CN105907028A - Color bituminous cement in bags or barrels and production device and method thereof - Google Patents
Color bituminous cement in bags or barrels and production device and method thereof Download PDFInfo
- Publication number
- CN105907028A CN105907028A CN201610485478.7A CN201610485478A CN105907028A CN 105907028 A CN105907028 A CN 105907028A CN 201610485478 A CN201610485478 A CN 201610485478A CN 105907028 A CN105907028 A CN 105907028A
- Authority
- CN
- China
- Prior art keywords
- chromatic
- bituminous cement
- weighing system
- barreled
- packed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C08L57/02—Copolymers of mineral oil hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention provides color bituminous cement in bags or barrels and production device and method thereof. The bituminous cement contains the following components in parts by weight: 8-15 parts of SBS, 35-50 parts of petroleum resin, 30-45 parts of aromatic oil and/or naphthenic oil, 3-10 parts of polyethylene wax and/or microcrystalline wax and 0.3-1.0 part of antioxidant, wherein the SBS is linear and/or star styrene-butadiene-styrene block copolymer, the block ratio of styrene to butadiene is 30/70, and the molecular weight is 100000-200000. The color bituminous cement provided by the invention has the advantages of easily available raw materials for production, convenient operation of production device, safety and reliability of products, superior performance, high percent of pass, stable product quality and performance, conveniently adjustable product variety and strong adaptability.
Description
Technical field
The present invention relates to ground surface material technical field, more particularly, to one is packed or barreled is colored
Bituminous cements and process units thereof and method.
Background technology
Colorful Asphalt Pavement is as a kind of beautifying urban environment, embodiment city characteristic, lifting city merit
, wagon flow and the high-tech ground surface material of warning traffic can be induced, because its functional effect is obvious, obtain
Being widely applied, Colorful Asphalt Pavement is also applied to garden community, square, gardens and sports equipment place
Deng, there is wide applicability, be the preferred material beautified the environment of road, square.
In existing technology, the technology about chromatic bituminous cement is a lot, many patent applications pair
This all has been reported that, such as: CN1478843, CN101831190, CN1233730,
CN10457009, CN101177533 etc..The chromatic bituminous cement of these patent application technology introductions
Production method, three kinds can be summarized as: 1, factorial praluction, i.e. by a whole set of fixing equipment,
Produce chromatic bituminous cement at workshop, then deliver to batching plant with special heating vehicle, make
Color asphalt concrete.2, mobile device produces, i.e. by a whole set of movably equipment, at batching plant
Neighbouring production, after producing cementitious matter, is delivered directly to batching plant, makes color asphalt coagulation
Soil.3, producing granular color bituminous cements with complete equipment, that directly renders to batching plant mixes cylinder
In, make color asphalt concrete.The whole series that above production method 1,2 is required for comparison huge set
Standby, the transport of special-purpose vehicle and heating repeatedly, not only power consumption is big and easily causes the aging of material, with
Time complex process, the production cycle is long, and relative efficiency is relatively low.The granular color Colophonium that method 3 produces
Cementitious matter is due to its product quality technical specification, the most straight with the quality index of chromatic bitumen mixture
Connect inevitable dependency, it is necessary to make the cementitious matter of liquid state, its quality and technical index could be measured,
Determining whether to prepare qualified chromatic bitumen mixture, therefore, granular color Colophonium is cementing
Material, it is rarely found that reality is applied.Therefore, easily store, transport and color asphalt glue easy to use
Ramming material, chromatic bituminous cement process units and method that technique is simple to operation are all highly desirable.
Summary of the invention
For solving the problems referred to above of the prior art, first purpose of the present invention is to provide a kind of packed
Or barreled chromatic bituminous cement.
Second object of the present invention is to provide coloured silk prepared by a kind of packed or barreled chromatic bituminous cement
Color asphalt.
Third object of the present invention is to provide a kind of packed or production dress of barreled chromatic bituminous cement
Put.
Fourth object of the present invention is to provide a kind of packed or preparation side of barreled chromatic bituminous cement
Method.
This packed or barreled chromatic bituminous cement function admirable, production technology is advanced, operational approach letter
Single.Use packaging bag or metal bucket packaging so that the storage of chromatic bituminous cement and transport convenient.
To achieve these goals, according to the first aspect of the invention, the invention provides a kind of bag
Dress or barreled chromatic bituminous cement, this cementitious matter contains the component of following parts by weight:
Wherein, described SBS is line style and/or star-like SBS,
Styrene is 30/70 with butadiene block ratio, and molecular weight is 10-20 ten thousand.
Preferably, described cementitious matter contains the component of following parts by weight:
It is highly preferred that described cementitious matter contains the component of following parts by weight:
Preferably, described Petropols are C5 Petropols, C9 Petropols or DCPD oil tree
Fat, the softening point temperature of described Petropols is 110-130 DEG C.DCPD Petropols refer to dicyclo penta
Diene resin.Preferably resin is conducive to the raising of product dispersive property and viscosity.
More preferably C5 Petropols or C9 Petropols.
More preferably C9 Petropols.Not polar functionalities in the structure of C9 Petropols, has good
Good resistance to water, resistance to acids and bases, weatherability and light fastness aging, and dissolubility in organic solvent
Good.Be conducive to product dispersive property and the raising of viscosity.
Preferably, described aromatic naphtha kinematic viscosity (100 DEG C) is 30-45mm2/ s, described naphthenic oil is
Pentamethylene. or hexamethylene or derivatives thereof.Described aromatic naphtha or naphthenic oil provide, for each component, the component that mixes,
It is easy to molding and the plasticizing of product.
At least one in described aromatic naphtha more preferably ethylbenzene, dimethylbenzene and trimethylbenzene.These
Solvent solute effect is more preferable, and more environmentally-friendly, cost performance is the highest.
Preferably, described Tissuemat E be relative molecular mass be the Tissuemat E of 1800-8000.
The further preferably trade mark is the Tissuemat E of H1001.Preferably weatherability and lubrication in conventional material
The Tissuemat E that property is higher.
Preferably, described antioxidant is polynary hindered phenol anti-oxidants.This type of antioxidant is being given birth to
Produce and melting process can preferably prevent the aging degeneration of material embrittlement, keep the build-in attribute of material.
Further preferably performance parameter is active component >=98, the polynary Hinered phenols of fugitive constituent≤0.5%
Antioxidant.
More preferably four [β-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] pentaerythritol ester.
Preferably, described cementitious matter can also include that initiator and/or accelerator, described initiator are even
Nitrogen two isobutyl cyanogen or benzoyl peroxide, described accelerator is rubber accelerator, add initiator and/or
Accelerator allows for physics extrusion and becomes chemical reaction extrusion.
According to the second aspect of the invention, the invention provides a kind of color by described packed or barreled
Chromatic bitumen mixture prepared by color bituminous cements, this chromatic bitumen mixture include graded broken stone,
Pigment and described cementitious matter, wherein, described pigment is inorganic pigment, and described amount of pigment is colored drip
The 1%-3% of blue or green compound weight, described cementitious matter consumption is more than chromatic bitumen mixture weight
5%, less than or equal to the 6% of chromatic bitumen mixture weight.
Preferably, described inorganic pigment is iron oxide red, chrome oxide green or iron oxide green.Select weather-proof
Property and the more preferable pigment of unfading.
In use, such as, packed or barreled chromatic bituminous cement being put into heating-up temperature is 170 DEG C
Melting tank dissolve, mix in cylinder through what bitumenpump squeezed into the Asphalt concrete mixing building that is attached thereto,
Mix and stir with the graded broken stone and pigment being heated to 170 DEG C, i.e. can be made into chromatic bitumen mixture.Also can be by
What packed or barreled chromatic bituminous cement was directly thrown into batching plant mixes in cylinder, be heated to certain
Graded broken stone and the pigment of temperature mix and stir, and make chromatic bitumen mixture.
According to the third aspect of the present invention, the invention provides a kind of packed or barreled color asphalt glue
The process units of ramming material, this device by weighing system, screw extruder, static mixer, compensator,
Valve, fill weighing system form；Wherein, described weighing system connects with the charging aperture of screw extruder
Connecing, described static mixer is connected with the discharging opening of screw extruder, described compensator and static mixing
Device connects, and described valve is arranged on the outlet of the bottom of compensator, described fill weighing system and valve
Connect.
Preferably, described weighing system is made up of liquid material weighing system and powder grain material weighing system,
Described screw extruder is double screw extruder or reciprocating single-bolt extruder.
Preferably, described compensator equipped with the discharging opening of more than 2, described discharging opening by Valve controlling,
Described valve is electric or pneumatic valve.
According to the fourth aspect of the present invention, the invention provides a kind of packed or barreled color asphalt glue
The production method of ramming material, the method includes: aromatic naphtha or naphthenic oil are added through liquid material weighing system
Entering screw extruder, by SBS, Petropols, Tissuemat E or microwax, antioxidant is through powder
Material metage system, adds screw extruder, and screw extruder preheating temperature is set as 50-220 DEG C,
Under the effect of machine inner screw and kneading block, make material mixing, melted, shear, modified, then enter
Enter static mixer, make material mix further, plastify, and temperature is controlled for 120-160 DEG C, so
Rear entrance compensator, by the discharging opening of compensator, makes product respectively enter fill weighing system,
In rear loading packaging bag or metal bucket.Wherein, the effect of compensator is to preferably pack cementitious matter,
The pressure of buffering discharging opening cementitious matter so that discharging is evenly.
Preferably, described material addition is set as required by PLC control system.
The raw materials for production of the present invention are easily purchased, and process units is easy to operate, product safety is reliable, function admirable,
Qualification rate height, product quality stable performance, product variety facilitate adjustable, adaptable.Also have
Exempt conventional high-temperature transport chromatic bituminous cement, simplify Contraction in Site, the advantage such as cost-effective.
Other features and advantages of the present invention will give specifically in detailed description of the invention part subsequently
Bright.
Accompanying drawing explanation
Fig. 1 shows the process units according to one embodiment of the present invention.
Reference: 1-liquid material weighing system, 2-powder grain material weighing system, 3-screw extruder,
4-static mixer, 5-compensator, 6-valve, 7-fill weighing system.
Detailed description of the invention
The preferred embodiment of the present invention is described in more detail below.There is provided these embodiments be for
Make the present invention more thorough and complete, and can will fully convey the scope of the invention to ability
The technical staff in territory.
Embodiment 1
The trimethylbenzene that weight portion is 40 parts is added screw extruder through liquid material weighing system, by 10
Part SBS, 40 parts of C5 Petropols, 9 parts of H1001 Tissuemat Es, 1 part of antioxidant 1010 is through powder
Grain material metage system adds double screw extruder, and double screw extruder is preheating to 200 DEG C, spiral shell in machine
Under the effect of bar and kneading block, make material mixing, melted, shear, modified, mix subsequently into static state
Clutch, makes material mix further, plastifies, and controls to be 160 DEG C by temperature, subsequently into compensator,
By the discharging opening of compensator, make product enter fill weighing system, finally load packaging bag and form glue
Ramming material product.
Embodiment 2
The dimethylbenzene that weight portion is 30 parts is added screw extruder through liquid material weighing system, by 12
Part SBS, 50 parts of C9 Petropols, 7 parts of H1001 Tissuemat Es, 1 part of antioxidant 1010 is through powder
Grain material metage system adds reciprocating single-bolt extruder, and reciprocating single-bolt extruder is preheating to
180 DEG C, under the effect of machine inner screw and kneading block, make material mixing, melted, shear, modified,
Subsequently into static mixer, make material mix further, plastify, and control to be 150 DEG C by temperature,
Subsequently into compensator, by the discharging opening of compensator, product is made to enter fill weighing system, finally
Load pail pack and form cementitious matter product.
Embodiment 3
The Pentamethylene. that weight portion is 40 parts is added screw extruder through liquid material weighing system, by 15
Part SBS, 35 parts of C9 Petropols, 9 parts of microwaxes, 1 part of antioxidant 1010 claims through powder grain material
Weight system, adds double screw extruder, and double screw extruder is preheating to 160 DEG C, at machine inner screw and pinching
Close under the effect of block, make material mixing, melted, shear, modified, subsequently into static mixer,
Make material mix further, plastify, and control to be 160 DEG C by temperature, subsequently into compensator, pass through
The discharging opening of compensator, makes product enter fill weighing system, finally loads packaging bag and form cementitious matter
Product.
In use, it is 170 DEG C melt that 6 parts of packed chromatic bituminous cement products are put into heating-up temperature
Change tank to dissolve, mix in cylinder through what bitumenpump squeezed into the Asphalt concrete mixing building that is attached thereto, and add
91 parts of graded broken stones and 3 parts of pigment of heat to 170 DEG C mix and stir, and i.e. can be made into chromatic bitumen mixture.
Being described above various embodiments of the present invention, described above is exemplary, and exhaustive
Property, and it is also not necessarily limited to disclosed each embodiment.At the model without departing from illustrated each embodiment
Enclose with spirit in the case of, many modifications and changes for those skilled in the art
Will be apparent from.
Claims (10)
1. a packed or barreled chromatic bituminous cement, it is characterised in that this cementitious matter contain as
The component of lower parts by weight:
Wherein, described SBS is line style and/or star-like SBS,
Styrene is 30/70 with butadiene block ratio, and molecular weight is 10-20 ten thousand.
The most according to claim 1 packed or barreled chromatic bituminous cement, wherein, described stone
Oleoresin is C5 Petropols, C9 Petropols or DCPD Petropols, described Petropols
Softening point temperature is 110-130 DEG C.
The most according to claim 1 packed or barreled chromatic bituminous cement, wherein, described anti-
Oxidant is polynary hindered phenol anti-oxidants.
The most according to claim 1 packed or barreled chromatic bituminous cement, wherein, described glue
Ramming material also includes that initiator and/or accelerator, described initiator are azo-bis-isobutyl cyanide or benzoyl peroxide first
Acyl, described accelerator is rubber accelerator.
5. one kind by the packed or barreled chromatic bituminous cement described in any one in claim 1-4
Preparation chromatic bitumen mixture, it is characterised in that this chromatic bitumen mixture include graded broken stone,
Pigment and described cementitious matter, wherein, described pigment is inorganic pigment, and described amount of pigment is colored drip
The 1%-3% of blue or green compound weight, described cementitious matter consumption is more than chromatic bitumen mixture weight
5%, less than or equal to the 6% of chromatic bitumen mixture weight.
Chromatic bitumen mixture the most according to claim 5, wherein, described inorganic pigment is oxygen
Change iron oxide red, chrome oxide green or iron oxide green.
7. the packed or barreled chromatic bituminous cement as described in any one in claim 1-4
Process units, it is characterised in that this device is by weighing system, screw extruder, static mixing
Device, compensator, valve, fill weighing system form；Wherein, described weighing system and Screw Extrusion
The charging aperture of machine connects, and described static mixer is connected with the discharging opening of screw extruder, described balance
Tank is connected with static mixer, and described valve is arranged on the bottom of compensator, described fill weighing system
It is connected with the outlet of valve.
Process units the most according to claim 7, wherein, described weighing system is by liquid material
Weighing system and powder grain material weighing system composition, described screw extruder is double screw extruder or past
Compound single screw extrusion machine.
Process units the most according to claim 7, wherein, described compensator is equipped with more than 2
Discharging opening, described discharging opening is by Valve controlling, and described valve is electric or pneumatic valve.
10. the packed or barreled chromatic bituminous cement as described in any one in claim 1-4
Production method, it is characterised in that the method includes: aromatic naphtha or naphthenic oil are claimed through liquid material
Weight system adds screw extruder, by SBS, Petropols, Tissuemat E or microwax, antioxidation
Agent, through powder grain material weighing system, adds screw extruder, and screw extruder preheating temperature is set as
50-220 DEG C, under the effect of machine inner screw and kneading block, material is made to mix, melt, shear, change
Property, subsequently into static mixer, make material mix further, plastify, static mixer temperature control
It is made as 120-160 DEG C, subsequently into compensator, by the discharging opening of compensator, makes product respectively enter
Fill weighing system, finally loads in packaging bag or metal bucket.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610485478.7A CN105907028A (en) | 2016-06-28 | 2016-06-28 | Color bituminous cement in bags or barrels and production device and method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610485478.7A CN105907028A (en) | 2016-06-28 | 2016-06-28 | Color bituminous cement in bags or barrels and production device and method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105907028A true CN105907028A (en) | 2016-08-31 |
Family
ID=56758776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610485478.7A Pending CN105907028A (en) | 2016-06-28 | 2016-06-28 | Color bituminous cement in bags or barrels and production device and method thereof |
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| CN (1) | CN105907028A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107129694A (en) * | 2017-04-28 | 2017-09-05 | 王胜林 | A kind of direct putting type chromatic bituminous cement |
| CN107793770A (en) * | 2017-11-17 | 2018-03-13 | 北京市政路桥建材集团有限公司昌平沥青厂 | A kind of chromatic bituminous cement and preparation method thereof |
| CN108264877A (en) * | 2017-12-26 | 2018-07-10 | 上海浦东路桥沥青材料有限公司 | Color asphalt glue and preparation method thereof |
| CN113004651A (en) * | 2021-02-04 | 2021-06-22 | 上海砼仁环保技术发展有限公司 | Direct-throwing environment-friendly color asphalt cement |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107129694A (en) * | 2017-04-28 | 2017-09-05 | 王胜林 | A kind of direct putting type chromatic bituminous cement |
| CN107793770A (en) * | 2017-11-17 | 2018-03-13 | 北京市政路桥建材集团有限公司昌平沥青厂 | A kind of chromatic bituminous cement and preparation method thereof |
| CN108264877A (en) * | 2017-12-26 | 2018-07-10 | 上海浦东路桥沥青材料有限公司 | Color asphalt glue and preparation method thereof |
| CN113004651A (en) * | 2021-02-04 | 2021-06-22 | 上海砼仁环保技术发展有限公司 | Direct-throwing environment-friendly color asphalt cement |
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