CN105885526A - Color-changing floor with temperature sensing material - Google Patents
Color-changing floor with temperature sensing material Download PDFInfo
- Publication number
- CN105885526A CN105885526A CN201610400497.5A CN201610400497A CN105885526A CN 105885526 A CN105885526 A CN 105885526A CN 201610400497 A CN201610400497 A CN 201610400497A CN 105885526 A CN105885526 A CN 105885526A
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- temperature
- floor
- paint
- microcapsule powder
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/26—Thermosensitive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to a color-changing floor with a temperature sensing material. The color-changing floor is characterized in that the floor is coated with solvent type ink with temperature-sensing color changing microcapsule powder or water-soluble primer to achieve temperature-sensing color changing; the solvent type ink is prepared from, by weight, 25-50 parts of resin, 3-5 parts of temperature-sensing microcapsule powder, 2-5 parts of flatting agent, 1-2 parts of dispersing agent, 5-20 parts of filler and 0.1-1.5 parts of ultraviolet absorber; the water-soluble primer is prepared from, by mass, 25-50 parts of resin, water-soluble adhesive agent, 3-5 parts of temperature-sensing microcapsule powder, 80-150 parts of solvent water, 0.3-1 part of dispersing agent, 1-3 parts of flatting agent and 5-8 parts of pigment. The floor has the sensory effect that different colors are changed along with temperature changes, people have different feelings through different colors, the sentiment of people can be effectively influenced, the comfort degree can be improved, and the function of monitoring indoor and floor surface temperature is achieved.
Description
Technical field
The present invention relates to a kind of color changing floor with temperature sensing paint, belong to Environmental protection floor field.
Background technology
It is to protect floor body that floor is coated with decoration paint, is impregnated with pollutes with dirty thing from mechanical friction, direct sunlight, moisture, improve service life and the value thereof on floor to greatest extent.Heat discoloration coating is to utilize the change of temperature to control the change of color.As CN103113766A discloses a kind of heat discoloration ceramic coating and coating, described heat discoloration ceramic coating is made up of Ludox, organosilan, catalyst, inorganic variable color powder and organic variable color powder, gained heat discoloration coating can occur according to the change of temperature significantly changing, and has good wearability.CN104470296A discloses a kind of heat discoloration rack, the present invention relates to a kind of rack and scribbles temperature-sensing color-changing material on cabinet door, changes color when cabinet temperature is too high.Convenient and practical, stability is high, with low cost, is with a wide range of applications.
As can be seen here, heat discoloration coating has been widely used in industrial monitoring, decoration, food, clothes show business, but rarely have the case being applied to floor, the present invention provides a kind of floor heat discoloration coating, with this coating, floor is covered with paint, lacquer, colour wash, etc., not only enrich the kind on floor, promote the added value on floor；Also achieve the innovation of floor kind, improve the aesthetic property on floor and functional；Floor is made to have good economic benefit and social benefit.
Summary of the invention
It is an object of the invention to provide a kind of color changing floor with temperature sensing paint, floor is made to have the sensory effects varying with temperature and converting different color, different colours is utilized to make people produce different sensation, can not only effectively mould the sentiment of people, moreover it is possible to improve comfort level and Control Room is interior and the effect of floor surface temperature.
For achieving the above object, the invention provides following technical scheme, a kind of color changing floor with temperature sensing paint, it is characterised in that: solvent type ink or aqueous priming paint with heat discoloration microcapsule powder are covered with paint, lacquer, colour wash, etc. floor and are realized floor heat discoloration；
Solvent type ink is made up of following raw material by weight: resin 25 ~ 50 parts, temperature-sensitive microcapsule powder 3 ~ 5 parts, levelling agent 2 ~ 5 parts, dispersant 1 ~ 2 part, filler 5 ~ 20 parts, and described UV absorbers is 0.1 ~ 1.5 part；Aqueous priming paint is made up of aqueous adhesive agent, temperature-sensitive microcapsule powder, water, is made up of following raw material by weight: resin 25 ~ 50 parts, temperature-sensitive microcapsule powder 3 ~ 5 parts, dispersant 0.3 ~ 1 part, levelling agent 1 ~ 3 part, 5 ~ 8 parts of colorant, aqueous solvent 80 ~ 150 parts.There was added of described colorant helps aging-resistant effect.
The resin of described solvent type ink is polyurethane resin, and selected resin coating effect is good, and price is relatively cheap.Described UV absorbers is 2-hydroxyl-4 methoxy benzophenone.
The described resin in aqueous priming paint is acrylic resin and polystyrene resin, and solvent is water, with acrylic acid and polystyrene are plentiful as the priming paint film forming of resin, glossiness is high, mechanical strength good.
Described temperature-sensitive microcapsule powder and temperature-sensitive aqueous emulsion particle diameter average out to 3 ~ 10 m.
Described levelling agent is dimethyl silicone polymer, improves the wetability to floor base material and controls surface flow, plays the effect improving levelling effect, improve the gloss of film.
Described dispersant is polyacrylate, makes temperature-sensitive powder have good dispersiveness in ink, prevents precipitation.
Described filler is calcene, and fineness is 0.2 ~ 0.3 m, and it has the stability of excellence, and can play the effect reducing cost.
Described floor body is solid wooden compound floor/diatom needle floor/Wood-plastic floor.
There is multistage reversible color in heat discoloration floor paint provided by the present invention: be shade during low temperature according to temperature change, is that darker is adjusted during middle low temperature, and middle Wen Shiwei relatively thin shade, is thin shade during high temperature, and its colourshifting process is reversible.
Accompanying drawing explanation
Fig. 1 is color matching pigment and the design sketch thereof of present example 1.
Fig. 2 is color matching pigment and the design sketch thereof of present example 2.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described, and floor leaching paint technique is as follows: 1, roller coating UV aqueous priming paint → 2, infra-red drying tunnel → 3, putty → 4, UV solidification half-dried → 5, roller coating UV priming paint → 6, UV semi-solid preparation → 7, priming paint → 8, UV solidifying full dry → 9, sanding → 10, roller coating UV priming paint (twice) → 11, UV solidification (half-dried) → 12, sanding → 13, roller coating UV gloss oil → 14, UV solidification (half-dried) → 15, roller coating UV gloss oil → 16, UV at the bottom of roller coating UV solidify (absolutely dry) → 17, rewinding.Process above is arranged and can be basically reached floor covering with paint requirement, but above-mentioned technique imperfection, depend on the circumstances if any particular/special requirement.
The present invention realizes floor variable color by following two mode: one, added the UV absorbers of 0.1 ~ 1.5% as the priming paint of leaching paint processing step 5 and step 15 with the solvent type ink of heat discoloration microcapsule powder by preparation；Two or preparation with the aqueous priming paint of heat discoloration microcapsule powder as the aqueous priming paint of step 1; coating used by other coatings is held essentially constant; so that floor can heat discoloration; the technique on heat discoloration paint finishing floor is simpler; prior art can meet the effect of protection temperature sensing paint, it is not necessary to additionally adds protective layer.
Embodiment 1
As shown in Figure 1 by preparing the priming paint as leaching paint processing step 5 of the solvent type ink with heat discoloration microcapsule powder；Coating used by other coatings is held essentially constant so that floor can heat discoloration, it is made up of the raw material of following weight fraction: polyurethane resin 30 parts, temperature-sensitive microcapsule powder 5 parts, dimethyl silicone polymer 3 parts, polyacrylate 1 part, calcene 10 parts.
Calcene uses fineness to be 0.2 ~ 0.3 m；Temperature-sensitive microcapsule powder particle diameter average out to 3 ~ 10 m, wherein temperature-sensitive microcapsule powder selects three kinds, color is blue, yellow and rose-red, add polyurethane resin after mixing and other auxiliary agents are configured to solvent type ink, solvent type ink is carried out floor covering with paint as the priming paint of step 5 according to leaching paint technique, finally make floor when temperature is raised to 25 DEG C by 20 DEG C, crocus is become from bottle green, when temperature is raised to 29 DEG C by 25 DEG C, lightpink is become from crocus, when temperature is raised to 33 DEG C by 29 DEG C, light pink becoming colorless, its colourshifting process is reversible.
Embodiment 2
As shown in Figure 2 by preparing the priming paint as leaching paint processing step 5 of the solvent type ink with heat discoloration microcapsule powder；Coating used by other coatings is held essentially constant so that floor can heat discoloration, it is made up of the raw material of following weight fraction: polyurethane resin 25 parts, temperature-sensitive microcapsule powder 3 parts, dimethyl silicone polymer 2 parts, polyacrylate 1.5 parts, calcene 5 parts
Calcene uses fineness to be 0.2 ~ 0.3 m；Temperature-sensitive microcapsule powder particle diameter average out to 3 ~ 10 m, wherein temperature-sensitive microcapsule powder selects three kinds, color is blue, yellow and rose-red, add polyurethane resin after mixing and other auxiliary agents are configured to solvent type ink, solvent type ink is covered with paint, lacquer, colour wash, etc. as the priming paint of step 5 according to leaching paint technique, finally make floor when temperature is raised to 25 DEG C by 20 DEG C, crocus is become from bottle green, when temperature is raised to 29 DEG C by 25 DEG C, lightpink is become from crocus, when temperature is raised to 33 DEG C by 29 DEG C, light pink becoming colorless, its colourshifting process is reversible.
Embodiment 3
By preparing the priming paint as leaching paint processing step 5 of the solvent type ink with heat discoloration microcapsule powder；
Coating used by other coatings is held essentially constant so that floor can heat discoloration, it is made up of the raw material of following weight fraction: polyurethane resin 35 parts, temperature-sensitive microcapsule powder 5 parts, dimethyl silicone polymer 5 parts, polyacrylate 2 parts, calcene 20 parts
Calcene uses fineness to be 0.2 ~ 0.3 m；Temperature-sensitive microcapsule powder particle diameter average out to 3 ~ 10 m, wherein temperature-sensitive microcapsule powder selects three kinds, color is blue, yellow and rose-red, add polyurethane resin after mixing and other auxiliary agents are configured to solvent type ink, solvent type ink is covered with paint, lacquer, colour wash, etc. as the priming paint of step 5 according to leaching paint technique, finally make floor when temperature is raised to 25 DEG C by 20 DEG C, crocus is become from bottle green, when temperature is raised to 29 DEG C by 25 DEG C, lightpink is become from crocus, when temperature is raised to 33 DEG C by 29 DEG C, light pink becoming colorless, its colourshifting process is reversible.
Embodiment 4
Preparing the aqueous priming paint as step 1 of the aqueous priming paint with heat discoloration microcapsule powder, coating used by other coatings is held essentially constant.Described aqueous priming paint, it is characterized in that: aqueous priming paint is made up of aqueous adhesive agent, temperature-sensitive microcapsule powder, water etc., weight fraction is as follows: acrylic resin and polystyrene resin totally 35 parts, temperature-sensitive microcapsule powder 5 parts, polyacrylate 0.5 part, dimethyl silicone polymer 1 part, 8 parts of colorant, 100 parts of water.
Temperature-sensitive microcapsule powder particle diameter average out to 3 ~ 10 m, wherein temperature-sensitive microcapsule powder selects four kinds, color is violet, yellow, blue, rose-red, aqueous adhesive agent is added after being mixed, water etc. are configured to aqueous priming paint, the aqueous priming paint of described preparation is covered with paint, lacquer, colour wash, etc. as the aqueous priming paint of step 1 according to leaching paint technique, finally make floor when temperature is raised to 25 DEG C by 20 DEG C, blue-green is become from hyacinthine, when temperature is raised to 31 DEG C by 25 DEG C, become blue from blue-green, when temperature is raised to 38 DEG C by 31 DEG C, lotus root starch look is become from blueness, when temperature is raised to 43 DEG C by 38 DEG C, become colorless by lotus root starch look, its colourshifting process is reversible.
Embodiment 5
Preparing the aqueous priming paint as step 1 of the aqueous priming paint with heat discoloration microcapsule powder, coating used by other coatings is held essentially constant.Described aqueous priming paint, it is characterized in that: aqueous priming paint is made up of aqueous adhesive agent, temperature-sensitive microcapsule powder, water etc., weight fraction is as follows: acrylic resin and polystyrene resin totally 25 parts, temperature-sensitive microcapsule powder 3 parts, polyacrylate 0.3 part, dimethyl silicone polymer 2 parts, 5 parts of colorant, 100 parts of water.
Temperature-sensitive microcapsule powder particle diameter average out to 3 ~ 10 m, wherein temperature-sensitive microcapsule powder selects four kinds, color is violet, yellow, blue, rose-red, aqueous adhesive agent is added after being mixed, water etc. are configured to aqueous priming paint, the aqueous priming paint of described preparation is covered with paint, lacquer, colour wash, etc. as the aqueous priming paint of step 1 according to leaching paint technique, finally make floor when temperature is raised to 25 DEG C by 20 DEG C, blue-green is become from hyacinthine, when temperature is raised to 31 DEG C by 25 DEG C, become blue from blue-green, when temperature is raised to 38 DEG C by 31 DEG C, lotus root starch look is become from blueness, when temperature is raised to 43 DEG C by 38 DEG C, become colorless by lotus root starch look, its colourshifting process is reversible.
Embodiment 6
Preparing the aqueous priming paint as step 1 of the aqueous priming paint with heat discoloration microcapsule powder, coating used by other coatings is held essentially constant.Described aqueous priming paint, it is characterized in that: aqueous priming paint is made up of aqueous adhesive agent, temperature-sensitive microcapsule powder, water etc., weight fraction is as follows: acrylic resin and polystyrene resin totally 50 parts, temperature-sensitive microcapsule powder 5 parts, polyacrylate 1 part, dimethyl silicone polymer 3 parts, 8 parts of colorant, 100 parts of water.
Temperature-sensitive microcapsule powder particle diameter average out to 3 ~ 10 m, wherein temperature-sensitive microcapsule powder selects four kinds, color is violet, yellow, blue, rose-red, aqueous adhesive agent is added after being mixed, water etc. are configured to aqueous priming paint, the aqueous priming paint of described preparation is covered with paint, lacquer, colour wash, etc. as the aqueous priming paint of step 1 according to leaching paint technique, finally make floor when temperature is raised to 25 DEG C by 20 DEG C, blue-green is become from hyacinthine, when temperature is raised to 31 DEG C by 25 DEG C, become blue from blue-green, when temperature is raised to 38 DEG C by 31 DEG C, lotus root starch look is become from blueness, when temperature is raised to 43 DEG C by 38 DEG C, become colorless by lotus root starch look, its colourshifting process is reversible.
Claims (8)
1. the color changing floor with temperature sensing paint, it is characterised in that: solvent type ink or aqueous priming paint with heat discoloration microcapsule powder are covered with paint, lacquer, colour wash, etc. floor and are realized floor heat discoloration；Solvent type ink is made up of following raw material by weight: resin 25 ~ 50 parts, temperature-sensitive microcapsule powder 3 ~ 5 parts, levelling agent 2 ~ 5 parts, dispersant 1 ~ 2 part, filler 5 ~ 20 parts, and UV absorbers is 0.1 ~ 1.5 part；Aqueous priming paint is made up of aqueous adhesive agent, temperature-sensitive microcapsule powder, water, is made up of following raw material by weight: resin 25 ~ 50 parts, temperature-sensitive microcapsule powder 3 ~ 5 parts, dispersant 0.3 ~ 1 part, levelling agent 1 ~ 3 part, 5 ~ 8 parts of colorant, aqueous solvent 80 ~ 150 parts.
2. according to a kind of color changing floor with temperature sensing paint described in claim 1, it is characterised in that the resin of described solvent type ink is polyurethane resin.
3. according to a kind of color changing floor with temperature sensing paint described in claim 1, it is characterised in that described UV absorbers is 2-hydroxyl-4 methoxy benzophenone.
4., according to a kind of color changing floor with temperature sensing paint described in claim 1, it is characterised in that the described resin in aqueous priming paint is acrylic resin and polystyrene resin, solvent is water.
5. according to a kind of color changing floor with temperature sensing paint described in claim 1, it is characterised in that described temperature-sensitive microcapsule powder and temperature-sensitive aqueous emulsion particle diameter average out to 3 ~ 10 m.
6. according to a kind of color changing floor with temperature sensing paint described in claim 1, it is characterised in that described levelling agent is dimethyl silicone polymer.
7. according to a kind of color changing floor with temperature sensing paint described in claim 1, it is characterised in that described dispersant is polyacrylate.
8., according to a kind of color changing floor with temperature sensing paint described in claim 1, it is characterised in that described filler is calcene, fineness is 0.2 ~ 0.3 m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610400497.5A CN105885526A (en) | 2016-06-08 | 2016-06-08 | Color-changing floor with temperature sensing material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610400497.5A CN105885526A (en) | 2016-06-08 | 2016-06-08 | Color-changing floor with temperature sensing material |
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| CN105885526A true CN105885526A (en) | 2016-08-24 |
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| CN201610400497.5A Pending CN105885526A (en) | 2016-06-08 | 2016-06-08 | Color-changing floor with temperature sensing material |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107841234A (en) * | 2017-11-20 | 2018-03-27 | 广东华兹卜新材料科技有限公司 | A kind of silicon-modified epoxy acrylic acid allochroic paint and preparation method thereof |
| TWI656181B (en) * | 2016-11-07 | 2019-04-11 | 趙自立 | Method for producing water-based paint, article using the water-based paint, and use of the water-based paint |
| CN114958188A (en) * | 2022-05-31 | 2022-08-30 | 书香门地集团股份有限公司 | Thermochromic water-based UV coating and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0886079A (en) * | 1994-09-20 | 1996-04-02 | Chugoku Marine Paints Ltd | Temperature-sensing laminated color floor material |
| CN101116988A (en) * | 2007-09-03 | 2008-02-06 | 孙英瀚 | Method for preparation of |
| CN204176727U (en) * | 2014-10-03 | 2015-02-25 | 北京中科联众科技股份有限公司 | A kind of infrared induction heater of changeable colour |
| CN104712122A (en) * | 2015-02-05 | 2015-06-17 | 中山市极地阳光木业有限公司 | Temperature control color-variable decorative sheet |
-
2016
- 2016-06-08 CN CN201610400497.5A patent/CN105885526A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0886079A (en) * | 1994-09-20 | 1996-04-02 | Chugoku Marine Paints Ltd | Temperature-sensing laminated color floor material |
| CN101116988A (en) * | 2007-09-03 | 2008-02-06 | 孙英瀚 | Method for preparation of |
| CN204176727U (en) * | 2014-10-03 | 2015-02-25 | 北京中科联众科技股份有限公司 | A kind of infrared induction heater of changeable colour |
| CN104712122A (en) * | 2015-02-05 | 2015-06-17 | 中山市极地阳光木业有限公司 | Temperature control color-variable decorative sheet |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI656181B (en) * | 2016-11-07 | 2019-04-11 | 趙自立 | Method for producing water-based paint, article using the water-based paint, and use of the water-based paint |
| CN107841234A (en) * | 2017-11-20 | 2018-03-27 | 广东华兹卜新材料科技有限公司 | A kind of silicon-modified epoxy acrylic acid allochroic paint and preparation method thereof |
| CN114958188A (en) * | 2022-05-31 | 2022-08-30 | 书香门地集团股份有限公司 | Thermochromic water-based UV coating and preparation method thereof |
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Application publication date: 20160824 |