CN105887107B - A kind of efficient environmental-protection engine aqueous rinsing liquid - Google Patents
A kind of efficient environmental-protection engine aqueous rinsing liquid Download PDFInfo
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- CN105887107B CN105887107B CN201610237874.8A CN201610237874A CN105887107B CN 105887107 B CN105887107 B CN 105887107B CN 201610237874 A CN201610237874 A CN 201610237874A CN 105887107 B CN105887107 B CN 105887107B
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
- C23G1/26—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions using inhibitors
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Abstract
The invention discloses a kind of efficient environmental-protection engine aqueous rinsing liquids, by weight comprising following component and content: 6-10 parts of low-foam wetting agents；4-8 parts of polyoxyethylene stearic acid ester；3-6 parts of C10 fatty alcohol ether of isomery alcohol；3-5 parts of sodium secondary alkyl sulfonate；3-5 parts of linear alkyl benzene sulfonic acid；1-3 parts of coconut oleoyl amine MEA；1-3 parts of sodium xylene sulfonate；1-2 parts of dodecyl benzyl dimethyl ammonium chloride；0.5-1 parts of sodium benzoate；0.5-1 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid；0.5-1 parts of aminotrimethylenephosphonic acid；1.5-2 parts of sodium hydroxide；60-70 parts of water.Efficient environmental-protection engine aqueous rinsing liquid cleaning effect of the invention is good, scavenging period is short, high-efficient.
Description
Technical field
The present invention relates to surface clean fields, and in particular to a kind of efficient environmental-protection engine aqueous rinsing liquid.
Background technique
Currently used cleaning means are usually to carry out soaking and washing with strong acid and strong base, although can clean up in this way,
But inevitably engine apparatus is caused to damage in the process of cleaning, meanwhile, this cleaning way, to environment
Pollution and the harm of human body are all bigger.With the development of economy, awareness of safety of the people to the protection of environment and human body itself
It is more strong.The cleaning solution cleaning effect of existing cleaning engine is poor, and scavenging period is long, and low efficiency, chemicals content are big.
Summary of the invention
In order to solve the above technical problems, it is an object of the invention to propose that a kind of cleaning effect is good, scavenging period is short, efficiency
High efficient environmental-protection engine aqueous rinsing liquid.
Used technical solution are as follows:
A kind of efficient environmental-protection engine aqueous rinsing liquid, by weight comprising following component and content:
6-10 parts of low-foam wetting agents；
4-8 parts of polyoxyethylene stearic acid ester；
3-6 parts of C10 fatty alcohol ether of isomery alcohol；
3-5 parts of sodium secondary alkyl sulfonate；
3-5 parts of linear alkyl benzene sulfonic acid；
1-3 parts of coconut oleoyl amine MEA；
1-3 parts of sodium xylene sulfonate；
1-2 parts of dodecyl benzyl dimethyl ammonium chloride；
0.5-1 parts of sodium benzoate；
0.5-1 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid；
0.5-1 parts of aminotrimethylenephosphonic acid；
1.5-2 parts of sodium hydroxide；
60-70 parts of water.
Preferably, by weight comprising following component and content:
8 parts of low-foam wetting agents；
6 parts of polyoxyethylene stearic acid ester；
5 parts of fatty alcohol ether of isomery alcohol C10；
4 parts of sodium secondary alkyl sulfonate；
4 parts of linear alkyl benzene sulfonic acid；
2 parts of coconut oleoyl amine MEA；
2 parts of sodium xylene sulfonate；
1 part of dodecyl benzyl dimethyl ammonium chloride；
0.5 part of sodium benzoate；
0.5 part of 1-hydroxy ethylidene-1,1-diphosphonic acid；
0.5 part of aminotrimethylenephosphonic acid；
1.5 parts of sodium hydroxide；
65 parts of water.
When preparation, above-mentioned formula each component is added in water in sequence, high-efficiency environment friendly hair can be prepared by stirring evenly
Motivation aqueous rinsing liquid.
Compared with prior art, the beneficial effects of the present invention are:
1, far super 5 times of similar product or more of dirt-removing power；
2, colorless and odorless, be free of any pigment, essence；
3, water-soluble products are free of any solvent, decontamination noresidue；
4, product is environment friendly and pollution-free, will not damage to environment；
5, cleaning effect is good, scavenging period is short, high-efficient.
Specific embodiment
Below by specific embodiment, the present invention is described in detail, but the purposes of these exemplary embodiments and
Purpose is only used to enumerate the present invention, not constitutes any type of any restriction to real protection scope of the invention, more non-to incite somebody to action
Protection scope of the present invention is confined to this.
Embodiment 1
A kind of efficient environmental-protection engine aqueous rinsing liquid, by weight comprising following component and content:
6 parts of low-foam wetting agents；
4 parts of polyoxyethylene stearic acid ester；
3 parts of fatty alcohol ether of isomery alcohol C10；
3 parts of sodium secondary alkyl sulfonate；
3 parts of linear alkyl benzene sulfonic acid；
1 part of coconut oleoyl amine MEA；
1 part of sodium xylene sulfonate；
1 part of dodecyl benzyl dimethyl ammonium chloride；
0.5 part of sodium benzoate；
0.5 part of 1-hydroxy ethylidene-1,1-diphosphonic acid；
0.5 part of aminotrimethylenephosphonic acid；
1.5 parts of sodium hydroxide；
60 parts of water.
Wherein, the surfactant of the preferred low-foam wetting agents CF-10 of low-foam wetting agents, Tao Shi DOW TRITON, belong to
Nonionic surfactant, transparency liquid have splendid wetability, improve the dispersion performance of dispersing agent.
Polyoxyethylene stearic acid ester, No. CAS is 9004-99-3, has excellent emulsification, dispersion, solubilising, antistatic, profit
Sliding, thickening capabilities.Low bubble.With excellent calcium and magnesium dispersibility.It can act synergistically with low-foam wetting agents CF-10.
Isomery alcohol C10 fatty alcohol ether, also known as isomery C10 fatty alcohol ether, belong to nonionic surfactant.By C10-
The alkyl polyoxyethylene ether that the pure and mild ethylene oxide,1,2-epoxyethane of Guerbet is constituted.It meets following rules:
RO(CH2CH2O)XH, R=C10H21；X=3,5,7,8,9,10,14.
It is with extremely low gel tendency, good emulsifier, excellent dynamic characteristic and complete biodegradable characteristic.
Sodium secondary alkyl sulfonate has good decontamination and emulsifying ability, and resistance to hard water and foaming power are good, and biological degradability is splendid,
It is anionic surfactant.And there is extremely strong penetration under highly basic, hot conditions, have both emulsification, de-oiling, washing function
Energy.It is good with yin, nonionic surfactant compatibility, it is remarkably improved the application effect of formula.
Linear alkyl benzene sulfonic acid (linear-Alkylbenzenesulfonic Acid), alias: dodecyl benzene sulfonic acid,
Molecular formula C18H30O3S, molecular weight 326.49 are organic monoacid, are used as surfactant to exist in formula.
Coconut oleoyl amine MEA is made of the fatty acid that coconut oil and ethanol amine mix, it is the waxy substance of white.It can be with
As thickener, foaming agent and emulsifier.Its effect is to make formula thickening and opaque, and enhances the cleaning of surfactant
Ability.
Sodium xylene sulfonate, as solubilized conditioner, for making the other components of formula preferably mix.Diformazan can be passed through
It is produced after benzene sulfonation with liquid alkaline neutralization.Such as by dimethylbenzene sulfuric acid sulfonation, xylene monosulfonic acid is obtained, then neutralizes to obtain dimethylbenzene with liquid alkaline
Sodium sulfonate crude product, then through decoloration, concentration, crystallization, separation, get product.
Dodecyl benzyl dimethyl ammonium chloride alias: 1227, benzalkonium chloride, alkyldimethylbenzylammonium chloride DDBAC, geramine, benzene bundle chlorine
Ammonium (medical grade), dodecyl benzyl dimethyl ammonium chloride, molecular formula: C21H38NCl, relative molecular mass: 340.00.1227
It is a kind of cationic surfactant, belongs to non oxidizing bactericide, there is wide spectrum, efficient sterilization algae removal ability, it can be effectively
Bacterium algae breeding and foundry loam growth in water are controlled, and there is good sludge stripping effect and certain dispersion, osmosis, simultaneously
With it is certain deoil, deodorizing capability and corrosion inhibition.
Sodium benzoate is soluble easily in water, is used as fungicide and preservative in formula.
1-hydroxy ethylidene-1,1-diphosphonic acid (HEDP) is a kind of organic phosphorus acids anti-incrustation corrosion inhibitor, can be with a variety of gold such as iron, copper, zinc
Belong to ion and form stable complex compound, the oxide of metal surface can be dissolved.
Aminotrimethylenephosphonic acid (Amino Trimethylene Phosphonic Acid, ATMP), name: amino trimethylene first
Base phosphonic acids；Relative molecular mass: 299.05, ATMP have good chelating, lower bound inhibition and distortion of lattice effect.It can prevent water
Middle scaling salt class forms the formation of scale, especially calcium carbonate scale.ATMP in water stablize by chemical property, not facile hydrolysis.In water
When middle concentration is higher, there is good corrosion mitigating effect.The aminotrimethylenephosphonic acid (ATMP) and 1-hydroxy ethylidene-1,1-diphosphonic acid (HEDP) are assisted
Same-action, the chelating agent as metal ion.
Sodium hydroxide can be used as alkaline cleaner in water process, and as the effect for adjusting pH value, entire for being turned up
The pH value of formula.
To reduce impurity, the preferred deionized water of water.
When preparation, above-mentioned formula each component is added in water in sequence, multifunctional efficient can be prepared by stirring evenly
Environmentally friendly heavy oil dirt detergent.
Embodiment 2
Referring to embodiment 1, unlike the first embodiment, it is formulated as follows:
A kind of efficient environmental-protection engine aqueous rinsing liquid, by weight comprising following component and content:
8 parts of low-foam wetting agents；
6 parts of polyoxyethylene stearic acid ester；
5 parts of fatty alcohol ether of isomery alcohol C10；
4 parts of sodium secondary alkyl sulfonate；
4 parts of linear alkyl benzene sulfonic acid；
2 parts of coconut oleoyl amine MEA；
2 parts of sodium xylene sulfonate；
1 part of dodecyl benzyl dimethyl ammonium chloride；
0.5 part of sodium benzoate；
0.5 part of 1-hydroxy ethylidene-1,1-diphosphonic acid；
0.5 part of aminotrimethylenephosphonic acid；
1.5 parts of sodium hydroxide；
65 parts of water.
Embodiment 3
Referring to embodiment 1, unlike the first embodiment, it is formulated as follows:
A kind of efficient environmental-protection engine aqueous rinsing liquid, by weight comprising following component and content:
10 parts of low-foam wetting agents；
8 parts of polyoxyethylene stearic acid ester；
6 parts of fatty alcohol ether of isomery alcohol C10；
5 parts of sodium secondary alkyl sulfonate；
5 parts of linear alkyl benzene sulfonic acid；
3 parts of coconut oleoyl amine MEA；
3 parts of sodium xylene sulfonate；
2 parts of dodecyl benzyl dimethyl ammonium chloride；
1 part of sodium benzoate；
1 part of 1-hydroxy ethylidene-1,1-diphosphonic acid；
1 part of aminotrimethylenephosphonic acid；
2 parts of sodium hydroxide；
70 parts of water.
By efficient environmental-protection engine aqueous rinsing liquid made from embodiment 1 to embodiment 3, detected, test method is adopted
It is tested with corresponding national standard (such as cleaning ability uses GB/T 31027-2014), testing result is referring to such as the following table 1:
Table 1
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (2)
1. a kind of efficient environmental-protection engine aqueous rinsing liquid, which is characterized in that by weight comprising following component and contain
Amount:
6-10 parts of low-foam wetting agents CF-10；
4-8 parts of polyoxyethylene stearic acid ester；
3-6 parts of C10 fatty alcohol ether of isomery alcohol；
3-5 parts of sodium secondary alkyl sulfonate；
3-5 parts of linear alkyl benzene sulfonic acid；
1-3 parts of coconut oleoyl amine MEA；
1-3 parts of sodium xylene sulfonate；
1-2 parts of dodecyl benzyl dimethyl ammonium chloride；
0.5-1 parts of sodium benzoate；
0.5-1 parts of 1-hydroxy ethylidene-1,1-diphosphonic acid；
0.5-1 parts of aminotrimethylenephosphonic acid；
1.5-2 parts of sodium hydroxide；
60-70 parts of water.
2. efficient environmental-protection engine aqueous rinsing liquid as described in claim 1, which is characterized in that by weight comprising
Following component and content:
8 parts of low-foam wetting agents CF-10；
6 parts of polyoxyethylene stearic acid ester；
5 parts of fatty alcohol ether of isomery alcohol C10；
4 parts of sodium secondary alkyl sulfonate；
4 parts of linear alkyl benzene sulfonic acid；
2 parts of coconut oleoyl amine MEA；
2 parts of sodium xylene sulfonate；
1 part of dodecyl benzyl dimethyl ammonium chloride；
0.5 part of sodium benzoate；
0.5 part of 1-hydroxy ethylidene-1,1-diphosphonic acid；
0.5 part of aminotrimethylenephosphonic acid；
1.5 parts of sodium hydroxide；
65 parts of water.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610237874.8A CN105887107B (en) | 2016-04-15 | 2016-04-15 | A kind of efficient environmental-protection engine aqueous rinsing liquid |
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| CN201610237874.8A CN105887107B (en) | 2016-04-15 | 2016-04-15 | A kind of efficient environmental-protection engine aqueous rinsing liquid |
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| CN105887107A CN105887107A (en) | 2016-08-24 |
| CN105887107B true CN105887107B (en) | 2019-03-12 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107904609A (en) * | 2017-12-05 | 2018-04-13 | 苏州市宽道模具机械有限公司 | A kind of normal temperature metal degreaser and preparation method thereof |
| CN108950574A (en) * | 2018-08-03 | 2018-12-07 | 广州正利金属表面处理剂有限公司 | Without phosphorus low bubble degreasing agent and preparation method thereof, application method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1056904A (en) * | 1990-05-30 | 1991-12-11 | 李洪耀 | High efficiency clening agent for engine of vehicle |
| CN101468351A (en) * | 2007-12-27 | 2009-07-01 | 川化股份有限公司 | Method for removing fat from large-sized equipment using ultrasonic technology at normal temperature |
-
2016
- 2016-04-15 CN CN201610237874.8A patent/CN105887107B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1056904A (en) * | 1990-05-30 | 1991-12-11 | 李洪耀 | High efficiency clening agent for engine of vehicle |
| CN101468351A (en) * | 2007-12-27 | 2009-07-01 | 川化股份有限公司 | Method for removing fat from large-sized equipment using ultrasonic technology at normal temperature |
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Effective date of registration: 20190203 Address after: 366000 Nige Road 2233, Nige High-tech Development Zone, Yongan City, Sanming City, Fujian Province Applicant after: Fujian Chunjie Green Technology Co., Ltd. Address before: 350000 Gulou District, Fuzhou City, Fujian Province, No. 6, No. 7, No. 603 Applicant before: Zhang Xiangming |
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