CN105924723A - Anti-freezing and anti-burst drinking water pipe and preparation method thereof - Google Patents

Anti-freezing and anti-burst drinking water pipe and preparation method thereof Download PDF

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Publication number
CN105924723A
CN105924723A CN201610334191.4A CN201610334191A CN105924723A CN 105924723 A CN105924723 A CN 105924723A CN 201610334191 A CN201610334191 A CN 201610334191A CN 105924723 A CN105924723 A CN 105924723A
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CN
China
Prior art keywords
water pipe
parts
fiber
resin
temperature
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610334191.4A
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Chinese (zh)
Inventor
梅家让
陈元龙
赵升
张波
周亚峰
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Laian Shaihua Pipe Industry Co Ltd
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Laian Shaihua Pipe Industry Co Ltd
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Priority to CN201610334191.4A priority Critical patent/CN105924723A/en
Publication of CN105924723A publication Critical patent/CN105924723A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Abstract

Anti-freezing and anti-burst drinking water pipe is characterized by being prepared from, by weight, 120 parts of PE resin, 1.5 parts of zinc stearate, 2 parts of vulcanizing agent, 0.1 part of low shrinkage agent, 0.1 part of anti-aging agent, 0.1 part of stabilizer, 0.1 part of antioxidant, 5 parts of nano-silica, 0.2 part of ultra-fine barium, 0.6 part of calcined chromium calcium pomegranate powder, 5 parts of anti-cracking fiber material, 0.5 part of glass fiber, 0.2 part of sepiolite fabric, 0.1 part of shell powder, 0.5 part of boron fiber and 2 parts of hybrid fiber resin. The anti-cracking fiber material, the glass fiber, the sepiolite fabric, the shell powder, the boron fiber and the hybrid fiber resin are added to a water pipe material, the crack resistance and toughness of the water pipe material can be remarkably improved, and a water pipe blowout phenomenon caused by low temperature is decreased.

Description

Drinking-water pipe and preparation method thereof is split in a kind of antifreeze antiknock
Technical field
The present invention relates to drinking-water pipe technical field, be specifically related to a kind of antifreeze antiknock split drinking-water pipe and Preparation method.
Background technology
Along with popularizing of tap water, running water pipe has become as the requisite water supply line in rural area and city. Water supply line and faucet are directly connected at present, have occluded water after closing faucet in water pipe, this part Water was easy to freeze in winter, blocked pipeline, even by water pipe from freezing crack, caused user to supply water interruption.
Summary of the invention
The technical problem to be solved is to provide a kind of stable performance, service life length antifreeze Drinking-water pipe is split in antiknock.
The technical problem to be solved realizes by the following technical solutions:
Drinking-water pipe is split in a kind of antifreeze antiknock, is made up of the component of following weight: PE resin 120 parts, tristearin Acid 1.5 parts of zinc, vulcanizing agent 2 parts, shrinking agent 0.1 part, 0.1 part of age resistor, stabilizer 0.1 part, antioxygen Agent 0.1 part, nano silicon 5 parts, ultra-fine barium 0.2 part, 0.6 part of trautwinite powder of calcining, anticracking fibre Tie up 5 parts of material, glass fibre 0.5 part, sepiolite cashmere 0.2 part, conch meal 0.1 part, boron fibre 0.5 part, mix Condensating fiber resin 2 parts;
The preparation method of above-mentioned anticracking fiber material is as follows:
(1) by cotton fiber low-temperature bake 2-3 hour under 40-70 DEG C of environment, the activity of cotton fiber is improved, It is easy to subsequent treatment, also is able to play bactericidal action simultaneously;
(2) room temperature state is down in the cotton fiber taking-up after baking in step (2), is then fed into low temperature In freezing equipment freezing 2-3 time, each cooling time 1-3 hour, cryogenic temperature between-5-0 DEG C, in Between be spaced 6 hours, improve the performance of fiber with this, chilled after fiber not easy fracture;
(4) cotton fiber completed freezing in step (3) is placed in drying equipment at a temperature of 65-72 DEG C It is dried 10-20 minute, sends in smelting furnace and carry out melting, reach molten condition, then filter, remove inorganic Impurity, obtains pelletize semi-finished stock;
(5) pelletize semi-finished stock feeding comminutor is carried out pelletize, obtain graininess anticracking fiber material.
Above-mentioned composite fibre resin is by carbon fiber, epoxy resin, linear polyethylene, expanded graphite and to consolidate Agent is made by the weight ratio of 1:3:2:0.2:0.1 is mixing.
The preparation method that drinking-water pipe is split in above-mentioned antifreeze antiknock is as follows:
(1) first in PE resin add zinc stearate, nano silicon, calcining trautwinite powder, Sepiolite cashmere, conch meal and ultra-fine barium are the most mixing in kneader, and 170 DEG C of heat mix 2 hours;
(2), when the material after heat is mixed in step (1) is cooled to below 60 DEG C, leftover materials are added, On twin-screw extruder mixing uniformly, be made into mixing materials;
(3) mixing materials in step (2) is melted through granulator heating, be expressed into mould molding, To semi-finished product water pipe;
(4) carry out the semi-finished product water pipe in step (3) humidifying cured, obtain product water tube; Wherein solidification adds wet process and includes following three phases:
First stage: control in curing room positive plate solidification temperature at 60 DEG C, relative humidity 100%, Gu The change time controlled at 5 hours;
Second stage: control in curing room positive plate solidification temperature at 85 DEG C, relative humidity 100%, Gu The change time controlled at 24 hours;
Phase III: in controlling curing room, positive plate solidification temperature is at 60 DEG C, relative humidity, 80%, solidifies Time controlled at 5 hours.By humidification cured so that the water pipe mechanical strength of preparation strengthens, toughness Good, not easy fracture, service life is long.
By anticracking fiber material, glass fibre, sepiolite cashmere, conch meal, boron fibre and composite fibre resin Join in supplying pipe, it is possible to significantly improve the crack resistance of supplying pipe, toughness, reduce water pipe because of low The Decrepitation Phenomena that temperature causes.
The invention has the beneficial effects as follows: drinking-water pipe prepared by the present invention have antifreeze, antiknock is split, heat-resisting, The performances such as resistant to chemical media corrosion, inner and outer walls of pipeline is smooth, not scaling.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
Drinking-water pipe is split in a kind of antifreeze antiknock, is made up of the component of following weight: PE resin 120 parts, tristearin Acid 1.5 parts of zinc, vulcanizing agent 2 parts, shrinking agent 0.1 part, 0.1 part of age resistor, stabilizer 0.1 part, antioxygen Agent 0.1 part, nano silicon 5 parts, ultra-fine barium 0.2 part, 0.6 part of trautwinite powder of calcining, anticracking fibre Tie up 5 parts of material, glass fibre 0.5 part, sepiolite cashmere 0.2 part, conch meal 0.1 part, boron fibre 0.5 part, mix Condensating fiber resin 2 parts;
The preparation method of above-mentioned anticracking fiber material is as follows:
(1) by cotton fiber low-temperature bake 2-3 hour under 40-70 DEG C of environment, the activity of cotton fiber is improved, It is easy to subsequent treatment, also is able to play bactericidal action simultaneously;
(2) room temperature state is down in the cotton fiber taking-up after baking in step (2), is then fed into low temperature In freezing equipment freezing 2-3 time, each cooling time 1-3 hour, cryogenic temperature between-5-0 DEG C, in Between be spaced 6 hours, improve the performance of fiber with this, chilled after fiber not easy fracture;
(4) cotton fiber completed freezing in step (3) is placed in drying equipment at a temperature of 65-72 DEG C It is dried 10-20 minute, sends in smelting furnace and carry out melting, reach molten condition, then filter, remove inorganic Impurity, obtains pelletize semi-finished stock;
(5) pelletize semi-finished stock feeding comminutor is carried out pelletize, obtain graininess anticracking fiber material.
Above-mentioned composite fibre resin is by carbon fiber, epoxy resin, linear polyethylene, expanded graphite and to consolidate Agent is made by the weight ratio of 1:3:2:0.2:0.1 is mixing.
The preparation method that drinking-water pipe is split in above-mentioned antifreeze antiknock is as follows:
(1) first in PE resin add zinc stearate, nano silicon, calcining trautwinite powder, Sepiolite cashmere, conch meal and ultra-fine barium are the most mixing in kneader, and 170 DEG C of heat mix 2 hours;
(2), when the material after heat is mixed in step (1) is cooled to below 60 DEG C, leftover materials are added, On twin-screw extruder mixing uniformly, be made into mixing materials;
(3) mixing materials in step (2) is melted through granulator heating, be expressed into mould molding, To semi-finished product water pipe;
(4) carry out the semi-finished product water pipe in step (3) humidifying cured, obtain product water tube; Wherein solidification adds wet process and includes following three phases:
First stage: control in curing room positive plate solidification temperature at 60 DEG C, relative humidity 100%, Gu The change time controlled at 5 hours;
Second stage: control in curing room positive plate solidification temperature at 85 DEG C, relative humidity 100%, Gu The change time controlled at 24 hours;
Phase III: in controlling curing room, positive plate solidification temperature is at 60 DEG C, relative humidity, 80%, solidifies Time controlled at 5 hours.By humidification cured so that the water pipe mechanical strength of preparation strengthens, toughness Good, not easy fracture, service life is long.
By anticracking fiber material, glass fibre, sepiolite cashmere, conch meal, boron fibre and composite fibre resin Join in supplying pipe, it is possible to significantly improve the crack resistance of supplying pipe, toughness, reduce water pipe because of low The Decrepitation Phenomena that temperature causes.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention, The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model In enclosing.Claimed scope is defined by appending claims and equivalent thereof.

Claims (3)

1. drinking-water pipe is split in an antifreeze antiknock, it is characterised in that be made up of the component of following weight: PE Resin 120 parts, zinc stearate 1.5 parts, vulcanizing agent 2 parts, shrinking agent 0.1 part, 0.1 part of age resistor, steady Determine agent 0.1 part, 0.1 part of antioxidant, nano silicon 5 parts, ultra-fine barium 0.2 part, calcining trautwinite 0.6 part of powder, 5 parts of anticracking fiber material, glass fibre 0.5 part, sepiolite cashmere 0.2 part, conch meal 0.1 part, Boron fibre 0.5 part, composite fibre resin 2 parts;
The preparation method of above-mentioned anticracking fiber material is as follows:
(1) by cotton fiber low-temperature bake 2-3 hour under 40-70 DEG C of environment;
(2) room temperature state is down in the cotton fiber taking-up after baking in step (2), is then fed into low temperature In freezing equipment freezing 2-3 time, each cooling time 1-3 hour, cryogenic temperature between-5-0 DEG C, in Between be spaced 6 hours;
(4) cotton fiber completed freezing in step (3) is placed in drying equipment at a temperature of 65-72 DEG C It is dried 10-20 minute, sends in smelting furnace and carry out melting, reach molten condition, then filter, remove inorganic Impurity, obtains pelletize semi-finished stock;
(5) pelletize semi-finished stock feeding comminutor is carried out pelletize, obtain graininess anticracking fiber material.
Drinking-water pipe is split in the antifreeze antiknock of one the most according to claim 1, it is characterised in that above-mentioned Composite fibre resin be by carbon fiber, epoxy resin, linear polyethylene, expanded graphite and firming agent by The weight ratio of 1:3:2:0.2:0.1 is mixing to be made.
3. prepare the method that drinking-water pipe is split in antifreeze antiknock described in claim 1 or 2 for one kind, it is characterised in that Specifically comprise the following steps that
(1) first in PE resin add zinc stearate, nano silicon, calcining trautwinite powder, Sepiolite cashmere, conch meal and ultra-fine barium are the most mixing in kneader, and 170 DEG C of heat mix 2 hours;
(2), when the material after heat is mixed in step (1) is cooled to below 60 DEG C, leftover materials are added, On twin-screw extruder mixing uniformly, be made into mixing materials;
(3) mixing materials in step (2) is melted through granulator heating, be expressed into mould molding, To semi-finished product water pipe;
(4) carry out the semi-finished product water pipe in step (3) humidifying cured, obtain product water tube; Wherein solidification adds wet process and includes following three phases:
First stage: control in curing room positive plate solidification temperature at 60 DEG C, relative humidity 100%, Gu The change time controlled at 5 hours;
Second stage: control in curing room positive plate solidification temperature at 85 DEG C, relative humidity 100%, Gu The change time controlled at 24 hours;
Phase III: in controlling curing room, positive plate solidification temperature is at 60 DEG C, relative humidity, 80%, solidifies Time controlled at 5 hours.
CN201610334191.4A 2016-05-18 2016-05-18 Anti-freezing and anti-burst drinking water pipe and preparation method thereof Pending CN105924723A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610334191.4A CN105924723A (en) 2016-05-18 2016-05-18 Anti-freezing and anti-burst drinking water pipe and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201610334191.4A CN105924723A (en) 2016-05-18 2016-05-18 Anti-freezing and anti-burst drinking water pipe and preparation method thereof

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Publication Number Publication Date
CN105924723A true CN105924723A (en) 2016-09-07

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103467809A (en) * 2013-08-16 2013-12-25 安徽省振云塑胶有限公司 High impact resistant PE water supply pipe
CN103467808A (en) * 2013-08-16 2013-12-25 安徽省振云塑胶有限公司 Heat-resistant stable PE water supply pipe
CN103467833A (en) * 2013-08-16 2013-12-25 安徽省振云塑胶有限公司 Trenchless dedicated PE water supply pipe
CN103601943A (en) * 2013-08-16 2014-02-26 安徽省振云塑胶有限公司 Water supply pipe made of cross-linked PE
CN103694534A (en) * 2013-12-05 2014-04-02 江苏金波新材料科技有限公司 Pressure-tolerant polyethylene tubular product and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103467809A (en) * 2013-08-16 2013-12-25 安徽省振云塑胶有限公司 High impact resistant PE water supply pipe
CN103467808A (en) * 2013-08-16 2013-12-25 安徽省振云塑胶有限公司 Heat-resistant stable PE water supply pipe
CN103467833A (en) * 2013-08-16 2013-12-25 安徽省振云塑胶有限公司 Trenchless dedicated PE water supply pipe
CN103601943A (en) * 2013-08-16 2014-02-26 安徽省振云塑胶有限公司 Water supply pipe made of cross-linked PE
CN103694534A (en) * 2013-12-05 2014-04-02 江苏金波新材料科技有限公司 Pressure-tolerant polyethylene tubular product and preparation method thereof

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Application publication date: 20160907