CN105925102B - A kind of lacquer for blending glass microballoon and preparation method thereof - Google Patents
A kind of lacquer for blending glass microballoon and preparation method thereof Download PDFInfo
- Publication number
- CN105925102B CN105925102B CN201610309952.0A CN201610309952A CN105925102B CN 105925102 B CN105925102 B CN 105925102B CN 201610309952 A CN201610309952 A CN 201610309952A CN 105925102 B CN105925102 B CN 105925102B
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- China
- Prior art keywords
- lacquer
- glass microballoon
- color
- siliceous sand
- hydroxyethyl cellulose
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
It is by mass percentage, composed of the following components the invention discloses a kind of blending glass microballoon lacquer：Water, 8%~14%；Hydroxyethyl cellulose, 0.1%~0.2%；Special emulsion, 18%~24%；Assorted natural siliceous sand, 30%~55%；Glass microballoon, 20%~45%；Wetting agent, 0.01%~0.1%；Dispersant, 0.01%~0.5%；Antifoaming agent, 0.01%~0.05%；Thickener, 0.1%~0.3%；Coalescents, 0.05%~0.5%.The lacquer of the present invention, using reflection of the glass microballoon to light, refraction effect, the brightness of lacquer is enhanced, and the durability of glass microballoon is good, it will not be substantially change using rear lacquer color for a long time, have the advantages that brightness, the vividness of color and colour retention are unaffected.And it can preferably solve the problems, such as that quartz sand natural crystal transition exploitation mineral resources is exhausted with glass microballoon partial alternative natural siliceous sand in the present invention.
Description
Technical field
The present invention relates to building coating technical field more particularly to a kind of lacquer for blending glass microballoon and its preparation sides
Method.
Background technology
In recent years, natural real stone paint because its preparation process it is simple, color is various, it is easy for construction the advantages that, in building coating
In application percentage it is higher and higher.Traditional lacquer mainly emphasizes its adhesive force, water proofing property, resistance to soiling, anti-corrosive properties, but at it
The concern of brightness, the vividness of color and colour retention etc. is far from enough.Traditional lacquer is often because long-term illumination can fade.Base
It is particularly important to the research with stronger brightness and colour retention lacquer at present in above-mentioned present situation.
Invention content
A kind of lacquer for blending glass microballoon is provided it is an object of the invention to overcome the deficiency of the above-mentioned prior art,
The lacquer substitutes part natural siliceous sand with glass microballoon, using reflection of the glass microballoon to light, refraction effect, enhances true
The brightness of mineral varnish, and the durability of glass microballoon is good, will not be substantially change using rear lacquer color for a long time.The true stone
Paint not only has higher brightness, in bright gay color degree and reflecting rate, but also with preferable colour retention.
To achieve the above object, the present invention, which provides a kind of concrete component of Nano self-cleaning formula lacquer and weight ratio, is：
Water, 8%~14%；Hydroxyethyl cellulose, 0.1%~0.2%；Special emulsion, 18%~24%；Assorted natural siliceous sand, 30%~55%；
Glass microballoon, 20%~45%；Wetting agent, 0.01%~0.1%；Dispersant, 0.01%~0.5%；Antifoaming agent, 0.01%~0.05%；
Thickener, 0.1%~0.3%；Coalescents, 0.05%~0.5%.
Preferably, the glass microballoon partial alternative that natural siliceous sand is modified by surface polymer in the lacquer.
Preferably, the special emulsion is one or two kinds of in silicone acrylic emulsion or modified silicone acrylic emulsion.
Preferably, the hydroxyethyl cellulose solution has preferable flow adjustment, and dispersed protecting colloid ability is most
By force.
The present invention also provides a kind of lacquer preparation method, preparation process is：
Step 101, by the weight ratio of above-mentioned blending glass microballoon lacquer, first by water, various auxiliary agents, special emulsion into
Row mixing, stirring 10min；
Step 201, it is to be mixed uniformly after sequentially add assorted natural siliceous sand, glass microballoon, be sufficiently mixed stirring 20min
Left and right；
Step 301, adjustment viscosity and color after confirming uniformly, detection are canned.
Preferably, in step 101 and step 201, speed of agitator is 100~200r/min.
Compared with prior art, beneficial effects of the present invention：
1st, blending glass microballoon lacquer of the invention has stronger brightness, and durability is good, has preferable color
Vividness and colour retention.
2nd, the preparation method of blending glass microballoon lacquer of the invention is simple, and of low cost, form of construction work is also simple.
3rd, the lacquer stability of blending glass microballoon of the invention is good, highly reliable, easy to use, highly practical, easily
In popularization and application.The present invention is cheap, and economic value is high.
4th, lacquer of the invention, using reflection of the glass microballoon to light, refraction effect, enhances the brightness of lacquer,
And the durability of glass microballoon is good, will not be substantially change using rear lacquer color for a long time, have brightness, color it is fresh
The advantages of lightness and unaffected colour retention.It, can be preferable and with glass microballoon partial alternative natural siliceous sand in the present invention
Solve the problems, such as that quartz sand natural crystal transition exploitation mineral resources is exhausted.
Specific embodiment
Embodiment 1：A kind of lacquer preparation method
Water is added in paint can, add in while stirring 0.1% hydroxyethyl cellulose, 19% silicone acrylic emulsion, 0.05%
Wetting agent, 0.2% dispersant, 0.03% antifoaming agent, 0.05% coalescents, are sufficiently mixed stirring, time 10min, then
40% natural siliceous sand, 35% glass microballoon is added in while stirring, is sufficiently mixed stirring 20min or so, is adjusted after confirming uniformly
Whole viscosity and color, detection are canned.
Embodiment 2：A kind of lacquer preparation method
Water is added in paint can, while stirring add in 0.1% hydroxyethyl cellulose, 20% modification silicone acrylic emulsion,
0.07% wetting agent, 0.3% dispersant, 0.02% antifoaming agent, 0.1% coalescents, are sufficiently mixed stirring, and the time is
10min, then 50% natural siliceous sand, 25% glass microballoon are added in while stirring, stirring 20min or so is sufficiently mixed, is confirmed
Adjustment viscosity and color after uniformly, detection are canned.
Embodiment 3：A kind of lacquer preparation method
Water is added in paint can, while stirring add in 0.2% hydroxyethyl cellulose, 24% modification silicone acrylic emulsion,
0.1% wetting agent, 0.4% dispersant, 0.01% antifoaming agent, 0.3% coalescents, are sufficiently mixed stirring, and the time is
10min, then 35% natural siliceous sand, 40% glass microballoon are added in while stirring, stirring 20min or so is sufficiently mixed, is confirmed
Adjustment viscosity and color after uniformly, detection are canned.
Embodiment 4：A kind of lacquer preparation method
Water is added in paint can, while stirring the hydroxyethyl cellulose of addition 0.15%, 20% silicone acrylic emulsion, 0.01%
Wetting agent, 0.06% dispersant, 0.05% antifoaming agent, 0.5% coalescents, be sufficiently mixed stirring, time 10min,
It adds in 30% natural siliceous sand, 45% glass microballoon while stirring again, stirring 20min or so is sufficiently mixed, after confirming uniformly
Viscosity and color are adjusted, detection is canned.
Embodiment 5：A kind of lacquer preparation method
Water is added in paint can, while stirring the hydroxyethyl cellulose of addition 0.15%, 22% silicone acrylic emulsion, 0.07%
Wetting agent, 0.5% dispersant, 0.03% antifoaming agent, 0.2% coalescents, be sufficiently mixed stirring, time 10min,
It adds in 53% natural siliceous sand, 22% glass microballoon while stirring again, stirring 20min or so is sufficiently mixed, after confirming uniformly
Viscosity and color are adjusted, detection is canned.
Embodiment 6：Artificial ageing resistance is tested
" 6.16 artificial ageing resistance " test method in standard " JG/T 24-2000 " sets control group and experiment
Whether group has statistically aobvious to the lacquer in comparative analysis downstream and lacquer its artificial ageing resistance of the present invention
Sex differernce is write, to judge the durability of the lacquer of the present invention.
In conclusion the blending glass microballoon lacquer of the present invention has stronger brightness, durability is good, has preferable
The vividness and colour retention of color.The preparation method of the blending glass microballoon lacquer of the present invention is simple, of low cost, construction party
Formula is also simple.The lacquer stability of the blending glass microballoon of the present invention is good, highly reliable, easy to use, highly practical, is easy to
It promotes and applies.The present invention is cheap, and economic value is high.The lacquer of the present invention utilizes reflection of the glass microballoon to light, refraction
Effect enhances the brightness of lacquer, and the durability of glass microballoon is good, will not be occurred using rear lacquer color for a long time bright
It is aobvious to change, have the advantages that brightness, the vividness of color and colour retention are unaffected.And with glass microballoon part in the present invention
Natural siliceous sand is substituted, can preferably solve the problems, such as that quartz sand natural crystal transition exploitation mineral resources is exhausted.
Although the embodiments of the present invention has been shown and described above, it is to be understood that above-described embodiment is example
Property, it is impossible to limitation of the present invention is interpreted as, those of ordinary skill in the art are not departing from the principle of the present invention and objective
In the case of above-described embodiment can be changed within the scope of the invention, change, replace.
Claims (2)
1. a kind of blending glass microballoon lacquer, which is characterized in that by mass percentage, composed of the following components：
Water, 8%~14%；
Hydroxyethyl cellulose, 0.1%~0.2%；
Special emulsion, 18%~24%；
Assorted natural siliceous sand, 30%~55%；
Glass microballoon, 20%~45%；
Wetting agent, 0.01%~0.1%；
Dispersant, 0.01%~0.5%；
Antifoaming agent, 0.01%~0.05%；
Thickener, 0.1%~0.3%；
Coalescents, 0.05%~0.5%；The glass microballoon part that natural siliceous sand is modified by surface polymer in the lacquer
It substitutes；The special emulsion is one or two kinds of in silicone acrylic emulsion or modified silicone acrylic emulsion；The hydroxyethyl cellulose is solution.
2. a kind of lacquer preparation method, which is characterized in that its preparation process is：
Step 101, it is as described in claim 1 blending glass microballoon lacquer weight ratio, first by water, hydroxyethyl cellulose,
Wetting agent, dispersant, antifoaming agent, coalescents, special emulsion are mixed, and stir 10min；
Step 201, it is to be mixed uniformly after sequentially add assorted natural siliceous sand, glass microballoon, be sufficiently mixed stirring 20min；
Step 301, adjustment viscosity and color after confirming uniformly, detection are canned；
Wherein, in step 101 and step 201, speed of agitator is 100~200r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610309952.0A CN105925102B (en) | 2016-05-11 | 2016-05-11 | A kind of lacquer for blending glass microballoon and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610309952.0A CN105925102B (en) | 2016-05-11 | 2016-05-11 | A kind of lacquer for blending glass microballoon and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105925102A CN105925102A (en) | 2016-09-07 |
| CN105925102B true CN105925102B (en) | 2018-07-06 |
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| CN201610309952.0A Active CN105925102B (en) | 2016-05-11 | 2016-05-11 | A kind of lacquer for blending glass microballoon and preparation method thereof |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108424044A (en) * | 2018-04-16 | 2018-08-21 | 合肥协耀玻璃制品有限公司 | A kind of decoration of exterior wall lacquer of addition colorful glass microbead |
| CN109337482A (en) * | 2018-10-24 | 2019-02-15 | 宿松汉邦新型建材有限公司 | A kind of snowflake white sand lacquer and preparation method thereof |
| CN110218027B (en) * | 2019-06-17 | 2021-12-31 | 济宁学院 | Self-cleaning stone-like paint with glass beads as aggregates and preparation method thereof |
| CN110256920A (en) * | 2019-06-25 | 2019-09-20 | 济宁学院 | A kind of Nano self-cleaning formula lacquer and method blending organic coating glass microballoon |
| CN110228970B (en) * | 2019-06-27 | 2021-11-12 | 济宁学院 | Real stone paint with good anti-fouling and self-cleaning capabilities and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2858978A1 (en) * | 2003-08-22 | 2005-02-25 | Tf Chimie | Hardenable, granite-effect coating material for protection and decoration of floors, e.g. in bathrooms or hospitals, contains cold-curing liquid binder, colored inert solid particles and inert solid filler particles |
| CN103450766A (en) * | 2013-08-14 | 2013-12-18 | 青岛益群漆业集团有限公司 | Development of high-grade water-based finish paint |
| CN103571234A (en) * | 2012-08-09 | 2014-02-12 | 常州华日升反光材料股份有限公司 | Preparation method of modified glass beads for light reflecting film |
| CN104109439A (en) * | 2014-07-28 | 2014-10-22 | 漳州三德利油漆涂料有限公司 | Heat preserving really stone paint and preparation method thereof |
-
2016
- 2016-05-11 CN CN201610309952.0A patent/CN105925102B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2858978A1 (en) * | 2003-08-22 | 2005-02-25 | Tf Chimie | Hardenable, granite-effect coating material for protection and decoration of floors, e.g. in bathrooms or hospitals, contains cold-curing liquid binder, colored inert solid particles and inert solid filler particles |
| CN103571234A (en) * | 2012-08-09 | 2014-02-12 | 常州华日升反光材料股份有限公司 | Preparation method of modified glass beads for light reflecting film |
| CN103450766A (en) * | 2013-08-14 | 2013-12-18 | 青岛益群漆业集团有限公司 | Development of high-grade water-based finish paint |
| CN104109439A (en) * | 2014-07-28 | 2014-10-22 | 漳州三德利油漆涂料有限公司 | Heat preserving really stone paint and preparation method thereof |
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| CN105925102A (en) | 2016-09-07 |
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Address after: 272200 Jining Chemical Industrial Development Zone, Hu Ji Town, Jinxiang County, Jining, Shandong Applicant after: Shandong Saideli new materials Limited by Share Ltd. Address before: 272200 Jining Chemical Industrial Development Zone, Hu Ji Town, Jinxiang County, Jining, Shandong Applicant before: JINING SAIDELI NEW MATERIAL CO.,LTD. |
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| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: The invention relates to a real stone paint mixed with glass beads and a preparation method thereof Effective date of registration: 20220303 Granted publication date: 20180706 Pledgee: Bank of China Limited Jinxiang Branch Pledgor: Shandong Saideli new materials Limited by Share Ltd. Registration number: Y2022980002119 |
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Date of cancellation: 20230403 Granted publication date: 20180706 Pledgee: Bank of China Limited Jinxiang Branch Pledgor: Shandong Saideli new materials Limited by Share Ltd. Registration number: Y2022980002119 |
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