CN105924226B - A kind of anti-corrosion reinforced concrete sleeper and preparation method thereof - Google Patents

A kind of anti-corrosion reinforced concrete sleeper and preparation method thereof Download PDF

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Publication number
CN105924226B
CN105924226B CN201610264026.6A CN201610264026A CN105924226B CN 105924226 B CN105924226 B CN 105924226B CN 201610264026 A CN201610264026 A CN 201610264026A CN 105924226 B CN105924226 B CN 105924226B
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CN
China
Prior art keywords
sleeper
epoxy resin
concrete sleeper
reinforced concrete
resin mortar
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CN201610264026.6A
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Chinese (zh)
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CN105924226A (en
Inventor
丁江民
丁尉哲
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Dalian Jiaotong University
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Dalian Jiaotong University
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Priority to CN201610264026.6A priority Critical patent/CN105924226B/en
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Expired - Fee Related legal-status Critical Current
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/62Coating or impregnation with organic materials
    • C04B41/63Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5024Silicates
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01BPERMANENT WAY; PERMANENT-WAY TOOLS; MACHINES FOR MAKING RAILWAYS OF ALL KINDS
    • E01B3/00Transverse or longitudinal sleepers; Other means resting directly on the ballastway for supporting rails
    • E01B3/28Transverse or longitudinal sleepers; Other means resting directly on the ballastway for supporting rails made from concrete or from natural or artificial stone
    • E01B3/32Transverse or longitudinal sleepers; Other means resting directly on the ballastway for supporting rails made from concrete or from natural or artificial stone with armouring or reinforcement

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Bridges Or Land Bridges (AREA)

Abstract

The invention discloses a kind of anti-corrosion reinforced concrete sleeper, it is characterised in that:The reinforced concrete sleeper surface uniformly sets one layer of anticorrosive coat, and the anticorrosive coat is the epoxy resin mortar after solidification.The invention also discloses the preparation method of the anti-corrosion reinforced concrete sleeper, according to country《The quality standard of concrete sleeper and requirement》The reinforced concrete sleeper of traditional form is manufactured, its exterior surface dimension is to inside contracting 1mm;Epoxy resin mortar is configured to after each component material for preparing anticorrosive coat is mixed according to weight proportion;By epoxy resin mortar even application to sleeper surface, skin depth is 1mm 1.2mm, solidification timeliness 12 hours.The present invention is using a kind of organic composite material with higher densification and intensity, conventional steel bar concrete sleeper surface is combined to, makes sleeper surface from the corrosion of all erosion media, increases the service life of sleeper, extend the cycle for changing sleeper, effectively reduce the maintenance cost of sleeper.

Description

A kind of anti-corrosion reinforced concrete sleeper and preparation method thereof
Technical field
The present invention relates to technical field of rail traffic, gives sleeper surface recombination one layer of anti-corrosion material, solves traditional reinforcing bar and mix Coagulate native sleeper because surface corrosion cause sleeper to destroy the problem of, specifically a kind of reinforced concrete sleeper of anti-corrosion and its preparation Method.
Background technology
At present, it is all reinforced concrete sleeper that the track traffic sleeper in China is most of.The architectural characteristic of concrete is one The structural material of kind of non-homogeneity, it is to belong to porous body from microstructure, is had inside it many of different sizes fine Hole, the medium of all erosions can carry out corrosion concrete by these holes and crack.It is as armored concrete rail The main material of pillow, when sleeper surface exposure in adverse circumstances easily by aqueous corrosion, acid corrosion, caustic corrosion, and then in dynamic load The lower cracking of lotus effect, which is further permeated inside it, makes reinforcement corrosion, causes sleeper to destroy.
The content of the invention
According to technical problem set forth above, and provide a kind of anti-corrosion reinforced concrete sleeper and preparation method thereof.This hair It is bright using a kind of organic composite material with higher densification and intensity, be combined to conventional steel bar concrete sleeper table Face, make sleeper surface from the corrosion of all erosion media, increase the service life of sleeper, extend the cycle for changing sleeper, Effectively reduce the maintenance cost of sleeper.
The technological means that the present invention uses is as follows:
A kind of anti-corrosion reinforced concrete sleeper, it is characterised in that:The reinforced concrete sleeper surface uniformly sets one Layer anticorrosive coat, the anticorrosive coat are the epoxy resin mortar after solidification.
Further, the epoxy resin mortar includes the following each component of weight proportion:
The cementing agent is epoxy resin, and the curing agent is ethylenediamine, and the toughener is dibutyl phthalate, The diluent is acetone, and the aggregate is the fine sand that particle diameter is less than 0.5mm.
Further, the reinforced concrete sleeper is according to country《The quality standard of concrete sleeper and requirement》Manufacture , its exterior surface dimension is to inside contracting 1mm.
Further, the thickness of the anticorrosive coat is 1mm-1.2mm.
The invention also discloses a kind of preparation method of above-mentioned anti-corrosion reinforced concrete sleeper, it is characterised in that:Including Following steps:
S1, according to country《The quality standard of concrete sleeper and requirement》The reinforced concrete sleeper of traditional form is manufactured, Its exterior surface dimension is to inside contracting 1mm;After treating the above-mentioned sleeper timeliness phase, by the clean rear neat spaced horizontal pendulum of its removing surface Put;
S2, it is configured to epoxy resin mortar after each component material for preparing anticorrosive coat is mixed according to weight proportion;
S3, by epoxy resin mortar even application to sleeper surface, skin depth 1mm-1.2mm, solidification timeliness 12 is small When.
Further, the epoxy resin mortar is the asphalt mixtures modified by epoxy resin for first putting preset weight in mixer at 20 ± 1 DEG C Fat, the diluent and toughener of default proportioning are then added, add the fine sand and flyash of default proportioning, the uniform 3- of stirring at low speed 4min;The ethylenediamine for adding preset ratio is sufficiently stirred 4-6min, and the epoxy resin mortar finally prepared is used in 50min It is complete.
Further, the fine sand and the flyash are drying regime, and the fine sand particle diameter is less than 0.5mm.
The present invention is used as cementing agent using epoxy resin, and epoxy resin is as a kind of organic matter, containing largely in its molecule Polar hydroxyl groups and ehter bond, there is very high cohesive force to various materials, reacted with curing agent, produce hydrogen bond association, Its cure shrinkage is very low, has very strong cohesive force, and the epoxy main chains after solidification are ehter bond and phenyl ring, three-dimensional crosslinking knot Structure is fine and close to be closed again, therefore has excellent alkali resistance, acid resistance and solvent resistance.In epoxy resin mortar, epoxy resin is made Pass through spraying into mortar by aggregate and flyash are Nian Jie after being chemically reacted for cementing agent with curing agent, toughener, diluent Conventional steel bar concrete sleeper surface is combined to, forms effective anticorrosive coat, makes sleeper surface from the corruption of all erosion media Erosion.
The reinforced concrete sleeper after composite epoxy resin screed of the present invention has compared to raw steel reinforced concrete sleeper Following advantage:Sleeper surface strength hardness is significantly improved without cracky;Water can not be inside surface penetration sleeper;General concentration Soda acid can not permeating corrosion sleeper;Reinforcing bar inside sleeper is not perishable;Sleeper face crack significantly reduces.
Present invention can apply to all moist and acid-base value contents, reinforcing bar that is larger and easily being used by corrosive environment mixes The design and manufacture of native sleeper are coagulated, such as:The interior railroad sleeper of extractive industry mine, annual rainfall larger area railroad sleeper, northwest Acid-base value larger area railroad sleeper etc..
Embodiment
The present invention is combined to traditional reinforcing bar and mixed using a kind of organic composite material with higher densification and intensity Native sleeper surface is coagulated, makes sleeper surface from the corrosion of all erosion media, the service life of sleeper can be increased, extend and change In the cycle of sleeper, effectively reduce the maintenance cost of sleeper.
A kind of anti-corrosion reinforced concrete sleeper, the reinforced concrete sleeper surface uniformly set one layer of anticorrosive coat, institute Anticorrosive coat is stated as the epoxy resin mortar after solidification.The reinforced concrete sleeper is according to country《The quality of concrete sleeper Standard and requirement》The reinforced concrete sleeper of the traditional type of manufacture, its exterior surface dimension is to inside contracting 1mm.It is uniform on sleeper surface Spray the anticorrosive coat that a layer thickness is 1mm-1.2mm.
The epoxy resin mortar includes the following each component of weight proportion:
The cementing agent is epoxy resin, and the curing agent is ethylenediamine, and the toughener is dibutyl phthalate, The diluent is acetone, and the aggregate is the fine sand that particle diameter is less than 0.5mm.
The invention also discloses a kind of preparation method of above-mentioned anti-corrosion reinforced concrete sleeper, comprise the following steps:
S1, according to country《The quality standard of concrete sleeper and requirement》The reinforced concrete sleeper of traditional form is manufactured, Its exterior surface dimension is to inside contracting 1mm;It is after treating the above-mentioned sleeper timeliness phase (the timeliness phase is generally 28 days), its removing surface is clean Neat spaced horizontal is put afterwards;
S2, it is configured to epoxy resin mortar after each component material for preparing anticorrosive coat is mixed according to weight proportion;It is described Epoxy resin mortar is the epoxy resin for first putting preset weight in mixer at 20 ± 1 DEG C, then adds default proportioning Diluent and toughener, the fine sand and flyash of default proportioning are added, the uniform 3-4min of stirring at low speed, is stirred using low speed is high-power Mix machine (15-20rpm) stirring;The fine sand and the flyash are drying regime, and the fine sand particle diameter is less than 0.5mm.Again plus The ethylenediamine for entering preset ratio is sufficiently stirred 4-6min, and the epoxy resin mortar finally prepared is finished in 50min.
S3, by epoxy resin mortar even application to sleeper surface, skin depth 1mm-1.2mm, solidification timeliness 12 is small When.
Embodiment 1
III type concrete sleeper
Epoxy resin mortar includes the following each component of weight proportion:
Preparation process is as follows:
S1, according to country《The quality standard of concrete sleeper and requirement》The reinforced concrete sleeper of traditional form is manufactured, Its exterior surface dimension is to inside contracting 1mm;It is after 28 days timeliness phases, its removing surface is clean;
S2, at 20 ± 1 DEG C of room temperature each component material for preparing anticorrosive coat weighed according to weight proportion stand-by, first stirred The epoxy resin that preset weight is put in machine is mixed, then adds the diluent and toughener of default proportioning, adds the thin of default proportioning Sand and flyash, stirring at low speed 4min, reach uniform, mixer is JJ-5 type cement mortar mixers;The fine sand and described Flyash must pass through drying, and the ethylenediamine for adding preset ratio is sufficiently stirred 5min, completes the preparation of epoxy resin mortar.
S3, by epoxy resin mortar even application to sleeper surface, skin depth 1mm-1.2mm, solidification timeliness 12 is small When, finished product is made.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (6)

  1. A kind of 1. anti-corrosion reinforced concrete sleeper, it is characterised in that:The reinforced concrete sleeper surface uniformly sets one layer Anticorrosive coat, the anticorrosive coat are the epoxy resin mortar after solidification;
    The epoxy resin mortar includes the following each component of weight proportion:
    The cementing agent is epoxy resin, and the curing agent is ethylenediamine, and the toughener is dibutyl phthalate, described Diluent is acetone, and the aggregate is the fine sand that particle diameter is less than 0.5mm.
  2. 2. anti-corrosion reinforced concrete sleeper according to claim 1, it is characterised in that:The reinforced concrete sleeper be by According to country《The quality standard of concrete sleeper and requirement》Manufacture, its exterior surface dimension is to inside contracting 1mm.
  3. 3. anti-corrosion reinforced concrete sleeper according to claim 1, it is characterised in that:The thickness of the anticorrosive coat is 1mm- 1.2mm。
  4. A kind of 4. preparation method of the anti-corrosion reinforced concrete sleeper described in claim 1-3 any one, it is characterised in that:Bag Include following steps:
    S1, according to country《The quality standard of concrete sleeper and requirement》The reinforced concrete sleeper of traditional form is manufactured, outside it Surface size is to inside contracting 1mm;After treating the above-mentioned sleeper timeliness phase, the clean rear neat spaced horizontal of its removing surface is put;
    S2, it is configured to epoxy resin mortar after each component material for preparing anticorrosive coat is mixed according to weight proportion;
    S3, by epoxy resin mortar even application to sleeper surface, skin depth 1mm-1.2mm, solidification timeliness 12 hours.
  5. 5. preparation method according to claim 4, it is characterised in that:The epoxy resin mortar is at 20 ± 1 DEG C, first The epoxy resin of preset weight is put in mixer, then adds the diluent and toughener of default proportioning, adds default proportioning Fine sand and flyash, the uniform 3-4min of stirring at low speed;The ethylenediamine for adding preset ratio is sufficiently stirred 4-6min, finally matches somebody with somebody The epoxy resin mortar made is finished in 50min.
  6. 6. preparation method according to claim 5, it is characterised in that:The fine sand and the flyash are drying regime, The fine sand particle diameter is less than 0.5mm.
CN201610264026.6A 2016-04-26 2016-04-26 A kind of anti-corrosion reinforced concrete sleeper and preparation method thereof Expired - Fee Related CN105924226B (en)

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112897935B (en) * 2021-01-30 2022-06-21 威海瑞合铁路轨枕有限公司 Resin concrete sleeper
CN113800828B (en) * 2021-09-03 2023-03-24 山东省冶金产品质量监督检验站有限公司 Microcapsule technology-based reinforcement anticorrosion system for concrete

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB785758A (en) * 1954-07-08 1957-11-06 Dow Mac Products Ltd A new or improved process for improving the electrical resistivity of concrete sleepers
CN101913192A (en) * 2010-08-03 2010-12-15 大连交通大学 Concrete machine tool body structure and manufacturing method thereof
CN102605683A (en) * 2012-04-01 2012-07-25 中国铁道科学研究院铁道建筑研究所 Integral insulation concrete track plate and preparation technology thereof
CN103189569A (en) * 2010-08-11 2013-07-03 福斯罗·科吉富有限公司 Sleeper made of composite material and used for track and switching gear

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB785758A (en) * 1954-07-08 1957-11-06 Dow Mac Products Ltd A new or improved process for improving the electrical resistivity of concrete sleepers
CN101913192A (en) * 2010-08-03 2010-12-15 大连交通大学 Concrete machine tool body structure and manufacturing method thereof
CN103189569A (en) * 2010-08-11 2013-07-03 福斯罗·科吉富有限公司 Sleeper made of composite material and used for track and switching gear
CN102605683A (en) * 2012-04-01 2012-07-25 中国铁道科学研究院铁道建筑研究所 Integral insulation concrete track plate and preparation technology thereof

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