CN105906429A - Liquid water-soluble color-changing fertilizer containing amino acid and trace element and dilution control method of fertilizer - Google Patents
Liquid water-soluble color-changing fertilizer containing amino acid and trace element and dilution control method of fertilizer Download PDFInfo
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- CN105906429A CN105906429A CN201610258810.6A CN201610258810A CN105906429A CN 105906429 A CN105906429 A CN 105906429A CN 201610258810 A CN201610258810 A CN 201610258810A CN 105906429 A CN105906429 A CN 105906429A
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- acid
- potassium
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C11/00—Other nitrogenous fertilisers
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
The invention relates to a liquid water-soluble color-changing fertilizer containing an amino acid and a trace element and a dilution control method of the fertilizer; an amino acid-containing organic matter, a trace element fertilizer, an acid-base regulator, an acid-base buffer agent, a color-changing agent and water are added into a reaction kettle according to a certain mass ratio, and are stirred and dissolved completely in the reaction kettle to obtain the liquid water-soluble color-changing fertilizer containing the amino acid and the trace element; a certain mass of the liquid water-soluble color-changing fertilizer containing the amino acid and the trace element is taken and put in a container, and water is gradually added into the container to dilute the fertilizer to make the color changed, namely, the dilution concentration is achieved. By using a principle that the color-changing agent shows different colors along with the change of the concentration of H<+>, the purpose of controlling the dilution concentration of the liquid water-soluble fertilizer is achieved by color changing.
Description
Technical field
The present invention relates to a kind of liquid containing amino-acid trace element water-soluble variable color fertilizer and the dilution control method of this fertilizer.
Background technology
At present Water soluble fertilizer was through development in 10 years, the most commercially occupied certain seat, but owing to Chinese soil compares point
Dissipate, crops cannot large-scale production, have a lot of place to start to have gone up the equipment such as drip irrigation and spray irrigation, and used Water soluble fertilizer, by
Using to use after water dilutes in Water soluble fertilizer, the effect that therefore Water soluble fertilizer is played is affected very by the size of extension rate
Greatly, extension rate is little to be likely to result in burn seedlings or burns leaf, in turn results in the underproduction;The big then possible DeGrain of extension rate, enters
And also result in the underproduction.
The control of China's Water soluble fertilizer extension rate is mainly by experience at present.Such as in some rural area, owing to lacking meter
Amount instrument or metering outfit are inconvenient to carry, and operator often relies on experience and grasps amount of water, is easy to cause diluted concentration
Inaccurate problem, affects the normal efficacy exertion of fertilizer.
Summary of the invention
It is fertile that the technical problem to be solved is to provide a kind of water-soluble variable color of the liquid Han amino-acid trace element, system
Standby a kind of water-soluble variable color of the liquid Han amino-acid trace element is fertile;Control Water soluble fertilizer extension rate more precisely, more easily, to play
Water soluble fertilizer maximum effect.
In order to solve above-mentioned technical problem, present invention employs techniques below scheme:
Aminoacid Organic substance, trace-element fertilizer, acid-base modifier, acid-base buffer agent, colour-changing agent and water will be contained according to certain matter
Amount ratio joins in reactor, and stirring and dissolving is complete in a kettle., obtains the water-soluble variable color of the liquid containing amino-acid trace element fertile;
The described Organic substance containing aminoacid refer to glycine, Glycine sodium, glycine potassium, alanine, Sodium L-alaninate, alanine potassium,
Valine, Valine sodium salt, valine potassium, leucine, (S)-Leucine sodium salt, leucine potassium, isoleucine, Isoleucine sodium salt, different bright ammonia
Acid potassium, phenylalanine, Isoleucine sodium salt, isoleucine potassium, proline, Sodium proline, proline potassium, tryptophan, L-Tryptophan sodium,
Tryptophan potassium, serine, L-Serine sodium, serine potassium, tyrosine, L-Tyrosine, sodium salt, tyrosine potassium, cysteine, cysteine
Sodium, cysteine potassium, methionine, L-Methionine sodium, methionine potassium, agedoite, agedoite sodium, agedoite potassium, glutamy
Amine, glutamine sodium, glutamine potassium, threonine, L-Threonine sodium, threonine potassium, aspartic acid, NaAsp, Radix Asparagi ammonia
Acid potassium, glutamic acid, sodium glutamate, Kaglutam, lysine, L-Lysine sodium salt, lysine potassium, arginine, Arginine sodium, arginine
One or more in potassium, histidine, Histidine sodium and histidine potassium;
Trace-element fertilizer be ethylenediamine tetraacetic acid disodium zinc salt, disodiumedetate ferrous iron, disodiumedetate copper,
One or several in disodiumedetate manganese, ammonium molybdate, boric acid and Borax;
Acid-base modifier is citric acid, oxalic acid, malic acid, potassium hydroxide, sodium hydroxide, potassium carbonate, potassium bicarbonate, sodium bicarbonate
With one or more in sodium carbonate;
Acid-base buffer agent is polymeric amino acid and its esters, disodium citrate, citric acid dipotassium, trisodium citrate, citric acid three
In potassium, disodiumedetate, ethylenediamine tetraacetic acid,dipotassium salt, oxalic acid one sodium, oxalic acid one potassium, oxalic acid disodium and oxalic acid dipotassium
One or more;
Described containing the matter between aminoacid Organic substance, trace-element fertilizer, acid-base modifier, acid-base buffer agent, colour-changing agent and water
Amount ratio is 40~55:1~10:0~10:0~10:0.1~6:44~59.
Colour-changing agent is one or more in phenolphthalein, purple cabbage and Herba Cladoniae rangiferinae.
The dilution control method that the water-soluble variable color of a kind of liquid containing amino-acid trace element is fertile, it is characterised in that according to following step
Suddenly implement to control:
The water-soluble variable color fertilizer of the liquid containing amino-acid trace element taking certain mass is put in container, gradually adds water in container, liquid
After body variable color, i.e. think and reach diluted concentration.
The present invention has following Advantageous Effects: the present invention utilizes colour-changing agent to show different colours with H+ concentration change
Principle, H+ concentration in solution when controlling different extension rate by the interpolation of acid-base modifier and acid-base buffer agent, and then
Control the change of colour-changing agent color, to reach the purpose precisely diluted, play the maximum efficiency of product;The addition of acid-base buffer agent
It is possible to prevent fertilizer because of peracid or to cross alkali, the destruction to the environment of soil;Product variable color is directly perceived, easy to use, simple to operate.
Detailed description of the invention
The present invention is further illustrated below in conjunction with instantiation.
Embodiment one prepared by variable color fertilizer
By glycine potassium, Sodium L-alaninate, ethylenediamine tetraacetic acid disodium zinc salt, phenolphthalein and water according to mass ratio 30:10:4:1:55, add
Entering in reactor, stirring and dissolving is complete in a kettle., obtains the water-soluble variable color of the liquid containing amino-acid trace element fertile.
Embodiment two prepared by variable color fertilizer
By valine potassium, leucine, isoleucine potassium, ethylenediamine tetraacetic acid disodium zinc salt, disodiumedetate ferrous iron, Fructus Citri Limoniae
Acid, sodium dihydrogen citrate, trisodium citrate, phenolphthalein, purple cabbage and water are according to mass ratio 10:20:11:3:3:0.2:0.3:0.1:
0.1:0.3:52, joins in reactor, and stirring and dissolving is complete in a kettle., obtains the liquid containing amino-acid trace element water-soluble
Variable color is fertile.
Embodiment three prepared by variable color fertilizer
By phenylalanine potassium, proline potassium, tryptophan, boric acid, poly-aspartic-acid potassium, Herba Cladoniae rangiferinae and water according to mass ratio 18:20:
8:4:0.6:0.4:49, joins in reactor, and stirring and dissolving is complete in a kettle., obtains containing amino-acid trace element liquid
Water-soluble variable color is fertile.
Embodiment four prepared by variable color fertilizer
By threonine potassium, potassium aspartate, Kaglutam, ethylenediamine tetraacetic acid disodium zinc salt, boric acid, potassium bicarbonate, polyglutamic acid,
Purple cabbage and water, according to mass ratio 5:25:12:1:1:0.5:0.5:1:54, join in reactor, stir molten in a kettle.
Solve completely, obtain the water-soluble variable color of the liquid containing amino-acid trace element fertile.
Diluted concentration controls embodiment
Take variable color fertilizer and prepare the fertilizer 10g of embodiment three preparation, be loaded in transparent vessel, slowly add water, when color is become by redness
Au bleu, stops adding water.
Beneficial effects of the present invention is further illustrated below in conjunction with experimental data:
1, experimental water: take use for laboratory tap water.
2, experiment material to be tested
Through experimental results demonstrate 2200 times of using effects of dilution optimal containing amino-acid trace element liquid Water soluble fertilizer 3 kilograms, its
In 1 kilogram for variable color fertilizer of the present invention i.e. by adding acid-base modifier, acid-base buffer agent, colour-changing agent are adjusted in dilution
Can the most from red to blue when 2200 times;1 kilogram (is removed for common fertilizer and is not added with acid-base modifier, acid-base buffer agent, colour-changing agent
Outward, other preparation condition is identical with variable color fertilizer of the present invention);1 kilogram for common dyeing fertilizer (production adds light green, but
Being not added with acid-base modifier, acid-base buffer agent, colour-changing agent, other preparation condition is identical with variable color fertilizer of the present invention);Same management
1 mu of intensive shadow on lung ground.
3, experimental design
Setup Experiments divides 2 process, is respectively as follows: (1): product dilutes;(2): the product after dilution carries out blade face spray to intensive shadow on lung
Execute.6 communities of experiment point, repeat for 2 times, cross arrangement, set protection row between neighbor cell, and every plot area is 100m2。
4, experiment is implemented
Within 2015, JIUYUE is diluted and intensive shadow on lung carries out foliage-spray on the 10th, dilutes variable color fertilizer of the present invention and is diluted to color
From red to blue, stop dilution, peeling after gross weight be called 2198 kilograms, extension rate is 2197 times;Common fertilizer is by feel
Dilution, dilution without color change, after dilution peeling after weight be called 2408 kilograms, extension rate is 2407 times;Commonly
Dyeing fertilizer dilute the most by feel, dilution color is the most thin out, but inconspicuous, after dilution peeling after weight be called 1920
Kilogram, extension rate is 1919 times.After dilution, fertilizer carries out foliage-spray to 2 communities respectively, within after spraying the 5th day, observes, sends out
The intensive shadow on lung growth of the community, 2 communities now spraying common dyeing fertilizer receives significantly suppression, and the longest, other 4 little
District's growth is normal, and within 2015, intensive shadow on lung is gathered in the crops by JIUYUE 26, and adds up yield.
5, result and analysis
Yield | Repeat 1(kg) | Repeat 2(kg) | Averagely (kg) |
Variable color fertilizer of the present invention | 65.7 | 69.3 | 67.5 |
Common fertilizer | 59.7 | 63.2 | 61.5 |
Common dyeing fertilizer | 43.2 | 46.1 | 44.7 |
As can be seen from the above results, variable color fertilizer of the present invention can accomplish the control to product diluted concentration by variable color, sends out
Wave the maximum efficiency of product;After the dilution of common dyeing fertilizer, concentration is excessive, and the growth to intensive shadow on lung serves inhibitory action, finally
Cause the underproduction;After common fertilizer dilution, concentration is on the low side, though not growth inhibited to intensive shadow on lung, but fail to play the maximum effect of fertilizer
Really, yield does not reaches maximization yet.This experiment is in addition to foliage-spray processes difference, and other operating conditions are the most consistent.
6, discuss: along with social progress, the acceleration of land transformation, original fertilization mode cannot meet modern agriculture
Demand, Water soluble fertilizer not only can economize on water but also can save fertilizer, arise at the historic moment, and the development prospect of following Water soluble fertilizer is the most wide, how to send out
The maximum efficiency waving Water soluble fertilizer is the direction that we study.
Claims (3)
1. the water-soluble variable color of the liquid Han amino-acid trace element is fertile, it is characterised in that be prepared from according to following steps:
Aminoacid Organic substance, trace-element fertilizer, acid-base modifier, acid-base buffer agent, colour-changing agent and water will be contained according to certain matter
Amount ratio joins in reactor, and stirring and dissolving is complete in a kettle., obtains the water-soluble variable color of the liquid containing amino-acid trace element fertile;
The described Organic substance containing aminoacid refer to glycine, Glycine sodium, glycine potassium, alanine, Sodium L-alaninate, alanine potassium,
Valine, Valine sodium salt, valine potassium, leucine, (S)-Leucine sodium salt, leucine potassium, isoleucine, Isoleucine sodium salt, different bright ammonia
Acid potassium, phenylalanine, Isoleucine sodium salt, isoleucine potassium, proline, Sodium proline, proline potassium, tryptophan, L-Tryptophan sodium,
Tryptophan potassium, serine, L-Serine sodium, serine potassium, tyrosine, L-Tyrosine, sodium salt, tyrosine potassium, cysteine, cysteine
Sodium, cysteine potassium, methionine, L-Methionine sodium, methionine potassium, agedoite, agedoite sodium, agedoite potassium, glutamy
Amine, glutamine sodium, glutamine potassium, threonine, L-Threonine sodium, threonine potassium, aspartic acid, NaAsp, Radix Asparagi ammonia
Acid potassium, glutamic acid, sodium glutamate, Kaglutam, lysine, L-Lysine sodium salt, lysine potassium, arginine, Arginine sodium, arginine
One or more in potassium, histidine, Histidine sodium and histidine potassium;
Trace-element fertilizer be ethylenediamine tetraacetic acid disodium zinc salt, disodiumedetate ferrous iron, disodiumedetate copper,
One or several in disodiumedetate manganese, ammonium molybdate, boric acid and Borax;
Acid-base modifier is citric acid, oxalic acid, malic acid, potassium hydroxide, sodium hydroxide, potassium carbonate, potassium bicarbonate, sodium bicarbonate
With one or more in sodium carbonate;
Acid-base buffer agent is polymeric amino acid and its esters, disodium citrate, citric acid dipotassium, trisodium citrate, citric acid three
In potassium, disodiumedetate, ethylenediamine tetraacetic acid,dipotassium salt, oxalic acid one sodium, oxalic acid one potassium, oxalic acid disodium and oxalic acid dipotassium
One or more;
Described containing the matter between aminoacid Organic substance, trace-element fertilizer, acid-base modifier, acid-base buffer agent, colour-changing agent and water
Amount ratio is 40~55:1~10:0~10:0~10:0.1~6:44~59.
2. the water-soluble variable color of the liquid Han amino-acid trace element as claimed in claim 1 is fertile, it is characterised in that: colour-changing agent is phenol
One or more in phthalein, purple cabbage and Herba Cladoniae rangiferinae.
3. the dilution control method that the water-soluble variable color of the liquid Han amino-acid trace element is fertile, it is characterised in that according to following steps
Implement to control:
The water-soluble variable color fertilizer of the liquid containing amino-acid trace element taking certain mass is put in container, gradually adds water in container, liquid
After body variable color, i.e. think and reach diluted concentration.
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Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104926536A (en) * | 2015-07-03 | 2015-09-23 | 刘彬 | Production method of discoloring anti-counterfeit water-soluble microelement fertilizer |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN104926536A (en) * | 2015-07-03 | 2015-09-23 | 刘彬 | Production method of discoloring anti-counterfeit water-soluble microelement fertilizer |
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