CN105886997B - A kind of printing machine anilox roll preparation method based on plasma spray technology - Google Patents

A kind of printing machine anilox roll preparation method based on plasma spray technology Download PDF

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CN105886997B
CN105886997B CN201510039377.2A CN201510039377A CN105886997B CN 105886997 B CN105886997 B CN 105886997B CN 201510039377 A CN201510039377 A CN 201510039377A CN 105886997 B CN105886997 B CN 105886997B
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coating
anilox roll
spraying
printing machine
method based
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CN105886997A (en
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袁建辉
于治水
李东
秦优琼
马春伟
任江伟
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Suzhou Zhongpeng Technology Co ltd
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Shanghai University of Engineering Science
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Abstract

The present invention relates to a kind of printing machine anilox roll preparation method based on plasma spray technology, using hollow heavy wall roller or solid roll as matrix, matrix is cleaned, degreasing and rust removal and surface coarsening;Metal coating is prepared in matrix surface using heat spraying method;Ceramic coating is prepared in metal coating surface using heat spraying method;One layer of cylindrical screen is tightly fastened in ceramic coating surface;Ceramic powders are continued to spray on the surface by screen cloth masking using heat spraying method, spray gun removes screen cloth after scanning 5 15 times, multiple salient points of coating surface formation rule arrangement, that is, anilox roll is made.The anilox roll matrix deformation that the present invention is handled is small, and heat affected area is very shallow;Material selection is extensive, and roll surface hardness it is larger (>70HRC), the service life of anilox roll can be effectively improved, while this method technique is simple, is applicable not only to prepare novel anilox roller, is equally useful for the reparation to waste and old anilox roll, plays energy-saving effect.

Description

A kind of printing machine anilox roll preparation method based on plasma spray technology
Technical field
The present invention relates to printing machine anilox roll technical field of surface, more particularly, to a kind of based on plasma spray technology Printing machine anilox roll preparation method.
Background technology
Flexible version printing has turned into a kind of mode of printing of most vitality in packages printing.For many years, anilox roll is claimed For " heart " of flexographic printing process, in flexible version printing, anilox roll controls the transfer of ink in printing press, and it is not only controlled The storage capacity of liquefaction ink, moreover it is possible to make conveying capacity balanced, the final class and uniformity for controlling printing quality.
Traditional anilox roll preparation method is as follows:
Rolling process:Rolling process processing ink cell it is similar with common annular knurl, hobboing cutter body surface face cut forward-reverse spiral line formed and Raised site corresponding to required anilox roll ink cell.Make hobboing cutter with anilox roll roll body combined pressure to be processed to rolling on lathe, Can cold rolling complete ink cell processing.
Electronic engraving method:It is similar with the electronic engraving Method And Principle of gravure cylinder.
The process of both approaches is:Roll body preprocessing (material is 45 steel) → electro-coppering (making reticulate pattern layers of copper) → Before plating post-processing (making roller surface reach the requirement of processing reticulate pattern) processing of → reticulate pattern (rolling or electronic engraving) → chromium plating at degreasing Manage (enhancing coating adhesion) → chromium plating process (raising anti-wear performance).No. 45 steel of material selection of this method, heavier-weight, electricity The chromium for plating raw material is Cr VI, and the symptoms such as pneumosclerosis, pulmonary emphysema, nausea, and Cr VI chemical combination occurs after sucking human body Thing be the plating solution such as carcinogen, copper, hydrochloric acid, sulfuric acid, sodium hydroxide can to artificial into various diseases, prepared by both approaches Anilox roll is heavier, and pole is not environmentally in process.
Laser engraving method:It is that laser beam is etched processing as power to reticulate pattern roller surface.Anilox roll is in laser First with the method for plasma spraying by metal oxide (Al before engraving2O3、Cr2O3Or alumina-titanium) it is sprayed on metalling roll surface Ceramic membrane firmly, fine and close is formed, is then made ceramic vaporization with laser engraving, the high-energy of laser and is formed ink cell. The process of laser engraving ceramic anilox roller is:The finishing of roll body preprocessing (material is 45 steel) → roll body (reaches roller surface To ceramic coated requirement) and → spray ceramics → grinding → polishing → laser engraving reticulate pattern (because surface is ceramic layer, its wearability It is very high).This anilox roll or heavier, although process has abolished the electroplating technology of pole not environmentally, but workhardness is very big Ceramic material can not be carved using electronic engraving equipment, it is necessary to it is high using laser engraving, cost.Therefore develop a kind of new The anilox roll preparation method of type has important economic implications.
Thermal spraying is a kind of conventional surface treatment technology of material, can be prepared using heat spraying method in reticulate pattern roller surface Go out the wear-resisting and excellent coating of corrosion resistance, and thermal spraying has and do not limited by workpiece size and construction site, deposits effect Rate is higher and the characteristics of heat affecting to matrix material is small, can be not only used for preparing novel anilox roller, is equally useful for useless The reparation of old anilox roll, integrated cost are relatively low.It is current to complete the whole technology made of anilox roll also not using heat spraying method Appear in the newspapers, main reasons is that not addressing how also to prepare in reticulate pattern roller surface using heat spraying method equally distributed micro- Small shrinkage pool or salient point.
Chinese patent CN202370993U is disclosed and a kind of composite roller, including interior tube layer, middle close binder, spray Coating, interior tube layer are roller matrix or base sleeve;Middle close binder spiral wound and the outer surface for being fixed on interior tube layer;In Between the outer thermal jet of binder course scribble sprayed coating.Obtained composite roller is made not limited by steel or aluminium-alloy pipe section bar specification System, the metal of any required size or guiding (or conduction, transmission) roller, anilox roll, the set of ceramic roll surface can be made Cartridge type anilox roll, it is widely used in printing, packs, weaves, dyeing apparatus or other association areas.Although employ thermal spraying structure Into sprayed coating, but the composite roller is still without solving the problems, such as how small shrinkage pool or salient point are formed on surface.
The content of the invention
Carved it is an object of the present invention to overcome the above-mentioned drawbacks of the prior art and provide one kind has with laser The equal performance of ceramic anilox roller is carved, but technique is relatively easy, energy-conserving and environment-protective, and integrated cost is relatively low based on thermal spraying skill The printing machine anilox roll preparation method of art.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of printing machine anilox roll preparation method based on plasma spray technology, using following steps:
(1) using hollow heavy wall roller or solid roll as matrix, matrix is cleaned, degreasing and rust removal and surface coarsening;
(2) metal coating is prepared in matrix surface using heat spraying method;
(3) ceramic coating is prepared in metal coating surface using heat spraying method;
(4) it is tightly fastened one layer of cylindrical screen in ceramic coating surface.
(5) ceramic powders are continued to spray on the surface by screen cloth masking using heat spraying method, spray gun scanning 5- Screen cloth is removed after 15 times, multiple salient points of coating surface formation rule arrangement, that is, anilox roll is made.
Preferably, the method for coarsening surface described in step (1) includes sandblasting, cutting thread, annular knurl or electric wharf's pavement quality.
Preferably, heat spraying method includes HVAF, detonation flame spraying, plasma spraying, flame-spraying or electricity Arc spraying method.
More preferred, the heat spraying method described in step (2) is supersonic flame spraying method, and its spray parameters is: Combustion-supporting gas, combustion gas and to aid in the pressure of gas be respectively 16~20bar, 3~6bar and 5~8bar, flow is respectively 300~ 800slpm, 50~70slpm and 300~500slpm, powder feeding atmospheric pressure are 3~9bar, and flow is 10~20slpm, and powder feeding is fast Rate is 40~150g/min, and spray distance is 150~300mm.
The metal coating obtained by thermal spraying for NiCr, NiCrBSi, NiAl, NiCrAl, NiCrBSiFe or NiCrBSiMoFe coatings, thickness are 80 μm~150 μm.
More preferred, the heat spraying method described in step (3) is plasma spraying method, and its spray parameters is:It is main The pressure of gas and auxiliary gas is respectively 3~5bar and 1~3bar, and flow is respectively 30~50slpm and 2~4slpm;Powder feeding air pressure Power is 0.5~1bar, and flow is 2~4slpm, and powder feeding rate is 20~100g/min;In spraying process electric current be 450~ 750A, voltage are 50~70V, and spray distance is 100~120mm.
The ceramic coating obtained by thermal spraying is Cr2O3、Al2O3, ZrO2、TiO2Or Cr3C2One kind or several in coating Kind, thickness is 200 μm~500 μm.
More preferred, the heat spraying method described in step (5) is plasma spraying method, and its spray parameters is:It is main The pressure of gas and auxiliary gas is respectively 3~5bar and 1~3bar, and flow is respectively 30~50slpm and 2~4slpm;Powder feeding air pressure Power is 0.5~1bar, and flow is 2~4slpm, and powder feeding rate is 20~100g/min;In spraying process electric current be 450~ 750A, voltage are 50~70V, and spray distance is 100~120mm.
The printing machine anilox roll novel processing step based on plasma spray technology has that technique is simple, integrated cost in the present invention Relatively low, production efficiency is high and the advantages of suitable for industrialization, alternative now widely used laser engraving technique, using this method The anilox roll matrix deformation of processing is small, and heat affected area is very shallow;Material selection is extensive, and roll surface hardness it is larger (>70HRC), can be with Effectively improve the service life of anilox roll.This method technique is simple simultaneously, is applicable not only to prepare novel anilox roller, equally also may be used For the reparation to waste and old anilox roll, energy-saving effect is played, is to meet national recycling economy and the strategy of sustainable development Green manufacture technology, have broad application prospects and economic benefit.
The present invention is tightly fastened one layer of cylindrical screen in ceramic coating surface in advance, and ceramic powders then are continued into thermal jet It is coated onto on the surface by screen cloth masking, spraying 5-15 removes screen cloth after, due to the part bridging effect of screen cloth, in sieve aperture portion Position occurs powder deposition and turns into salient point, and powder deposition does not occur by the position that screen cloth covers and turns into concave point, therefore, this method The regularly arranged salient point and concave point of ceramic coating and coating surface of reticulate pattern roller surface can be directly prepared by thermal spraying, is saved Laser engraving step conventional at this stage has been omited, has been had the following advantages that:
(1) metal coating and the bond strength of reticulate pattern roller surface are high, can effectively prevent coming off using process floating coat;Pottery Porcelain coating hardness is high, and abrasion resistance properties are good, can preferably bear the fretting wear being subjected to during anilox roll work, significantly extend it Service life.
(2) equipment and technique used in are relatively easy, and easily operated, production efficiency is higher, and not by anilox roll size and The limitation of construction site, suitable for the preparation of novel anilox roller and the reparation of waste and old anilox roll.
Brief description of the drawings
It is the technical process schematic diagram for preparing printing machine anilox roll in the present invention using heat spraying method that Fig. 1, which is,;
Fig. 2 is the microstructure figure after obtained anilox roll coating cross sections polishing in embodiment 1.
Embodiment
The present invention is described in detail with specific embodiment below in conjunction with the accompanying drawings.
In order to characterize the performance of anilox roll surface ceramic coat of the present invention, fluorescence metallographic microscope, cupping machine are utilized Resulting coating sample is characterized with microhardness testers, is specific performance test methods below.
(1) coating microhardness method of testing:
Polished after the cross section of coating sample is inlayed, the microhardness of coatings cross-section measured using digital display sclerometer, Added load is 300g, dwell time 10s.Hardness calculation formula is:
In formula:P --- added load;
D --- impression catercorner length;
α --- the square opposite face angle of four corner angle pyramid indenter two (being defined as 136 °).
5 points of each sample testing, last hardness take its average value.
(2) anchoring strength of coating method of testing:
The performance test is carried out according to national standard G98642-88 (measure of thermally sprayed coating bond strength).The material of tensile sample Matter is common Q235 steel, through turnery processing into a diameter of 25.4mm, highly the cylindrical standard sample for 30mm.Specific experiment Step is as follows:By sample mating plate A, B blasting treatment, test specimen end face A is equably sprayed to thermal spraying composite coating of the invention, Then test specimen A, B part are bonded with E-7 glue, and A test specimens is placed on B test specimens, make it coaxial, heated by 100 DEG C, 1h solid After change, test specimen is clipped on material universal test machine clamp, stretched with 1mm/min speed, writes down and is applied when breaking The magnitude of load added, while observation is when breaking, the peeling conditions of test specimen end coating.Every kind of coating carries out the stretching of more than five times Test, bond strength take its average value.
Embodiment 1
In the present embodiment, reticulate pattern roller coating is by NiCrBSi coatings and Cr successively outward from matrix surface2O3Coating forms, The NiCrBSi coating layer thicknesses are 90 μm, Cr2O3Coating layer thickness is 350 μm.NiCrBSi coatings are by commercially available 15~45 μm NiCrBSi powder is prepared through heat spraying method, Cr2O3Coating is by commercially available 10~40 μm of Cr2O3Powder is through thermal spraying side Method is prepared, and the specific preparation method of the anilox roll is as follows:
1st, before spraying, matrix is cleaned, carries out surface sand-blasting pretreatment using 20 mesh alloy sands after degreasing and rust removal, is made Its roughness reaches spraying and required;
2nd, NiCrBSi coatings are sprayed first, using supersonic flame spraying method, control the spray of HVAF rifle Applying parameter is:Combustion-supporting gas O2, combustion gas propane and compressed air pressure be respectively 10bar, 6bar, 7bar, flow is respectively 240slpm, 70slpm, 380slpm, powder feeding gas N2Flow is 15slpm, and powder transfer rate is 40g/min, and spray distance is 250mm.Then Cr is sprayed2O3Coating, using plasma spraying method, the spray parameters are controlled to be:Main gas Ar and auxiliary gas H2Pressure Respectively 4bar and 2bar, flow are respectively 40slpm and 3slpm;Powder feeding atmospheric pressure is 0.5bar, flow 3slpm, powder feeding Speed is 40g/min;Electric current is 600A in spraying process, and voltage 60V, spray distance is 110mm (in such as Fig. 1 shown in (1)). The stainless steel mesh of 150 mesh is tightly fixed to Cr2O3Coating surface (in such as Fig. 1 shown in (2)), finally using same as described above Plasma Spray Parameters by Cr2O3Powder spray to the coating surface (in such as Fig. 1 shown in (3)) by screen cloth masking, sweep by spray gun Screen cloth is removed after retouching 7 times, equally distributed salient point (in such as Fig. 1 shown in (4)) is formed in coating surface, that is, completes the system of anilox roll It is standby.
Following performance test is carried out to the above-mentioned reticulate pattern roller coating being prepared:
1. coating microhardness:Cr is measured using coating microhardness method of testing2O3The average hardness of coating is 1255.7HV(75.1HRC)。
2. anchoring strength of coating:Using anchoring strength of coating method of testing, drawn experiment measures coating in the cementing conjunctions of E7 Break at place, the results showed that the bond strength of coating is more than 70MPa.
Fig. 2 is the cross-section morphology figure of obtained reticulate pattern roller coating in the present embodiment, as seen from the figure, micro- group of coating Knit very dense uniform, exist the defects of non-microcracked and hole, this is the original that repair layer has higher hardness and bond strength Cause, meanwhile, coating surface forms equally distributed microscopic bumps.
Embodiment 2
In the present embodiment, reticulate pattern roller coating is by NiAl coatings and Cr successively outward from matrix surface2O3Coating forms, should NiAl coating layer thicknesses are 100 μm, Cr2O3Coating layer thickness is 380 μm.NiAl coatings are by commercially available 15~45 μm of NiAl powder warp Heat spraying method is prepared, Cr2O3Coating is by commercially available 10~40 μm of Cr2O3Powder is prepared through heat spraying method.
The specific preparation method of above-mentioned reticulate pattern roller coating is identical with the preparation method in embodiment 1, except that, powder It is NiAl and Cr respectively2O3Powder, obtain anilox roll face coat.
Following performance test is carried out to the above-mentioned reticulate pattern roller coating being prepared:
1. coating microhardness:Cr is measured using coating microhardness method of testing2O3The average hardness of coating is 1335.1HV(76.4HRC)。
2. anchoring strength of coating:Using anchoring strength of coating method of testing, drawn experiment measures coating in the cementing conjunctions of E7 Break at place, the results showed that the bond strength of coating is more than 70MPa.
Embodiment 3
In the present embodiment, reticulate pattern roller coating is by NiCrBSi coatings and Al successively outward from matrix surface2O3Coating forms, The NiCrBSi coating layer thicknesses are 75 μm, Al2O3Coating layer thickness is 300 μm.NiCrBSi coatings are by commercially available 15~45 μm NiCrBSi powder is prepared through heat spraying method, Al2O3Coating is by commercially available 10~40 μm of Al2O3Powder is through thermal spraying side Method is prepared.
The specific preparation method of above-mentioned reticulate pattern roller coating is identical with the preparation method in embodiment 1, except that, powder It is NiCrBSi and Al respectively2O3Powder, obtain anilox roll face coat.
Following performance test is carried out to the above-mentioned reticulate pattern roller coating being prepared:
1. coating microhardness:Al is measured using coating microhardness method of testing2O3The average hardness of coating is 1175.4HV(73.7HRC)。
2. anchoring strength of coating:Using anchoring strength of coating method of testing, drawn experiment measures coating in the cementing conjunctions of E7 Break at place, the results showed that the bond strength of coating is more than 70MPa.
Embodiment 4
In the present embodiment, reticulate pattern roller coating is by NiCrBSi coatings and Al successively outward from matrix surface2O3-13TiO2 (ω t%) coating forms, and the NiCrBSi coating layer thicknesses are 125 μm, Al2O3-13TiO2(ω t%) coating layer thickness is 400 μm. NiCrBSi coatings are to be prepared by commercially available 15~45 μm of NiCrBSi powder through heat spraying method, Al2O3-13TiO2(ω T%) coating is by commercially available 10~40 μm of Al2O3-13TiO2(ω t%) powder is prepared through heat spraying method.
The specific preparation method of above-mentioned reticulate pattern roller coating is identical with the preparation method in embodiment 1, except that, powder It is NiCrBSi and Al respectively2O3-13TiO2(ω t%) powder, obtains anilox roll face coat.
Following performance test is carried out to the above-mentioned reticulate pattern roller coating being prepared:
1. coating microhardness:Al is measured using coating microhardness method of testing2O3-13TiO2(ω t%) coating is put down Equal hardness is 1185.1HV (73.9HRC).
2. anchoring strength of coating:Using anchoring strength of coating method of testing, drawn experiment measures coating in the cementing conjunctions of E7 Break at place, the results showed that the bond strength of coating is more than 70MPa.
Embodiment 5
In the present embodiment, reticulate pattern roller coating is by NiCrBSi coatings and Cr successively outward from matrix surface2O3Coating forms, The NiCrBSi coating layer thicknesses are 95 μm, Cr2O3Coating layer thickness is 340 μm.NiCrBSi coatings are by commercially available 15~45 μm NiCrBSi powder is prepared through heat spraying method, Cr2O3Coating is by commercially available 10~40 μm of Cr2O3Powder is through thermal spraying side Method is prepared, and the specific preparation method of the anilox roll is as follows:
1st, before spraying, matrix is cleaned, carries out surface sand-blasting pretreatment using 20 mesh alloy sands after degreasing and rust removal, is made Its roughness reaches spraying and required;
2nd, NiAl coatings are sprayed first, and using detonation flame spraying method, the spray parameters for controlling detonation flame spraying rifle are:Combustion-supporting gas O2, combustion gas C2H2With powder feeding gas N2Pressure be respectively 11.5bar, 12bar and 11.5bar, flow be respectively 55slpm, 26slpm and 25slpm, powder feeding rate 45g/min, spray distance 180mm.Then Cr is sprayed2O3Coating, using plasma Spraying method, controls the spray parameters to be:Main gas Ar and auxiliary gas H2Pressure be respectively 4bar and 2bar, flow is respectively 40slpm and 3slpm;Powder feeding atmospheric pressure is 0.5bar, flow 3slpm, powder feeding rate 40g/min;Electric current in spraying process For 600A, voltage 60V, spray distance 110mm.The stainless steel mesh of 150 mesh is tightly fixed to Cr2O3Coating surface, most Plasma Spray Parameters same as described above are used afterwards by Cr2O3Powder spray is swept to the coating surface by screen cloth masking, spray gun Screen cloth is removed after retouching 9 times, equally distributed salient point is formed in coating surface, that is, completes the preparation of anilox roll.
Following performance test is carried out to the above-mentioned reticulate pattern roller coating being prepared:
1. coating microhardness:Cr is measured using coating microhardness method of testing2O3The average hardness of coating is 1206.8HV(74.3HRC)。
2. anchoring strength of coating:Using anchoring strength of coating method of testing, drawn experiment measures coating in the cementing conjunctions of E7 Break at place, the results showed that the bond strength of coating is more than 70MPa.
Embodiment 6
In the present embodiment, reticulate pattern roller coating is by NiCrBSi coatings and Cr successively outward from matrix surface2O3Coating forms, The NiCrBSi coating layer thicknesses are 95 μm, Cr2O3Coating layer thickness is 340 μm.NiCrBSi coatings are by commercially available 15~45 μm NiCrBSi powder is prepared through heat spraying method, Cr2O3Coating is by commercially available 10~40 μm of Cr2O3Powder is through thermal spraying side Method is prepared.
The specific preparation method of above-mentioned reticulate pattern roller coating is identical with the preparation method in embodiment 1, except that, screen cloth It is the stainless steel mesh of 600 mesh, obtains anilox roll face coat.
Following performance test is carried out to the above-mentioned reticulate pattern roller coating being prepared:
1. coating microhardness:Cr is measured using coating microhardness method of testing2O3The average hardness of coating is 1235.4HV(74.8HRC)。
2. anchoring strength of coating:Using anchoring strength of coating method of testing, drawn experiment measures coating in the cementing conjunctions of E7 Break at place, the results showed that the bond strength of coating is more than 70MPa.
Technical scheme and beneficial effect are described in detail embodiment described above, it should be understood that The specific embodiment of the present invention is the foregoing is only, is not intended to limit the invention, it is all to be done in the spirit of the present invention Any modification, supplement and equivalent substitution etc., should be included in the scope of the protection.

Claims (10)

1. a kind of printing machine anilox roll preparation method based on plasma spray technology, it is characterised in that this method uses following steps:
(1) using hollow heavy wall roller or solid roll as matrix, matrix is cleaned, degreasing and rust removal and surface coarsening;
(2) metal coating is prepared in matrix surface using heat spraying method;
(3) ceramic coating is prepared in metal coating surface using heat spraying method;
(4) it is tightly fastened one layer of cylindrical screen in ceramic coating surface;
(5) ceramic powders are continued to spray on the surface by screen cloth masking using heat spraying method, spray gun scans 5-15 times After remove screen cloth, multiple salient points of coating surface formation rule arrangement, that is, anilox roll is made.
A kind of 2. printing machine anilox roll preparation method based on plasma spray technology according to claim 1, it is characterised in that Method for coarsening surface described in step (1) includes sandblasting, cutting thread, annular knurl or electric wharf's pavement quality.
A kind of 3. printing machine anilox roll preparation method based on plasma spray technology according to claim 1, it is characterised in that Described heat spraying method includes HVAF, detonation flame spraying, plasma spraying, flame-spraying or electric arc spraying side Method.
A kind of 4. printing machine anilox roll preparation method based on plasma spray technology according to claim 1, it is characterised in that Heat spraying method described in step (2) is supersonic flame spraying method, and its spray parameters is:Combustion-supporting gas, combustion gas and auxiliary gas Pressure be respectively 16~20bar, 3~6bar and 5~8bar, flow is respectively 300~800slpm, 50~70slpm and 300 ~500slpm, powder feeding atmospheric pressure are 3~9bar, and flow is 10~20slpm, and powder feeding rate is 40~150g/min, spray away from From for 150~300mm.
A kind of 5. printing machine anilox roll preparation method based on plasma spray technology according to claim 1, it is characterised in that Described metal coating is NiCr, NiCrBSi, NiAl, NiCrAl, NiCrBSiFe or NiCrBSiMoFe coating.
A kind of 6. printing machine anilox roll preparation method based on plasma spray technology according to claim 1, it is characterised in that The thickness of described metal coating is 80 μm~150 μm.
A kind of 7. printing machine anilox roll preparation method based on plasma spray technology according to claim 1, it is characterised in that Heat spraying method described in step (3) is plasma spraying method, and its spray parameters is:The pressure of main gas and auxiliary gas is respectively 3~5bar and 1~3bar, flow are respectively 30~50slpm and 2~4slpm;Powder feeding atmospheric pressure is 0.5~1bar, and flow is 2~4slpm, powder feeding rate are 20~100g/min;Electric current is 450~750A in spraying process, and voltage is 50~70V, spraying Distance is 100~120mm.
A kind of 8. printing machine anilox roll preparation method based on plasma spray technology according to claim 1, it is characterised in that Described ceramic coating is Cr2O3、Al2O3, ZrO2、TiO2Or Cr3C2One or more in coating.
A kind of 9. printing machine anilox roll preparation method based on plasma spray technology according to claim 1, it is characterised in that The thickness of described ceramic coating is 200 μm~500 μm.
10. a kind of printing machine anilox roll preparation method based on plasma spray technology according to claim 1, its feature exist In the heat spraying method described in step (5) is plasma spraying method, and its spray parameters is:The pressure of main gas and auxiliary gas point Not Wei 3~5bar and 1~3bar, flow is respectively 30~50slpm and 2~4slpm;Powder feeding atmospheric pressure is 0.5~1bar, stream It is 20~100g/min to measure as 2~4slpm, powder feeding rate;Electric current is 450~750A in spraying process, and voltage is 50~70V, Spray distance is 100~120mm.
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CN106756719A (en) * 2016-12-01 2017-05-31 郴州市泰益表面涂层技术有限公司 A kind of coupling coating with high-intensity high-tenacity and preparation method thereof
CN108468012A (en) * 2018-03-25 2018-08-31 王秀兰 Fabric guide roll surface wear-resistant layer spraying process
CN109082623B (en) * 2018-07-27 2020-09-04 芜湖通潮精密机械股份有限公司 Method for manufacturing salient points on surface of lower electrode by dry etching
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