CN105923686A - Sewage treatment material and preparing method thereof - Google Patents
Sewage treatment material and preparing method thereof Download PDFInfo
- Publication number
- CN105923686A CN105923686A CN201610320012.1A CN201610320012A CN105923686A CN 105923686 A CN105923686 A CN 105923686A CN 201610320012 A CN201610320012 A CN 201610320012A CN 105923686 A CN105923686 A CN 105923686A
- Authority
- CN
- China
- Prior art keywords
- sewage treating
- treating material
- ceramic balls
- sewage treatment
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
Abstract
The invention discloses a sewage treatment material, and relates to the field of water pollution control engineering. The sewage treatment material is prepared from, by weight, 13-16% of ceramic balls, 6-10% of sodium alkyl epoxy carboxylate, 10-16% of cationic flocculant, 5-8% of aluminum ammonium sulfate, 8-12% of polyferric sulfate, 1-2% of starch, 2-6% of activated carbon, 9-12% of acrylic acid-acrylate-sulfonate terpolymer, 6-8% of sodium lauroyl sarcosinate, 80-90 parts of flyash and 10-20% of porous kieselguhr. The invention further discloses a preparing method of the sewage treatment material. The preparing method includes the steps of manufacturing the ceramic balls and mixing. The sewage treatment material prepared through the method is capable of fast removing particulate matter, heavy metal, organic matter, impurities and the like in sewage, high in adsorption capacity and biodegradability, capable of avoiding eutrophication of a water body and emission secondary pollution and capable of substantially improving sewage treatment efficiency and treatment quality.
Description
Technical field
The present invention relates to water pollution control engineering field, be specifically related to a kind of sewage treating material and
A kind of preparation method of sewage treating material.
Background technology
For a long time, even developed country of developing country, municipal refuse, lead-acid accumulator system
Make, heavy metal ore deposit is exploited, radioactivity heavy metal ore deposit is exploited and processing, nuclear pollution discharge of wastewater,
Heavy metal smelting, thermal power generation, electroplating industry, coal mining company, discarded electricity-saving lamp reclaim
Process, heavy metallic pigment and printing, old and useless battery and Waste ammunition returned enterprise and industry
The discharge of the sewage disposal containing heavy metal that sewage treatment plant and city domestic sewage treatment plant produce,
Mud discharging, heavy metal can not effectively be administered recovery immobilization major part and be can not get
Rationally disposal and utilization, many employing compressions fill, topple over or contain the organic sludge mummification of heavy metal
Burning mode, the landfill of sludge containing heavy metal and arbitrarily toppling over, occupy a large amount of valuable soil
Resource defines huge heavy metal secondary pollution source;Thermal power plant fire coal burns generation
Lead, arsenic, cadmium, mercury emissions severe overweight, a lot of local city rural soils, irrigation canals and ditches, river
Stream, ocean are polluted in various degree.
Existing industry, municipal wastewater processing method have physical treatment process, method of chemical treatment and life
Thing facture.Wherein chemical treatment method is to process pollutant with inorganic agent, but treatment effeciency is relatively
Low, it is difficult to reach discharge standard.
Summary of the invention
Problem to be solved by this invention is to provide a kind of particulate matter that can quickly remove in water
And the sewage treating material of heavy metal, Organic substance, impurity etc. and preparation method thereof.
To achieve these goals, the technical scheme that the present invention takes by: provided is a kind of dirty
Material for water treatment, the percentage by weight of the chemical composition of described sewage treating material includes Ceramic Balls
13-16%, alkyl epoxy carboxylic acid sodium 6-10%, cationic flocculant 10-16%, Burnt ammonium alum
5-8%, bodied ferric sulfate 8-12%, starch 1-2%, activated carbon 2-6%, acrylic acid-acrylic
Acid esters-sulfonate terpolymer 9-12%, sodium N-lauroyl sarcosinate 6-8%, flyash
80-90%, porous silicon diatomaceous earth 10-20%.
Preferably, the percentage by weight of the chemical composition of described sewage treating material includes Ceramic Balls
14%, alkyl epoxy carboxylic acid sodium 8%, cationic flocculant 11%, Burnt ammonium alum 7%, polymerization
Iron sulfate 8%, starch 2%, activated carbon 3%, acrylic acid-acrylic ester-sulfonate ternary is altogether
Polymers 9%, sodium N-lauroyl sarcosinate 6%.
The preparation method of a kind of sewage treating material, described preparation technology enters according to following steps
OK,
(1) Ceramic Balls is made: by Maifanitum 25%, hexacyclic ring stone 18%, tourmaline 25%, glue
The compositions such as soil 13%, kieselguhr 13%, zeolite 6%.By crushing material to 325 mesh fine powders,
Take powder precisely to allocate by corresponding proportion, after making mother bulb, mother bulb put in bowling machine,
Making ball, ball drying enters kiln, calcines 12-20 hour with oxidizing flame, after cooling
Go out kiln.
(2) mixing: by alkyl epoxy carboxylic acid sodium 8%, cationic flocculant 12%, aluminum sulfate
Ammonium 6%, bodied ferric sulfate 8-12%, starch 2%, activated carbon 3%, acrylic acid-acrylic ester
-sulfonate terpolymer 10%, sodium N-lauroyl sarcosinate 7% mixes, and remaining is water, so
After by step (1) prepare Ceramic Balls at room temperature place 24h weigh after put into wherein.
Preferably, in described step (1), the temperature of oxidizing flame is 1000-1050 DEG C.
Preferably, in described step (1), the temperature of kiln is 800-850 DEG C.
Preferably, bowling machine model used in described step (2) is BY-300 bowling machine.
Use technical scheme, use the processing technology of Ceramic Balls, preparation to have inside
Aperture passage keeps aperture frame structure and the molecular sieve function of original mineral material, and specific surface area is big,
The Ceramic Balls that absorption affinity is strong, by optimizing the weight of the chemical composition of sewage treating material in this method
Amount percentage ratio, each technological parameter in strict control preparation process so that at the sewage prepared
Reason excellent material performance, sewage treating material of the present invention can quickly remove in water
Grain thing and heavy metal, and there is biological degradability, it is possible to avoid eutrophication and the row of water body
Put secondary pollution, it is possible to increase sewage treating efficiency and process quality.
Detailed description of the invention
Embodiment 1:
A kind of sewage treating material and preparation method thereof, the chemical composition of described sewage treating material
Percentage by weight include Ceramic Balls 14%, alkyl epoxy carboxylic acid sodium 8%, cationic flocculant
12%, Burnt ammonium alum 6%, bodied ferric sulfate 8%, starch 2%, activated carbon 3%, acrylic acid
-acrylate-sulfonate terpolymer 10%, sodium N-lauroyl sarcosinate 7%.
The preparation method of a kind of sewage treating material, described preparation technology enters according to following steps
OK,
(1) Ceramic Balls is made: by Maifanitum 25%, hexacyclic ring stone 18%, tourmaline 25%, glue
The compositions such as soil 13%, kieselguhr 13%, zeolite 6%.By crushing material to 325 mesh fine powders,
Taking powder precisely to allocate by corresponding proportion, after making mother bulb, mother bulb is put into model is
In BY-300 bowling machine, making ball, ball drying enters kiln, and the temperature of kiln is
800 DEG C, calcining 12 hours with oxidizing flame, the temperature controlling oxidizing flame is 1000 DEG C, cooling
After go out kiln.
(2) mixing: by alkyl epoxy carboxylic acid sodium 6-10%, cationic flocculant 10-16%,
Burnt ammonium alum 5-8%, bodied ferric sulfate 8-12%, starch 1-2%, activated carbon 2-6%, third
Olefin(e) acid-acrylate-sulfonate terpolymer 9-12%, sodium N-lauroyl sarcosinate 6-8%
Mixing, then at room temperature places the Ceramic Balls prepared in step (1) after 24h weighs and puts
Enter wherein.
Embodiment 2: remaining is same as in Example 1, difference is described sewage treating material
The percentage by weight of chemical composition includes Ceramic Balls 13%, alkyl epoxy carboxylic acid sodium 9%, sun from
Sub-flocculant 11%, Burnt ammonium alum 7%, bodied ferric sulfate 9%, starch 1%, activated carbon 2%,
Acrylic acid-acrylic ester-sulfonate terpolymer 10%, sodium N-lauroyl sarcosinate 7%;
In described step (1), the temperature of kiln is 850 DEG C, calcines 16 hours with oxidizing flame, control
The temperature of oxygenerating flame is 1000 DEG C.
Embodiment 3: remaining is same as in Example 1, difference is described sewage treating material
The percentage by weight of chemical composition includes Ceramic Balls 15%, alkyl epoxy carboxylic acid sodium 9%, sun from
Sub-flocculant 11%, Burnt ammonium alum 6%, bodied ferric sulfate 11%, starch 1%, activated carbon 3%,
Acrylic acid-acrylic ester-sulfonate terpolymer 8%, sodium N-lauroyl sarcosinate 7%;Institute
Stating in step (1), the temperature of kiln is 830 DEG C, calcines 16 hours with oxidizing flame, controls
The temperature of oxidizing flame is 1020 DEG C.
After process above step, the sewage treating material obtained can quickly be removed in water
Particulate matter and heavy metal, and there is biological degradability, it is possible to avoid the eutrophication of water body
With discharge secondary pollution, it is possible to increase sewage treating efficiency and process quality.
Obviously the present invention implements and is not subject to the restrictions described above, if the present invention of have employed
Method design and the improvement of various unsubstantialities that carries out of technical scheme, or the most improved incite somebody to action this
Design and the technical scheme of invention directly apply to other occasion, all at the protection model of the present invention
Within enclosing.
Claims (6)
1. a sewage treating material, it is characterised in that: the chemistry of described sewage treating material
The percentage by weight of composition includes Ceramic Balls 13-16%, alkyl epoxy carboxylic acid sodium 6-10%, sun
Ionic flocculant 10-16%, Burnt ammonium alum 5-8%, bodied ferric sulfate 8-12%, starch 1-2%,
Activated carbon 2-6%, acrylic acid-acrylic ester-sulfonate terpolymer 9-12%, lauroyl
Base sodium sarcosinate 6-8%.
A kind of sewage treating material the most according to claim 1, it is characterised in that: institute
The percentage by weight of the chemical composition stating sewage treating material includes Ceramic Balls 14%, alkyl epoxy
Carboxylic acid sodium 8%, cationic flocculant 12%, Burnt ammonium alum 6%, bodied ferric sulfate 8%, forms sediment
Powder 2%, activated carbon 3%, acrylic acid-acrylic ester-sulfonate terpolymer 10%, the moon
Osmanthus sarcosinate 7%.
3. a preparation method for sewage treating material according to claim 1 and 2,
It is characterized in that: described preparation technology follows the steps below,
(1) Ceramic Balls is made: described pottery is by Maifanitum 25%, hexacyclic ring stone 18%, electrically
Stone 25%, clay 13%, kieselguhr 13%, zeolite 6% etc. form, by crushing material to 325
Mesh fine powder, takes powder and precisely allocates by corresponding proportion, after making mother bulb, mother bulb is put into rolling
In ball machine, making ball, ball drying enters kiln, calcines 12 hours with oxidizing flame, cold
Go out kiln the most afterwards and can obtain Ceramic Balls.
(2) mixing: by alkyl epoxy carboxylic acid sodium 6-10%, cationic flocculant 10-16%,
Burnt ammonium alum 5-8%, bodied ferric sulfate 8-12%, starch 1-2%, activated carbon 2-6%, third
Olefin(e) acid-acrylate-sulfonate terpolymer 9-12%, sodium N-lauroyl sarcosinate 6-8%
Mixing, then at room temperature places the Ceramic Balls prepared in step (1) after 24h weighs and puts
Enter wherein.
The preparation method of a kind of sewage treating material the most according to claim 3, it is special
Levy and be: in described step (1), the temperature of oxidizing flame is 1000-1050 DEG C.
The preparation method of a kind of sewage treating material the most according to claim 3, it is special
Levy and be: in described step (1), the furnace temperature of kiln is 850 DEG C.
The preparation method of a kind of sewage treating material the most according to claim 3, it is special
Levy and be: bowling machine used in described step (2) is BY-300 bowling machine.
Priority Applications (1)
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CN201610320012.1A CN105923686A (en) | 2016-05-12 | 2016-05-12 | Sewage treatment material and preparing method thereof |
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CN201610320012.1A CN105923686A (en) | 2016-05-12 | 2016-05-12 | Sewage treatment material and preparing method thereof |
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CN201610320012.1A Pending CN105923686A (en) | 2016-05-12 | 2016-05-12 | Sewage treatment material and preparing method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106277259A (en) * | 2016-10-14 | 2017-01-04 | 安徽理工大学 | A kind of clay class clarifying contaminated liquids method based on high-iron fly ash |
CN107597078A (en) * | 2017-10-17 | 2018-01-19 | 广西银英生物质能源科技开发股份有限公司 | One kind is used for heavy metal-polluted water process material and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2004243312A (en) * | 2003-10-15 | 2004-09-02 | Kikuya Tamura | Production and using methods of environmental agents a and b as flocculating and purifying material using montmorillonite for flocculating sludge in various types of slurry, adsorbing and flocculating heavy metals and solid/liquid separating to form colorless clear water |
CN104496420A (en) * | 2015-01-13 | 2015-04-08 | 唐山立雄峰汇材料科技有限公司 | Ceramic balls with drinking water purifying function |
CN104556978A (en) * | 2014-12-24 | 2015-04-29 | 唐山立雄峰汇材料科技有限公司 | Functional ceramic wine set |
CN105417599A (en) * | 2015-12-21 | 2016-03-23 | 天津欧盼科技开发有限公司 | Highly-efficient water-pollution treating agent |
-
2016
- 2016-05-12 CN CN201610320012.1A patent/CN105923686A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004243312A (en) * | 2003-10-15 | 2004-09-02 | Kikuya Tamura | Production and using methods of environmental agents a and b as flocculating and purifying material using montmorillonite for flocculating sludge in various types of slurry, adsorbing and flocculating heavy metals and solid/liquid separating to form colorless clear water |
CN104556978A (en) * | 2014-12-24 | 2015-04-29 | 唐山立雄峰汇材料科技有限公司 | Functional ceramic wine set |
CN104496420A (en) * | 2015-01-13 | 2015-04-08 | 唐山立雄峰汇材料科技有限公司 | Ceramic balls with drinking water purifying function |
CN105417599A (en) * | 2015-12-21 | 2016-03-23 | 天津欧盼科技开发有限公司 | Highly-efficient water-pollution treating agent |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106277259A (en) * | 2016-10-14 | 2017-01-04 | 安徽理工大学 | A kind of clay class clarifying contaminated liquids method based on high-iron fly ash |
CN107597078A (en) * | 2017-10-17 | 2018-01-19 | 广西银英生物质能源科技开发股份有限公司 | One kind is used for heavy metal-polluted water process material and preparation method thereof |
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Application publication date: 20160907 |