CN105862410A - Method for producing functional cotton fabric through complexing trivalent cerium ions and phytic acid - Google Patents
Method for producing functional cotton fabric through complexing trivalent cerium ions and phytic acid Download PDFInfo
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- CN105862410A CN105862410A CN201610180649.5A CN201610180649A CN105862410A CN 105862410 A CN105862410 A CN 105862410A CN 201610180649 A CN201610180649 A CN 201610180649A CN 105862410 A CN105862410 A CN 105862410A
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- phytic acid
- cotton
- trivalent cerium
- cotton fabric
- aqueous solution
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920000742 Cotton Polymers 0.000 title claims abstract description 30
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 title claims abstract description 27
- 235000002949 phytic acid Nutrition 0.000 title claims abstract description 27
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 229940068041 phytic acid Drugs 0.000 title claims abstract description 25
- 239000000467 phytic acid Substances 0.000 title claims abstract description 25
- 229910052684 Cerium Inorganic materials 0.000 title claims abstract description 16
- -1 cerium ions Chemical class 0.000 title claims abstract description 16
- 239000004744 fabric Substances 0.000 title abstract description 13
- 230000000536 complexating effect Effects 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 claims abstract description 19
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000007864 aqueous solution Substances 0.000 claims abstract description 14
- 238000003756 stirring Methods 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims abstract description 7
- 238000010668 complexation reaction Methods 0.000 claims description 5
- VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical group Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 claims description 3
- WTVAYLQYAWAHAX-UHFFFAOYSA-J cerium(4+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Ce+4] WTVAYLQYAWAHAX-UHFFFAOYSA-J 0.000 claims 1
- 229920000767 polyaniline Polymers 0.000 abstract description 8
- 238000002360 preparation method Methods 0.000 abstract description 5
- 238000011065 in-situ storage Methods 0.000 abstract description 3
- 238000005406 washing Methods 0.000 abstract description 3
- 239000003463 adsorbent Substances 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 1
- 238000005189 flocculation Methods 0.000 abstract 1
- 230000016615 flocculation Effects 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 102000053602 DNA Human genes 0.000 description 2
- 108020004414 DNA Proteins 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229920000137 polyphosphoric acid Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 206010000234 Abortion spontaneous Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 208000007502 anemia Diseases 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- SQKWGPOIVHMUNF-UHFFFAOYSA-K cerium(3+);trichloride;hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Cl-].[Ce+3] SQKWGPOIVHMUNF-UHFFFAOYSA-K 0.000 description 1
- SMKFCFKIYPLYNY-UHFFFAOYSA-K cerium(3+);trichloride;hydrate Chemical compound O.Cl[Ce](Cl)Cl SMKFCFKIYPLYNY-UHFFFAOYSA-K 0.000 description 1
- 230000002759 chromosomal effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 230000002068 genetic effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- 208000032839 leukemia Diseases 0.000 description 1
- 210000004880 lymph fluid Anatomy 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 210000002826 placenta Anatomy 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 208000000995 spontaneous abortion Diseases 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/20—Halides of elements of Groups 4 or 14 of the Periodic Table, e.g. zirconyl chloride
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
- D06M11/65—Salts of oxyacids of nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a method for producing a functional cotton fabric through complexing trivalent cerium ions and phytic acid. The method includes the following steps: (1) dissolving a trivalent cerium ion salt in 50mL of water, adding a cotton cloth, stirring at 60DEG C for 30min, taking out the cotton cloth, and drying the cotton cloth; (2) placing the processed cotton cloth in an aqueous solution of phytic acid, and stirring at 80DEG C for 45min; (3) cooling the solution to 0-5DEG C, and adding aniline; (4) slowly adding an aqueous solution of ammonium persulfate in a dropwise manner, and standing for 30min after the dropwise addition ends; and (5) taking out the processed cotton fabric, washing the cotton fabric with water, and drying. The trivalent cerium ions are adopted in the preparation method as a phytic acid adsorbent and enrich phytic acid on the surfaces of cotton fibers, and in situ polymerization of aniline is carried on the surfaces of the cotton fibers, so the cotton fabric has conduction and flame retardation performances; and the flocculation technology of the trivalent cerium ions to phytic acid is combined with the polyaniline in situ chemical synthesis technology, so the washing resistance of phytic acid is increased, and the stability and the durability of the conduction and flame retardation performances of the cotton fabric and durability are improved.
Description
Technical field
The present invention relates to a kind of function bafta preparation method, a kind of method utilizing trivalent cerium ion complexation phytic acid to prepare function bafta.
Background technology
Along with the progress of science and technology, more electric equipment products get their way into people's lives, and have brought electromagnetic pollution, are referred to as the fourth-largest pollution after air pollution, water pollution and sound pollution.After the human body electromagnetic wave radiation by excess, blood, lymph fluid and cellular plasm can change, cause intracellular DNA (deoxyribonucleic acid) impaired and genetic undergoing mutation and lopsided, and then induce leukemia and tumor, also can cause Placenta Hominis chromosomal change, cause the deformity of baby or the spontaneous abortion of anemia of pregnant woman.
Conducting polymer is that the organic polymer with controllable electric conductivity, especially polyaniline have been widely used for the fields such as conduction, electromagnetic shielding, antistatic, anti-corrosion of metal, opto-electronic device, gas-sensing probe, super capacitor.Utilizing the in situ chemical oxidation technology can be by polyaniline-coated at textile surface, especially cotton fiber surface, so that nonconducting bafta has electric conductivity.Polyaniline generally regulates and controls electric conductivity by doping, and conventional adulterant is proton acid.Current published polyaniline-coated bafta mainly uses some small molecular organic acids to be doped, the easy dedoping of dopant acid in washing process and lose electric conductivity.
Phytic acid is a kind of polyphosphoric acids, as chelating agen, antioxidant, antistaling agent, water softener, fermentation accelerant, anticorrosive metal agent etc., it is widely used in the industry fields such as food, medicine, paint, coating, daily-use chemical industry, anti-corrosion of metal, textile industry, plastics industry and Polymeric Industry.Phytate molecule, with 6 electronegative phosphate groups, may be used for the doping of polyaniline, and has preferable flame retardant effect to cotton fiber；Phytate molecule has coplanarity, and affinity is relatively big, can be formed the complex of more macromolecule by trivalent cerium ion so that it is have preferable washability.
Summary of the invention
The technical problem to be solved is, the shortcoming existed for above prior art, a kind of method utilizing trivalent cerium ion complexation phytic acid to prepare function bafta is proposed, this preparation method is simple, preparation cost is cheap, the bafta prepared has good electric conductivity and fire resistance, has the advantages such as washability simultaneously.
The present invention adopts the following technical scheme that to achieve these goals.
A kind of method utilizing trivalent cerium ion complexation phytic acid to prepare function bafta that the present invention provides, this preparation method comprises the steps: that 0.5-2g trivalent cerium ion salt is dissolved in 50mL water by (1), adds cotton, stirs 30min, take out and dry under 60 C；(2) cotton of above-mentioned process is placed in 100mL and contains in 5-10g phytic acid aqueous solution, under 80 C, stir 45min；(3) it is cooled to 0-5 C, adds 0.5-5mL aniline；(4) it is slowly added dropwise the 20mL aqueous solution containing 2-7g Ammonium persulfate., after dripping off, stands 30min；(5) bafta after above-mentioned process is taken out, wash, dry.
The beneficial effects of the present invention is, this technology of preparing (1) is coated with polyaniline at surface of cotton fabric, using phytic acid as dopant acid, makes bafta have electric conductivity；(2) owing to being coated with doped polyaniline at surface of cotton fabric, introducing more nitrogen element and P elements at surface of cotton fabric, synergism therebetween can improve the fire resistance of bafta；(3) phytic acid is a kind of ring-type polyphosphoric acids, has coplanarity, and affinity is big, is difficult to dedoping；(4) using trivalent cerium ion as phytic acid adsorbent, phytic acid is enriched in cotton fiber surface, and forms water-fast complex, improve the washability of phytic acid, reduce further the dedoping probability of phytic acid, improve conduction and fire-retardant stability.
Detailed description of the invention
The present invention is described in detail below in conjunction with specific embodiment.It should be noted that, what the combination of technical characteristic described in following embodiment or technical characteristic was not construed as isolating, they can be mutually combined thus be reached superior technique effect.
Embodiment 1
(1) 0.5g cerium chloride is dissolved in 50mL water, adds cotton, stir 30min under 60 C, take out and dry；
(2) cotton of above-mentioned process is placed in 100mL and contains in 5g phytic acid aqueous solution, under 80 C, stir 45min；
(3) it is cooled to 0 C, adds 0.5mL aniline；
(4) it is slowly added dropwise the 20mL aqueous solution containing 2g Ammonium persulfate., after dripping off, stands 30min；
(5) bafta after above-mentioned process is taken out, wash, dry.
Embodiment 2
(1) 2g seven chloride hydrate cerium is dissolved in 50mL water, adds cotton, stir 30min under 60 C, take out and dry；
(2) cotton of above-mentioned process is placed in 100mL and contains in 10g phytic acid aqueous solution, under 80 C, stir 45min；
(3) it is cooled to 5 C, adds 5mL aniline；
(4) it is slowly added dropwise the 20mL aqueous solution containing 7g Ammonium persulfate., after dripping off, stands 30min；
(5) bafta after above-mentioned process is taken out, wash, dry.
Embodiment 3
(1) 1g cerium chloride is dissolved in 50mL water, adds cotton, stir 30min under 60 C, take out and dry；
(2) cotton of above-mentioned process is placed in 100mL and contains in 8g phytic acid aqueous solution, under 80 C, stir 45min；
(3) it is cooled to 0 C, adds 3mL aniline；
(4) it is slowly added dropwise the 20mL aqueous solution containing 5g Ammonium persulfate., after dripping off, stands 30min；
(5) bafta after above-mentioned process is taken out, wash, dry.
Embodiment 4
(1) 1.5g Cerium trichloride hexahydrate. is dissolved in 50mL water, adds cotton, stir 30min under 60 C, take out and dry；
(2) cotton of above-mentioned process is placed in 100mL and contains in 5g phytic acid aqueous solution, under 80 C, stir 45min；
(3) it is cooled to 2 C, adds 4mL aniline；
(4) it is slowly added dropwise the 20mL aqueous solution containing 6g Ammonium persulfate., after dripping off, stands 30min；
(5) bafta after above-mentioned process is taken out, wash, dry.
Although having been presented for some embodiments of the present invention herein, it will be appreciated by those of skill in the art that without departing from the spirit of the invention, the embodiments herein can be changed.Above-described embodiment is exemplary, should be using the embodiments herein as the restriction of interest field of the present invention.
Claims (2)
1. one kind utilizes the method that trivalent cerium ion complexation phytic acid prepares function bafta, it is characterised in that comprise the steps:
(1) 0.5-2g trivalent cerium ion salt is dissolved in 50mL water, adds cotton, stir 30min under 60 C, take out and dry；
(2) cotton of above-mentioned process is placed in 100mL and contains in 5-10g phytic acid aqueous solution, under 80 C, stir 45min；
(3) it is cooled to 0-5 C, adds 0.5-5mL aniline；
(4) it is slowly added dropwise the 20mL aqueous solution containing 2-7g Ammonium persulfate., after dripping off, stands 30min；
(5) bafta after above-mentioned process is taken out, wash, dry.
2. according to the trivalent cerium ion salt described in claim 1, it is characterised in that trivalent cerium ion salt is cerium chloride and hydrate thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610180649.5A CN105862410A (en) | 2016-03-28 | 2016-03-28 | Method for producing functional cotton fabric through complexing trivalent cerium ions and phytic acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610180649.5A CN105862410A (en) | 2016-03-28 | 2016-03-28 | Method for producing functional cotton fabric through complexing trivalent cerium ions and phytic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105862410A true CN105862410A (en) | 2016-08-17 |
Family
ID=56624789
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610180649.5A Pending CN105862410A (en) | 2016-03-28 | 2016-03-28 | Method for producing functional cotton fabric through complexing trivalent cerium ions and phytic acid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105862410A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109161318A (en) * | 2018-06-28 | 2019-01-08 | 南京信息工程大学 | A kind of functional paint and the preparation method and application thereof |
| CN110197905A (en) * | 2018-02-27 | 2019-09-03 | 湖南省银峰新能源有限公司 | A kind of modifying carbon material and the electrode of liquid flow cell of class graphene nanometer sheet prepared therefrom modification |
-
2016
- 2016-03-28 CN CN201610180649.5A patent/CN105862410A/en active Pending
Non-Patent Citations (3)
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| 刘高峰: "聚苯胺/纯棉导电复合织物的制备及性能研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
| 唐俊云等: "聚苯胺复合导电织物的研究进展", 《纺织学报》 * |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110197905A (en) * | 2018-02-27 | 2019-09-03 | 湖南省银峰新能源有限公司 | A kind of modifying carbon material and the electrode of liquid flow cell of class graphene nanometer sheet prepared therefrom modification |
| CN110197905B (en) * | 2018-02-27 | 2021-03-30 | 湖南省银峰新能源有限公司 | Modified carbon material and graphene-like nanosheet-modified redox flow battery electrode prepared from same |
| CN109161318A (en) * | 2018-06-28 | 2019-01-08 | 南京信息工程大学 | A kind of functional paint and the preparation method and application thereof |
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Application publication date: 20160817 |