material that takes joins and carries out melting in electric induction furnace；
3) come out of the stove when temperature reaches 1200 DEG C ~ 1300 DEG C, aluminium alloy is poured in the wharve of airtight multilayer and be cooled to room temperature；
4) by 3) aluminium alloy that cools down is crushed to required particle diameter, is processed into final package packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610357795.0A CN105925749A (en) | 2016-05-26 | 2016-05-26 | High-nodularity nodulizer for nodular cast iron |
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| CN201610357795.0A CN105925749A (en) | 2016-05-26 | 2016-05-26 | High-nodularity nodulizer for nodular cast iron |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624732A (en) * | 2018-07-16 | 2018-10-09 | 佛山市高明康得球铁有限公司 | A kind of Nodulizing agent for nodular cast iron |
| CN108796161A (en) * | 2018-07-16 | 2018-11-13 | 佛山市高明康得球铁有限公司 | A kind of preparation method of Nodulizing agent for nodular cast iron |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85100068A (en) * | 1985-04-01 | 1986-07-30 | 清华大学 | Nodulizer for heavy section nodular graphite cast iron and manufacture method thereof |
| CN102560227A (en) * | 2010-12-23 | 2012-07-11 | 龙南龙钇重稀土科技股份有限公司 | Method for producing low-silicon spheroidizing agent by adopting melting distributing and punching composite method |
| CN102717035A (en) * | 2012-07-09 | 2012-10-10 | 江苏多为泵业股份有限公司 | Low Si-Mg ratio and low RE-Mg nodularizer |
| CN102827987A (en) * | 2012-09-24 | 2012-12-19 | 芜湖市金贸流体科技股份有限公司 | Spheroidizing agent as well as production method and usage thereof |
| CN104878277A (en) * | 2015-05-12 | 2015-09-02 | 含山县兴达球墨铸铁厂 | Corrosion-resistant ductile cast iron material for hydraulic wrench piston and preparation method of corrosion-resistant ductile cast iron material |
-
2016
- 2016-05-26 CN CN201610357795.0A patent/CN105925749A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85100068A (en) * | 1985-04-01 | 1986-07-30 | 清华大学 | Nodulizer for heavy section nodular graphite cast iron and manufacture method thereof |
| CN102560227A (en) * | 2010-12-23 | 2012-07-11 | 龙南龙钇重稀土科技股份有限公司 | Method for producing low-silicon spheroidizing agent by adopting melting distributing and punching composite method |
| CN102717035A (en) * | 2012-07-09 | 2012-10-10 | 江苏多为泵业股份有限公司 | Low Si-Mg ratio and low RE-Mg nodularizer |
| CN102827987A (en) * | 2012-09-24 | 2012-12-19 | 芜湖市金贸流体科技股份有限公司 | Spheroidizing agent as well as production method and usage thereof |
| CN104878277A (en) * | 2015-05-12 | 2015-09-02 | 含山县兴达球墨铸铁厂 | Corrosion-resistant ductile cast iron material for hydraulic wrench piston and preparation method of corrosion-resistant ductile cast iron material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108624732A (en) * | 2018-07-16 | 2018-10-09 | 佛山市高明康得球铁有限公司 | A kind of Nodulizing agent for nodular cast iron |
| CN108796161A (en) * | 2018-07-16 | 2018-11-13 | 佛山市高明康得球铁有限公司 | A kind of preparation method of Nodulizing agent for nodular cast iron |
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Application publication date: 20160907 |