CN105924760A - Packaging film for electronic components - Google Patents
Packaging film for electronic components Download PDFInfo
- Publication number
- CN105924760A CN105924760A CN201610435288.4A CN201610435288A CN105924760A CN 105924760 A CN105924760 A CN 105924760A CN 201610435288 A CN201610435288 A CN 201610435288A CN 105924760 A CN105924760 A CN 105924760A
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- Prior art keywords
- electronic components
- packaging film
- packaging
- components
- film
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2493/00—Characterised by the use of natural resins; Derivatives thereof
- C08J2493/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
- C08L2203/162—Applications used for films sealable films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/206—Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention belongs to the field of electronic components and discloses a packaging film for the electronic components. The packaging film is prepared from ethylene-vinyl acetate copolymer, silane coupling agent, rosin resin, plant ash, illite, stearic acid, zeolite powder and fatty acid polyglycol ester. The packaging film is a thin film being 10-100micron in thickness or a coating being 30-100micron in thickness; by treatment at 200DEG C for one hour, the elongation of the packaging film is lower than 4.5% while the tensile strength of the packaging film is higher than 56MPa at 30DEG C, so that the packaging film is excellent in mechanical property and capable of strongly protecting the electronic components from physical and electron loss caused by external or other surrounding electronic components after packaging the electronic components; the vapor permeation rate is lower than 0.03g/m<2>/24h, so that the packaging film has an excellent waterproof and damp-proof function and is capable of protecting the electronic components from water damage in storage, transport and utilization after packaging the electronic components, and oxidative corrosion of the electronic components can be greatly decelerated.
Description
Technical field
The present invention relates to electronic devices and components field, particularly to a kind of electronic devices and components encapsulating film.
Background technology
Electronic devices and components are to constitute electronic equipment or the important component part of electromechanical equipment, and the kind of electronic devices and components is numerous
Many, and volume is relatively small, is the most sporadically distributed.But, owing to electronic devices and components are using
During, usually affected by environment (the such as factor such as water, heat) and surrounding components and parts and be deformed, oxidized or other reason
Change damage, thus affect the normal use of present equipment.
In order to solve the problems referred to above, it is fixing that general employing rubber membrane etc. carries out protection, such as Chinese patent application
CN103773257A, it discloses a kind of glued membrane encapsulating electronic component, although this glued membrane can solve problem to a certain extent,
But, the mechanical strength of this film is the most poor, and while water-blocking moistureproof performance is the most poor, and time length can cause electronic devices and components
Oxide etch.
Summary of the invention
The goal of the invention of the present invention is: providing a kind of electronic devices and components encapsulating film, this encapsulating film has excellent simultaneously
Different mechanical performance and water resistance, to solve the problems referred to above.
The technical solution used in the present invention is such that a kind of electronic devices and components encapsulating film, by following weight percentage ratio
The component composition of meter:
Ethylene-vinyl acetate copolymer 45-50%
Silane coupler 3-5%
Rosin resin 15-20%
Plant ash 2-5%
Illite 12-15%
Stearic acid 3-5%
Zeolite powder 2-5%
Fatty acid polyethylene glycol ester 1-3%;
Said components adds up to 100%.
In said components, the residue after plant ash is draft and xylophyta is fully burnt, wherein contains the most inorganic
Ion and trace element, the plant ash preferred powder of the present invention is broken to particle diameter less than 30 μm;
Illite, be otherwise known as hydromuscovite, is the silicate mica group clay mineral of a kind of rich potassium, its preferable chemical composition
It is K0.75(Al1.75R)[Si3.5Al0.5O10](OH)2, i.e. its main chemical compositions is SiO2、Al2O3、K2O and Na2O, the application
Illite from Sichuan, the application mainly utilizes SiO therein2、Al2O3、K2O、Na2O and other elements of trace therein and
Its special proportioning, and utilize its special crystal structure, illite is crushed to particle diameter less than after 10 μm, and sieves by the application
Selecting suitable organic polymer, work in coordination with other compositions, the sizing material obtained can make thin film, or sizing material is coated in electricity
Sub-component surface, can have the mechanical performance of excellence and waterproof and dampproof performance, meanwhile, also to the grass of waste in prior art
The resources such as wood ash, Erie's stone ore have carried out effectively recycling, and have great economic benefit and social benefit;
The preparation method of the electronic devices and components encapsulating film of the present invention is to comprise the following steps:
(1) weigh: weigh in described ratio;
(2) pulverize: plant ash is crushed to particle diameter and is less than 30 μm, illite is crushed to particle diameter less than 10 μm;
(3) frit reaction: by ethylene-vinyl acetate copolymer, silane coupler, rosin resin, plant ash, stearic acid and fat
Acid polyethylene glycol ester is mixed in described ratio, and 650r/min stirs 15min, is then heated to molten condition, and stirs at 195 DEG C
Mix 20min, be subsequently adding illite and the zeolite powder of described ratio, at 175 DEG C, react 20min, obtain sizing material;
(4) masking or coating: sizing material step (3) obtained, uses the techniques such as blowing to make the thin film that thickness is 10-100 μm,
Or use the mode of spraying, obtain the thin film that thickness is 30-100 μm.
As preferred technical scheme: described silane coupler is isobutyl triethoxy silane.There is more preferably machinery
Performance and waterproof and dampproof performance.
In sum, owing to have employed technique scheme, the invention has the beneficial effects as follows: the thickness that the present invention prepares is
The thin film of 10-100 μm or the coat film that thickness is 30-100 μm, at 30 DEG C after processing with 200 DEG C × 1 hour
Hot strength reaches more than 56MPa, percentage elongation is below 4.5%, has the mechanical performance of excellence, is used for encapsulating electronics unit device
Electronic devices and components can be formed strong protection after part so that it is be not subject to the external world or other components and parts of surrounding physically and electrically
Son loss;Its its steam permeability is less than 0.03g/m2/ 24h, has the waterproof and dampproof function of excellence, is used for encapsulating electronics
Electronic devices and components can be protected after components and parts storing, transport, use during from the infringement of water, thus its quilt is greatly reduced
The speed of oxide etch.
Detailed description of the invention
The present invention is described in detail below.
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, to the present invention
It is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not used to
Limit the present invention.
Embodiment 1:
A kind of electronic devices and components encapsulating film, is made up of following components in parts by weight:
Ethylene-vinyl acetate copolymer 45%
Isobutyl triethoxy silane 5%
Rosin resin 20%
Plant ash 5%
Illite 15%
Stearic acid 5%
Zeolite powder 3%
Fatty acid polyethylene glycol ester 2%
The preparation method of above-mentioned electronic devices and components encapsulating film is to comprise the following steps:
(1) weigh: weigh in described ratio;
(2) pulverize: plant ash is crushed to particle diameter and is less than 30 μm, illite is crushed to particle diameter less than 10 μm;
(3) frit reaction: by ethylene-vinyl acetate copolymer, silane coupler, rosin resin, plant ash, stearic acid and fat
Acid polyethylene glycol ester is mixed in described ratio, and 650r/min stirs 15min, is then heated to molten condition, and stirs at 195 DEG C
Mix 20min, be subsequently adding illite and the zeolite powder of described ratio, at 175 DEG C, react 20min, obtain sizing material;
(4) masking or coating: sizing material step (3) obtained, uses the techniques such as blowing to make the thin film that thickness is 10-100 μm,
Or use the mode of spraying, obtain " encapsulating film A " that thickness is 30-100 μm;
Performance test:
A, measuring mechanical property:
The hot strength at 30 DEG C after " encapsulating film A " (1*10cm) being processed with 200 DEG C × 1 hour is
63.8MPa, percentage elongation are 3.1%;
B, water resistance are tested:
The WVTR-9001 steam penetrating capacity analyzer using Jinan think of gram carries out steam penetrating capacity test, operates according to it
Handbook operates, follow-on test 10 times, averages, and the steam penetrating capacity of final " encapsulating film A " is 0.026g/m2/
24h;
In terms of above-mentioned the performance test results, " encapsulating film A " especially has more excellent mechanical performance.
Embodiment 2
A kind of electronic devices and components encapsulating film, is made up of the component of following weight percentages:
Ethylene-vinyl acetate copolymer 50%
Butadienyl triethoxysilicane 3%
Rosin resin 17%
Plant ash 5%
Illite 12%
Stearic acid 5%
Zeolite powder 5%
Fatty acid polyethylene glycol ester 3%
The preparation method of above-mentioned electronic devices and components encapsulating film is to comprise the following steps:
(1) weigh: weigh in described ratio;
(2) pulverize: plant ash is crushed to particle diameter and is less than 30 μm, illite is crushed to particle diameter less than 10 μm;
(3) frit reaction: by ethylene-vinyl acetate copolymer, silane coupler, rosin resin, plant ash, stearic acid and fat
Acid polyethylene glycol ester is mixed in described ratio, and 650r/min stirs 15min, is then heated to molten condition, and stirs at 195 DEG C
Mix 20min, be subsequently adding illite and the zeolite powder of described ratio, at 175 DEG C, react 20min, obtain sizing material;
(4) masking or coating: sizing material step (3) obtained, uses the techniques such as blowing to make the thin film that thickness is 10-100 μm,
Or use the mode of spraying, obtain " encapsulating film B " that thickness is 30-100 μm;
Performance test:
A, measuring mechanical property:
The hot strength at 30 DEG C after " encapsulating film B " (1*10cm) was processed with 200 DEG C × 1 hour as 56.6MPa,
Percentage elongation is 4.1%;
B, water resistance are tested:
The WVTR-9001 steam penetrating capacity analyzer using Jinan think of gram carries out steam penetrating capacity test, operates according to it
Handbook operates, follow-on test 10 times, averages, and the steam penetrating capacity of final " encapsulating film A " is 0.012g/m2/
24h;
In terms of above-mentioned the performance test results, " encapsulating film B " especially has the water resistance of excellence.
Claims (2)
1. an electronic devices and components encapsulating film, it is characterised in that be made up of the component of following weight percentages:
Ethylene-vinyl acetate copolymer 45-50%
Silane coupler 3-5%
Rosin resin 15-20%
Plant ash 2-5%
Illite 12-15%
Stearic acid 3-5%
Zeolite powder 2-5%
Fatty acid polyethylene glycol ester 1-3%;
Said components adds up to 100%.
Electronic devices and components encapsulating film the most according to claim 1, it is characterised in that described silane coupler is isobutyl group
Triethoxysilane.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610652148.2A CN106279941A (en) | 2016-06-18 | 2016-06-18 | The preparation method of electronic devices and components encapsulating film |
CN201610651620.0A CN106046529A (en) | 2016-06-18 | 2016-06-18 | Electronic component packaging film with high water resistance |
CN201610435288.4A CN105924760A (en) | 2016-06-18 | 2016-06-18 | Packaging film for electronic components |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610435288.4A CN105924760A (en) | 2016-06-18 | 2016-06-18 | Packaging film for electronic components |
Related Child Applications (2)
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CN201610652148.2A Division CN106279941A (en) | 2016-06-18 | 2016-06-18 | The preparation method of electronic devices and components encapsulating film |
CN201610651620.0A Division CN106046529A (en) | 2016-06-18 | 2016-06-18 | Electronic component packaging film with high water resistance |
Publications (1)
Publication Number | Publication Date |
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CN105924760A true CN105924760A (en) | 2016-09-07 |
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CN201610652148.2A Pending CN106279941A (en) | 2016-06-18 | 2016-06-18 | The preparation method of electronic devices and components encapsulating film |
CN201610651620.0A Pending CN106046529A (en) | 2016-06-18 | 2016-06-18 | Electronic component packaging film with high water resistance |
CN201610435288.4A Pending CN105924760A (en) | 2016-06-18 | 2016-06-18 | Packaging film for electronic components |
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CN201610652148.2A Pending CN106279941A (en) | 2016-06-18 | 2016-06-18 | The preparation method of electronic devices and components encapsulating film |
CN201610651620.0A Pending CN106046529A (en) | 2016-06-18 | 2016-06-18 | Electronic component packaging film with high water resistance |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107011570A (en) * | 2017-04-25 | 2017-08-04 | 柳州市乾阳机电设备有限公司 | Waterproofing membrane |
CN108117690A (en) * | 2017-12-31 | 2018-06-05 | 安徽普发照明有限公司 | A kind of diode package resin material for semi-conductor lighting lamp |
CN112920647A (en) * | 2021-04-06 | 2021-06-08 | 广州飞虹微电子有限公司 | Waterproof and anti-oxidation coating for electronic device and preparation method thereof |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109081996A (en) * | 2018-06-30 | 2018-12-25 | 蔡易霖 | One kind is for photovoltaic solar cell encapsulation polymer material, production method and packaging method |
CN114806459B (en) * | 2022-06-01 | 2023-09-01 | 云阳金田塑业有限公司 | Modified EVA hot melt adhesive suitable for glue-free film and preparation method thereof |
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CN105348625A (en) * | 2014-04-28 | 2016-02-24 | 赵月 | Preparation method of halogen-free low-smoke and flame retardant cable |
CN105419664A (en) * | 2015-12-23 | 2016-03-23 | 芜湖馨源海绵有限公司 | Hot melt adhesive membrane with high caking property |
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CN103865157A (en) * | 2014-03-31 | 2014-06-18 | 宋旭 | Water-absorbable composite environment-friendly stone paper and preparation method thereof |
CN105153474B (en) * | 2015-09-30 | 2017-10-24 | 北京化工大学 | A kind of stretchable type organic waste residues base degradable mulch and preparation method thereof |
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2016
- 2016-06-18 CN CN201610652148.2A patent/CN106279941A/en active Pending
- 2016-06-18 CN CN201610651620.0A patent/CN106046529A/en active Pending
- 2016-06-18 CN CN201610435288.4A patent/CN105924760A/en active Pending
Patent Citations (5)
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CN1467245A (en) * | 2002-07-08 | 2004-01-14 | 北京崇高纳米科技有限公司 | Fruit and vegetable fresh-keeping plastic film and method for making the same |
CN102115642A (en) * | 2010-12-31 | 2011-07-06 | 广州鹿山新材料股份有限公司 | EVA (ethylene vinyl-acetate copolymer) adhesive film capable of simplifying packaging structure of solar battery |
CN103725212A (en) * | 2013-12-14 | 2014-04-16 | 宁波华丰包装有限公司 | High transparency EVA (ethylene-vinyl acetate) encapsulation adhesive film and preparation method thereof |
CN105348625A (en) * | 2014-04-28 | 2016-02-24 | 赵月 | Preparation method of halogen-free low-smoke and flame retardant cable |
CN105419664A (en) * | 2015-12-23 | 2016-03-23 | 芜湖馨源海绵有限公司 | Hot melt adhesive membrane with high caking property |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107011570A (en) * | 2017-04-25 | 2017-08-04 | 柳州市乾阳机电设备有限公司 | Waterproofing membrane |
CN108117690A (en) * | 2017-12-31 | 2018-06-05 | 安徽普发照明有限公司 | A kind of diode package resin material for semi-conductor lighting lamp |
CN112920647A (en) * | 2021-04-06 | 2021-06-08 | 广州飞虹微电子有限公司 | Waterproof and anti-oxidation coating for electronic device and preparation method thereof |
CN112920647B (en) * | 2021-04-06 | 2022-08-12 | 广州飞虹微电子有限公司 | Waterproof and anti-oxidation coating for electronic device and preparation method thereof |
Also Published As
Publication number | Publication date |
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CN106279941A (en) | 2017-01-04 |
CN106046529A (en) | 2016-10-26 |
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