CN105906964B - 一种阻燃高分子复合材料及其制备方法 - Google Patents
一种阻燃高分子复合材料及其制备方法 Download PDFInfo
- Publication number
- CN105906964B CN105906964B CN201610318678.3A CN201610318678A CN105906964B CN 105906964 B CN105906964 B CN 105906964B CN 201610318678 A CN201610318678 A CN 201610318678A CN 105906964 B CN105906964 B CN 105906964B
- Authority
- CN
- China
- Prior art keywords
- retardant
- graphene microchip
- flame
- environmentally friendly
- fire retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 60
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000002131 composite material Substances 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000000463 material Substances 0.000 claims abstract description 42
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 39
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims abstract description 22
- 239000006185 dispersion Substances 0.000 claims abstract description 21
- 239000004793 Polystyrene Substances 0.000 claims abstract description 5
- 229920002223 polystyrene Polymers 0.000 claims abstract description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 7
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052794 bromium Inorganic materials 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 241000446313 Lamella Species 0.000 claims 1
- 229920000265 Polyparaphenylene Polymers 0.000 claims 1
- -1 polyphenylene Polymers 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 14
- 239000000779 smoke Substances 0.000 abstract description 10
- 229920000642 polymer Polymers 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 6
- 238000004079 fireproofing Methods 0.000 abstract description 4
- 239000000654 additive Substances 0.000 abstract description 2
- 230000000996 additive effect Effects 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract description 2
- 239000003546 flue gas Substances 0.000 description 9
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 239000003610 charcoal Substances 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000013065 commercial product Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000000979 retarding effect Effects 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000011365 complex material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 230000005183 environmental health Effects 0.000 description 1
- 229920002903 fire-safe polymer Polymers 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 231100000518 lethal Toxicity 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Carbon And Carbon Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610318678.3A CN105906964B (zh) | 2016-05-13 | 2016-05-13 | 一种阻燃高分子复合材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610318678.3A CN105906964B (zh) | 2016-05-13 | 2016-05-13 | 一种阻燃高分子复合材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105906964A CN105906964A (zh) | 2016-08-31 |
CN105906964B true CN105906964B (zh) | 2018-08-31 |
Family
ID=56749070
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610318678.3A Active CN105906964B (zh) | 2016-05-13 | 2016-05-13 | 一种阻燃高分子复合材料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105906964B (zh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106883540A (zh) * | 2017-04-14 | 2017-06-23 | 明光市安盛非金属材料厂 | 一种高阻燃凹凸棒土基纳米复合材料及制备方法 |
CN110975435A (zh) * | 2019-12-23 | 2020-04-10 | 应城市天润产业用布有限责任公司 | 一种工业除尘的复合过滤材料及其制备工艺 |
CN114318579B (zh) * | 2022-01-12 | 2024-03-15 | 东华大学 | 高隔热抑烟的聚苯硫醚复合材料的制备方法及复合纤维 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1373329B1 (en) * | 2001-03-12 | 2007-05-30 | Albemarle Corporation | Improved brominated polystyrenic resins |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103819597B (zh) * | 2014-02-19 | 2016-01-20 | 哈尔滨工业大学 | 含石墨烯的可发性聚苯乙烯聚合物的制备方法 |
CN104448884A (zh) * | 2014-11-13 | 2015-03-25 | 苏州经贸职业技术学院 | 一种阻燃石墨烯纳米复合材料及其制备方法 |
-
2016
- 2016-05-13 CN CN201610318678.3A patent/CN105906964B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1373329B1 (en) * | 2001-03-12 | 2007-05-30 | Albemarle Corporation | Improved brominated polystyrenic resins |
Also Published As
Publication number | Publication date |
---|---|
CN105906964A (zh) | 2016-08-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Chiu et al. | The dynamic flammability and toxicity of magnesium hydroxide filled intumescent fire retardant polypropylene | |
Xie et al. | Expandable graphite systems for halogen‐free flame‐retarding of polyolefins. I. Flammability characterization and synergistic effect | |
CN105906964B (zh) | 一种阻燃高分子复合材料及其制备方法 | |
Wang et al. | Synergistic effect of expandable graphite and melamine phosphate on flame‐retardant polystyrene | |
Liu et al. | Fire property and charring behavior of high impact polystyrene containing expandable graphite and microencapsulated red phosphorus | |
Jin et al. | Flame retardant properties of polyurethane/expandable praphite composites | |
Wang et al. | Flame‐retardant mechanism of expandable polystyrene foam with a macromolecular nitrogen–phosphorus intumescent flame retardant | |
Xu et al. | EG-based coatings for flame retardance of shape stabilized phase change materials | |
Wen et al. | Organically modified montmorillonite as a synergist for intumescent flame retardant against the flammable polypropylene | |
Xu et al. | Flame retardancy and thermal behavior of intumescent flame-retardant EVA composites with an efficient triazine-based charring agent | |
CN102634351B (zh) | 水性无卤柔性防火堵料 | |
Kuan et al. | Preparation of expandable graphite via H2O2‐hydrothermal process and its effect on properties of high‐density polyethylene composites | |
Chen et al. | Effect of charring agent THEIC on flame retardant properties of polypropylene | |
Zhou et al. | Application of intumescent flame retardant containing aluminum diethyphosphinate, neopentyl glycol, and melamine for polyethylene | |
Liu et al. | Effect of carbon black on the thermal degradation and flammability properties of flame‐retarded high impact polystyrene/magnesium hydroxide/microencapsulated red phosphorus composite | |
Ran et al. | Synergistic flame retardant mechanism of lanthanum phenylphosphonate and decabromodiphenyl oxide in polycarbonate | |
Liang et al. | Role of expandable graphite on flame retardancy, smoke suppression, and acid resistance of polypropylene/magnesium hydroxide composites | |
CN106904929A (zh) | 一种a级防火不燃聚苯乙烯颗粒保温板制备方法 | |
Zhou et al. | Combined effect of transition metal phosphide (MxPy, M= Ni, Co, and Cu) and intumescent flame retardant system on polypropylene | |
CN108676248A (zh) | 一种高阻燃聚丙烯材料及其制备方法与应用 | |
Hu et al. | Metal‐phenolic networks: a biobased synergist for EVA/APP composites toward enhanced thermal stability and flame retardancy | |
Wu et al. | Experimental study on polystyrene with intumescent flame retardants from different scale experiments | |
Liu et al. | Effect of sepiolite on properties of silicone rubber/melamine/starch/sepiolite flame retardant composites | |
CN104262875B (zh) | 以植物基活性炭为协效剂的膨胀阻燃电缆料及制备方法 | |
Shen et al. | Preparation of expandable graphite and its flame retardant properties in HDPE composites |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CP03 | Change of name, title or address | ||
CP03 | Change of name, title or address |
Address after: 315100 No.1 Qianhu South Road, higher education park, Shounan street, Yinzhou District, Ningbo City, Zhejiang Province Patentee after: Zhejiang University of science and engineering Ningbo Address before: 315100, Qian 1, Yinzhou District, Ningbo, Zhejiang, Hunan Road Patentee before: Ningbo Institute of Technology, Zhejiang University |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210826 Address after: 315300 West Industrial Park, Guanhaiwei town, Cixi City, Ningbo City, Zhejiang Province Patentee after: FU-DAY SCIENCE AND TECHNOLOGY Co.,Ltd. Address before: 315100 No.1 Qianhu South Road, higher education park, Shounan street, Yinzhou District, Ningbo City, Zhejiang Province Patentee before: Zhejiang University of science and engineering Ningbo |