CN105062711A - Anti-microbial and anti-corrosion industrial cleaning fluid - Google Patents

Anti-microbial and anti-corrosion industrial cleaning fluid Download PDF

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Publication number
CN105062711A
CN105062711A CN201510414856.8A CN201510414856A CN105062711A CN 105062711 A CN105062711 A CN 105062711A CN 201510414856 A CN201510414856 A CN 201510414856A CN 105062711 A CN105062711 A CN 105062711A
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parts
solution
deionized water
triazine
corrosion
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CN201510414856.8A
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龚灿锋
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龚灿锋
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Priority to CN201510414856.8A priority Critical patent/CN105062711A/en
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Abstract

The invention relates to an anti-microbial and anti-corrosion industrial cleaning fluid. The anti-microbial and anti-corrosion industrial cleaning fluid comprises components in parts by mass as follows: 10-20 parts of ethoxyl aminopropyl polydimethylsiloxane, 20-30 parts of sym-triazine, 20-30 parts of HDTMPA, 10-20 parts of oxirane, 2-methyl-, polymer with oxirane, mono(2-propylheptyl) ether, 60-70 parts of N-sodium lauryl sarcosinate, 30-40 parts of sorbitan monopalmitate, 30-40 parts of 1-hydroxyethyl-2-tridecanyl imidazoline, 10-20 parts of potassiam polyoxyethylene laurylether phosphate, 10-20 parts of T203 and 100-200 parts of deionized water. The anti-microbial and anti-corrosion industrial cleaning fluid is suitable for cleaning industrial products, after cleaning, the surfaces are glossy and are not darkened, and the cleaning fluid has no corrosion effect on the surfaces of the industrial products; the cleaning fluid has high degreasing capacity and good cleaning effect, is non-toxic and nonflammable, has the anti-microbial and anti-oxidative effects, is simple and convenient to use and reduces pollution and the cleaning cost.

Description

The corrosion-resistant scavenging solution of industrial antimicrobial
Technical field
The present invention relates to the corrosion-resistant scavenging solution of a kind of industrial antimicrobial, belong to cleaning technique field.
Background technology
The visual plant that the enterprises such as various condenser, interchanger and strainer, reverse osmosis equipment etc. are iron and steel, metallurgy, electric power, chemical industry, papermaking, food, pharmacy, weaving extensively adopt.This equipment, in operational process, due to water quality and difference variation, very easily causes interior pipe scale formation, thus greatly reduces heat exchange and the filtration efficiency of equipment, causes shutting down stopping production.Traditional method is generally manual cleaning, high-pressure washing and matting, not only cleaning performance is poor, very easily causes corrosion and damage to metal tube and screen cloth, shortens the work-ing life of equipment, accelerate the buying replacement cycle of equipment, cause tremendous economic to lose to user.
Summary of the invention
The object of the present invention is to provide the corrosion-resistant scavenging solution of a kind of industrial antimicrobial, to provide a kind of scavenging solution carrying out cleaning better for Industrial products, to the non-corrosive effect in the surface of Industrial products; This scavenging solution degrease ability is strong, and cleaning performance is good; Nontoxic, nonflammable; Easy to use, decreasing pollution, reduces cleaning cost.
To achieve these goals, technical scheme of the present invention is as follows.
The corrosion-resistant scavenging solution of a kind of industrial antimicrobial, consist of the following composition according to the mass fraction: 10 ~ 20 parts of oxyethyl group aminopropyl polydimethylsiloxanes, 20 ~ 30 parts of triazine s-triazine, 20 ~ 30 parts of hexapotassium, 10 ~ 20 parts of ethylhexanol polyoxyethylene polyoxypropylene ethers, 60 ~ 70 parts of N-acyl group musculamine acid sodium, 30 ~ 40 parts of sorbitol anhydride cetylates, 30 ~ 40 parts of hydroxyethyl tetradecanoic acid tetrahydroglyoxalines, 20 ~ 40 parts of N-acyl group musculamine acid sodium, 10 ~ 20 parts of lauryl alcohol phosphoric acid ester potassium, 10 ~ 20 parts of two pungent primary alkyl zinc salts of sulphur phosphorus, 100 ~ 200 parts of deionized waters.
Further; the corrosion-resistant scavenging solution of above-mentioned industrial antimicrobial; consist of the following composition according to the mass fraction: 15 parts of oxyethyl group aminopropyl polydimethylsiloxanes; 25 parts of triazine s-triazine; 25 parts of hexapotassium; 15 parts of ethylhexanol polyoxyethylene polyoxypropylene ethers; 65 parts of N-acyl group musculamine acid sodium; 35 parts of sorbitol anhydride cetylates; 35 parts of hydroxyethyl tetradecanoic acid tetrahydroglyoxalines, 30 parts of N-acyl group musculamine acid sodium, 15 parts of lauryl alcohol phosphoric acid ester potassium; 15 parts of two pungent primary alkyl zinc salts of sulphur phosphorus, 150 parts of deionized waters.
Above-mentioned scavenging solution preparation method is as follows:
(1) deionized water of above-mentioned mass fraction is divided into trisection, is respectively deionized water A, deionized water B and deionized water C, is heated to 60 ~ 80 DEG C respectively;
(2) in deionized water A, add the oxyethyl group aminopropyl polydimethylsiloxane of above-mentioned mass fraction, triazine s-triazine, hexapotassium and ethylhexanol polyoxyethylene polyoxypropylene ether, stir 30 ~ 60 minutes, be cooled to 40 ~ 60 DEG C, obtain solution A;
(3) in deionized water B, add N-acyl group musculamine acid sodium and the sorbitol anhydride cetylate of above-mentioned mass fraction, stir 30 ~ 60 minutes, be cooled to 40 ~ 60 DEG C, obtain B solution;
(4) in deionized water C, add the leftover materials of above-mentioned mass fraction, stir 30 ~ 60 minutes, be cooled to 40 ~ 60 DEG C, obtain C solution;
(5) above-mentioned solution A, B solution and C solution are mixed, stirred, be cooled to room temperature, namely obtained this product.
(1) oxyethyl group aminopropyl polydimethylsiloxane: there is excellent antistatic, dispersion, adsorptive power.Defoamer.Brightening agent.
(2) triazine s-triazine: efficient, wide spectrum, there is dual function that is antibacterial and sterilization.Compatibility is good, does not affect the physicalies such as the colourity of paper, intensity, corrosion-free to equipment.In larger pH value range effectively, the activity that can maintain a long-term stability.Addition is little, rapid-action, and sterilizing power is strong.Environment-friendly type " green product ".As metal working fluid, the metal finishing of electroplating industry, tackiness agent, industrial additive, polymeric dispersant and lubricant.
(3) hexapotassium: inhibitor, can suppress the generation of various incrustation scale.
(4) ethylhexanol polyoxyethylene polyoxypropylene ether: as stain remover, dispersion agent, emulsifying agent etc., is widely used in the fields such as personal-care supplies, household washing, industry cleaning link, weaving, leather, chemical fibre.As wetting agent, permeate agent etc., be applied to the industries such as weaving, fiber.As levelling agent etc., be applied to the fields such as weaving, printing and dyeing.
(5) N-acyl group musculamine acid sodium: having good synergy with cats product, reach higher flotation efficiency, is novel amino analog anion surfactants; There is the characteristics such as washing, emulsification, infiltration, solubilising; Superior foaminess, and foam is fine and smooth, lasting, be suitable for make toothpaste and makeup foaming agent, shampoo, painting cream of shaving raw material; There is antibiotic and sterilizing, mildew-resistant and anticorrosive, antistatic effect; Low toxicity, low irritant; Biological degradability is good, environmentally safe; Inhibiter, rust remover etc. is made in intermetallic composite coating.
(6) sorbitol anhydride cetylate: as emulsifying agent, lubricant, wetting agent, dispersion agent, thickening material etc.
(7) hydroxyethyl tetradecanoic acid tetrahydroglyoxaline: amphoterics, outward appearance is milky white liquid, have that surface tension is low, lathering property is excellent, nontoxic, to character such as skin and eye irritation, readily biodegradable, anti-hard water.Foam is fine and smooth, and stability is high.
(8) lauryl alcohol phosphoric acid ester potassium: for washing the anion surfactant of class articles for use, have excellent skin compatibility, mainly as anion surfactant or the co-surfactant on basis.Distinctive mildness and extremely strong wetting capacity; Lather quickness is fast, and foamy structure is evenly fine and smooth; Soluble in water-organic-compound system, can with water by arbitrarily than mixing, and solubleness is temperature influence not; Can be made into the aqueous solution that transparency is high; Easily and ether alcohol sulfate, lauryl sulfate and other various types of tensio-active agent compatibility; Ph stability is good.
(9) the two pungent primary alkyl zinc salt of sulphur phosphorus: there is anti-oxidant, wear-resistant and anticorrosive effect.There is good thermostability and hydrolysis stability.
This beneficial effect of the invention is: product of the present invention is applicable to the clean of Industrial products, and clean rear surface is glossy does not send out crow, to the non-corrosive effect in the surface of Industrial products; This scavenging solution degrease ability is strong, and cleaning performance is good; Nontoxic, nonflammable; Have antibacterial, antioxidant effect, easy to use, decreasing pollution, reduces cleaning cost.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described, better to understand the present invention.
embodiment 1
The corrosion-resistant scavenging solution of industrial antimicrobial in the present embodiment; consist of the following composition according to the mass fraction: 10 parts of oxyethyl group aminopropyl polydimethylsiloxanes; 20 parts of triazine s-triazine; 20 parts of hexapotassium; 10 parts of ethylhexanol polyoxyethylene polyoxypropylene ethers; 60 parts of N-acyl group musculamine acid sodium; 30 parts of sorbitol anhydride cetylates; 30 parts of hydroxyethyl tetradecanoic acid tetrahydroglyoxalines; 20 parts of N-acyl group musculamine acid sodium; 10 parts of lauryl alcohol phosphoric acid ester potassium, 10 parts of two pungent primary alkyl zinc salts of sulphur phosphorus, 100 parts of deionized waters.
Above-mentioned scavenging solution preparation method is as follows:
(1) deionized water of above-mentioned mass fraction is divided into trisection, is respectively deionized water A, deionized water B and deionized water C, is heated to 60 DEG C respectively;
(2) in deionized water A, add the oxyethyl group aminopropyl polydimethylsiloxane of above-mentioned mass fraction, triazine s-triazine, hexapotassium and ethylhexanol polyoxyethylene polyoxypropylene ether, stir 30 minutes, be cooled to 40 DEG C, obtain solution A;
(3) in deionized water B, add N-acyl group musculamine acid sodium and the sorbitol anhydride cetylate of above-mentioned mass fraction, stir 30 minutes, be cooled to 40 DEG C, obtain B solution;
(4) in deionized water C, add the leftover materials of above-mentioned mass fraction, stir 30 minutes, be cooled to 40 DEG C, obtain C solution;
(5) above-mentioned solution A, B solution and C solution are mixed, stirred, be cooled to room temperature, namely obtained this product.
embodiment 2
The corrosion-resistant scavenging solution of industrial antimicrobial in the present embodiment; consist of the following composition according to the mass fraction: 15 parts of oxyethyl group aminopropyl polydimethylsiloxanes; 25 parts of triazine s-triazine; 25 parts of hexapotassium; 15 parts of ethylhexanol polyoxyethylene polyoxypropylene ethers; 65 parts of N-acyl group musculamine acid sodium; 35 parts of sorbitol anhydride cetylates; 35 parts of hydroxyethyl tetradecanoic acid tetrahydroglyoxalines; 30 parts of N-acyl group musculamine acid sodium; 15 parts of lauryl alcohol phosphoric acid ester potassium, 15 parts of two pungent primary alkyl zinc salts of sulphur phosphorus, 150 parts of deionized waters.
Above-mentioned scavenging solution preparation method is as follows:
(1) deionized water of above-mentioned mass fraction is divided into trisection, is respectively deionized water A, deionized water B and deionized water C, is heated to 70 DEG C respectively;
(2) in deionized water A, add the oxyethyl group aminopropyl polydimethylsiloxane of above-mentioned mass fraction, triazine s-triazine, hexapotassium and ethylhexanol polyoxyethylene polyoxypropylene ether, stir 45 minutes, be cooled to 50 DEG C, obtain solution A;
(3) in deionized water B, add N-acyl group musculamine acid sodium and the sorbitol anhydride cetylate of above-mentioned mass fraction, stir 45 minutes, be cooled to 50 DEG C, obtain B solution;
(4) in deionized water C, add the leftover materials of above-mentioned mass fraction, stir 45 minutes, be cooled to 50 DEG C, obtain C solution;
(5) above-mentioned solution A, B solution and C solution are mixed, stirred, be cooled to room temperature, namely obtained this product.
embodiment 3
The corrosion-resistant scavenging solution of industrial antimicrobial in the present embodiment; consist of the following composition according to the mass fraction: 20 parts of oxyethyl group aminopropyl polydimethylsiloxanes; 30 parts of triazine s-triazine; 30 parts of hexapotassium; 20 parts of ethylhexanol polyoxyethylene polyoxypropylene ethers; 70 parts of N-acyl group musculamine acid sodium; 40 parts of sorbitol anhydride cetylates; 40 parts of hydroxyethyl tetradecanoic acid tetrahydroglyoxalines; 40 parts of N-acyl group musculamine acid sodium; 20 parts of lauryl alcohol phosphoric acid ester potassium, 20 parts of two pungent primary alkyl zinc salts of sulphur phosphorus, 200 parts of deionized waters.
Above-mentioned scavenging solution preparation method is as follows:
(1) deionized water of above-mentioned mass fraction is divided into trisection, is respectively deionized water A, deionized water B and deionized water C, is heated to 80 DEG C respectively;
(2) in deionized water A, add the oxyethyl group aminopropyl polydimethylsiloxane of above-mentioned mass fraction, triazine s-triazine, hexapotassium and ethylhexanol polyoxyethylene polyoxypropylene ether, stir 60 minutes, be cooled to 60 DEG C, obtain solution A;
(3) in deionized water B, add N-acyl group musculamine acid sodium and the sorbitol anhydride cetylate of above-mentioned mass fraction, stir 60 minutes, be cooled to 60 DEG C, obtain B solution;
(4) in deionized water C, add the leftover materials of above-mentioned mass fraction, stir 60 minutes, be cooled to 60 DEG C, obtain C solution;
(5) above-mentioned solution A, B solution and C solution are mixed, stirred, be cooled to room temperature, namely obtained this product.
Scavenging solution of the present invention has extremely strong cleaning force, and cleaning force (4%, 70 DEG C) experiment reaches more than 99%; Corrodibility is weak, is 0 grade to the corrosion test outward appearance of Industrial products product, and etching extent Industrial products product is 0.5mg.In addition, after being used by above-described embodiment scavenging solution, after giving standing 5 ~ 10 hours, the scavenging solution that can continue to take out its top is continued to use.The Industrial products product pipe scavenging solution of Example 3, carries out performance test, test event and method as follows:
Visual inspection: undertaken by the 4th chapter of JB/T4323.2-1999.
Cleaning force is tested: undertaken (iron 70 ± 2 DEG C, artificial greasy dirt, be only applicable to clean-out system) by the 6th chapter of JB/T4323.2-1999.
Corrosion test: undertaken (70 ± 2 DEG C) by the 9th chapter of JB/T4323.2-1999.
Defoaming is tested: undertaken (after 30 ± 2 DEG C of 10min residual foam height) by the 10th chapter of JB/T4323.2-1999.
High/low temperature stability test: undertaken by the 13rd chapter of JB/T4323.2-1999.
Rinsability test: undertaken (65 ± 2 DEG C, only applicable clean-out system) by the 14th chapter of JB/T4323.2-1999.
Rust-preventing characteristic is tested: undertaken by the 8th chapter of JB/T4323.2-1999.
Test result is as shown in the table.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.

Claims (3)

1. the corrosion-resistant scavenging solution of industrial antimicrobial; it is characterized in that: consist of the following composition according to the mass fraction: 10 ~ 20 parts of oxyethyl group aminopropyl polydimethylsiloxanes; 20 ~ 30 parts of triazine s-triazine; 20 ~ 30 parts of hexapotassium; 10 ~ 20 parts of ethylhexanol polyoxyethylene polyoxypropylene ethers; 60 ~ 70 parts of N-acyl group musculamine acid sodium; 30 ~ 40 parts of sorbitol anhydride cetylates; 30 ~ 40 parts of hydroxyethyl tetradecanoic acid tetrahydroglyoxalines; 10 ~ 20 parts of lauryl alcohol phosphoric acid ester potassium; 10 ~ 20 parts of two pungent primary alkyl zinc salts of sulphur phosphorus, 100 ~ 200 parts of deionized waters.
2. the corrosion-resistant scavenging solution of industrial antimicrobial according to claim 1, it is characterized in that: the corrosion-resistant scavenging solution of described industrial antimicrobial, consist of the following composition according to the mass fraction: 15 parts of oxyethyl group aminopropyl polydimethylsiloxanes, 25 parts of triazine s-triazine, 25 parts of hexapotassium, 15 parts of ethylhexanol polyoxyethylene polyoxypropylene ethers, 65 parts of N-acyl group musculamine acid sodium, 35 parts of sorbitol anhydride cetylates, 35 parts of hydroxyethyl tetradecanoic acid tetrahydroglyoxalines, 30 parts of N-acyl group musculamine acid sodium, 15 parts of lauryl alcohol phosphoric acid ester potassium, 15 parts of two pungent primary alkyl zinc salts of sulphur phosphorus, 150 parts of deionized waters.
3. the corrosion-resistant scavenging solution of industrial antimicrobial according to claim 1 and 2, is characterized in that: described scavenging solution preparation method is as follows:
(1) deionized water of above-mentioned mass fraction is divided into trisection, is respectively deionized water A, deionized water B and deionized water C, be heated to about 60 ~ 80 DEG C respectively;
(2) in deionized water A, add the oxyethyl group aminopropyl polydimethylsiloxane of above-mentioned mass fraction, triazine s-triazine, hexapotassium and ethylhexanol polyoxyethylene polyoxypropylene ether, stir about 30 ~ 60 minutes, be cooled to 40 ~ 60 DEG C, obtain solution A;
(3) in deionized water B, add N-acyl group musculamine acid sodium and the sorbitol anhydride cetylate of above-mentioned mass fraction, stir 30 ~ 60 minutes, be cooled to about 40 ~ 60 DEG C, obtain B solution;
(4) in deionized water C, add the leftover materials of above-mentioned mass fraction, stir about 30 ~ 60 minutes, be cooled to 40 ~ 60 DEG C, obtain C solution;
(5) above-mentioned solution A, B solution and C solution are mixed, stirred, be cooled to room temperature, namely obtained this product.
CN201510414856.8A 2015-07-15 2015-07-15 Anti-microbial and anti-corrosion industrial cleaning fluid Pending CN105062711A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107674775A (en) * 2017-11-07 2018-02-09 邵莹 Bag type filtering machine filter core cleaning fluid

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0673573A (en) * 1991-11-23 1994-03-15 Fmc Corp Uk Ltd Corrosion- and/or scale-preventive composition
CN104278287A (en) * 2014-09-25 2015-01-14 巢湖广丰金属制品有限公司 Corrosion-inhibition type water-based metal cleaner

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0673573A (en) * 1991-11-23 1994-03-15 Fmc Corp Uk Ltd Corrosion- and/or scale-preventive composition
CN104278287A (en) * 2014-09-25 2015-01-14 巢湖广丰金属制品有限公司 Corrosion-inhibition type water-based metal cleaner

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107674775A (en) * 2017-11-07 2018-02-09 邵莹 Bag type filtering machine filter core cleaning fluid

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Application publication date: 20151118