CN105907321A - A plastic sucking moulding PVC label for insides of matrixes and punches and a preparing method thereof - Google Patents

A plastic sucking moulding PVC label for insides of matrixes and punches and a preparing method thereof Download PDF

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Publication number
CN105907321A
CN105907321A CN201610240162.1A CN201610240162A CN105907321A CN 105907321 A CN105907321 A CN 105907321A CN 201610240162 A CN201610240162 A CN 201610240162A CN 105907321 A CN105907321 A CN 105907321A
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Prior art keywords
glue
ink
pvc
concave
plastic uptake
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CN201610240162.1A
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CN105907321B (en
Inventor
罗明亮
罗斌
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Taizhou Luobin Print Co Ltd
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Taizhou Luobin Print Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J129/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
    • C09J129/02Homopolymers or copolymers of unsaturated alcohols
    • C09J129/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/24Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/245Vinyl resins, e.g. polyvinyl chloride [PVC]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention relates to plastic sucking moulding labels and particularly relates to a plastic sucking moulding PVC label for insides of matrixes and punches and a preparing method thereof. The PVC label is formed by compositing a base layer, a pattern layer and a glue layer. The base layer is a PVC film. The pattern layer is prepared by coating the base layer with an ink glue composition and drying. The ink content of the ink glue composition is 60-70% by mass, and the glue content is 30-40% by mass. The PVC label can be composited with a plastic product through plastic sucking moulding. A plurality of patterns can be designed on the PVC label. The PVC label has luster and hardness like porcelain.

Description

Plastic uptake PVC labeling and preparation method thereof in a kind of concave-convex mold
Technical field
The present invention relates to a kind of plastic uptake label, particularly to plastic uptake PVC labeling and preparation method thereof in a kind of concave-convex mold.
Background technology
The mark such as existing various labeling or label uses the most in the plane, and general employing plastic sheeting is made.This kind of label cannot be fitted at the product surface of special shape, and the most various plastic product demands are bigger, it is desirable to the highest, needs to design more diversified pattern.
Summary of the invention
The present invention provides plastic uptake PVC labeling in a kind of concave-convex mold, can be combined with each other with plastic plastic uptake, can design various pattern, and have the gloss as porcelain and hardness on plastic uptake PVC labeling.
The technical solution adopted for the present invention to solve the technical problems is:
Plastic uptake PVC labeling in a kind of concave-convex mold, in described concave-convex mold, plastic uptake PVC labeling is composited by bottom, patterned layer, glue layer three layers, described bottom is PVC film, patterned layer is to be coated on bottom by ink glue composition to be dried to obtain, in described ink glue composition, the mass content of ink is 60-70%, and the content of glue is 30-40%.
Ink and glue have been grouped together into patterned layer by the present invention, patterned layer is positioned at inside plastic after plastic uptake, and bottom is the outer surface of plastic, in this concave-convex mold, plastic uptake PVC labeling uses relatively broad, can carry out compound use on the surface of various food containers, decorative plastic articles.This structure and formula special be applicable to plastic uptake in concave-convex mold, make the plastic finally given have a pattern of design, and its film glossiness formed in surface of plastic products be brighter, harder, it appears that closer to porcelain.
As preferably, the glue formula described in patterned layer and glue layer is: 7-8% polyvinyl alcohol, 14-16% white glue with vinyl, 5-6% sodium stearate, 12-15% Pulvis Talci, 10-12% carbamide, 8-10% ethylene glycol, 2-3% sucrose, and surplus is water.The color stability that there was added beneficially patterned layer of sucrose.
As preferably, being in terms of 100% by the gross weight of ink, the formula of described ink is: aqueous polyurethane 50-60%, pigment 10-12%, anti-wear agent 1-2%, auxiliary agent 1-2%, and surplus is water.
The preparation method of plastic uptake PVC labeling in a kind of described concave-convex mold, the method comprises the steps:
A, preparing ink glue composition, in said composition, the mass content of ink is 60-70%, and the content of glue is 30-40%, by being incubated 10-15 minute in the range of ink and glue mixing post-heating to 130 DEG C-200 DEG C, obtains ink glue composition;
Ink glue composition is coated in PVC film, and coats the ink glue composition of different colours according to the pattern of design successively by b, employing intaglio printing machine, obtains the PVC film composite bed with layout, is i.e. compounded with patterned layer in PVC film;
C, at the surface-coated glue layer of patterned layer, obtain product after cooling.
A kind of method producing the plastic with layout with plastic uptake PVC labeling in described concave-convex mold, plastic uptake PVC labeling in described concave-convex mold is covered in the surface of the plastic with stereochemical structure, carrying out plastic uptake at a temperature of 170 DEG C-280 DEG C, in making concave-convex mold, plastic uptake PVC labeling is fixed on surface of plastic products.
Plastic uptake PVC labeling in the concave-convex mold of the present invention, can be combined with each other with plastic plastic uptake, can design various pattern, and have the gloss as porcelain and hardness on plastic uptake PVC labeling.
Detailed description of the invention
Below by specific embodiment, technical scheme is described in further detail.Should be appreciated that the enforcement of the present invention is not limited to the following examples, any pro forma accommodation and/or the change of being made the present invention fall within scope.
In the present invention, if not refering in particular to, all of part, percentage ratio are unit of weight, and the equipment used and raw material etc. are all commercially available or commonly used in the art.Method in following embodiment, if no special instructions, is the conventional method of this area.
The ink used in the present invention is standard aqueous ink, it is also possible to need to select the ink of other compositions according to producing.
Embodiment 1:
In a kind of concave-convex mold, plastic uptake PVC labeling is composited by bottom, patterned layer, glue layer three layers, and described bottom is PVC film, and patterned layer is to be coated on bottom by ink glue composition to be dried to obtain.In this concave-convex mold, the preparation method of plastic uptake PVC labeling is:
A, preparing ink glue composition, in said composition, the mass content of ink is 70%, and the content of glue is 30%, by being incubated 15 minutes in the range of ink and glue mixing post-heating to 180-190 DEG C, obtains ink glue composition;
Ink glue composition is coated in PVC film, and coats the ink glue composition of different colours according to the pattern of design successively by b, employing intaglio printing machine, obtains the PVC film composite bed with layout, is i.e. compounded with patterned layer in PVC film;
C, at the surface-coated glue layer of patterned layer, obtain plastic uptake PVC labeling product after cooling.
Glue formula described in patterned layer and glue layer is: 8% polyvinyl alcohol, 16% white glue with vinyl, 6% sodium stearate, 15% Pulvis Talci, 12% carbamide, 10% ethylene glycol, 3% sucrose, and surplus is water.Being in terms of 100% by the gross weight of ink, the formula of described ink is: aqueous polyurethane 50%, pigment 10%, anti-wear agent 2%, auxiliary agent 2%, and surplus is water.
Embodiment 2:
In a kind of concave-convex mold, plastic uptake PVC labeling is composited by bottom, patterned layer, glue layer three layers, and described bottom is PVC film, and patterned layer is to be coated on bottom by ink glue composition to be dried to obtain.In this concave-convex mold, the preparation method of plastic uptake PVC labeling is:
A, preparing ink glue composition, in said composition, the mass content of ink is 60%, and the content of glue is 30-40%, by being incubated 10 minutes in the range of ink and glue mixing post-heating to 190 DEG C-200 DEG C, obtains ink glue composition;
Ink glue composition is coated in PVC film, and coats the ink glue composition of different colours according to the pattern of design successively by b, employing intaglio printing machine, obtains the PVC film composite bed with layout, is i.e. compounded with patterned layer in PVC film;
C, at the surface-coated glue layer of patterned layer, obtain plastic uptake PVC labeling product after cooling.
Glue formula described in patterned layer and glue layer is: 7% polyvinyl alcohol, 14% white glue with vinyl, 6% sodium stearate, 15% Pulvis Talci, 12% carbamide, 8% ethylene glycol, 3% sucrose, and surplus is water.Being in terms of 100% by the gross weight of ink, the formula of described ink is: aqueous polyurethane 55%, pigment 10%, anti-wear agent 2%, auxiliary agent 2%, and surplus is water.
Embodiment 3:
In a kind of concave-convex mold, plastic uptake PVC labeling is composited by bottom, patterned layer, glue layer three layers, and described bottom is PVC film, and patterned layer is to be coated on bottom by ink glue composition to be dried to obtain.In this concave-convex mold, the preparation method of plastic uptake PVC labeling is:
A, preparing ink glue composition, in said composition, the mass content of ink is 65%, and the content of glue is 35%, by being incubated 10-15 minute in the range of ink and glue mixing post-heating to 150 DEG C-160 DEG C, obtains ink glue composition;
Ink glue composition is coated in PVC film, and coats the ink glue composition of different colours according to the pattern of design successively by b, employing intaglio printing machine, obtains the PVC film composite bed with layout, is i.e. compounded with patterned layer in PVC film;
C, at the surface-coated glue layer of patterned layer, obtain plastic uptake PVC labeling product after cooling.
Glue formula described in patterned layer and glue layer is: 8% polyvinyl alcohol, 15% white glue with vinyl, 6% sodium stearate, 14% Pulvis Talci, 10% carbamide, 10% ethylene glycol, 2% sucrose, and surplus is water.Being in terms of 100% by the gross weight of ink, the formula of described ink is: aqueous polyurethane 60%, pigment 10%, anti-wear agent 2%, auxiliary agent 2%, and surplus is water.
Embodiment
In the concave-convex mold prepared with above-described embodiment, plastic uptake PVC labeling produces the method for plastic with layout, specifically: plastic uptake PVC labeling in described concave-convex mold is covered in the surface of the plastic with stereochemical structure, carrying out plastic uptake at a temperature of 170 DEG C-280 DEG C, in making concave-convex mold, plastic uptake PVC labeling is fixed on surface of plastic products.The plastic used can be the ornaments such as basin, bowl, plate or vase.
The surface of plastic products obtained has the pattern designed, and color is gorgeous, and environmental protection meets the safety criterion in the fields such as food.The film that in concave-convex mold, plastic uptake PVC labeling is formed in surface of plastic products, glossiness is brighter, harder, it appears that closer to porcelain, ageing resistace is preferable.
Embodiment described above is the one preferably scheme of the present invention, and the present invention not makees any pro forma restriction, also has other variant and remodeling on the premise of without departing from the technical scheme described in claim.

Claims (5)

1. plastic uptake PVC labeling in a concave-convex mold, it is characterized in that: in described concave-convex mold, plastic uptake PVC labeling is composited by bottom, patterned layer, glue layer three layers, described bottom is PVC film, patterned layer is to be coated on bottom by ink glue composition to be dried to obtain, in described ink glue composition, the mass content of ink is 60-70%, and the content of glue is 30-40%.
Plastic uptake PVC labeling in concave-convex mold the most according to claim 1, it is characterised in that: the glue formula described in patterned layer and glue layer is: 7-8% polyvinyl alcohol, 14-16% white glue with vinyl, 5-6% sodium stearate, 12-15% Pulvis Talci, 10-12% carbamide, 8-10% ethylene glycol, 2-3% sucrose, surplus is water.
Plastic uptake PVC labeling in concave-convex mold the most according to claim 1, it is characterised in that be in terms of 100% by the gross weight of ink, the formula of described ink is: aqueous polyurethane 50-60%, pigment 10-12%, anti-wear agent 1-2%, auxiliary agent 1-2%, and surplus is water.
4. the preparation method of plastic uptake PVC labeling in the concave-convex mold described in a claim 1, it is characterised in that the method comprises the steps:
A, preparing ink glue composition, in said composition, the mass content of ink is 60-70%, and the content of glue is 30-40%, by being incubated 10-15 minute in the range of ink and glue mixing post-heating to 130 DEG C-200 DEG C, obtains ink glue composition;
Ink glue composition is coated in PVC film, and coats the ink glue composition of different colours according to the pattern of design successively by b, employing intaglio printing machine, obtains the PVC film composite bed with layout, is i.e. compounded with patterned layer in PVC film;
C, at the surface-coated glue layer of patterned layer, obtain product after cooling.
5. the method producing the plastic with layout with plastic uptake PVC labeling in the concave-convex mold described in claim 1, it is characterized in that: plastic uptake PVC labeling in described concave-convex mold is covered in the surface of the plastic with stereochemical structure, carrying out plastic uptake at a temperature of 170 DEG C-280 DEG C, in making concave-convex mold, plastic uptake PVC labeling is fixed on surface of plastic products.
CN201610240162.1A 2016-04-18 2016-04-18 Plastic uptake PVC labeling and preparation method thereof in a kind of concave-convex mold Active CN105907321B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106479268A (en) * 2016-10-27 2017-03-08 北京印刷学院 For printing pure water type gravure white ink of PVC decorative Film and preparation method thereof
CN106479269A (en) * 2016-10-27 2017-03-08 北京印刷学院 For printing pure water type gravure magenta ink of PVC decorative Film and preparation method thereof
CN106479267A (en) * 2016-10-27 2017-03-08 北京印刷学院 For printing pure water type gravure green grass or young crops ink of PVC decorative Film and preparation method thereof
CN106479264A (en) * 2016-10-27 2017-03-08 北京印刷学院 For printing pure water type gravure yellow ink of PVC decorative Film and preparation method thereof
CN106497221A (en) * 2016-10-27 2017-03-15 北京印刷学院 For printing pure water type gravure black ink of PVC decorative Film and preparation method thereof
CN107722878A (en) * 2017-10-31 2018-02-23 温州市稳泰轻化科技有限公司 A kind of environmentally friendly Beer rubberizing and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1318608A (en) * 2001-05-23 2001-10-24 广东药学院 Solid stationery glue and its prduction process
CN1802255A (en) * 2003-06-09 2006-07-12 艾利丹尼森公司 Multilayer film
CN101508225A (en) * 2009-03-09 2009-08-19 何庭佳 Glass reflective film composite plate
CN102689483A (en) * 2011-12-31 2012-09-26 3M中国有限公司 Film for decoration and preparation method thereof
CN104910687A (en) * 2015-05-18 2015-09-16 常州博硕新材料科技有限公司 Printing ink used in water-soluble PVA film inkjet printing, and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1318608A (en) * 2001-05-23 2001-10-24 广东药学院 Solid stationery glue and its prduction process
CN1802255A (en) * 2003-06-09 2006-07-12 艾利丹尼森公司 Multilayer film
CN101508225A (en) * 2009-03-09 2009-08-19 何庭佳 Glass reflective film composite plate
CN102689483A (en) * 2011-12-31 2012-09-26 3M中国有限公司 Film for decoration and preparation method thereof
CN104910687A (en) * 2015-05-18 2015-09-16 常州博硕新材料科技有限公司 Printing ink used in water-soluble PVA film inkjet printing, and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106479268A (en) * 2016-10-27 2017-03-08 北京印刷学院 For printing pure water type gravure white ink of PVC decorative Film and preparation method thereof
CN106479269A (en) * 2016-10-27 2017-03-08 北京印刷学院 For printing pure water type gravure magenta ink of PVC decorative Film and preparation method thereof
CN106479267A (en) * 2016-10-27 2017-03-08 北京印刷学院 For printing pure water type gravure green grass or young crops ink of PVC decorative Film and preparation method thereof
CN106479264A (en) * 2016-10-27 2017-03-08 北京印刷学院 For printing pure water type gravure yellow ink of PVC decorative Film and preparation method thereof
CN106497221A (en) * 2016-10-27 2017-03-15 北京印刷学院 For printing pure water type gravure black ink of PVC decorative Film and preparation method thereof
CN107722878A (en) * 2017-10-31 2018-02-23 温州市稳泰轻化科技有限公司 A kind of environmentally friendly Beer rubberizing and preparation method thereof

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Denomination of invention: The invention relates to a blister PVC label in a concave convex mold and a preparation method thereof

Effective date of registration: 20220222

Granted publication date: 20171201

Pledgee: Zhejiang Luqiao Taizhou rural commercial bank Limited by Share Ltd.

Pledgor: Taizhou Luobin Print Co.,Ltd.

Registration number: Y2022330000243