CN105419664A - Hot melt adhesive membrane with high caking property - Google Patents
Hot melt adhesive membrane with high caking property Download PDFInfo
- Publication number
- CN105419664A CN105419664A CN201510996706.2A CN201510996706A CN105419664A CN 105419664 A CN105419664 A CN 105419664A CN 201510996706 A CN201510996706 A CN 201510996706A CN 105419664 A CN105419664 A CN 105419664A
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- China
- Prior art keywords
- melt adhesive
- hot melt
- adhesive film
- parts
- agent
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C09J123/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/304—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C
Abstract
Belonging to the field of hot melt adhesive packaging materials, the invention relates to a hot-melt adhesive membrane with high caking property. The hot-melt adhesive membrane with high caking property is prepared from the following raw materials by weight: 80-120 parts of a film forming matter, 1-4 parts of a tackifier, 0.5-1 part of a viscosity regulator, 0.2-1.2 parts of an antioxidant, 0.6-1.2 parts of a plasticizer, 5-10 parts of a filler, and 0.3-0.8 part of a crosslinking agent. The hot-melt adhesive membrane with high caking property provided by the invention has a wide temperate zone, good thermal stability, low polarity, and excellent substrate caking property and firm adhesive force, can be used for structural adhesives with high strength requirements, also has outstanding light transmittance, peel strength and aging resistance, and long service life, and is also prominent in terms of green and environmental protection.
Description
Technical field
The present invention relates to a kind of hot melt adhesive film with high-adhesion, belong to hot melt adhesive packaged material field.
Background technology
Hot melt film adhesive is a kind of with separate-type paper or the film series products not with separate-type paper, can carry out easily continuously or periodical operation.Can the multiple material such as bonding metal, plastics, paper, wood, pottery, yarn fabric, in the bonding effect that also can obtain of unfairness body surface; Be mainly used in nameplate, plastics, handware bonding, being adhesively fixed of metal shell of electronic product, being adhesively fixed of stiffening plate, smart card, chip type passport laminate adhesive, handset viewing window frame and protecgulum bonding, camera battery groove bonding etc.The kind of hot melt adhesive film is a lot, and its characteristic such as viscosity, softening temperature of hot melt adhesive film that different material is made is also different.
Summary of the invention
The object of the invention is to the weak point solving the existence of above-mentioned prior art, a kind of environmental protection, the ageing-resistant hot melt adhesive film with high-adhesion are provided.
The present invention is achieved by the following technical solutions:
Have a hot melt adhesive film for high-adhesion, its special character is to be made up of following raw material by weight ratio: filmogen 80-120 part, tackifier 1-4 part, viscosity-controlling agent 0.5-1 part, antioxidant 0.2-1.2 part, softening agent 0.6-1.2 part, weighting agent 5-10 part, linking agent 0.3-0.8 part;
Described filmogen is that APAO (ethylene-propylene-butene-1 copolymer), Low Density Polyethylene and EVA (ethylene-vinyl acetate copolymer) mix;
Described tackifier are polymerized rosin;
Described viscosity-controlling agent is dimethyl silicone oil;
Described antioxidant is the mixture of 2,4 dimethyl 6 tert butyl phenol and 2,6 ditertiary butyl p cresol;
Described softening agent is the mixture of epoxy aliphatic acid methyl ester, bis(pentaerythritolester), tributyl citrate and clorafin;
Described weighting agent is the mixture of aluminum oxide powder, oxide powder and zinc and glass powder;
Described linking agent is N hydroxymethyl acrylamide;
Described a kind of hot melt adhesive film with high-adhesion, is made up of the raw material of following optimal proportion by weight: filmogen 100 parts, tackifier 3 parts, viscosity-controlling agent 0.8 part, antioxidant 1 part, 0.8 part, softening agent, weighting agent 7 parts, linking agent 0.5 part.
A kind of hot melt adhesive film with high-adhesion of the present invention, there is temperate zone widely, Heat stability is good, polarity are low, there is excellent ground cohesiveness, firmly cohesive force, can be used for the structure glue that requirement of strength is very high, and its transmittance, stripping strength, ageing-resistant performance are also very outstanding, long service life, and also more outstanding in environmental protection.
Embodiment
Below provide the specific embodiment of the present invention, be used for being described in further detail formation of the present invention.
Embodiment 1
A kind of hot melt adhesive film with high-adhesion of the present embodiment, is made up of following raw material by weight ratio: filmogen 80 parts, tackifier 1 part, viscosity-controlling agent 0.5 part, antioxidant 0.2 part, 0.6 part, softening agent, weighting agent 5 parts, linking agent 0.3 part;
Described filmogen is that APAO (ethylene-propylene-butene-1 copolymer), Low Density Polyethylene and EVA (ethylene-vinyl acetate copolymer) mix;
Described tackifier are polymerized rosin;
Described viscosity-controlling agent is dimethyl silicone oil;
Described antioxidant is the mixture of 2,4 dimethyl 6 tert butyl phenol and 2,6 ditertiary butyl p cresol;
Described softening agent is the mixture of epoxy aliphatic acid methyl ester, bis(pentaerythritolester), tributyl citrate and clorafin;
Described weighting agent is the mixture of aluminum oxide powder, oxide powder and zinc and glass powder;
Described linking agent is N hydroxymethyl acrylamide.
Embodiment 2
A kind of hot melt adhesive film with high-adhesion of the present embodiment, is made up of following raw material by weight ratio: filmogen 120 parts, tackifier 4 parts, viscosity-controlling agent 1 part, antioxidant 1.2 parts, 1.2 parts, softening agent, weighting agent 10 parts, linking agent 0.8 part.
Embodiment 3
A kind of hot melt adhesive film with high-adhesion of the present embodiment, is made up of the raw material of following optimal proportion by weight: filmogen 100 parts, tackifier 3 parts, viscosity-controlling agent 0.8 part, antioxidant 1 part, 0.8 part, softening agent, weighting agent 7 parts, linking agent 0.5 part.
The hot melt adhesive film that above embodiment a kind of has high-adhesion adopts following methods preparation: after namely in proportion each component being weighed through mixing, melting, mixing, roll prolong, trimming, rolling, packaging obtain.
A kind of hot melt adhesive film with high-adhesion of above embodiment, there is temperate zone widely, Heat stability is good, polarity are low, there is excellent ground cohesiveness, firmly cohesive force, can be used for the structure glue that requirement of strength is very high, and its transmittance, stripping strength, ageing-resistant performance are also very outstanding, long service life, and also more outstanding in environmental protection.
Claims (9)
1. there is a hot melt adhesive film for high-adhesion, it is characterized in that being made up of following raw material by weight ratio: become filmogen 80-120 part, increase tackifier 1-4 part, stick viscosity-controlling agent 0.5-1 part, antioxidant 0.2-1.2 part, softening agent 0.6-1.2 part, weighting agent 5-10 part, linking agent 0.3-0.8 part.
2. a kind of hot melt adhesive film with high-adhesion according to claim 1, is characterized in that described filmogen is that APAO (ethylene-propylene-butene-1 copolymer), Low Density Polyethylene and EVA (ethylene-vinyl acetate copolymer) mix.
3. a kind of hot melt adhesive film with high-adhesion according to claim 1, is characterized in that described tackifier are polymerized rosin.
4. a kind of hot melt adhesive film with high-adhesion according to claim 1, is characterized in that described viscosity-controlling agent is dimethyl silicone oil.
5. a kind of hot melt adhesive film with high-adhesion according to claim 1, is characterized in that described antioxidant is the mixture of 2,4 dimethyl 6 tert butyl phenol and 2,6 ditertiary butyl p cresol.
6. a kind of hot melt adhesive film with high-adhesion according to claim 1, is characterized in that described softening agent is the mixture of epoxy aliphatic acid methyl ester, bis(pentaerythritolester), tributyl citrate and clorafin.
7. a kind of hot melt adhesive film with high-adhesion according to claim 1, is characterized in that described weighting agent is the mixture of aluminum oxide powder, oxide powder and zinc and glass powder.
8. a kind of hot melt adhesive film with high-adhesion according to claim 1, is characterized in that described linking agent is N hydroxymethyl acrylamide.
9. a kind of hot melt adhesive film with high-adhesion according to claim 1, is characterized in that being made up of the raw material of following optimal proportion by weight: filmogen 100 parts, tackifier 3 parts, viscosity-controlling agent 0.8 part, antioxidant 1 part, 0.8 part, softening agent, weighting agent 7 parts, linking agent 0.5 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510996706.2A CN105419664A (en) | 2015-12-23 | 2015-12-23 | Hot melt adhesive membrane with high caking property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510996706.2A CN105419664A (en) | 2015-12-23 | 2015-12-23 | Hot melt adhesive membrane with high caking property |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105419664A true CN105419664A (en) | 2016-03-23 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510996706.2A Pending CN105419664A (en) | 2015-12-23 | 2015-12-23 | Hot melt adhesive membrane with high caking property |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105419664A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105924760A (en) * | 2016-06-18 | 2016-09-07 | 赵月 | Packaging film for electronic components |
| CN108395856A (en) * | 2018-03-29 | 2018-08-14 | 重庆渝茁科技有限公司 | Cover plate of spare tire of automobile PP cellular board materials |
| CN108728017A (en) * | 2018-05-07 | 2018-11-02 | 安徽盛美金属科技有限公司 | A kind of fabric hot melt adhesive and preparation method thereof |
| CN110484161A (en) * | 2019-09-16 | 2019-11-22 | 常州驰科光电科技有限公司 | It is a kind of for being bonded the hot melt adhesive film of ethylene propylene diene rubber |
| WO2021253611A1 (en) * | 2020-06-15 | 2021-12-23 | 杭州福斯特应用材料股份有限公司 | Adhesive film, composition for forming same and electronic device |
| EP4019601A4 (en) * | 2019-11-19 | 2023-12-13 | Hangzhou First Applied Material Co., Ltd. | Adhesive film, anti-pid encapsulation adhesive film, composition forming adhesive film, and photovoltaic module and laminated glass |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102993993A (en) * | 2011-09-15 | 2013-03-27 | 韩欲滋 | Hot melting adhesive film and manufacturing method thereof |
| CN103320055A (en) * | 2013-05-17 | 2013-09-25 | 温州大学 | High-insulation hot melt adhesive membrane |
| CN103756577A (en) * | 2013-12-31 | 2014-04-30 | 广州鹿山新材料股份有限公司 | PVC (polyvinyl chloride)/metal bonding hot melt adhesive film and preparation method thereof |
| CN104479572A (en) * | 2014-11-27 | 2015-04-01 | 祝根平 | Hot-melt adhesive film for fixing solder strip reflective films |
| CN104804659A (en) * | 2015-05-11 | 2015-07-29 | 上海天洋热熔粘接材料股份有限公司 | Hot melt rubber film for adhering metal and non-polar material and preparation method of hot melt rubber film |
-
2015
- 2015-12-23 CN CN201510996706.2A patent/CN105419664A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102993993A (en) * | 2011-09-15 | 2013-03-27 | 韩欲滋 | Hot melting adhesive film and manufacturing method thereof |
| CN103320055A (en) * | 2013-05-17 | 2013-09-25 | 温州大学 | High-insulation hot melt adhesive membrane |
| CN103756577A (en) * | 2013-12-31 | 2014-04-30 | 广州鹿山新材料股份有限公司 | PVC (polyvinyl chloride)/metal bonding hot melt adhesive film and preparation method thereof |
| CN104479572A (en) * | 2014-11-27 | 2015-04-01 | 祝根平 | Hot-melt adhesive film for fixing solder strip reflective films |
| CN104804659A (en) * | 2015-05-11 | 2015-07-29 | 上海天洋热熔粘接材料股份有限公司 | Hot melt rubber film for adhering metal and non-polar material and preparation method of hot melt rubber film |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105924760A (en) * | 2016-06-18 | 2016-09-07 | 赵月 | Packaging film for electronic components |
| CN106046529A (en) * | 2016-06-18 | 2016-10-26 | 赵月 | Electronic component packaging film with high water resistance |
| CN108395856A (en) * | 2018-03-29 | 2018-08-14 | 重庆渝茁科技有限公司 | Cover plate of spare tire of automobile PP cellular board materials |
| CN108728017A (en) * | 2018-05-07 | 2018-11-02 | 安徽盛美金属科技有限公司 | A kind of fabric hot melt adhesive and preparation method thereof |
| CN110484161A (en) * | 2019-09-16 | 2019-11-22 | 常州驰科光电科技有限公司 | It is a kind of for being bonded the hot melt adhesive film of ethylene propylene diene rubber |
| WO2021051980A1 (en) * | 2019-09-16 | 2021-03-25 | 常州驰科光电科技有限公司 | Hot melt adhesive film for bonding ethylene propylene diene monomer rubber |
| EP4019601A4 (en) * | 2019-11-19 | 2023-12-13 | Hangzhou First Applied Material Co., Ltd. | Adhesive film, anti-pid encapsulation adhesive film, composition forming adhesive film, and photovoltaic module and laminated glass |
| WO2021253611A1 (en) * | 2020-06-15 | 2021-12-23 | 杭州福斯特应用材料股份有限公司 | Adhesive film, composition for forming same and electronic device |
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Application publication date: 20160323 |