CN105603734B - A kind of method for preparing function cotton fabric using bivalent nickel ion complexing phytic acid - Google Patents
A kind of method for preparing function cotton fabric using bivalent nickel ion complexing phytic acid Download PDFInfo
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- CN105603734B CN105603734B CN201610180648.0A CN201610180648A CN105603734B CN 105603734 B CN105603734 B CN 105603734B CN 201610180648 A CN201610180648 A CN 201610180648A CN 105603734 B CN105603734 B CN 105603734B
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- phytic acid
- cotton
- nickel ion
- cotton fabric
- bivalent nickel
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- 229920000742 Cotton Polymers 0.000 title claims abstract description 45
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 title claims abstract description 28
- 235000002949 phytic acid Nutrition 0.000 title claims abstract description 28
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000004744 fabric Substances 0.000 title claims abstract description 26
- 229940068041 phytic acid Drugs 0.000 title claims abstract description 26
- 239000000467 phytic acid Substances 0.000 title claims abstract description 26
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 11
- 229910001453 nickel ion Inorganic materials 0.000 title claims abstract description 11
- 230000000536 complexating effect Effects 0.000 title claims abstract description 8
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000007864 aqueous solution Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 7
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims description 4
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical group Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 2
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims 1
- 229920000767 polyaniline Polymers 0.000 abstract description 8
- 238000005516 engineering process Methods 0.000 abstract description 7
- 239000003063 flame retardant Substances 0.000 abstract description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 4
- 238000011065 in-situ storage Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000003463 adsorbent Substances 0.000 abstract 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 abstract 1
- 230000016615 flocculation Effects 0.000 abstract 1
- 238000005189 flocculation Methods 0.000 abstract 1
- 230000002688 persistence Effects 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000137 polyphosphoric acid Polymers 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 206010000234 Abortion spontaneous Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 230000002759 chromosomal effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- 208000032839 leukemia Diseases 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 210000002751 lymph Anatomy 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 208000015994 miscarriage Diseases 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 210000002826 placenta Anatomy 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 208000000995 spontaneous abortion Diseases 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/28—Halides of elements of Groups 8, 9, 10 or 18 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
- D06M11/65—Salts of oxyacids of nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention provides a kind of methods for preparing function cotton fabric using bivalent nickel ion complexing phytic acid, and this method comprises the following steps:(1)Bivalent nickel ion salt is dissolved in 50mL water, cotton is added in, stirs 30min under 60oC, take out and dry;(2)The cotton of above-mentioned processing is placed in phytic acid aqueous solution, 45min is stirred under 80oC;(3)0 5oC is cooled to, adds in aniline;(4)Ammonium persulfate aqueous solution is slowly added dropwise, 30min is stood after dripping off;(5)Treated cotton fabric is taken out, washes, dry.This technology of preparing is using bivalent nickel ion as phytic acid adsorbent, and phytic acid is enriched in cotton fiber surface, cotton fabric is made to have conductive and flame retardant property on cotton fiber surface aniline in-situ polymerization based on this;Bivalent nickel ion is combined the flocculation technique of phytic acid with polyaniline in-situ chemical synthetic technology, increases the washability of phytic acid, improves cotton fabric conduction, fire-retardant stability and persistence.
Description
Technical field
It is especially a kind of to be prepared using bivalent nickel ion complexing phytic acid the present invention relates to a kind of function cotton fabric preparation method
The method of function cotton fabric.
Background technology
With the development of science and technology more electric equipment products get their way into people's lives, electromagnetic pollution has been brought,
The fourth-largest pollution referred to as after air pollution, water pollution and noise pollution.Human body is by after excessive electromagnetic wave radiation, blood
Liquid, lymph and cellular plasm can change, and intracellular DNA is caused to be damaged and occurs to dash forward with gene
Become and lopsided, and then induce leukaemia and tumour, can also cause placenta chromosomal change, cause baby deformity or pregnant woman oneself
So miscarriage.
Conducting polymer is that the organic polymer for having controllable electric conductivity, especially polyaniline have been widely used for
The fields such as conduction, electromagnetic shielding, antistatic, anti-corrosion of metal, opto-electronic device, gas-sensing probe, super capacitor.Utilize in-situ chemical
Oxidation technology can be by polyaniline-coated in textile surface, especially cotton fiber surface, so as to have nonconducting cotton fabric
It is conductive.Polyaniline usually regulates and controls electric conductivity by adulterating, and common dopant is proton acid.It is published at present
Polyaniline-coated cotton fabric is mainly doped using some small molecular organic acids, the easy dedoping of dopant acid in washing process
And lose electric conductivity.
Phytic acid is a kind of polyphosphoric acids, as chelating agent, antioxidant, antistaling agent, water softener, fermentation accelerant, metal
Anticorrosive etc. is widely used in food, medicine, paint, coating, daily-use chemical industry, anti-corrosion of metal, textile industry, plastics industry
And the industry fields such as Polymeric Industry.Phytate molecule carries 6 electronegative phosphate groups, can be used for mixing for polyaniline
It is miscellaneous, and there is preferable flame retardant effect to cotton fiber;Phytate molecule has coplanarity, and affinity is larger, can pass through divalent
Nickel ion forms the complex compound of more macromolecule, makes it have preferable washability.
Invention content
The technical problems to be solved by the invention are that, for above shortcoming of the existing technology, proposition is a kind of to utilize two
The method that valency nickel ion complexing phytic acid prepares function cotton fabric, the preparation method is simple and practicable, and manufacturing cost is cheap, prepares
Cotton fabric has many advantages, such as good electric conductivity and flame retardant property, while has washability.
The present invention adopts the following technical scheme that achieve these goals.
A kind of method for preparing function cotton fabric using bivalent nickel ion complexing phytic acid provided by the invention, this preparation method
Include the following steps:(1)3-5g bivalent nickel ion salt is dissolved in 50mL water, cotton is added in, stirs 30min under 60oC, take
Go out and dry;(2)The cotton of above-mentioned processing is placed in 100mL to contain in 5-10g phytic acid aqueous solutions, 45min is stirred under 80oC;
(3)0-5oC is cooled to, adds in 0.5-5mL aniline;(4)The 20mL aqueous solutions containing 2-7g ammonium persulfates are slowly added dropwise, after dripping off
Stand 30min;(5)Treated cotton fabric is taken out, washes, dry.
The beneficial effects of the present invention are this technologies of preparing(1)Polyaniline is coated in surface of cotton fabric, using phytic acid as mixing
Heteroacid makes cotton fabric conductive;(2)Due to having coated doped polyaniline in surface of cotton fabric, in surface of cotton fabric
More nitrogen and P elements are introduced, synergistic effect therebetween can improve the flame retardant property of cotton fabric;(3)Phytic acid is
A kind of ring-type polyphosphoric acids, has coplanarity, affinity is big, is not easy dedoping;(4)It is adsorbed bivalent nickel ion as phytic acid
Phytic acid is enriched in cotton fiber surface, and forms complex compound not soluble in water by agent, improves the washability of phytic acid, is further dropped
The low dedoping possibility of phytic acid improves conductive and fire-retardant stability.
Specific embodiment
The present invention is described in detail below in conjunction with specific embodiment.It should be noted that the skill described in following embodiments
The combination of art feature or technical characteristic is not construed as isolated, they can be combined with each other to reach better
Technique effect.
Embodiment 1
(1)3g nickel chlorides are dissolved in 50mL water, cotton is added in, stirs 30min under 60oC, take out and dry;
(2)The cotton of above-mentioned processing is placed in 100mL to contain in 5g phytic acid aqueous solutions, 45min is stirred under 80oC;
(3)0oC is cooled to, adds in 0.5mL aniline;
(4)The 20mL aqueous solutions containing 2g ammonium persulfates are slowly added dropwise, 30min is stood after dripping off;
(5)Treated cotton fabric is taken out, washes, dry.
Embodiment 2
(1)5g nickel nitrates are dissolved in 50mL water, cotton is added in, stirs 30min under 60oC, take out and dry;
(2)The cotton of above-mentioned processing is placed in 100mL to contain in 10g phytic acid aqueous solutions, 45min is stirred under 80oC;
(3)5oC is cooled to, adds in 5mL aniline;
(4)The 20mL aqueous solutions containing 7g ammonium persulfates are slowly added dropwise, 30min is stood after dripping off;
(5)Treated cotton fabric is taken out, washes, dry.
Embodiment 3
(1)4g nickel nitrates are dissolved in 50mL water, cotton is added in, stirs 30min under 60oC, take out and dry;
(2)The cotton of above-mentioned processing is placed in 100mL to contain in 8g phytic acid aqueous solutions, 45min is stirred under 80oC;
(3)0oC is cooled to, adds in 3mL aniline;
(4)The 20mL aqueous solutions containing 5g ammonium persulfates are slowly added dropwise, 30min is stood after dripping off;
(5)Treated cotton fabric is taken out, washes, dry.
Embodiment 4
(1)3g nickel nitrates are dissolved in 50mL water, cotton is added in, stirs 30min under 60oC, take out and dry;
(2)The cotton of above-mentioned processing is placed in 100mL to contain in 5g phytic acid aqueous solutions, 45min is stirred under 80oC;
(3)2oC is cooled to, adds in 4mL aniline;
(4)The 20mL aqueous solutions containing 6g ammonium persulfates are slowly added dropwise, 30min is stood after dripping off;
(5)Treated cotton fabric is taken out, washes, dry.
Although having been presented for some embodiments of the present invention herein, it will be appreciated by those of skill in the art that
Without departing from the spirit of the invention, the embodiments herein can be changed.Above-described embodiment is only exemplary, no
It should be using the embodiments herein as the restriction of interest field of the present invention.
Claims (2)
- A kind of 1. method for preparing function cotton fabric using bivalent nickel ion complexing phytic acid, which is characterized in that include the following steps:(1)3-5g bivalent nickel ion salt is dissolved in 50mL water, cotton is added in, stirs 30min under 60oC, take out and dry;(2)The cotton of above-mentioned processing is placed in 100mL to contain in 5-10g phytic acid aqueous solutions, 45min is stirred under 80oC;(3)0-5oC is cooled to, adds in 0.5-5mL aniline;(4)The 20mL aqueous solutions containing 2-7g ammonium persulfates are slowly added dropwise, 30min is stood after dripping off;(5)Treated cotton fabric is taken out, washes, dry.
- 2. a kind of method for preparing function cotton fabric using bivalent nickel ion complexing phytic acid according to claim 1, special Sign is that the bivalent nickel ion salt is nickel chloride, nickel nitrate.
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CN105603734B true CN105603734B (en) | 2018-06-15 |
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CN112359597B (en) * | 2020-12-07 | 2022-02-18 | 东华大学 | Organic/inorganic hybrid film-coated cotton textile and preparation method thereof |
CN116554555B (en) * | 2023-07-06 | 2023-08-29 | 广州市寅源新材料股份有限公司 | Expandable graphite/phytic acid composite flame retardant, and preparation method and application thereof |
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