CN105884428A - Anti-caking water-retaining compound fertilizer and preparation method thereof - Google Patents
Anti-caking water-retaining compound fertilizer and preparation method thereof Download PDFInfo
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- CN105884428A CN105884428A CN201610249667.4A CN201610249667A CN105884428A CN 105884428 A CN105884428 A CN 105884428A CN 201610249667 A CN201610249667 A CN 201610249667A CN 105884428 A CN105884428 A CN 105884428A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Abstract
The invention discloses an anti-caking water-retaining compound fertilizer and a preparation method thereof. The anti-caking water-retaining compound fertilizer comprises, by weight parts, 20-22 parts of urea, 10-12 parts of expanded perlite, 3-5 parts of EM fungicide, 20-25 parts of weathered coal, 13-15 parts of sodium humic acid, 12-14 parts of monopotassium phosphate, 10-11 parts of chitosan, 2-3 parts of polyacrylamide, 2-3 parts of ferric ammonium citrate, 5-8 parts of magnesium sulfate, 4-6 parts of activated carbon, 6-8 parts of Chinese herb residues, 8-10 parts of plant ash, 6-8 parts of pine needle mulch, 6-9 parts of polylactic acid, 8-12 parts of polyvinyl alcohol, 0.5-1 part of N,N-methylene-bisacrylamide and an appropriate amount of water. According to the anti-caking water-retaining compound fertilizer, the functional components including the plant ash, the pine needle mulch, the weathered coal and the activated carbon are added, fertilizer particle pores are added, and the particle stability is improved, so that the anti-caking effect of the fertilizer is good; mutual adhesion and caking between fertilizer particles can be avoided during use, and thus the fertilizer efficiency is guaranteed.
Description
Technical field
The present invention relates to slow release fertilizer technical field, particularly relate to a kind of anti-caking water-holding compound fertilizer material fertilizer and preparation side thereof
Method.
Background technology
At present, China market agricultural fertilizer material, substantially there are three kinds: a kind of fertile for industrial chemicals, one is fertilizer, also
Have a kind of fertile for industrial chemicals and organic fertilizer mixing;The shortcoming of industrial chemicals: life-time service can cause soil soil property to harden,
Affect plant growth, cause the progressively underproduction;The shortcoming of organic fertilizer is: needed for plant, nutrient is not enough, can not meet crops
The demand produced;Affect crop yield;The shortcoming that mixing is fertile: organic matter and full nutrient in fertilizer formula are conflicting,
This is high, and that are low, such as organic too high levels, produce granule difficulty.It addition, China's Arid&semi-arid area gross area accounts for territory
The 50% of the gross area, China's agricultural is again to use water rich and influential family, and Water Consumption in Agriculture exceedes the 70% of total water consumption, and production efficiency
The lowest, China's annual agricultural water breach is about at 30,000,000,000 m 3, and agricultural water crisis presents and constantly aggravates situation.Soil
Earth water-retaining agent is used alone not only increases work number of times and cost, and because water-loss reducer of soil consumption is the most less, it is difficult to
Fertilizer is fully contacted so that received moisture is difficult to and nutritional labeling generation reciprocal action, largely reduces water-retaining agent
Effect.It addition, the common fertilizer water solublity used at present is the highest, rate of release is very fast, and the release phase is shorter and many
Using totally basal dressing techniques so that fertilizer nutrient rate of release is poor with crop regulation of fertilizer requirement synchronicity, fertilizer nutrient loses
Very big, fertilizer nutrient utilization is relatively low, though and split application method can improve crop different growing nutrient demand, but take a lot of work
Time-consuming, it is not suitable with the requirement of modern agriculture high-efficient development.And, the fertilizer efficiency height in being manured into soil and soil moisture shape
Condition is in close relations, and " with fertile water transfer, promoting fertilizer with water " is highly important rich water control technique in agricultural production.
Mulch film has the effects such as insulation, water conservation, frost protection to crop, and the application of ground membrane technology improves greatly and adds
The yield of crops and benefit, but tradition mulch film is the macromolecular compound of a kind of synthetic, the most hardly
Degradable, after using, place to go is not comprehended soil environment is caused the biggest pollution, affects crop root growth, and the mulch film processed because of
Moist, damaged, the most not reusable edible, only as garbage reclamation, work consuming is time-consuming.
Therefore, being modified fertilizer, improving fertilizer efficiency is to reduce fertilizer use, the effective way increased operation rate.Such as mesh
Front slow-release or control-release fertilizer is exactly one of effective measures improving chemical fertilizer utilization ratio, and slow-release or control-release fertilizer can efficiently control the release of nutrient, prolong
Long fertilizer efficiency period, meet the whole period of duration of crop to the needs of fertilizer nutrient, the utilization rate of fertilizer, minimizing can be improved to greatest extent
The wasting of resources and environmental pollution, to promoting agriculture and forestry volume increase, increasing peasant income, agriculture and forestry sustainable development important role, be
The important development direction of 21 century fertilizer industry.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of anti-caking water-holding compound fertilizer material fertile and
Preparation method.
The present invention is achieved by the following technical solutions:
A kind of anti-caking water-holding compound fertilizer material, is prepared by the raw materials in: carbamide 20-22, fine perlite 10-12,
EM microbial inoculum 3-5, weathered coal 20-25, sodium humate 13-15, potassium dihydrogen phosphate 12-14, chitosan 10-11, polyacrylamide 2-
3, ferric ammonium citrate 2-3, magnesium sulfate 5-8, activated carbon 4-6, Chinese herb residues 6-8, plant ash 8-10, pine soil 6-8, polylactic acid 6-
9, polyvinyl alcohol 8-12, N,N methylene bis acrylamide 0.5-1, water are appropriate.
The preparation method of described anti-caking water-holding compound fertilizer material, comprises the following steps:
(1), by weathered coal drying and be ground to 150-200 mesh, the 1.5-2 times of water taking powder weight adds in reactor, adds powder
End and appropriate potassium permanganate are formulated as 4-8% potassium permanganate solution, stirring oxidation 40-50 minute, are heated to 90-100 DEG C, add
The potassium hydroxide of solution weight part 0.2-0.5%, stirs 30-40 minute at 2200-2500rpm high speed machine, centrifugation, filter
It is 50-60% that liquid is concentrated into moisture content, and filtering residue is stand-by;
(2), by step (1) concentrated solution and polyvinyl alcohol, N, N-methylene-bisacrylamide mix and blend, it is heated with stirring to 40-
React 20-30 minute at 50 DEG C, carbamide is added and is ground to 40-60 mesh, add suitable quantity of water stirring and melt, and reactant liquor mix and blend,
Joining in drying oven, dry 1-2 hour at 80-90 DEG C, cooling crush crosses 200 mesh sieves, standby;
(3), filtering residue, fine perlite, activated carbon mixed grinding being crossed 200 mesh sieves, the citric acid putting into 0.1-0.2mol/L is molten
In liquid, 1-2 hour processed of stirring leaching, stands and removes liquid, and oven drying at low temperature is baked 40-60 minute at 350-400 DEG C, and discharging spray profit water steams
Gas extinguishes cooling to powder body, adds 3-5 times of water stirring extremely suspended shape, adds polylactic acid, and high pressure homogenize stirs, and obtains peplos
Liquid;
(4), by sodium humate, polyacrylamide, ferric ammonium citrate, magnesium sulfate, potassium dihydrogen phosphate mixing, and gross weight 3-is added
The water mixing and stirring of 4 times, obtains nutritional solution;
(5), by Chinese herb residues, plant ash, pine soil co-grinding, nutritional solution, EM microbial inoculum and gross weight 0.3-are added afterwards
After the water of 0.5 times stirs, fermentation 25-35 days of banking up at 32-38 DEG C, stand-by;
(6), by fermentation material being crushed to 80-100 mesh, add chitosan mix and blend, adjustment moisture is gross weight 46-50%,
The ball-type fertiliser granulates of granulator granulation diameter 1-1.2mm, places band high-pressure nozzle and rolling at high temperature of air cooking fluidizes
On bed, coating liquid step (3) obtained repeats to be sprayed at ball-type fertiliser granulates for 3-5 time uniformly by high-pressure nozzle, sends into
Tumbling disk granulator, is simultaneously introduced step (2) and bakes powder, after granulating and forming, within dry 8-10 hour, cools down at 45-50 DEG C, packed
Obtain.
The invention have the advantage that
(1) anti-caking water-holding compound fertilizer material of the present invention adds plant ash, pine soil, weathered coal, active carbon functional composition, increases fertilizer
Material pellet pores, improves granule stability so that fertilizer preventing blocking effect is good, and can stop between fertiliser granulates during use is mutual
Phase adhesion conglomeration, thus ensure that the fertilizer efficiency of fertilizer.
(2) anti-caking water-holding compound fertilizer material of the present invention is also added with conventional bacterial manure and works in coordination with microbial activity with inorganic fertilizer and become
Point, use multilayer coating structure release structures, external sheath liquid-state mulch film functional component, not only there is the sustained release performance of nutrition release,
Serve again water retention, can be that soil provides the multiple resources such as carbon, nitrogen after degraded, stimulate growth and development of plants, increase simultaneously
The resistance of crop, the effect of the nutriture of plant improved, collaborative internal layer bioactive ingredients, further improvement soil knot
Structure, gives full play to fertilizer efficiency, promotes plant growing, improves crop yield.
Detailed description of the invention
Embodiment 1
A kind of anti-caking water-holding compound fertilizer material, is made up of the raw material of following weight (kg): carbamide 20, fine perlite 10, EM bacterium
Agent 3, weathered coal 20, sodium humate 13, potassium dihydrogen phosphate 12, chitosan 10, polyacrylamide 2, ferric ammonium citrate 2, magnesium sulfate
5, activated carbon 4, Chinese herb residues 6, plant ash 8, pine soil 6, polylactic acid 6, polyvinyl alcohol 8, N,N methylene bis acrylamide
0.5, water is appropriate.
The preparation method of described anti-caking water-holding compound fertilizer material, it is characterised in that comprise the following steps:
(1), by weathered coal drying and be ground to 180 mesh, the 2 times of water taking powder weight add in reactors, add powder and appropriate
Potassium permanganate is formulated as 4-8% potassium permanganate solution, stirring oxidation 50 minutes, is heated to 100 DEG C, adds solution weight part 0.5%
Potassium hydroxide, 2500rpm high speed machine stir 40 minutes, centrifugation, it is 60% that filtrate is concentrated into moisture content, and filtering residue is treated
With;
(2), by step (1) concentrated solution and polyvinyl alcohol, N, N-methylene-bisacrylamide mix and blend, it is heated with stirring to 50
React 30 minutes at DEG C, carbamide is added and is ground to 60 mesh, add suitable quantity of water stirring and melt, with reactant liquor mix and blend, join baking
In dry stove, drying 2 hours at 90 DEG C, cooling crush crosses 200 mesh sieves, standby;
(3), filtering residue, fine perlite, activated carbon mixed grinding are crossed 200 mesh sieves, put in the citric acid solution of 0.2mol/L
Stirring leaching system 2 hours, stands and removes liquid, and oven drying at low temperature is baked 40 minutes at 400 DEG C, and discharging spray profit steam extinguishes to powder body
Cooling, adds 4 times of water stirring extremely suspended shapes, adds polylactic acid, and high pressure homogenize stirs, and obtains coating liquid;
(4), by sodium humate, polyacrylamide, ferric ammonium citrate, magnesium sulfate, potassium dihydrogen phosphate mixing, and gross weight 3 is added
Water mixing and stirring again, obtains nutritional solution;
(5), by Chinese herb residues, plant ash, pine soil co-grinding, nutritional solution, EM microbial inoculum and gross weight 0..5 are added afterwards
After water again stirs, fermentation 30 days of banking up at 38 DEG C, stand-by;
(6), by fermentation material being crushed to 100 mesh, add chitosan mix and blend, adjusting moisture is gross weight 50%, comminutor
The ball-type fertiliser granulates of pelletize diameter 1.2mm, that places band high-pressure nozzle and air cooking rolls on fluid bed at high temperature, will step
Suddenly the coating liquid that (3) obtain is repeated 5 times by high-pressure nozzle and is sprayed at ball-type fertiliser granulates uniformly, sends into tumbling disk granulator,
It is simultaneously introduced step (2) and bakes powder, after granulating and forming, be dried cooling in 10 hours at 50 DEG C, packed and get final product.
Embodiment 2
A kind of anti-caking water-holding compound fertilizer material, is made up of the raw material of following weight (kg): carbamide 21, fine perlite 11, EM bacterium
Agent 4, weathered coal 24, sodium humate 14, potassium dihydrogen phosphate 13, chitosan 10, polyacrylamide 2, ferric ammonium citrate 3, magnesium sulfate
6, activated carbon 5, Chinese herb residues 7, plant ash 9, pine soil 7, polylactic acid 8, polyvinyl alcohol 10, N,N methylene bis acrylamide
0.8, water is appropriate.
The preparation method of described anti-caking water-holding compound fertilizer material, with embodiment 1.
Embodiment 3
A kind of anti-caking water-holding compound fertilizer material, is made up of the raw material of following weight (kg): carbamide 22, fine perlite 12, EM bacterium
Agent 5, weathered coal 25, sodium humate 15, potassium dihydrogen phosphate 14, chitosan 11, polyacrylamide 3, ferric ammonium citrate 3, magnesium sulfate
8, activated carbon 6, Chinese herb residues 8, plant ash 10, pine soil 8, polylactic acid 9, polyvinyl alcohol 12, N,N methylene bis acrylamide
1, water is appropriate.
The preparation method of described anti-caking water-holding compound fertilizer material, with embodiment 1.
Take the wheat paddock that two pieces of areas are 5 mu, be divided into matched group and experimental group.Matched group uses commercially available common slow release
Fertilizer, uses Wheat in Field good luster, plant health that the improvement soil acidification water-holding compound fertilizer material of the present invention is fertile, and the speed of growth is also
Comparatively fast, the wheat grain after maturation is golden yellow full, and yield increases, and compared with the farmland not using product of the present invention, every mu of volume increase 110 is public
Jin, and use the pest and disease damage in the farmland of product of the present invention also to greatly reduce.
From the above-mentioned anti-caking water-holding compound fertilizer material fertilizer that the present invention can be described can not only preventing disease and pest effectively, and should
Fertilizer nutrient equalizes, it is possible to promotes that crops more preferably grow, improves soil environment, improves crop yield.
Claims (2)
1. an anti-caking water-holding compound fertilizer material, it is characterised in that be prepared by the raw materials in: carbamide 20-22, expanded
Perlite 10-12, EM microbial inoculum 3-5, weathered coal 20-25, sodium humate 13-15, potassium dihydrogen phosphate 12-14, chitosan 10-11,
Polyacrylamide 2-3, ferric ammonium citrate 2-3, magnesium sulfate 5-8, activated carbon 4-6, Chinese herb residues 6-8, plant ash 8-10, pine soil
6-8, polylactic acid 6-9, polyvinyl alcohol 8-12, N,N methylene bis acrylamide 0.5-1, water are appropriate.
2. the preparation method of an anti-caking water-holding compound fertilizer material as claimed in claim 1, it is characterised in that include following step
Rapid:
(1), by weathered coal drying and be ground to 150-200 mesh, the 1.5-2 times of water taking powder weight adds in reactor, adds powder
End and appropriate potassium permanganate are formulated as 4-8% potassium permanganate solution, stirring oxidation 40-50 minute, are heated to 90-100 DEG C, add
The potassium hydroxide of solution weight part 0.2-0.5%, stirs 30-40 minute at 2200-2500rpm high speed machine, centrifugation, filter
It is 50-60% that liquid is concentrated into moisture content, and filtering residue is stand-by;
(2), by step (1) concentrated solution and polyvinyl alcohol, N, N-methylene-bisacrylamide mix and blend, it is heated with stirring to 40-
React 20-30 minute at 50 DEG C, carbamide is added and is ground to 40-60 mesh, add suitable quantity of water stirring and melt, and reactant liquor mix and blend,
Joining in drying oven, dry 1-2 hour at 80-90 DEG C, cooling crush crosses 200 mesh sieves, standby;
(3), filtering residue, fine perlite, activated carbon mixed grinding being crossed 200 mesh sieves, the citric acid putting into 0.1-0.2mol/L is molten
In liquid, 1-2 hour processed of stirring leaching, stands and removes liquid, and oven drying at low temperature is baked 40-60 minute at 350-400 DEG C, and discharging spray profit water steams
Gas extinguishes cooling to powder body, adds 3-5 times of water stirring extremely suspended shape, adds polylactic acid, and high pressure homogenize stirs, and obtains peplos
Liquid;
(4), by sodium humate, polyacrylamide, ferric ammonium citrate, magnesium sulfate, potassium dihydrogen phosphate mixing, and gross weight 3-is added
The water mixing and stirring of 4 times, obtains nutritional solution;
(5), by Chinese herb residues, plant ash, pine soil co-grinding, nutritional solution, EM microbial inoculum and gross weight 0.3-are added afterwards
After the water of 0.5 times stirs, fermentation 25-35 days of banking up at 32-38 DEG C, stand-by;
(6), by fermentation material being crushed to 80-100 mesh, add chitosan mix and blend, adjustment moisture is gross weight 46-50%,
The ball-type fertiliser granulates of granulator granulation diameter 1-1.2mm, places band high-pressure nozzle and rolling at high temperature of air cooking fluidizes
On bed, coating liquid step (3) obtained repeats to be sprayed at ball-type fertiliser granulates for 3-5 time uniformly by high-pressure nozzle, sends into
Tumbling disk granulator, is simultaneously introduced step (2) and bakes powder, after granulating and forming, within dry 8-10 hour, cools down at 45-50 DEG C, packed
Obtain.
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106396983A (en) * | 2016-11-30 | 2017-02-15 | 广西壮族自治区药用植物园 | Water-retention and growth-promoting fertilizer for planting gynostemma pentaphylla as well as preparation method and use method of fertilizer |
CN106478232A (en) * | 2016-09-28 | 2017-03-08 | 苏州蓝士环保科技有限公司 | A kind of ecological organic fertilizer containing the organic conditioner of nanometer humus soil |
CN106472276A (en) * | 2016-09-28 | 2017-03-08 | 苏州蓝士环保科技有限公司 | A kind of ecological cultivation matrix with water conservation, pollution treatment and trophic function |
CN106748285A (en) * | 2017-02-06 | 2017-05-31 | 闵军 | A kind of drought-hit area vegetable cultivation fertilizer |
CN107282628A (en) * | 2017-07-27 | 2017-10-24 | 吉林省利泽生物科技有限公司 | A kind of composite modifying agent for repairing farmland pollution soil and preparation method thereof |
CN107624397A (en) * | 2017-10-20 | 2018-01-26 | 百色学院 | A kind of cuttage breeding method of Pasania cuspidata |
CN107628869A (en) * | 2017-09-30 | 2018-01-26 | 无为县双荠荸荠种植专业合作社 | A kind of water chestnut slow release fertilizer |
CN108264416A (en) * | 2018-03-16 | 2018-07-10 | 山东绿增农业有限公司 | High-performance livestock and poultry feces conversion aquaculture organisms rich water material and preparation method thereof |
CN108440144A (en) * | 2018-05-30 | 2018-08-24 | 安徽辉隆集团五禾生态肥业有限公司 | With anti-caking, the compound fertilizer of slow release effect and preparation method |
CN114920603A (en) * | 2022-07-01 | 2022-08-19 | 江苏科邦生态肥有限公司 | Efficient drought-resistant functional fertilizer special for corn and preparation method thereof |
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CN105347916A (en) * | 2015-10-30 | 2016-02-24 | 全椒县琪悦家庭农场 | Sterilization soil-improvement slow-release composite fertilizer and preparation method thereof |
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CN103613474A (en) * | 2013-11-08 | 2014-03-05 | 苏州仁成生物科技有限公司 | Long-acting slow-control bio-fertilizer and preparation method thereof |
CN104844318A (en) * | 2015-04-14 | 2015-08-19 | 安徽绿园肥业有限公司 | Modified stalk water-retaining fertilizer, and preparation method thereof |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106478232A (en) * | 2016-09-28 | 2017-03-08 | 苏州蓝士环保科技有限公司 | A kind of ecological organic fertilizer containing the organic conditioner of nanometer humus soil |
CN106472276A (en) * | 2016-09-28 | 2017-03-08 | 苏州蓝士环保科技有限公司 | A kind of ecological cultivation matrix with water conservation, pollution treatment and trophic function |
CN106396983A (en) * | 2016-11-30 | 2017-02-15 | 广西壮族自治区药用植物园 | Water-retention and growth-promoting fertilizer for planting gynostemma pentaphylla as well as preparation method and use method of fertilizer |
CN106748285A (en) * | 2017-02-06 | 2017-05-31 | 闵军 | A kind of drought-hit area vegetable cultivation fertilizer |
CN107282628A (en) * | 2017-07-27 | 2017-10-24 | 吉林省利泽生物科技有限公司 | A kind of composite modifying agent for repairing farmland pollution soil and preparation method thereof |
CN107628869A (en) * | 2017-09-30 | 2018-01-26 | 无为县双荠荸荠种植专业合作社 | A kind of water chestnut slow release fertilizer |
CN107624397A (en) * | 2017-10-20 | 2018-01-26 | 百色学院 | A kind of cuttage breeding method of Pasania cuspidata |
CN108264416A (en) * | 2018-03-16 | 2018-07-10 | 山东绿增农业有限公司 | High-performance livestock and poultry feces conversion aquaculture organisms rich water material and preparation method thereof |
CN108440144A (en) * | 2018-05-30 | 2018-08-24 | 安徽辉隆集团五禾生态肥业有限公司 | With anti-caking, the compound fertilizer of slow release effect and preparation method |
CN108440144B (en) * | 2018-05-30 | 2021-08-03 | 安徽辉隆集团五禾生态肥业有限公司 | Compound fertilizer with anti-caking and slow-release effects and preparation method thereof |
CN114920603A (en) * | 2022-07-01 | 2022-08-19 | 江苏科邦生态肥有限公司 | Efficient drought-resistant functional fertilizer special for corn and preparation method thereof |
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Application publication date: 20160824 |