CN105924925A - Novel flame-retardant door and window profile and preparation method thereof - Google Patents
Novel flame-retardant door and window profile and preparation method thereof Download PDFInfo
- Publication number
- CN105924925A CN105924925A CN201610448027.6A CN201610448027A CN105924925A CN 105924925 A CN105924925 A CN 105924925A CN 201610448027 A CN201610448027 A CN 201610448027A CN 105924925 A CN105924925 A CN 105924925A
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- China
- Prior art keywords
- door
- preparation
- retardant
- section bar
- flame
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention provides a novel flame-retardant door and window profile and a preparation method thereof. The door and window profile comprises polycarbonate, ABS (acrylonitrile butadiene styrene) resin, MBS (methacrylate butadiene styrene) resin, composite flame retardant and composite auxiliaries. The preparation method includes the steps: a) mixing raw materials; b) squeezing granulation; c) injection molding. The door and window profile has fine mechanical property, high heat resistance and excellent halogen-free flame retardation, and is extremely wide in application prospect.
Description
Technical field
The present invention relates to a kind of door-window section bar, be specifically related to a kind of novel flame-retardant door-window section bar and preparation method thereof, belong to
Window technology field.
Background technology
Door and window is an indispensable part in room.Door and window can be divided into Wood-door window, steel casement door window, aluminium alloy door by material
Window, plastic door-window etc..Wherein, Wood-door window is moderate, appearance poor, and tightness is poor, inflammable inflammable, strain cracking, safeguards and spends
Height, service life is short;Steel casement door window price is low, of low grade, perishable, yielding, and maintenance cost is high, and service life is short, and it is naughty to face
Eliminate;Aluminum alloy doors and windows are from heavy and light, sturdy and durable, good seal performance, good flame resistance, and outward appearance is luxurious, but yielding, perishable, and
Heat insulating ability difference poor, heat insulation, soundproof effect are the strongest;Plastic door-window corrosion resistance and good, defening effect is good, and energy-saving heat preserving performance is excellent
Different, recyclable recycling, but bulk strength is poor.
At present, plastic door-window is with its good corrosion resistance, air-tightness, sound insulation property and heat preservation energy-saving, at building field
It is widely applied.Owing to plastic door-window exists the defect that bulk strength is poor, therefore the section bar of plastic door-window is many with composite plastic
Material material is main, to improve its intensity.In existing plastic door-window section bar, Merlon/ABS resin composite be one relatively
Conventional section bar.On the one hand this composite can improve thermostability and the mechanical property of ABS resin, on the other hand can drop
The melt viscosity of oligo-ester carbonate, improves processing characteristics, reduces cost.But, the fire resistance of this composite is poor;For
This, halogenated flame retardant is applied in Merlon/ABS resin composite by many plastic door-window manufacturing enterprises, to improve it
Fire resistance, but along with environment is more and more higher to the ecological requirements of material, halogen system fire-retardant polycarbonate/ABS resin composite
Increasingly denounced by people.
Summary of the invention
For the demand, the invention provides a kind of novel flame-retardant door-window section bar and preparation method thereof, this door-window section bar
Having the halogen-free flameproof performance of good mechanical property, higher heat resistance and excellence, application prospect is the most wide.
The present invention is a kind of novel flame-retardant door-window section bar and preparation method thereof, the raw material components that described door-window section bar comprises
Having Merlon, ABS resin, MBS resin, composite flame-retardant agent, composite assistant, described preparation method comprises the steps: a)
Mixing raw material, b) extruding pelletization, c) injection mo(u)lding.
In a preferred embodiment of the present invention, the raw material components percentage by weight that described door-window section bar comprises is: poly-carbon
Acid esters 78%, ABS resin 10%, MBS resin 3%, composite flame-retardant agent 8%, composite assistant 1%.
In a preferred embodiment of the present invention, the raw material components percentage by weight that described door-window section bar comprises is: poly-carbon
Acid esters 85%, ABS resin 3%, MBS resin 3%, composite flame-retardant agent 8%, composite assistant 1%.
In a preferred embodiment of the present invention, described composite flame-retardant agent is by bisphenol-A double (diphenyl phosphoester) and perfluor
Butyl sulfonic acid potassium 120:1 in mass ratio is compounding to be formed.
In a preferred embodiment of the present invention, described composite assistant is pressed matter by anti-dripping agent SN3300 and antioxidant 1010
Measure form more compounding than 2:3.
In a preferred embodiment of the present invention, in described step b), extruding and pelletizing process condition is: extruder rotating speed
40r/min, each section of temperature of extruder is 200 DEG C, 210 DEG C, 220 DEG C, 210 DEG C.
In a preferred embodiment of the present invention, in described step c), Shooting Technique condition is: barrel temperature 220 DEG C, note
Injection pressure 85MPa, injection time 40s.
Present invention is disclosed a kind of novel flame-retardant door-window section bar and preparation method thereof, this door-window section bar has good mechanics
The halogen-free flameproof performance of performance, higher heat resistance and excellence, application prospect is the most wide.
Accompanying drawing explanation
The present invention is further detailed explanation with detailed description of the invention below in conjunction with the accompanying drawings:
Fig. 1 is the process figure of embodiment of the present invention novel flame-retardant door-window section bar preparation method.
Detailed description of the invention
Below in conjunction with the accompanying drawings presently preferred embodiments of the present invention is described in detail, so that advantages and features of the invention energy
It is easier to be readily appreciated by one skilled in the art, thus protection scope of the present invention is made apparent clear and definite defining.
Fig. 1 is the process figure of embodiment of the present invention novel flame-retardant door-window section bar preparation method;This door-window section bar comprises
Raw material components have Merlon, ABS resin, MBS resin, composite flame-retardant agent, composite assistant, described preparation method include as
Lower step: a) mixing raw material, b) extruding pelletization, c) injection mo(u)lding.
The novel flame-retardant door-window section bar that the present invention mentions, passes through as matrix material with Merlon/ABS resin composite plastic
Add composite flame-retardant agent, compatibilization and toughening agent and composite assistant, use the method for melt blending extrusion to be prepared from.Wherein, compound
Fire retardant is formed by bisphenol-A double (diphenyl phosphoester) and perfluorobutyl potassium sulfonate 120:1 in mass ratio are compounding;This composite flame-proof
Agent is a kind of excellent halogen-free flame retardants, and decomposability high temperature resistant, water-fast is good, and the halogen-free flame-retardance of material can be greatly improved.Increase
Holding toughener is MBS resin.Composite assistant is formed by anti-dripping agent SN3300 and antioxidant 1010 2:3 in mass ratio is compounding;Should
Anti-dripping agent in composite assistant can be effectively prevented from drip phenomenon during material combustion, makes material have the most fire-retardant
Property.By Reasonable adjustment Merlon content in the material, the heat distortion temperature of material can be effectively improved, the most effectively increase
The mechanical properties such as strong tensile strength of material, bending strength and impact strength.
Embodiment 1
Concrete preparation method is as follows:
A) mixing raw material, weighs the Merlon of 78% the most by weight percentage, the ABS resin of 10%, the MBS resin of 3%, and 8%
Composite flame-retardant agent, the composite assistant of 1%;Then above-mentioned raw materials is put into mix homogeneously in high-speed stirred container, wherein, stirring
Speed is 500r/min, and mixing time is 10min.
B) extruding pelletization, batch mixing step a) produced is put into double screw extruder, is squeezed by extruder process conditions are melted
Go out, obtain pellet;Wherein, extruder process conditions are: extruder rotating speed 40r/min, each section of temperature of extruder from charge door to
Head is followed successively by 200 DEG C, 210 DEG C, 220 DEG C, 210 DEG C.
C) injection mo(u)lding, the pellet first step b) produced preheats 2h under the conditions of 80 DEG C, then utilizes injection machine by note
Mould process conditions by pellet injection mo(u)lding;Wherein, Shooting Technique condition is: barrel temperature 220 DEG C, injection pressure 85MPa, injection
Time 40s.
Embodiment 2
Concrete preparation method is as follows:
A) mixing raw material, weighs the Merlon of 85% the most by weight percentage, the ABS resin of 3%, the MBS resin of 3%, 8%
Composite flame-retardant agent, the composite assistant of 1%;Then above-mentioned raw materials is put into mix homogeneously in high-speed stirred container, wherein, stirring speed
Degree is 500r/min, and mixing time is 10min.
B) extruding pelletization, batch mixing step a) produced is put into double screw extruder, is squeezed by extruder process conditions are melted
Go out, obtain pellet;Wherein, extruder process conditions are: extruder rotating speed 40r/min, each section of temperature of extruder from charge door to
Head is followed successively by 200 DEG C, 210 DEG C, 220 DEG C, 210 DEG C.
C) injection mo(u)lding, the pellet first step b) produced preheats 2h under the conditions of 80 DEG C, then utilizes injection machine by note
Mould process conditions by pellet injection mo(u)lding;Wherein, Shooting Technique condition is: barrel temperature 220 DEG C, injection pressure 85MPa, injection
Time 40s.
Present invention is disclosed a kind of novel flame-retardant door-window section bar and preparation method thereof, this door-window section bar has good mechanics
The halogen-free flameproof performance of performance, higher heat resistance and excellence, application prospect is the most wide.
The above, the only detailed description of the invention of the present invention, but protection scope of the present invention is not limited thereto, and any
Those of ordinary skill in the art in the technical scope that disclosed herein, the change that can expect without creative work or
Replace, all should contain within protection scope of the present invention.Therefore, protection scope of the present invention should be limited with claims
Fixed protection domain is as the criterion.
Claims (7)
1. novel flame-retardant door-window section bar and preparation method thereof, it is characterised in that the raw material group that described door-window section bar comprises
Dividing and have Merlon, ABS resin, MBS resin, composite flame-retardant agent, composite assistant, described preparation method comprises the steps:
A) mixing raw material, b) extruding pelletization, c) injection mo(u)lding.
Novel flame-retardant door-window section bar the most according to claim 1 and preparation method thereof, it is characterised in that described door and window type
The raw material components percentage by weight that material comprises is: Merlon 78%, ABS resin 10%, MBS resin 3%, composite flame-retardant agent 8%, multiple
Close auxiliary agent 1%.
Novel flame-retardant door-window section bar the most according to claim 1 and preparation method thereof, it is characterised in that described door and window type
The raw material components percentage by weight that material comprises is: Merlon 85%, ABS resin 3%, MBS resin 3%, composite flame-retardant agent 8%, multiple
Close auxiliary agent 1%.
Novel flame-retardant door-window section bar the most according to claim 1 and preparation method thereof, it is characterised in that described compound resistance
Combustion agent is by bisphenol-A double (diphenyl phosphoester) and perfluorobutyl potassium sulfonate in mass ratio
120:1 is compounding to be formed.
Novel flame-retardant door-window section bar the most according to claim 1 and preparation method thereof, it is characterised in that described compound help
Agent is formed by anti-dripping agent SN3300 and antioxidant 1010 2:3 in mass ratio is compounding.
Novel flame-retardant door-window section bar the most according to claim 1 and preparation method thereof, it is characterised in that described step
B) in, extruding and pelletizing process condition is: extruder rotating speed 40r/min, each section of temperature of extruder be 200 DEG C, 210 DEG C, 220 DEG C,
210℃。
Novel flame-retardant door-window section bar the most according to claim 1 and preparation method thereof, it is characterised in that described step c)
In, Shooting Technique condition is: barrel temperature 220 DEG C, injection pressure 85MPa, injection time 40s.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610448027.6A CN105924925A (en) | 2016-06-21 | 2016-06-21 | Novel flame-retardant door and window profile and preparation method thereof |
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Application Number | Priority Date | Filing Date | Title |
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CN201610448027.6A CN105924925A (en) | 2016-06-21 | 2016-06-21 | Novel flame-retardant door and window profile and preparation method thereof |
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Publication Number | Publication Date |
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CN105924925A true CN105924925A (en) | 2016-09-07 |
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CN201610448027.6A Pending CN105924925A (en) | 2016-06-21 | 2016-06-21 | Novel flame-retardant door and window profile and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109988387A (en) * | 2019-04-15 | 2019-07-09 | 安徽百祺瑞建材科技有限公司 | A kind of reinforced fireproof door and window and its production method |
WO2020151552A1 (en) * | 2019-01-24 | 2020-07-30 | 金发科技股份有限公司 | Makrolon composition and use of sulfonate and phosphorous compound in reducing fuming and heat release of makrolon |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1489618A (en) * | 2001-01-25 | 2004-04-14 | Flame-retardant polycarbonate compositions, which are reinforced with minerals and having high seam resistance | |
CN101173089A (en) * | 2006-10-31 | 2008-05-07 | 佛山市顺德区汉达精密电子科技有限公司 | Modified PC/ABS alloy |
CN104403295A (en) * | 2014-12-17 | 2015-03-11 | 安徽科聚新材料有限公司 | Halogen-free flame-retardant high-gloss inorganic-fiber-reinforced PC/ABS material and preparation method thereof |
-
2016
- 2016-06-21 CN CN201610448027.6A patent/CN105924925A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1489618A (en) * | 2001-01-25 | 2004-04-14 | Flame-retardant polycarbonate compositions, which are reinforced with minerals and having high seam resistance | |
CN101173089A (en) * | 2006-10-31 | 2008-05-07 | 佛山市顺德区汉达精密电子科技有限公司 | Modified PC/ABS alloy |
CN104403295A (en) * | 2014-12-17 | 2015-03-11 | 安徽科聚新材料有限公司 | Halogen-free flame-retardant high-gloss inorganic-fiber-reinforced PC/ABS material and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020151552A1 (en) * | 2019-01-24 | 2020-07-30 | 金发科技股份有限公司 | Makrolon composition and use of sulfonate and phosphorous compound in reducing fuming and heat release of makrolon |
CN109988387A (en) * | 2019-04-15 | 2019-07-09 | 安徽百祺瑞建材科技有限公司 | A kind of reinforced fireproof door and window and its production method |
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Application publication date: 20160907 |
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