CN105861201A - Method for preparing cleaning supply by taking Chinese soapberry fruit pulp as partial raw material - Google Patents
Method for preparing cleaning supply by taking Chinese soapberry fruit pulp as partial raw material Download PDFInfo
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- CN105861201A CN105861201A CN201610242288.2A CN201610242288A CN105861201A CN 105861201 A CN105861201 A CN 105861201A CN 201610242288 A CN201610242288 A CN 201610242288A CN 105861201 A CN105861201 A CN 105861201A
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- Prior art keywords
- sodium
- enediol
- water
- grease
- cooking liquid
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a method for preparing a cleaning supply by taking Chinese soapberry fruit pulp as a partial raw material. The method comprises the steps that the Chinese soapberry fruit pulp is boiled with water to enable monosaccharides and saponins in the Chinese soapberry fruit pulp to be released into the water, and boiled liquid is taken; ring opening is conducted on the monosaccharides in the boiled liquid to form 1,2-enediol, 2,3-enediol and 3,4-enediol to remove saccharides and convert the saccharides into ingredients favorable for cleaning; 1,2-enediol, 2,3-enediol and 3,4-enediol in the boiled liquid are oxidized in the presence of sodium hydroxide to generate sodium bicarbonate, sodium carbonate, sodium acetate, sodium oxalate and sodium lactate; grease is added into the boiled liquid in the presence of strong alkali to enable the grease and the strong alkali to be saponified into soap containing saponins, sodium bicarbonate, sodium carbonate, sodium acetate, sodium oxalate and sodium lactate. According to the method, the problem that a bacteriostatic agent and washing ingredients need to be additionally added into an existing final product obtained when saponins are extracted from Chinese soapberry fruit can be solved.
Description
Technical field
The present invention relates to the use of a kind of soapberry pulp, and be part material particularly to one with this pulp
The method of preparation cleaning supplies.
Background technology
Saponin(e (saponin) is that aglycon connects to, not only with glycosidic bond (glycosidic bond) with carbohydrate
Exist as, in the Chinese herbal medicines such as ginseng, polygala root, balloonflower root, Radix Glycyrrhizae, radix bupleuri or soapberry, there is also such as starfish
Or in the marine animal such as sea cucumber.And soapberry pulp rich in saponin(e, be more added into the cleaning of daily life
Articles for use are used for foam, therefore have many cleaning supplies relevant to soapberry to arise at the historic moment.Mainly need
The technical problem overcome is in soapberry pulp in addition to saponin(e, and also organic acid and the existence of carbohydrate content, have
Machine acid easily makes product oxidative rancidity；If not removing carbohydrate, easily cause bacterial growth, therefore except effectively carrying
Taking outside saponin constituent, the removal of organic acid and carbohydrate is also one of the problem that need to overcome.
From soapberry extract prepare the flow process of soap can refer to TaiWan, China patent of invention notification number I341329,
U.S. patent Nos publication number US20100316752 A1 and TaiWan, China patent of invention notification number I383047.
In the flow process shown in TaiWan, China patent of invention notification number I341329, for soapberry extract as raw material,
First carry out ion-exchange treatment step with strong-base anion-exchange resin for material, to remove soapberry extraction
Organic acid in liquid, after carry out ion-exchange treatment step with weak-base anion-exchange resin for material, with
Remove the carbohydrate in soapberry extract, after process step through reverse osmosis again, to remove excessive moisture, take
Must purify containing saponin(e soapberry extract.
And U.S. patent Nos publication number US20100316752 A1 and TaiWan, China patent of invention notification number
Flow process shown in I383047 comprises: is placed a period of time at a temperature by the soapberry fruit without seed, makes
It accumulates wine fermentation naturally；Put into accumulateing the soapberry fruit after sending out process in dialysis apparatus, and dialyse with liquid
Go out the product () containing ferment；The ripest pericarp of the soapberry fruit after dialysis is put into separation dress
In putting, to carry out pulp, fruit fiber decomposes processing；Pulp after decomposing is mixed into liquid with fruit fiber, with
Time put in pressing device and squeeze so that liquid extraction is taken pulp out of and become fruit liquid, and the fruit stayed is fine
Dimension then becomes product (two)；Fruit liquid is introduced in steaming plant, through thermophilic digestion, harmful bacteria is removed；
And will complete in the fruit liquid introducing vacuum plant after sterilization, placement a period of time makes it naturally accumulate wine fermentation,
With alcoholization mode by saccharide converted fall, make carbohydrate be not present in product, and become containing interfacial activity saponin(e
With organic acid, the soapberry fruit liquid of carbohydrate ferment enzyme organic matter.
But, the end product of above-mentioned existing procedure gained cannot suppress bacterium or fungus growth, and must be additionally
Organic acid is removed with ion exchange resin or alcoholization removes carbohydrate, once be fabricated to cleaning supplies, for keeping away
Exempting from cleaning supplies breed bacteria or mould so that reducing its useful life, still must additionally add bacteriostatic agent.
Summary of the invention
One purpose of the present invention is that providing a kind of soapberry pulp is the side that part material prepares cleaning supplies
Method, it is with soapberry pulp as part material, and can improve existing from soapberry extraction saponin(e gained final
The problem that product must additionally add bacteriostatic agent and cleaning ingredients.
Then, an aspect of of the present present invention proposes a kind of soapberry pulp is that part material prepares cleaning supplies
Method, it comprises the steps of water and boils soapberry pulp, makes the monose in soapberry pulp discharge with saponin(e
To water, to obtain a water cooking liquid；Add a highly basic to the monose open loop in water cooking liquid, to form 1,2-alkene
Glycol (1,2-enediol), 2,3-enediol (2,3-enediol) and 3,4-enediol (3,4-enediol)；
In oxidation water cooking liquid 1,2-enediol, 2,3-enediol and 3,4-enediol, and under NaOH effect,
Form sodium acid carbonate (sodium hydrocarbonate), sodium carbonate (sodium carbonate), sodium acetate
(sodium acetate), sodium oxalate (sodium oxalate) and sodium lactate (sodium lactate)；With
And in the presence of this NaOH, add a grease to water cooking liquid, make grease become one with this sodium hydroxide saponification
Soap containing saponin(e, sodium acid carbonate, sodium carbonate, sodium acetate, sodium oxalate and sodium lactate.
Wherein, this highly basic is NaOH or potassium hydroxide, and this grease is coconut oil, palm oil, olive
Oil or soapberry oil.
Wherein, this open loop step further includes: add another highly basic to this water cooking liquid.
Wherein, this oxidation step further includes: add a strong oxidizer to this water cooking liquid.
Wherein, this strong oxidizer is ozone, potassium nitrate, the concentrated sulfuric acid, nitric acid, potassium chlorate, sodium chlorate, mistake
Hydrogen oxide or potassium perchlorate.
It is the side that part material prepares cleaning supplies that another aspect of the present invention proposes a kind of soapberry pulp
Method, it comprises following step: water boils soapberry pulp, makes the monose in soapberry pulp discharge extremely with saponin(e
In water, to obtain a water cooking liquid；Add a highly basic to the monose open loop in water cooking liquid, to form 1,2-alkene two
Alcohol, 2,3-enediol and 3,4-enediol；1,2-enediol, 2,3-enediol and 3,4-in oxidation water cooking liquid
Enediol, and under NaOH effect, form sodium acid carbonate, sodium carbonate, sodium acetate, sodium oxalate and breast
Acid sodium；Heating water cooking liquid, makes the formaldehyde in water cooking liquid remove with water, to obtain a desciccate；Add one
Grease to desciccate, does not dissolves component and a dissolved constituent being separated into one, and insoluble component contains on a small quantity
Grease, sodium acid carbonate, sodium carbonate, sodium acetate, sodium oxalate and sodium lactate, dissolved constituent contains volume grease
And saponin(e；In the presence of a highly basic, add and add water to insoluble component, make the grease in insoluble component with strong
Alkali soap chemical conversion one is containing sodium acid carbonate, sodium carbonate, sodium acetate, sodium oxalate and the cleaning agent of sodium lactate；And
Add a strong base solution to dissolved constituent, make the grease in dissolved constituent be saponified into one containing saponin(e with strong base solution
Soap.
Wherein, this highly basic is NaOH or potassium hydroxide, and this grease is coconut oil, palm oil, olive
Oil or soapberry oil.
Wherein, this open loop step further includes: add another highly basic to this water cooking liquid.
Wherein, this oxidation step further includes: add a strong oxidizer to this water cooking liquid.
Wherein, this strong oxidizer is ozone, potassium nitrate, the concentrated sulfuric acid, nitric acid, potassium chlorate, sodium chlorate, mistake
Hydrogen oxide or potassium perchlorate.
The present invention provides a kind of method of novel preparation cleaning supplies, and it is with soapberry pulp as part material,
And can improve existing from soapberry extraction saponin(e gained end product must additionally add bacteriostatic agent and cleaning ingredients
Problem.
Describe the present invention below in conjunction with the drawings and specific embodiments, but not as to the present invention's
Limit.
Accompanying drawing explanation
Fig. 1 is a flow chart, and what first embodiment of the invention was described is part material with soapberry pulp
The method of preparation cleaning supplies.
Fig. 2 is a flow chart, and what second embodiment of the invention was described is part material with soapberry pulp
The method of preparation cleaning supplies.
Wherein, reference:
S11 water boils step
S12 open loop step
S13 oxidation step
S14 saponification step
11 soapberry pulp
111 water
12 monose
121 highly basic
13 saponin(es
14 1,2-enediols, 2,3-enediol and 3,4-enediol
141 strong oxidizers
15 organic acids
151 NaOH
16 organic acid sodium salts
161 greases
17 soap
S21 water boils step
S22 open loop step
S23 oxidation step
S24 heating steps
S25 separating step
S26 does not dissolves the saponification step of component
The saponification step of S27 dissolved constituent
21 soapberry pulp
211 water
22 monose
221 highly basic
23 saponin(es
24 1,2-enediols, 2,3-enediol and 3,4-enediol
241 strong oxidizers
25 organic acids
251 greases
252 NaOH
26 organic acid sodium salts
261 do not dissolve component
262 dissolved constituents
263 water
27 soap
28 soap bases
29 daily use chemicals product additives
30 cleaning agents
Detailed description of the invention
In order becoming apparent, the present invention is above-mentioned and/or other purpose, effect, feature, preferable reality cited below particularly
Execute example, elaborate:
Embodiment one
Refer to Fig. 1, first embodiment of the invention prepare cleaning with soapberry pulp 11 for part material
The method of articles for use, has steps of: water boil step S11, open loop step S12, oxidation step S13 and
Saponification step S14.
It is that water boils soapberry pulp 11 that water boils step S11, makes the monose 12 in soapberry pulp 11 and saponin(e
13 discharge to water 111, to obtain a water cooking liquid.In detail, step S11 may utilize water 111 and infiltrates into
Pulp 11 is to take out of in monose 12 and saponin(e 13 to water 111, therefore water cooking liquid at least contains monose 12 and soap
Glycosides 13.
Open loop step S12 is to monose 12 open loop in water cooking liquid, to form 1, and 2-enediol, 2,3-alkene two
Alcohol and 3,4-enediol 14.In present embodiment, step S12 can be added a small amount of highly basic 121 to water and be boiled
Liquid carries out ring-opening reaction S12.The example of highly basic 121 can be but be not limited to, NaOH or hydroxide
Potassium.
Oxidation step S13 is in the presence of a small amount of NaOH 121,1,2-in heavy oxidation water cooking liquid
Enediol, 2,3-enediol and 3,4-enediol 14 forms organic acid 15, wherein 1,2-enediol forms carbonic acid
With acetic acid, 2,3-enediols form oxalic acid, and 3,4-enediols form lactic acid.Again with the NaOH 151 of volume
Effect, forms the organic acid sodium salts 16 such as sodium acid carbonate, sodium carbonate, sodium acetate, sodium oxalate and sodium lactate, its
Middle sodium acid carbonate is washing sodium bicarbonate, and sodium carbonate is washing soda, and sodium acetate can be flavouring mould inhibitor,
Sodium oxalate is blotchy remover, and sodium lactate has antiseptic effect, also can be lubricant and emollient.Yu Benshi
Executing in mode, step S13 can add strong oxidizer 141 a to water cooking liquid to carry out oxidation reaction S13.By force
The example of oxidant 141 can be but be not limited to, ozone, potassium nitrate, the concentrated sulfuric acid, nitric acid, potassium chlorate,
Sodium chlorate, hydrogen peroxide or potassium perchlorate.Wherein, ozone is then changed into after being gaseous state and ozone oxidation reaction
The same oxygen in gaseous state, so can avoid ozone to react thing and residue in water cooking liquid.
Saponification step S14 is in the presence of the NaOH 151 of volume, adds grease 161 a to water cooking liquid,
Grease 161 is made to be saponified into one containing saponin(e 13, sodium acid carbonate, sodium carbonate, second with the NaOH 151 of volume
Acid sodium, sodium oxalate and the soap 17 of sodium lactate.The example of grease 161 can be but be not limited to, coconut oil,
Palm oil, olive oil or soapberry oil.
According to present embodiment, the monose in soapberry pulp through a series of process be changed into widely known bacteriostatic agent and
Sodium bicarbonate etc. contribute to the composition of cleaning, such as sodium acid carbonate, sodium carbonate, sodium acetate, sodium oxalate or sodium lactate.
By this kind of mode, the soap of gained then can reduce the extra demand adding other bacteriostatic agent and washing agent；As
Being necessary, the amount added is by the amount less than existing interpolation.
Embodiment two
Refer to Fig. 2, second embodiment of the invention prepare cleaning with soapberry pulp 21 for part material
The method of articles for use, has steps of: water boils step S21, open loop step S22, oxidation step S23, adds
The saponification step of hot step S24, separating step S25, saponification step S26 of insoluble component and dissolved constituent
Rapid S27.
It is that water 211 boils soapberry pulp 21 that water boils step S21, make monose in soapberry pulp 21 22 with
Saponin(e 23 discharges to water, to obtain a water cooking liquid.In detail, step S21 may utilize water 211 and permeates
To pulp 21 with take out of monose 22 with in saponin(e 23 to water 211, therefore water cooking liquid at least contain monose 22 and
Saponin(e 23.
Open loop step S22 is to monose 22 open loop in water cooking liquid, to form 1, and 2-enediol, 2,3-alkene two
Alcohol and 3,4-enediol 24.In present embodiment, step S22 can add a small amount of one first highly basic 221 to
Water cooking liquid carries out ring-opening reaction S22.The example of the first highly basic 221 can be but be not limited to, NaOH
Or potassium hydroxide.
Oxidation step S23 is in the presence of the first highly basic 221,1 in oxidation water cooking liquid, 2-enediol, 2,3-
Enediol and 3,4-enediol 24, to form organic acid 25, wherein 1,2-enediol forms carbonic acid and acetic acid,
2,3-enediols form oxalic acid, and 3,4-enediols form lactic acid.Act on NaOH 252, form bicarbonate
The organic acid sodium salts 26 such as sodium, sodium carbonate, sodium acetate, sodium oxalate and sodium lactate, wherein sodium acid carbonate is washing
With sodium bicarbonate, sodium carbonate is washing soda, and sodium acetate can be flavouring mould inhibitor, and sodium oxalate is that blotchy is removed
Agent, sodium lactate has antiseptic effect, also can be lubricant and emollient.In present embodiment, step S23
Strong oxidizer 241 a to water cooking liquid can be added to carry out oxidation reaction S23.The example of strong oxidizer 241 can
Think but be not limited to, ozone, potassium nitrate, the concentrated sulfuric acid, nitric acid, potassium chlorate, sodium chlorate, hydrogen peroxide or
Potassium perchlorate.Wherein, ozone is then to be changed into the same oxygen in gaseous state after gaseous state and ozone oxidation reaction,
Ozone so can be avoided to react thing and to residue in water cooking liquid.
Heating steps S24 is heating water cooking liquid (S23 product), makes the first in water cooking liquid (S23 product)
Aldehyde (not shown) is removed with water (not shown), to obtain a desciccate (not shown).By
It is the accessory substance of oxidation reaction in formaldehyde (not shown), and the World Health Organization has proven to formaldehyde for one
Carcinogenic with teratogenic harmful substance, therefore for avoid residuing in follow-up product, be really necessary to remove it.
Separating step S25 is for adding grease 251 a to desciccate (S24 product), to be separated into one not
Dissolved constituent 261 and a dissolved constituent 262, insoluble component 261 is containing a small amount of grease 251, organic acid sodium
Salt 26 (such as: sodium acid carbonate, sodium carbonate, sodium acetate, sodium oxalate and sodium lactate) and highly basic 221, dissolve
Component 261 is containing volume grease 251 and saponin(e 23.Specifically, such as saponin(e 23 lipophilic substance energy such as grade
It is dissolved in volume grease 251, to form dissolved constituent 262；Otherwise, as sodium acid carbonate, sodium carbonate,
The non-lipophilic substances such as sodium acetate, sodium oxalate and sodium lactate can not be dissolved in volume grease 251, to be formed not
Dissolved constituent 261.And, it is insoluble that component 261 is the most residual a small amount of grease 251.The example of grease 251 can
Think but be not limited to, coconut oil, palm oil, olive oil or soapberry oil.
Saponification step S26 of insoluble component is in the presence of highly basic 221, adds water 263 to the insoluble system of solutions
Divide 261, make a small amount of grease 251 of water insoluble 263 in insoluble component 261 form one with highly basic 221
Soap base 28 floats, can be as the raw material of cleaning agent 30；And do not dissolve in component 261 and be dissolved in having of water 263
Machine acid sodium-salt 26 (sodium acid carbonate, sodium carbonate, sodium acetate, sodium oxalate and sodium lactate), can be as daily
The additive 29 of chemical industries (daily use chemicals product), makes an addition in cleaning agent 30 described above.
Saponification step S27 of dissolved constituent to dissolved constituent 262, makes dissolving for interpolation one highly basic 221 solution
Grease 251 in component 262 and highly basic 221 solution are saponified into the soap 27 containing saponin(e 23.Highly basic 221
The example of solution can be but be not limited to, sodium hydroxide solution or potassium hydroxide solution.
Should be noted that, step S26 there is no a definite limitation with the carrying out order of step S27.For example,
Can first carry out step S26, or first carry out step S27, or carry out this two steps S26, S27 simultaneously.In addition
Product organic acid sodium salt 26 and the soap base 28 of step S26 also can add in S27 step.
According to present embodiment, the monose in soapberry pulp is changed into widely known bacteriostatic agent such as through a series of process
Sodium acetate, washing soda such as sodium acid carbonate, sodium carbonate or sodium oxalate and wetting agent such as sodium lactate.By this kind
The cleaning agent of mode gained, it is to avoid what organic acid caused become sour and carbohydrate is easily multiplied bacterium etc. and preserved and be difficult to
Problem, and can reduce and extra add other wetting agent, bacteriostatic agent or the demand of cleaning ingredients；If it is necessary,
The amount added is by the amount less than existing interpolation.
Certainly, the present invention also can have other various embodiments, without departing substantially from present invention spirit and the feelings of essence thereof
Under condition, those of ordinary skill in the art can make various corresponding change and deformation according to the present invention, but this
A little corresponding changes and deformation all should belong to the protection domain of the claims in the present invention.
Claims (10)
1. one kind is the method that part material prepares cleaning supplies with soapberry pulp, it is characterised in that bag
Include:
Water boils this soapberry pulp, makes the monose in this soapberry pulp discharge to this water with saponin(e, to take
Obtain a water cooking liquid；
Add a highly basic to the monose open loop in this water cooking liquid, to form 1,2-enediol, 2,3-enediol and
3,4-enediol；
Aoxidize 1 in this water cooking liquid, 2-enediol, 2,3-enediol and 3,4-enediol, and in a hydroxide
Under sodium effect, form sodium acid carbonate, sodium carbonate, sodium acetate, sodium oxalate and sodium lactate；And in this hydrogen-oxygen
Change in the presence of sodium, add a grease to this water cooking liquid, make this grease become with this sodium hydroxide saponification one to contain this soap
Glycosides, this sodium acid carbonate, this sodium carbonate, this sodium acetate, this sodium oxalate and the soap of this sodium lactate.
Method the most according to claim 1, it is characterised in that this highly basic is NaOH or hydrogen-oxygen
Change potassium, and this grease is coconut oil, palm oil, olive oil or soapberry oil.
Method the most according to claim 1, it is characterised in that this open loop step further includes:
Add another highly basic to this water cooking liquid.
Method the most according to claim 1, it is characterised in that this oxidation step further includes:
Add a strong oxidizer to this water cooking liquid.
Method the most according to claim 4, it is characterised in that this strong oxidizer is ozone, nitric acid
Potassium, the concentrated sulfuric acid, nitric acid, potassium chlorate, sodium chlorate, hydrogen peroxide or potassium perchlorate.
6. one kind is the method that part material prepares cleaning supplies with soapberry pulp, it is characterised in that bag
Include:
Water boils this soapberry pulp, makes the monose in this soapberry pulp discharge to this water with saponin(e, to take
Obtain a water cooking liquid；
Add a highly basic to the monose open loop in this water cooking liquid, to form 1,2-enediol, 2,3-enediol and
3,4-enediol；Aoxidize 1 in this water cooking liquid, 2-enediol, 2,3-enediol and 3,4-enediol, and in hydrogen
Under sodium oxide molybdena effect, form sodium acid carbonate, sodium carbonate, sodium acetate, sodium oxalate and sodium lactate；Heat this water
Boil liquid, make the formaldehyde in this water cooking liquid remove with water, to obtain a desciccate；
Adding a grease to this desciccate, do not dissolve component and a dissolved constituent being separated into one, this is insoluble
Solve component and contain this grease, this sodium acid carbonate, this sodium carbonate, this sodium acetate, this sodium oxalate and this sodium lactate,
This dissolved constituent contains this grease and this saponin(e, and the amount of this grease in this dissolving part is more than this insoluble system of solutions
The amount of this grease in Fen；
In the presence of this highly basic, add and add water to this insoluble component, make the grease in this insoluble component and be somebody's turn to do
Highly basic is saponified into one containing this sodium acid carbonate, this sodium carbonate, this sodium acetate, this sodium oxalate and this sodium lactate
Cleaning agent；And
Add the solution of this highly basic to this dissolved constituent, make the solution of the grease in this dissolved constituent and this highly basic
It is saponified into the soap containing this saponin(e.
Method the most according to claim 6, it is characterised in that this highly basic is NaOH or hydrogen-oxygen
Change potassium, and this grease is coconut oil, palm oil, olive oil or soapberry oil.
Method the most according to claim 6, it is characterised in that this open loop step further includes:
Add another highly basic to this water cooking liquid.
Method the most according to claim 6, it is characterised in that this oxidation step further includes:
Add a strong oxidizer to this water cooking liquid.
Method the most according to claim 9, it is characterised in that this strong oxidizer is ozone, nitric acid
Potassium, the concentrated sulfuric acid, nitric acid, potassium chlorate, sodium chlorate, hydrogen peroxide or potassium perchlorate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610242288.2A CN105861201B (en) | 2016-04-19 | 2016-04-19 | It is the method that part material prepares cleaning supplies with soapberry pulp |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610242288.2A CN105861201B (en) | 2016-04-19 | 2016-04-19 | It is the method that part material prepares cleaning supplies with soapberry pulp |
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| Publication Number | Publication Date |
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| CN105861201A true CN105861201A (en) | 2016-08-17 |
| CN105861201B CN105861201B (en) | 2018-04-27 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100316752A1 (en) * | 2009-06-10 | 2010-12-16 | Heng-Jui Hsu | Method for extracing substances from soapberry fruit and seed and products made therefrom |
| TWI341329B (en) * | 2005-05-30 | 2011-05-01 | ||
| TWI383047B (en) * | 2008-06-11 | 2013-01-21 | ||
| CN103122287A (en) * | 2013-03-26 | 2013-05-29 | 西南大学 | Soapberry total-nutrient handmade soap and preparation method thereof |
| CN103881838A (en) * | 2014-03-07 | 2014-06-25 | 北京林业大学 | Soapberry liquid composition and dish washing detergent containing same |
| US9217127B2 (en) * | 2013-08-05 | 2015-12-22 | Greenology Products, Inc. | Organic cleaning composition |
-
2016
- 2016-04-19 CN CN201610242288.2A patent/CN105861201B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI341329B (en) * | 2005-05-30 | 2011-05-01 | ||
| TWI383047B (en) * | 2008-06-11 | 2013-01-21 | ||
| US20100316752A1 (en) * | 2009-06-10 | 2010-12-16 | Heng-Jui Hsu | Method for extracing substances from soapberry fruit and seed and products made therefrom |
| CN103122287A (en) * | 2013-03-26 | 2013-05-29 | 西南大学 | Soapberry total-nutrient handmade soap and preparation method thereof |
| US9217127B2 (en) * | 2013-08-05 | 2015-12-22 | Greenology Products, Inc. | Organic cleaning composition |
| CN103881838A (en) * | 2014-03-07 | 2014-06-25 | 北京林业大学 | Soapberry liquid composition and dish washing detergent containing same |
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| Publication number | Publication date |
|---|---|
| CN105861201B (en) | 2018-04-27 |
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