CN105906206A - A glass bottle with good crack resistance and a preparing process thereof - Google Patents

A glass bottle with good crack resistance and a preparing process thereof Download PDF

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Publication number
CN105906206A
CN105906206A CN201610240541.0A CN201610240541A CN105906206A CN 105906206 A CN105906206 A CN 105906206A CN 201610240541 A CN201610240541 A CN 201610240541A CN 105906206 A CN105906206 A CN 105906206A
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CN
China
Prior art keywords
glass
vial
glass bottle
granule
dry
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610240541.0A
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Chinese (zh)
Inventor
王夕增
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI QIANLI GLASSWORK Co Ltd
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ANHUI QIANLI GLASSWORK Co Ltd
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Filing date
Publication date
Application filed by ANHUI QIANLI GLASSWORK Co Ltd filed Critical ANHUI QIANLI GLASSWORK Co Ltd
Priority to CN201610240541.0A priority Critical patent/CN105906206A/en
Publication of CN105906206A publication Critical patent/CN105906206A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B1/00Preparing the batches
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00Tempering or quenching glass products
    • C03B27/012Tempering or quenching glass products by heat treatment, e.g. for crystallisation; Heat treatment of glass products before tempering by cooling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Glass Compositions (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A glass bottle with good crack resistance is disclosed. The glass bottle is characterized in that the glass bottle is prepared from 200 g of waste glass, 20 g of sodium carbonate, 1.3 g of potassium carbonate, 4.6 g of barium carbonate, 15.4 g of borax, 3 g of foamed aluminum particles, 3 g of calcium oxide, 8 g of dolomite, 6.6 g of tourmaline, 0.5 g of ferric oxide, 2 g of zirconium silicate, 10 g of cordierite, 3.5 g of sepiolite, 4 g of phosphate ore particles, 1.5 g of pyrite concentrate, 2 g of agate stone particles, 0.2 g of graphene micro sheets, 1.5 g of sodium lignosulphonate and 1.5 of silicon nitride; the glass bottle adopts the waste glass as the main raw material, thus overcoming the problem that the waste glass is difficult to recover; through special preparation of raw materials, the prepared glass bottle is smooth in surface, beautiful in color and good in strength; and compared with traditional processes, the glass bottle is short in time, low in energy consumption, good in product quality and free of toxic and harmful compound residues.

Description

Vial that a kind of cracking resistance is good and preparation technology thereof
Technical field
The present invention relates to technical field of living goods, be specifically related to the good vial of a kind of cracking resistance and Preparation technology.
Background technology
The institutes of department such as glass is built widely because of the performance of its uniqueness, chemical industry, equipment, daily life Use, along with development and the development of other industry, building, door/window glass of automobile, the glass of building industry The various glass such as container, electrical type glass and vial are widely used in a large number in national economy so that useless Abandon glass substantial increase.On the other hand, unprecedented in Chinese large-sized infrastructure scale, natural aggregate is day by day Shortage, therefore under the situation that discarded glass discharge capacity increases the most day by day, scrap glass is substituted sky by research So gather materials to come the thought of concrete batching, meet the macro-economic strategy of sustainable development.
Summary of the invention
The technical problem to be solved is to provide a kind of color natural, and composition stable performance is anti- The vial that fragility energy is good.
The technical problem to be solved realizes by the following technical solutions:
The vial that a kind of cracking resistance is good, is made up of the component of following weight: discarded glass 200g, pure Alkali 20g, potassium carbonate 1.3g, brium carbonate 4.6g, Borax 15.4g, foamed aluminium granule 3g, calcium oxide 3g, Dolomite 8g, tourmaline 6.6g, ferrum oxide 0.5g, Zirconium orthosilicate. 2g, cordierite 10g, meerschaum 3.5g, Rock phosphate in powder granule 4g, pyrite concentrate 1.5g, Agate granule 2g, graphene microchip 0.2g, sodium lignosulfonate 1.5g, silicon nitride 1.5g;
The preparation technology of above-mentioned vial is as follows:
(1) collect discarded glass, classify according to different colours and quality, use Water spray mode pair Same class discarded glass carries out cleaning showers, washes away surface blot;The most again discarded glass is ground into Granular, send into cold wind drying plant, at temperature 50-55 DEG C, cold air drying 30-35 minute, makes glass Grain dry tack free is without moisture;Water after spray uses through precipitation flocculation Posterior circle;
(2) glass particle after cold air drying is sent into vacuum tumbler and carry out tumbling process, every during tumbling Every 5-8 minute evacuation once, exhaust tumbling 5-10 minute, then vacuum pumping after vacuum every time, so follow Ring 2-4 time, makes the impurity of glass surface start to decompose;
(3) glass particle after tumbling is taken out, put in water and soak 1.5-2 hour, then drag for filter screen Go out to drain the water, soak water and return first spray operation use;Process owing to have passed through tumbling, glass The foreign material on grain surface and oil stain are easy to fill to be washed off;
(4) glass particle after spray is drained away the water, send in drying plant and carry out drying and processing, dry Dry temperature controls at 55-60 DEG C, to glass particle surface without moisture;
(5) will dry after glass particle put into nylon ball grinder adds soda, potassium carbonate, brium carbonate, Borax, foamed aluminium granule, calcium oxide, dolomite, tourmaline, ferrum oxide, Zirconium orthosilicate., cordierite, Meerschaum, rock phosphate in powder granule, pyrite concentrate, Agate granule, graphene microchip, sodium lignosulfonate and nitrogen SiClx, continuous ball milling 4-6 hour, it is stand-by that collection obtains mixed powder;
(6) feed the mixture into dehydrator, dry at 60 DEG C, be then fed into smelting furnace, make whole material Carry out fusing mix homogeneously, obtain mother solution;
(7) mother solution is sent into forming machine, make the vial of the specification that varies in size, then by vial certainly Send into annealing kiln with conveyer after being so cooled to 600 DEG C of hardening, anneal complete;
(8) vial after annealing is sent into tempering case, first vial is heated to 750-900 DEG C, stops Only heating, sends into cold wind from all directions immediately, and after rapidly vial being cooled to room temperature, tempering terminates, Vial is taken out from tempering case, obtains finished product.
The invention has the beneficial effects as follows: the present invention uses discarded glass as major ingredient, solves discarded glass and returns The problem receiving difficulty, by the formulated to raw material, the vial mass color of preparation is sliding, beautiful in colour, Crack resistance is good, and compared with traditional handicraft, required time of the present invention is short, and energy consumption is low, and goods texture is good, nothing Harmful toxic matter remains.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
The vial that a kind of cracking resistance is good, is made up of the component of following weight: discarded glass 200g, pure Alkali 20g, potassium carbonate 1.3g, brium carbonate 4.6g, Borax 15.4g, foamed aluminium granule 3g, calcium oxide 3g, Dolomite 8g, tourmaline 6.6g, ferrum oxide 0.5g, Zirconium orthosilicate. 2g, cordierite 10g, meerschaum 3.5g, Rock phosphate in powder granule 4g, pyrite concentrate 1.5g, Agate granule 2g, graphene microchip 0.2g, sodium lignosulfonate 1.5g, silicon nitride 1.5g;
The preparation technology of above-mentioned vial is as follows:
(1) collect discarded glass, classify according to different colours and quality, use Water spray mode pair Same class discarded glass carries out cleaning showers, washes away surface blot;The most again discarded glass is ground into Granular, send into cold wind drying plant, at temperature 50-55 DEG C, cold air drying 30-35 minute, makes glass Grain dry tack free is without moisture;Water after spray uses through precipitation flocculation Posterior circle;
(2) glass particle after cold air drying is sent into vacuum tumbler and carry out tumbling process, every during tumbling Every 5-8 minute evacuation once, exhaust tumbling 5-10 minute, then vacuum pumping after vacuum every time, so follow Ring 2-4 time, makes the impurity of glass surface start to decompose;
(3) glass particle after tumbling is taken out, put in water and soak 1.5-2 hour, then drag for filter screen Go out to drain the water, soak water and return first spray operation use;Process owing to have passed through tumbling, glass The foreign material on grain surface and oil stain are easy to fill to be washed off;
(4) glass particle after spray is drained away the water, send in drying plant and carry out drying and processing, dry Dry temperature controls at 55-60 DEG C, to glass particle surface without moisture;
(5) will dry after glass particle put into nylon ball grinder adds soda, potassium carbonate, brium carbonate, Borax, foamed aluminium granule, calcium oxide, dolomite, tourmaline, ferrum oxide, Zirconium orthosilicate., cordierite, Meerschaum, rock phosphate in powder granule, pyrite concentrate, Agate granule, graphene microchip, sodium lignosulfonate and nitrogen SiClx, continuous ball milling 4-6 hour, it is stand-by that collection obtains mixed powder;
(6) feed the mixture into dehydrator, dry at 60 DEG C, be then fed into smelting furnace, make whole material Carry out fusing mix homogeneously, obtain mother solution;
(7) mother solution is sent into forming machine, make the vial of the specification that varies in size, then by vial certainly Send into annealing kiln with conveyer after being so cooled to 600 DEG C of hardening, anneal complete;
(8) vial after annealing is sent into tempering case, first vial is heated to 750-900 DEG C, stops Only heating, sends into cold wind from all directions immediately, and after rapidly vial being cooled to room temperature, tempering terminates, Vial is taken out from tempering case, obtains finished product.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention, The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model In enclosing.Claimed scope is defined by appending claims and equivalent thereof.

Claims (1)

1. the vial that a cracking resistance is good, it is characterised in that be made up of the component of following weight: useless Old glass 200g, soda 20g, potassium carbonate 1.3g, brium carbonate 4.6g, Borax 15.4g, foamed aluminium granule 3g, calcium oxide 3g, dolomite 8g, tourmaline 6.6g, ferrum oxide 0.5g, Zirconium orthosilicate. 2g, cordierite 10g, Meerschaum 3.5g, rock phosphate in powder granule 4g, pyrite concentrate 1.5g, Agate granule 2g, graphene microchip 0.2g, Sodium lignosulfonate 1.5g, silicon nitride 1.5g;
The preparation technology of above-mentioned vial is as follows:
(1) collect discarded glass, classify according to different colours and quality, use Water spray mode pair Same class discarded glass carries out cleaning showers, washes away surface blot;The most again discarded glass is ground into Granular, send into cold wind drying plant, at temperature 50-55 DEG C, cold air drying 30-35 minute, makes glass Grain dry tack free is without moisture;
(2) glass particle after cold air drying is sent into vacuum tumbler and carry out tumbling process, every during tumbling Every 5-8 minute evacuation once, exhaust tumbling 5-10 minute, then vacuum pumping after vacuum every time, so follow Ring 2-4 time, makes the impurity of glass surface start to decompose;
(3) glass particle after tumbling is taken out, put in water and soak 1.5-2 hour, then drag for filter screen Go out to drain the water, soak water and return first spray operation use;
(4) glass particle after spray is drained away the water, send in drying plant and carry out drying and processing, dry Dry temperature controls at 55-60 DEG C, to glass particle surface without moisture;
(5) will dry after glass particle put into nylon ball grinder adds soda, potassium carbonate, brium carbonate, Borax, foamed aluminium granule, calcium oxide, dolomite, tourmaline, ferrum oxide, Zirconium orthosilicate., cordierite, Meerschaum, rock phosphate in powder granule, pyrite concentrate, Agate granule, graphene microchip, sodium lignosulfonate and nitrogen SiClx, continuous ball milling 4-6 hour, it is stand-by that collection obtains mixed powder;
(6) feed the mixture into dehydrator, dry at 60 DEG C, be then fed into smelting furnace, make whole material Carry out fusing mix homogeneously, obtain mother solution;
(7) mother solution is sent into forming machine, make the vial of the specification that varies in size, then by vial certainly Send into annealing kiln with conveyer after being so cooled to 600 DEG C of hardening, anneal complete;
(8) vial after annealing is sent into tempering case, first vial is heated to 750-900 DEG C, stops Only heating, sends into cold wind from all directions immediately, and after rapidly vial being cooled to room temperature, tempering terminates, Vial is taken out from tempering case, obtains finished product.
CN201610240541.0A 2016-04-15 2016-04-15 A glass bottle with good crack resistance and a preparing process thereof Pending CN105906206A (en)

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
CN105906206A true CN105906206A (en) 2016-08-31

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106526712A (en) * 2016-12-05 2017-03-22 安徽长庚光学科技有限公司 Strong-pressure-resistant optical lens for submarine detection, and preparation process thereof
CN106526713A (en) * 2016-12-05 2017-03-22 安徽长庚光学科技有限公司 High-definition optical lens and preparation process thereof
CN106587605A (en) * 2016-12-21 2017-04-26 柳州市昌泉贸易有限公司 Anti-smashing glass bottle and production method thereof
CN106680902A (en) * 2016-12-05 2017-05-17 安徽长庚光学科技有限公司 Optical lens without optical return and preparation technology thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101148317A (en) * 2007-08-22 2008-03-26 东营力诺玻璃制品有限责任公司 Formula of medicinal neutral borosilicate glass
CN102849948A (en) * 2012-09-29 2013-01-02 济南大学 Waste glass slag reutilization method and obtained glass

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101148317A (en) * 2007-08-22 2008-03-26 东营力诺玻璃制品有限责任公司 Formula of medicinal neutral borosilicate glass
CN102849948A (en) * 2012-09-29 2013-01-02 济南大学 Waste glass slag reutilization method and obtained glass

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106526712A (en) * 2016-12-05 2017-03-22 安徽长庚光学科技有限公司 Strong-pressure-resistant optical lens for submarine detection, and preparation process thereof
CN106526713A (en) * 2016-12-05 2017-03-22 安徽长庚光学科技有限公司 High-definition optical lens and preparation process thereof
CN106680902A (en) * 2016-12-05 2017-05-17 安徽长庚光学科技有限公司 Optical lens without optical return and preparation technology thereof
CN106680902B (en) * 2016-12-05 2018-07-13 安徽长庚光学科技有限公司 Without light loss optical lens and its preparation process
CN106526712B (en) * 2016-12-05 2018-08-03 安徽老蛙光学科技有限公司 Resistance to for habitata suppresses optical lens and its preparation process
CN106526713B (en) * 2016-12-05 2018-08-03 安徽老蛙光学科技有限公司 High-resolution optical lens and its preparation process
CN106587605A (en) * 2016-12-21 2017-04-26 柳州市昌泉贸易有限公司 Anti-smashing glass bottle and production method thereof

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Application publication date: 20160831