CN104086321B - Add sugar alcohol containing aminoacid water-soluble fertilizer and preparation method thereof - Google Patents
Add sugar alcohol containing aminoacid water-soluble fertilizer and preparation method thereof Download PDFInfo
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- CN104086321B CN104086321B CN201410378063.0A CN201410378063A CN104086321B CN 104086321 B CN104086321 B CN 104086321B CN 201410378063 A CN201410378063 A CN 201410378063A CN 104086321 B CN104086321 B CN 104086321B
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Abstract
The invention provides add sugar alcohol containing aminoacid water-soluble fertilizer and preparation method thereof, its raw material composition comprises aminoacid, calcium salt and water, wherein, by weight percentage, its raw material composition also comprises the sugar alcohol of 5%～10%.The present invention is calcium constituent type containing aminoacid water-soluble fertilizer, with the addition of again the sugar alcohol chelating agen as calcium constituent, by sugar alcohol, aminoacid and the rational proportion relation of calcium salt, sugar alcohol and calcium constituent chelating is made to form firm little molecule chelate, in addition the infiltration of sugar alcohol itself and wetting function, adds absorption and the conevying efficiency of the calcium constituent of its chelating；Meanwhile, aminoacid may also aid in calcium absorption, moreover it is possible to promotes photosynthesis, increases chlorophyll content.Therefore, the present invention add sugar alcohol containing in aminoacid water-soluble fertilizer under sugar alcohol and amino acid whose comprehensive function, its utilization rate is high, can increase the travelling speed of plant nutrient, increases absorption and the plant sugar content of Calcium in Plants.
Description
Technical field
The present invention relates to technical field of fertilizers, particularly relate to add sugar alcohol containing aminoacid water-soluble fertilizer and system thereof
Preparation Method.
Background technology
Water soluble fertilizer is one of major fields of new-type fertilizer exploitation, has absorption instant, easy, nutrient complete, sharp
By rate height, water saving, environmental protection, effect easy to use, can be applicable to sprinkling irrigation, drip irrigation and soilless culture, it is achieved water
Fertile integration, especially has a high potential in industrialized agriculture produces.Water-saving agriculture is to develop ring sustainable, ecological
Protect a kind of inexorable trend of agricultural, be also the only way which must be passed of development China modern agriculture." National Planting develops
12nd five-year-plan " (2011-2015) to explicitly point out the bearing capacity of China's water resource extremely limited,
Put forth effort advance Developing Water-saving Agriculture, calmodulin binding domain CaM feature, Optimization Planting layout, supporting field water saving facility,
Emphasis promotes farmland water-saving technology mode.The research and development of water-soluble fertilizer and application are water savings, save fertile tillage method
One of effective measures.Along with intensive, the large-scale development of China's agricultural, water resource further deficient,
The continuous propelling that " water-fertilizer integral " works, drip irrigation and spray irrigation water saving facility agricultural area will expand rapidly, indication
Water-soluble fertilizer market development potential huge.
Along with modern agriculture and the development of fertilizer science technology, the application of current Water soluble fertilizer start to diversification,
The direction such as specific aim, environment-friendly type is developed, and the development of product also tends to high concentration, seriation and multifunction.
The water-soluble fertilizer containing aminoacid is to be mixed, with the preparation such as calcium, trace element, the water-soluble fertilizer being concentrated to give by aminoacid,
Mainly make amino acid foliage fertilizer.Product divides microelement type and calcium constituent type two types.Current calcium constituent
There is calcium constituent and move difficulty in type water-soluble fertilizer in aminoacid, causes calcium constituent absorption rate low, fertilizer utilization
The problem that rate is low.
Summary of the invention
For drawbacks described above and the problem of prior art, it is an object of the invention to provide add sugar alcohol containing amino
Acid water-soluble fertilizer and preparation method thereof, solves current calcium constituent type water-soluble fertilizer in aminoacid and there is calcium unit
The mobile difficulty of element, causes calcium constituent absorption rate low, and the problem that utilization rate of fertilizer is low, developing one can be very
Controlling well the loss of fertilizer, the chelating calcium that sugar alcohol obtains with calcium ion chelating is easily absorbed by blade, improves calcium
Utilization rate, and then improve utilization rate of fertilizer, beneficially plant growth containing aminoacid water-soluble fertilizer.
In order to achieve the above object, the present invention provides following technical scheme:
Add sugar alcohol containing aminoacid water-soluble fertilizer, its raw material comprises aminoacid, calcium salt and water, wherein, presses
Percentage by weight, also comprises the sugar alcohol of 5%～10% in its raw material composition.
Preferably, its raw material composition also comprises the sugar alcohol of 6%～9%.
More preferably, its raw material composition also comprises the sugar alcohol of 8%～8.5%.
Most preferably, its raw material composition also comprises the sugar alcohol of 8.3%.
Preferably, described sugar alcohol is preferably natural sugar alcohol.
Specifically, aminoacid and the consumption of calcium salt in the raw material containing aminoacid water-soluble fertilizer of the present invention, as long as
Meet existing containing in aminoacid water-soluble fertilizer to aminoacid and the content of calcium constituent, such as, according to registration
Technical specification, the present invention is not less than 10% containing the content of free amino acid in aminoacid water-soluble fertilizer, calcium unit
The content of element is not less than 30%.
Further technical scheme is, the composition of the raw material containing aminoacid water-soluble fertilizer adding sugar alcohol of the present invention
In comprise 5%～10% the calcium salt of the aminoacid of sugar alcohol, 10%～20%, 50%～60% and the water of surplus.
Specifically, described calcium salt is water-soluble Ca salt, such as calcium nitrate, calcium ammonium nitrate or calcium chloride etc..
Specifically, described aminoacid is 1B, glycine, proline, aspartic acid, glutamic acid
Or light propylhomoserin etc..
Preferably technical scheme is, in the composition of the raw material containing aminoacid water-soluble fertilizer adding sugar alcohol of the present invention
Comprise calcium salt and the water of surplus of the aminoacid of sugar alcohol, 10%～15%, 54%～58% of 8%～9%.
Optimal technical scheme is, the raw material containing aminoacid water-soluble fertilizer adding sugar alcohol of the present invention is by 8.3%
Sugar alcohol, the aminoacid of 10%, the calcium salt of 56% and 25.7% water composition.
The preparation method containing aminoacid water-soluble fertilizer adding sugar alcohol of the present invention is as follows:
Step one, weigh sugar alcohol, aminoacid, calcium salt and water, wherein, by weight hundred by raw material composition and ratio
Proportion by subtraction, sugar alcohol accounts for 5%～10% in raw material composition；
Step 2, aminoacid, calcium salt and water by weighing in step one, mixed dissolution, preparation obtains basis
Containing aminoacid water-soluble fertilizer；
Step 3, the basis of step 2 water-soluble fertilizer in aminoacid is heated to 70～90 DEG C, is subsequently adding step
Rapid one sugar alcohol weighed, insulated and stirred, then filter, must add sugar alcohol containing aminoacid water-soluble fertilizer.
Further, the basis configuration process containing aminoacid water-soluble fertilizer described in step 2 is as follows: by step
One aminoacid weighed and water mixing, heated and stirred, obtain span amino acid mother liquor；Then by span amino acid mother liquor
PH value is adjusted to 6～10, then adds calcium salt, stirring and dissolving, obtains basis water-soluble fertilizer in aminoacid.
Specifically, the alkali compounds such as potassium hydroxide or sodium hydroxide is used to be adjusted to by the pH value of span amino acid mother liquor
6～10.
In step one, it is preferable that sugar alcohol accounts for 6%～9% in raw material composition；More preferably, sugar alcohol accounts for raw material group
In one-tenth 8%～8.5%；Most preferably, 8.3% during sugar alcohol accounts for raw material composition.
More specifically, step one weighs sugar alcohol, aminoacid, calcium salt and water by raw material composition and ratio, wherein,
By weight percentage, raw material composition in comprise 5%～10% the aminoacid of sugar alcohol, 10%～20%, 50%～
The calcium salt of 60% and the water of surplus.Preferably, raw material composition comprises sugar alcohol, 10%～15% of 8%～9%
The calcium salt of aminoacid, 54%～58% and the water of surplus.Most preferably, raw material composition comprises the sugar of 8.3%
Alcohol, the aminoacid of 10%, the calcium salt of 56% and the water of 25.7%.
Specifically, sugar alcohol described in step one is preferably natural sugar alcohol.
Calcium salt described in step one is water-soluble Ca salt, such as calcium nitrate, calcium ammonium nitrate or calcium chloride etc..
Aminoacid described in step one is 1B, glycine, proline, aspartic acid, glutamic acid
Or light propylhomoserin etc..
The water-soluble fertilizer containing aminoacid adding sugar alcohol of the present invention has the advantages that
1, sugar alcohol is as the carrier of nutrient, is greatly improved the nutrient travelling speed at crop phloem.Sugar
Alcohol has infiltration and wetting function, and after foliage-spray, solution can preferably be attached to blade and extend rapidly, increases
The absorption area of big blade, can promote that its calcium constituent nutrient chelated enters in blade through the horny layer of blade
Portion.Use this fertilizer, substantially increase the crop absorption and use efficiency to fertilizer.
2. this fertilizer substantially solves the problem that calcium constituent difficulty moves, and the conevying efficiency of calcium significantly improves, and effect is excellent
In the fertilizer of chelated calcium such as citric acid, aminoacid；And the calcium constituent in sugar alcohol Chelating state is difficult to be passivated, and more holds
Easily absorbed.
3. the chelate molecular weight that sugar alcohol and calcium constituent are formed is relatively low, it is easy to is absorbed by blade, enters into and plant
In strain body, easily degraded discharges nutrient, consumes energy low.
4. carry nutrient plant phloem carry out nutrient transport ability considerably beyond other containing aminoacid water-soluble
Fertile.
5. significantly improve the resistance of crop.On the one hand, sugar alcohol is the important thing participating in intracellular penetration regulation
Matter, under the environment stresses such as salt damage, arid, waterflooding, sugar alcohol can make crop fit by regulation cell permeability
Answer adverse growth, give full play to the sugar alcohol active function to crop, improve the resistivity of plant；The opposing party
Face, sugar alcohol can improve the resistance to active oxygen, it is to avoid due to reasons such as day bright, arid, disease, anoxias
The plant-active oxygen injury caused.
6, aminoacid (such as 1B), it is also possible to help the absorption of calcium, promotes photosynthesis, increases leaf
Chlorophyll contents, increases vitamin and sugar content.
In sum, the interpolation sugar alcohol of the present invention is calcium constituent type containing aminoacid water-soluble fertilizer, with the addition of again
Micromolecule sugar alcohol is as the chelating agen of calcium constituent, and its chelatropic reaction process is as it is shown in figure 1, micromolecule sugar alcohol exists
In fertilizer solution highly stable, will not with other salts produce antagonism problem, play and chelate well and transport
Effect；By sugar alcohol, aminoacid and the rational proportion relation of calcium salt, make sugar alcohol and calcium constituent chelating shape
Becoming firm little molecule chelate, the infiltration of sugar alcohol itself and wetting function, add its calcium chelated in addition
The absorption of element and conevying efficiency；Meanwhile, aminoacid is strong chelating agen, can be with calcium ion generation chela
Cooperation use, generates the chelate that dissolubility is good, the most absorbed by crops, and nutrient element is produced protective effect,
Improve its effectiveness, thus the beneficially crops absorption to calcium, moreover it is possible to promote photosynthesis, increase leaf green
Cellulose content；The present invention add sugar alcohol containing in aminoacid water-soluble fertilizer in sugar alcohol and amino acid whose comprehensive function
Under, its utilization rate is high, can increase the travelling speed of plant nutrient, and the absorption and the plant that increase Calcium in Plants are sugary
Amount.
Accompanying drawing explanation
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, below will be to enforcement
In example or description of the prior art, the required accompanying drawing used is briefly described, it should be apparent that, describe below
In accompanying drawing be only some embodiments of the present invention, for those of ordinary skill in the art, do not paying
On the premise of going out creative work, it is also possible to obtain other accompanying drawing according to these accompanying drawings.
Fig. 1 be the present invention add sugar alcohol containing sugar alcohol in aminoacid water-soluble fertilizer and the chelatropic reaction of calcium constituent
Schematic diagram；In figure, I is calcium constituent, and II is the little molecule of sugar alcohol, and III is chelate.
Detailed description of the invention
Below in conjunction with embodiments of the invention, technical scheme is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Base
Embodiment in the present invention, those of ordinary skill in the art are obtained under not making creative work premise
The every other embodiment obtained, broadly falls into the scope of protection of the invention.
Embodiment 1
Add sugar alcohol containing aminoacid water-soluble fertilizer, its raw material by 1B, calcium nitrate, natural sugar alcohol and
Water forms, and wherein, by weight percentage, the content of natural sugar alcohol is 8.3%；1B and calcium nitrate
Content, on the basis of the requirement meeting weight percentage proportioning, meets stepping on containing aminoacid water-soluble fertilizer simultaneously
Note technical specification, is i.e. not less than 10% containing the content of free amino acid in aminoacid water-soluble fertilizer, calcium unit
The content of element is not less than 30%, such as, and the 1B of 10%, the calcium nitrate of 56% and the water of 25.7%.
I.e. the present embodiment containing aminoacid water-soluble fertilizer, by weight percentage, its raw material can be by the sky of 8.3%
So water composition of sugar alcohol, the 1B of 10%, the calcium nitrate of 56% and 25.7%.
Preparation method is as follows: step one, by raw material form in comprise 8.3% sugar alcohol, the 1B of 10%,
The proportioning of the calcium nitrate of 56% and the water of 25.7% weighs sugar alcohol, 1B, calcium nitrate and water respectively；
Step 2, the 1B weighed in step one and water are mixed, heated and stirred, obtain aminoacid female
Liquid；It is subsequently adding potassium hydroxide and the pH value of span amino acid mother liquor is adjusted to 6～10, then add calcium nitrate,
Stirring and dissolving, obtains basis water-soluble fertilizer in aminoacid；
Step 3, the basis of step 2 water-soluble fertilizer in aminoacid is heated to 70～90 DEG C, is subsequently adding step
Rapid one sugar alcohol weighed, insulated and stirred, then filter, must add sugar alcohol containing aminoacid water-soluble fertilizer.
By the method for application in embodiment 4, the water-soluble fertilizer containing aminoacid of embodiment 1 is applied to Fructus Vitis viniferae (example
Such as Yunan border areas Fructus Vitis viniferae) on, the grape quality that this season is born significantly improves, and increases by 2 pols, and shedding is few,
Fruit type size uniformity.
Embodiment 2
Add sugar alcohol containing aminoacid water-soluble fertilizer, by weight percentage, its raw material can be by the natural sugar of 5%
The water composition of alcohol, the glycine of 20%, the calcium ammonium nitrate of 50% and 25%.
Consistent with described in embodiment 1 of preparation method.
By the method for application in embodiment 4, the water-soluble fertilizer containing aminoacid of embodiment 2 is applied to Fructus Vitis viniferae (example
Such as Yunan border areas Fructus Vitis viniferae) on, the grape quality that this season is born significantly improves, and increases by 0.8 pol, shedding
Few, fruit type size uniformity.
Embodiment 3
Add sugar alcohol containing aminoacid water-soluble fertilizer, by weight percentage, its raw material can by 10% natural
The water composition of sugar alcohol, the 1B of 10%, the calcium nitrate of 60% and 20%.
Consistent with described in embodiment 1 of preparation method.
By the method for application in embodiment 4, the water-soluble fertilizer containing aminoacid of embodiment 2 is applied to Fructus Vitis viniferae (example
Such as Yunan border areas Fructus Vitis viniferae) on, the grape quality that this season is born significantly improves, and increases by 1 pol, and shedding is few,
Fruit type size uniformity.
Embodiment 4
The present invention add sugar alcohol the method for application containing aminoacid water-soluble fertilizer: by add sugar alcohol containing amino
The molten Term Fertilization of sour water is in the growth of Fructus Vitis viniferae, in crop young fruit period, fruit expanding period, water-soluble fertilizer is dilute
After releasing 1500～2000 times, carry out foliage-spray.
The above, the only detailed description of the invention of the present invention, but protection scope of the present invention is not limited to
This, any those familiar with the art, in the technical scope that the invention discloses, can readily occur in
Change or replacement, all should contain within protection scope of the present invention.Therefore, protection scope of the present invention should
Described it is as the criterion with scope of the claims.
Claims (5)
1. add sugar alcohol containing aminoacid water-soluble fertilizer, it is characterised in that: described interpolation sugar alcohol containing aminoacid
The raw materials by weight of water-soluble fertilizer by 5%～10% the aminoacid of sugar alcohol, 10%～20%, 50%～
The calcium salt of 60% and the water composition of surplus.
Interpolation sugar alcohol the most according to claim 1 containing aminoacid water-soluble fertilizer, it is characterised in that: institute
State add sugar alcohol the raw materials by weight containing aminoacid water-soluble fertilizer by 8%～9% sugar alcohol, 10%～
The calcium salt of aminoacid, 54%～58% of 15% and the water composition of surplus.
Interpolation sugar alcohol the most according to claim 1 containing aminoacid water-soluble fertilizer, it is characterised in that: institute
State add sugar alcohol the raw materials by weight containing aminoacid water-soluble fertilizer by 8.3% sugar alcohol, the ammonia of 10%
The water composition of base acid, the calcium salt of 56% and 25.7%.
4. the preparation method containing aminoacid water-soluble fertilizer adding sugar alcohol as described in one of claims 1 to 3,
It is characterized in that: it is realized by following steps:
Step one, weigh sugar alcohol, aminoacid, calcium salt and water by raw material composition and ratio；
Step 2, aminoacid, calcium salt and water by weighing in step one, mixed dissolution, preparation obtains basis
Containing aminoacid water-soluble fertilizer；
Step 3, the basis of step 2 water-soluble fertilizer in aminoacid is heated to 70～90 DEG C, is subsequently adding step
Rapid one sugar alcohol weighed, insulated and stirred, then filter, must add sugar alcohol containing aminoacid water-soluble fertilizer.
The preparation method containing aminoacid water-soluble fertilizer of interpolation sugar alcohol the most according to claim 4, it is special
Levy and be: the basis configuration process containing aminoacid water-soluble fertilizer described in step 2 is as follows: step one weighed
Aminoacid and water mixing, heated and stirred, obtain span amino acid mother liquor；Then the pH value of span amino acid mother liquor is adjusted
Whole is 6～10, then adds calcium salt, stirring and dissolving, obtains basis water-soluble fertilizer in aminoacid.
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| CN104909901A (en) * | 2015-06-08 | 2015-09-16 | 京博农化科技股份有限公司 | Sugar alcohol chelator-amino acid calcium fertilizer and preparation method thereof |
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| CN108739019A (en) * | 2018-06-25 | 2018-11-06 | 山东省果树研究所 | A kind of method that salt-soda soil raises fruit trees |
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| CN110713415A (en) * | 2019-11-21 | 2020-01-21 | 河南心连心化学工业集团股份有限公司 | Water-soluble fertilizer containing neutralized bamboo vinegar for vegetables and preparation method thereof |
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Address after: Double high road Gaochun Economic Development Zone, Nanjing city of Jiangsu Province, No. 210000 86-4 Patentee after: Beyondchem Life Technology Ltd. Address before: Castle Village dam town of Gaochun County in Nanjing city in 211301 in Jiangsu Province Patentee before: Beyondchem Life Technology Ltd. |