CN105862508A - 松香施胶剂的制备方法 - Google Patents
松香施胶剂的制备方法 Download PDFInfo
- Publication number
- CN105862508A CN105862508A CN201610313827.7A CN201610313827A CN105862508A CN 105862508 A CN105862508 A CN 105862508A CN 201610313827 A CN201610313827 A CN 201610313827A CN 105862508 A CN105862508 A CN 105862508A
- Authority
- CN
- China
- Prior art keywords
- parts
- sizing agent
- rosin
- fatty acid
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 title claims abstract description 28
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 title claims abstract description 28
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 238000004513 sizing Methods 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229920001732 Lignosulfonate Polymers 0.000 claims abstract description 16
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 16
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 16
- 239000000194 fatty acid Substances 0.000 claims abstract description 16
- 229930195729 fatty acid Natural products 0.000 claims abstract description 16
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 16
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 16
- 235000017281 sodium acetate Nutrition 0.000 claims abstract description 16
- 239000001632 sodium acetate Substances 0.000 claims abstract description 16
- 238000010438 heat treatment Methods 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 6
- 229940008099 dimethicone Drugs 0.000 claims description 12
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 12
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 12
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 12
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 10
- 238000010792 warming Methods 0.000 claims description 5
- 229940082337 dimethicone 20 Drugs 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- 235000019357 lignosulphonate Nutrition 0.000 abstract 2
- 229920002545 silicone oil Polymers 0.000 abstract 2
- 235000012424 soybean oil Nutrition 0.000 abstract 2
- 239000003549 soybean oil Substances 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 235000004258 Cordia alliodora Nutrition 0.000 description 1
- 244000085692 Cordia alliodora Species 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/23—Lignins
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/59—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/62—Rosin; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开一种松香施胶剂的制备方法，属于松香深加工技术领域。本发明采用以下重量份的原料：松香100份、豆油脂肪酸15份～20份、三氯氧磷5份～8份、醋酸钠1份～2份、聚乙二醇6份～10份、磺化木质素0.1份～0.2份、二甲基硅油15份～25份以及电导率小于5μS/cm的去离子水10份～15份；其中，包括先将上述松香加热熔解，然后加入去离子水，并调节其pH值至9；然后加入豆油脂肪酸、三氯氧磷、醋酸钠、聚乙二醇、磺化木质素、二甲基硅油，先加热至80℃～95℃反应0.5小时，然后降温至55℃～65℃1小时，接着再升温至80℃～95℃反应0.5小时。本发明制得的产物松香施胶剂具有稳定性强的优点。
Description
技术领域
本发明属于松香深加工技术领域，尤其涉及一种松香施胶剂的制备方法。
背景技术
施胶剂是一种造纸的添加剂，它能赋予纸和纸板抗墨、抗水、抗乳液、抗腐蚀等性能以提高其平滑度、强度和使用期。施胶剂可分为浆内施胶剂和表面施胶剂，其中松香施胶剂属于造纸助剂浆内施胶剂的一种。
目前市场销售的松香施胶剂品种很多，但其大多表现稳定性能较差、保质期过短的缺陷。
发明内容
本发明所要解决的技术问题是提供一种松香施胶剂的制备方法，该方法解决了现有松香施胶剂存在稳定性能较差、保质期过短的问题。
为了解决上述技术问题，本发明所采用的技术方案是：
它采用以下重量份的原料：
松香100份、豆油脂肪酸15份～20份、三氯氧磷5份～8份、醋酸钠1份～2份、聚乙二醇6份～10份、磺化木质素0.1份～0.2份、二甲基硅油15份～25份以及电导率小于5μS/cm的去离子水10份～15份；
包括以下步骤：
A、将上述松香加热熔解，然后加入电导率小于5μS/cm的去离子水，并调节其pH值至9；
B、向A步骤制得的物料中加入豆油脂肪酸、三氯氧磷、醋酸钠、聚乙二醇、磺化木质素、二甲基硅油，并加热进行反应，制得；其中，所述加热的具体过程为：先加热至80℃～95℃反应0.5小时，然后降温至55℃～65℃1小时，接着再升温至80℃～95℃反应0.5小时。
上述技术方案中，更具体的技术方案是：松香100份、豆油脂肪酸15份、三氯氧磷5份、醋酸钠2份、聚乙二醇8份、磺化木质素0.15份、二甲基硅油20份以及电导率小于5μS/cm的去离子水15份；
更进一步的，松香100份、豆油脂肪酸17份、三氯氧磷8份、醋酸钠1份、聚乙二醇10份、磺化木质素0.1份、二甲基硅油15份以及电导率小于5μS/cm的去离子水12份；
更进一步的，松香100份、豆油脂肪酸20份、三氯氧磷6份、醋酸钠1.5份、聚乙二醇6份、磺化木质素0.2份、二甲基硅油25份以及电导率小于5μS/cm的去离子水10份。
由于采用上述技术方案，本发明具有如下有益效果：
本发明是通过在松香中加入豆油脂肪酸、三氯氧磷、醋酸钠、聚乙二醇、磺化木质素、二甲基硅油以及电导率小于5μS/cm的去离子水，并经特定的加热反应方式制备，从而使制得的产物松香施胶剂具有稳定性强的优点。
具体实施方式
以下结合具体实例对本发明作进一步详述：
实施例1
本松香施胶剂的制备方法包括以下步骤：
A、将上述100kg松香加热熔解，然后加入15kg电导率小于5μS/cm的去离子水，并调节其pH值至9；
B、向A步骤制得的物料中加入豆油脂肪酸15kg、5kg三氯氧磷、2kg醋酸钠、8kg聚乙二醇、0.15kg磺化木质素、20kg二甲基硅油，并加热进行反应，制得；其中，所述加热的具体过程为：先加热至90℃反应0.5小时，然后降温至60℃1小时，接着再升温至90℃反应0.5小时。
本实施例制得的松香施胶剂稳定性好，在40℃时可贮存2年。
实施例2
本松香施胶剂的制备方法包括以下步骤：
A、将上述100kg松香加热熔解，然后加入12kg电导率小于5μS/cm的去离子水，并调节其pH值至9；
B、向A步骤制得的物料中加入豆油脂肪酸17kg、8kg三氯氧磷、1kg醋酸钠、10kg聚乙二醇、0.1kg磺化木质素、15kg二甲基硅油，并加热进行反应，制得；其中，所述加热的具体过程为：先加热至95℃反应0.5小时，然后降温至55℃1小时，接着再升温至95℃反应0.5小时。
本实施例制得的松香施胶剂稳定性好，在40℃时可贮存2年。
实施例3
本松香施胶剂的制备方法包括以下步骤：
A、将上述100kg松香加热熔解，然后加入10kg电导率小于5μS/cm的去离子水，并调节其pH值至9；
B、向A步骤制得的物料中加入豆油脂肪酸20kg、6kg三氯氧磷、1.5kg醋酸钠、6kg聚乙二醇、0.2kg磺化木质素、25kg二甲基硅油，并加热进行反应，制得；其中，所述加热的具体过程为：先加热至80℃反应0.5小时，然后降温至65℃1小时，接着再升温至80℃反应0.5小时。
本实施例制得的松香施胶剂稳定性好，在40℃时可贮存2年。
Claims (4)
1.一种松香施胶剂的制备方法，其特征在于：
采用以下重量份的原料：
松香100份、豆油脂肪酸15份～20份、三氯氧磷5份～8份、醋酸钠1份～2份、聚乙二醇6份～10份、磺化木质素0.1份～0.2份、二甲基硅油15份～25份以及电导率小于5μS/cm的去离子水10份～15份；
包括以下步骤：
A、将上述松香加热熔解，然后加入电导率小于5μS/cm的去离子水，并调节其pH值至9；
B、向A步骤制得的物料中加入豆油脂肪酸、三氯氧磷、醋酸钠、聚乙二醇、磺化木质素、二甲基硅油，并加热进行反应，制得；其中，所述加热的具体过程为：先加热至80℃～95℃反应0.5小时，然后降温至55℃～65℃1小时，接着再升温至80℃～95℃反应0.5小时。
2.根据权利要求1所述的松香施胶剂的制备方法，其特征在于：松香100份、豆油脂肪酸15份、三氯氧磷5份、醋酸钠2份、聚乙二醇8份、磺化木质素0.15份、二甲基硅油20份以及电导率小于5μS/cm的去离子水15份。
3.根据权利要求1所述的松香施胶剂的制备方法，其特征在于：松香100份、豆油脂肪酸17份、三氯氧磷8份、醋酸钠1份、聚乙二醇10份、磺化木质素0.1份、二甲基硅油15份以及电导率小于5μS/cm的去离子水12份。
4.根据权利要求1所述的松香施胶剂的制备方法，其特征在于：松香100份、豆油脂肪酸20份、三氯氧磷6份、醋酸钠1.5份、聚乙二醇6份、磺化木质素0.2份、二甲基硅油25份以及电导率小于5μS/cm的去离子水10份。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313827.7A CN105862508B (zh) | 2016-05-12 | 2016-05-12 | 松香施胶剂的制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313827.7A CN105862508B (zh) | 2016-05-12 | 2016-05-12 | 松香施胶剂的制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105862508A true CN105862508A (zh) | 2016-08-17 |
| CN105862508B CN105862508B (zh) | 2018-04-03 |
Family
ID=56631864
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610313827.7A Expired - Fee Related CN105862508B (zh) | 2016-05-12 | 2016-05-12 | 松香施胶剂的制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105862508B (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107630387A (zh) * | 2017-08-14 | 2018-01-26 | 龙游富田造纸精化有限公司 | 一种阳离子松香乳液中碱性施胶剂及其制备方法 |
| CN116289300A (zh) * | 2023-02-20 | 2023-06-23 | 天津科技大学 | 一种木质素松香施胶剂、制备方法和应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1215444A (zh) * | 1996-02-02 | 1999-04-28 | 赫尔克里士公司 | 用于松香施胶剂的乳化剂体系 |
| CN1281390A (zh) * | 1997-10-10 | 2001-01-24 | 联合碳化化学品及塑料技术公司 | 在片材上喷涂添加剂组合物 |
| CN101880989A (zh) * | 2010-06-24 | 2010-11-10 | 杭州杭化播磨造纸化学品有限公司 | 一种耐温纸用松香乳液施胶剂 |
-
2016
- 2016-05-12 CN CN201610313827.7A patent/CN105862508B/zh not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1215444A (zh) * | 1996-02-02 | 1999-04-28 | 赫尔克里士公司 | 用于松香施胶剂的乳化剂体系 |
| CN1281390A (zh) * | 1997-10-10 | 2001-01-24 | 联合碳化化学品及塑料技术公司 | 在片材上喷涂添加剂组合物 |
| CN101880989A (zh) * | 2010-06-24 | 2010-11-10 | 杭州杭化播磨造纸化学品有限公司 | 一种耐温纸用松香乳液施胶剂 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107630387A (zh) * | 2017-08-14 | 2018-01-26 | 龙游富田造纸精化有限公司 | 一种阳离子松香乳液中碱性施胶剂及其制备方法 |
| CN107630387B (zh) * | 2017-08-14 | 2021-01-19 | 龙游富田造纸精化有限公司 | 一种阳离子松香乳液中碱性施胶剂及其制备方法 |
| CN116289300A (zh) * | 2023-02-20 | 2023-06-23 | 天津科技大学 | 一种木质素松香施胶剂、制备方法和应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105862508B (zh) | 2018-04-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105862508A (zh) | 松香施胶剂的制备方法 | |
| CN104591702A (zh) | 一种led用高抗热震氧化铝陶瓷基板及制造方法 | |
| CN105967293A (zh) | 一种磷化工废水处理剂及其制备方法 | |
| CN105703002A (zh) | 一种热电池用电解质材料及其制备方法 | |
| CN105295847A (zh) | 一种新型金属基材定型储热材料及其制备方法 | |
| CN103832991B (zh) | 一种磷酸铁纳米材料的制备方法 | |
| CN104525064A (zh) | 一种碱性硅溶胶及其制备方法 | |
| CN103183377B (zh) | 硫酸法钛白粉工艺中低浓度自生晶种水解方法 | |
| CN104628337A (zh) | 保温隔热材料 | |
| CN105970720A (zh) | 松香施胶剂 | |
| CN105860551A (zh) | 松香乳液的制备方法 | |
| CN203944436U (zh) | 一种球磨机的冷却装置 | |
| CN104388054A (zh) | 一种新型复合有机储热材料及其制备方法 | |
| CN103666384A (zh) | 一种无毒无味蓄冷剂及其制备方法 | |
| CN106744768A (zh) | 一种淡磷酸制备饲料级磷酸二氢钙方法 | |
| CN105154022A (zh) | 一种金属基材高导热储热材料及其制备方法 | |
| CN102515593A (zh) | 一种利用盐溶液生产半水石膏的方法 | |
| CN108117702A (zh) | 一种高性能环保型橡胶及其制备方法 | |
| CN105819782A (zh) | 一种优质建筑砖块及其制备方法 | |
| CN103614012B (zh) | 一种水性隔热防水涂料 | |
| CN103614015B (zh) | 一种耐持久性高低温的防水涂料 | |
| CN103509179A (zh) | 聚酰氨切片前聚合热水回收利用系统 | |
| CN103304174A (zh) | 一种膨胀珍珠岩的生产方法 | |
| CN102020310A (zh) | 一种光谱纯氧化铟的制备方法 | |
| CN104117378B (zh) | 酯化反应催化剂的制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180403 |