CN105860858A - Electronic commerce physical distribution commercial product RFID (radio frequency identification) anti-counterfeiting label adhesive - Google Patents
Electronic commerce physical distribution commercial product RFID (radio frequency identification) anti-counterfeiting label adhesive Download PDFInfo
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- CN105860858A CN105860858A CN201610447610.5A CN201610447610A CN105860858A CN 105860858 A CN105860858 A CN 105860858A CN 201610447610 A CN201610447610 A CN 201610447610A CN 105860858 A CN105860858 A CN 105860858A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to an electronic commerce physical distribution commercial product RFID (radio frequency identification) anti-counterfeiting label adhesive which is composed of the following components in parts by mass: 16-20 parts of, 18-22 parts of wollastonite powder, 14-18 parts of aluminum silicate, 12-16 parts of dimethyl carbonate, 18-22 parts of ethyl acetate, 14-18 parts of dichlorotetra-fluoroethane, 12-16 parts of dibutyl maleate, 18-22 parts of graphite, 14-18 parts of p-tert-octyl phenol formaldehyde resin, 12-16 parts of triisooctyl phosphite, 18-22 parts of oyster shell, 14-18 parts of sodium humate, 14-18 parts of ethylenediamine, 12-16 parts of iron naphthenate, 18-22 parts of tetraethyl silicate, 14-18 parts of bisphenol A epoxy resin, 12-16 parts of carboxylbutylbenzene modified emulsion, 18-22 parts of humic acid, 14-18 parts of corn starch, 12-16 parts of urea formaldehyde resin and 18-22 parts of dibasic lead phosphite. The adopted raw materials generate synergistic actions, thereby greatly enhancing the aging resistance of the adhesive and widening the temperature adaptation range of the adhesive.
Description
Technical field
The present invention relates to a kind of E-business logistics commodity RFID antifalsification label adhesive, belong to E-business logistics label
Technology for producing field.
Background technology
Microchip is embedded in the middle of product by RFID anti-counterfeiting technology, utilize intelligent electronic label to identify various article, this
Planting label to produce according to RFID radio frequency identification principle, label exchanges information with read write line by radio frequency signal,
Compared with conventional barcode technology, RFID can save more time and human and material resources, reduces production cost, carries
High workload efficiency, is just considered the substituent of bar codes technique by increasing people.The appearance of RFID antifalsification label helps
In improving the using effect of E-business logistics commodity, convenient preferably identifying and use, it typically uses bonding mode,
It is therefore desirable to provide suitable adhesive, in order to its using effect can be improved.
Summary of the invention
It is an object of the invention to provide a kind of E-business logistics commodity RFID antifalsification label adhesive, in order to preferably
Realize the function of E-business logistics commodity RFID antifalsification label adhesive.
To achieve these goals, technical scheme is as follows.
A kind of E-business logistics commodity RFID antifalsification label adhesive, is made up of the component of following mass fraction: titanium white
Powder 16～20 parts, wollastonite in powder 18～22 parts, alumina silicate 14～18 parts, dimethyl carbonate 12～16 parts, acetic acid second
Ester 18～22 parts, dichlorotetra-fluoroethane 14～18 parts, dibutyl maleate 12～16 parts, graphite 18～22 parts,
To t-Octylphenol formaldehyde resin 14～18 parts, tricresyl phosphite isooctyl acrylate 12～16 parts, oyster shell powder 18～22 parts,
Sodium humate 14～18 parts, ethylenediamine 14～18 parts, iron naphthenate 12～16 parts, tetraethyl orthosilicate 18～22 parts,
Bisphenol A type epoxy resin 14～18 parts, Carboxy modified emulsion 12～16 parts, humic acid 18～22 parts, corn
Starch 14～18 parts, Lauxite 12～16 parts, dibasic lead phosphite 18～22 parts.
Further, above-mentioned E-business logistics commodity RFID antifalsification label adhesive, by the component of following mass fraction
Composition: titanium dioxide 16 parts, wollastonite in powder 18 parts, alumina silicate 14 parts, dimethyl carbonate 12 parts, ethyl acetate 18
Part, dichlorotetra-fluoroethane 14 parts, dibutyl maleate 12 parts, 18 parts of graphite, to t-Octylphenol formaldehyde tree
14 parts of fat, tricresyl phosphite isooctyl acrylate 12 parts, oyster shell powder 18 parts, sodium humate 14 parts, ethylenediamine 14 parts, ring
Alkanoic acid iron 12 parts, tetraethyl orthosilicate 18 parts, bisphenol A type epoxy resin 14 parts, Carboxy modified emulsion 12 parts,
Humic acid 18 parts, cornstarch 14 parts, Lauxite 12 parts, dibasic lead phosphite 18 parts.
Further, above-mentioned E-business logistics commodity RFID antifalsification label adhesive, by the component of following mass fraction
Composition: titanium dioxide 18 parts, wollastonite in powder 20 parts, alumina silicate 16 parts, dimethyl carbonate 14 parts, ethyl acetate 20
Part, dichlorotetra-fluoroethane 16 parts, dibutyl maleate 14 parts, 20 parts of graphite, to t-Octylphenol formaldehyde tree
16 parts of fat, tricresyl phosphite isooctyl acrylate 14 parts, oyster shell powder 20 parts, sodium humate 16 parts, ethylenediamine 16 parts, ring
Alkanoic acid iron 14 parts, tetraethyl orthosilicate 20 parts, bisphenol A type epoxy resin 16 parts, Carboxy modified emulsion 14 parts,
Humic acid 20 parts, cornstarch 16 parts, Lauxite 14 parts, dibasic lead phosphite 20 parts.
Further, above-mentioned E-business logistics commodity RFID antifalsification label adhesive, by the component of following mass fraction
Composition: titanium dioxide 20 parts, wollastonite in powder 22 parts, alumina silicate 18 parts, dimethyl carbonate 16 parts, ethyl acetate 22
Part, dichlorotetra-fluoroethane 18 parts, dibutyl maleate 16 parts, 22 parts of graphite, to t-Octylphenol formaldehyde tree
18 parts of fat, tricresyl phosphite isooctyl acrylate 16 parts, oyster shell powder 22 parts, sodium humate 18 parts, ethylenediamine 18 parts, ring
Alkanoic acid iron 16 parts, tetraethyl orthosilicate 22 parts, bisphenol A type epoxy resin 18 parts, Carboxy modified emulsion 16 parts,
Humic acid 22 parts, cornstarch 18 parts, Lauxite 16 parts, dibasic lead phosphite 22 parts.
Further, described wollastonite in powder is made up of the powder of three kinds of particle diameter mesh numbers, and its particle diameter mesh number is respectively 30～50
Mesh, 50～80 mesh, 80～100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 3～7: 4～8: 1.
Further, described titanium dioxide is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number be respectively 30～50 mesh,
50～80 mesh, 80～100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 3～8: 2～8: 1.
Further, the viscosity of described tetraethyl orthosilicate is 12000～14000mpa.s at 25 DEG C.
Further, described oyster shell powder is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number be respectively 20～50 mesh,
50～70 mesh, 70～90 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 2～4: 3～5: 1.
Further, the viscosity of described bisphenol A type epoxy resin is 8000～10000mpa.s at 25 DEG C.
Further, above-mentioned E-business logistics commodity RFID antifalsification label adhesive preparation method step is as follows:
(1) by the titanium dioxide of described mass fraction, wollastonite in powder, alumina silicate, dimethyl carbonate, ethyl acetate, two
Chloro-tetrafluoroethane, dibutyl maleate, oyster shell powder, sodium humate, bisphenol A type epoxy resin, Carboxy change
Property emulsion, humic acid, cornstarch, Lauxite, dibasic lead phosphite are mixed, and are sequentially added in agitator tank,
It is sufficiently stirred for 30 minutes with the speed of 200rpm；
(2) adding the ethylenediamine of described mass fraction, iron naphthenate, tetraethyl orthosilicate, the speed with 300rpm is abundant
Stir 60 minutes；
(3) add the graphite of described mass fraction, to t-Octylphenol formaldehyde resin, tricresyl phosphite isooctyl acrylate, with
The speed of 400rpm is sufficiently stirred for 90 minutes, obtains binder product.
This beneficial effect of the invention is: this E-business logistics commodity RFID antifalsification label adhesive process of preparing
Simply, prepared product, by rational proportioning and mixing, makes to produce between each component synergy, overcomes each
Deficiency when being used alone, defines the friendship with performances such as excellent high temperature resistant, anticorrosive, high-adhesion, mechanicalnesses
Connection structure.The room temperature down cut intensity that the present invention provides can reach more than 45MPa, and shear strength when 250 DEG C is
More than 18MPa, it is possible to meet the requirement of long-term work at 250 DEG C of glued part.Raw material of the present invention produces
Synergy, the ageing resistace being greatly improved binding agent, the Acclimation temperature scope improving binding agent, its temperature is fitted
Answering scope is-80～250 DEG C.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is described, in order to be better understood from the present invention.
Embodiment 1
E-business logistics commodity RFID antifalsification label adhesive in the present embodiment, by the component group of following mass fraction
Become: titanium dioxide 16 parts, wollastonite in powder 18 parts, alumina silicate 14 parts, dimethyl carbonate 12 parts, ethyl acetate 18 parts,
Dichlorotetra-fluoroethane 14 parts, dibutyl maleate 12 parts, 18 parts of graphite, to t-Octylphenol formaldehyde resin 14
Part, tricresyl phosphite isooctyl acrylate 12 parts, oyster shell powder 18 parts, sodium humate 14 parts, ethylenediamine 14 parts, iron naphthenate
12 parts, tetraethyl orthosilicate 18 parts, bisphenol A type epoxy resin 14 parts, Carboxy modified emulsion 12 parts, humic acid
18 parts, cornstarch 14 parts, Lauxite 12 parts, dibasic lead phosphite 18 parts.
Described wollastonite in powder is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number be respectively 30～50 mesh, 50～80
Mesh, 80～100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 3: 4: 1.
Described titanium dioxide is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number be respectively 30～50 mesh, 50～80 mesh,
80～100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 3: 2: 1.
The viscosity of described tetraethyl orthosilicate is 12000mpa.s at 25 DEG C.
Described oyster shell powder is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number be respectively 20～50 mesh, 50～70 mesh,
70～90 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 2: 3: 1.
The viscosity of described bisphenol A type epoxy resin is 8000mpa.s at 25 DEG C.
Above-mentioned E-business logistics commodity RFID antifalsification label adhesive preparation method step is as follows:
(1) by the titanium dioxide of described mass fraction, wollastonite in powder, alumina silicate, dimethyl carbonate, ethyl acetate, two
Chloro-tetrafluoroethane, dibutyl maleate, oyster shell powder, sodium humate, bisphenol A type epoxy resin, Carboxy change
Property emulsion, humic acid, cornstarch, Lauxite, dibasic lead phosphite are mixed, and are sequentially added in agitator tank,
It is sufficiently stirred for 30 minutes with the speed of 200rpm；
(2) adding the ethylenediamine of described mass fraction, iron naphthenate, tetraethyl orthosilicate, the speed with 300rpm is abundant
Stir 60 minutes；
(3) add the graphite of described mass fraction, to t-Octylphenol formaldehyde resin, tricresyl phosphite isooctyl acrylate, with
The speed of 400rpm is sufficiently stirred for 90 minutes, obtains binder product.
Embodiment 2
E-business logistics commodity RFID antifalsification label adhesive in the present embodiment, by the component group of following mass fraction
Become: titanium dioxide 18 parts, wollastonite in powder 20 parts, alumina silicate 16 parts, dimethyl carbonate 14 parts, ethyl acetate 20 parts,
Dichlorotetra-fluoroethane 16 parts, dibutyl maleate 14 parts, 20 parts of graphite, to t-Octylphenol formaldehyde resin 16
Part, tricresyl phosphite isooctyl acrylate 14 parts, oyster shell powder 20 parts, sodium humate 16 parts, ethylenediamine 16 parts, iron naphthenate
14 parts, tetraethyl orthosilicate 20 parts, bisphenol A type epoxy resin 16 parts, Carboxy modified emulsion 14 parts, humic acid
20 parts, cornstarch 16 parts, Lauxite 14 parts, dibasic lead phosphite 20 parts.
Described wollastonite in powder is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number be respectively 30～50 mesh, 50～80
Mesh, 80～100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 5: 6: 1.
Described titanium dioxide is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number be respectively 30～50 mesh, 50～80 mesh,
80～100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 5: 5: 1.
The viscosity of described tetraethyl orthosilicate is 13000mpa.s at 25 DEG C.
Described oyster shell powder is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number be respectively 20～50 mesh, 50～70 mesh,
70～90 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 3: 4: 1.
The viscosity of described bisphenol A type epoxy resin is 9000mpa.s at 25 DEG C.
Above-mentioned E-business logistics commodity RFID antifalsification label adhesive preparation method step is as follows:
(1) by the titanium dioxide of described mass fraction, wollastonite in powder, alumina silicate, dimethyl carbonate, ethyl acetate, two
Chloro-tetrafluoroethane, dibutyl maleate, oyster shell powder, sodium humate, bisphenol A type epoxy resin, Carboxy change
Property emulsion, humic acid, cornstarch, Lauxite, dibasic lead phosphite are mixed, and are sequentially added in agitator tank,
It is sufficiently stirred for 30 minutes with the speed of 200rpm；
(2) adding the ethylenediamine of described mass fraction, iron naphthenate, tetraethyl orthosilicate, the speed with 300rpm is abundant
Stir 60 minutes；
(3) add the graphite of described mass fraction, to t-Octylphenol formaldehyde resin, tricresyl phosphite isooctyl acrylate, with
The speed of 400rpm is sufficiently stirred for 90 minutes, obtains binder product.
Embodiment 3
E-business logistics commodity RFID antifalsification label adhesive in the present embodiment, by the component group of following mass fraction
Become: titanium dioxide 20 parts, wollastonite in powder 22 parts, alumina silicate 18 parts, dimethyl carbonate 16 parts, ethyl acetate 22 parts,
Dichlorotetra-fluoroethane 18 parts, dibutyl maleate 16 parts, 22 parts of graphite, to t-Octylphenol formaldehyde resin 18
Part, tricresyl phosphite isooctyl acrylate 16 parts, oyster shell powder 22 parts, sodium humate 18 parts, ethylenediamine 18 parts, iron naphthenate
16 parts, tetraethyl orthosilicate 22 parts, bisphenol A type epoxy resin 18 parts, Carboxy modified emulsion 16 parts, humic acid
22 parts, cornstarch 18 parts, Lauxite 16 parts, dibasic lead phosphite 22 parts.
Described wollastonite in powder is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number be respectively 30～50 mesh, 50～80
Mesh, 80～100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 7: 8: 1.
Described titanium dioxide is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number be respectively 30～50 mesh, 50～80 mesh,
80～100 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 8: 8: 1.
The viscosity of described tetraethyl orthosilicate is 14000mpa.s at 25 DEG C.
Described oyster shell powder is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number be respectively 20～50 mesh, 50～70 mesh,
70～90 mesh, the mixing quality ratio of above-mentioned three kinds of powders is 4: 5: 1.
The viscosity of described bisphenol A type epoxy resin is 10000mpa.s at 25 DEG C.
Above-mentioned E-business logistics commodity RFID antifalsification label adhesive preparation method step is as follows:
(1) by the titanium dioxide of described mass fraction, wollastonite in powder, alumina silicate, dimethyl carbonate, ethyl acetate, two
Chloro-tetrafluoroethane, dibutyl maleate, oyster shell powder, sodium humate, bisphenol A type epoxy resin, Carboxy change
Property emulsion, humic acid, cornstarch, Lauxite, dibasic lead phosphite are mixed, and are sequentially added in agitator tank,
It is sufficiently stirred for 30 minutes with the speed of 200rpm；
(2) adding the ethylenediamine of described mass fraction, iron naphthenate, tetraethyl orthosilicate, the speed with 300rpm is abundant
Stir 60 minutes；
(3) add the graphite of described mass fraction, to t-Octylphenol formaldehyde resin, tricresyl phosphite isooctyl acrylate, with
The speed of 400rpm is sufficiently stirred for 90 minutes, obtains binder product.
Comparative example 1
1) thermoplastic acrylic resin 25 parts that weight average molecular weight is 70000～75000 is weighed respectively, organic-silicon-modified
Acrylic resin 20 parts, is sequentially added in agitator tank, is sufficiently stirred for 40 minutes with the speed of 100rpm；
B) melmac 10 parts is continuously added, phenyl trichlorosilane 7 parts, vinyltrimethoxy silane 5 parts,
It is sufficiently stirred for 60 minutes with the speed of 100rpm；
C) in the mixture of step b), titanium dioxide 7 parts is continuously added, attapulgite 5 parts, dichlorotetra-fluoroethane 5 parts,
Ethylene glycol monobutyl ether 20 parts, is sufficiently stirred for 60 minutes with the speed of 100rpm, obtains the binding agent in this comparative example and produces
Product.
Comparative example 2
1) weighing epoxy modified hydroxyl acrylic resin 25 parts respectively, weight average molecular weight is the thermoplastic of 70000～75000
Property acrylic resin 25 parts, is sequentially added in agitator tank, is sufficiently stirred for 40 minutes with the speed of 100rpm；
2) melmac 10 parts is continuously added, phenyl trichlorosilane 7 parts, vinyltrimethoxy silane 5 parts,
It is sufficiently stirred for 60 minutes with the speed of 100rpm；
3) in the mixture of step b), titanium dioxide 7 parts is continuously added, attapulgite 5 parts, dichlorotetra-fluoroethane 5 parts,
Ethylene glycol monobutyl ether 20 parts, is sufficiently stirred for 60 minutes with the speed of 100rpm, obtains binder product.
By the binding agent prepared by embodiment 1, embodiment 2, embodiment 3 and comparative example 1, comparative example 2 at-80～280 DEG C
The lower respective shear strength of test and tolerance time, the testing time is 360 days, and concrete outcome is as shown in following table 1-5:
Binder Properties test result at 1-80 DEG C of table
| Group | Tolerance time | Shear strength |
| Embodiment 1 | Not fragmentation in 50 days, does not falls off | 15MPa |
| Embodiment 2 | Not fragmentation in 52 days, does not falls off | 17MPa |
| Embodiment 3 | Not fragmentation in 48 days, does not falls off | 16MPa |
| Comparative example 1 | 0 day, binding agent fragmentation came off | 0 |
| Comparative example 2 | 0 day, binding agent fragmentation came off | 0 |
Binder Properties test result at 20 DEG C of table
| Group | Tolerance time | Shear strength |
| Embodiment 1 | Not fragmentation in 50 days, does not falls off | 25MPa |
| Embodiment 2 | Not fragmentation in 52 days, does not falls off | 28MPa |
| Embodiment 3 | Not fragmentation in 48 days, does not falls off | 23MPa |
| Comparative example 1 | After 30 days, binding agent fragmentation comes off | 10MPa |
| Comparative example 2 | After 20 days, binding agent fragmentation comes off | 8MPa |
Binder Properties test result at 3 20 DEG C of table
| Group | Tolerance time | Shear strength |
| Embodiment 1 | Not fragmentation in 360 days, does not falls off | 45MPa |
| Embodiment 2 | Not fragmentation in 360 days, does not falls off | 48MPa |
| Embodiment 3 | Not fragmentation in 360 days, does not falls off | 47MPa |
| Comparative example 1 | Not fragmentation in 360 days, does not falls off | 18MPa |
| Comparative example 2 | Not fragmentation in 360 days, does not falls off | 16MPa |
Binder Properties test result at 4 150 DEG C of table
| Group | Tolerance time | Shear strength |
| Embodiment 1 | 360 days not softening and sheddings | 23MPa |
| Embodiment 2 | 360 days not softening and sheddings | 24MPa |
| Embodiment 3 | 360 days not softening and sheddings | 23MPa |
| Comparative example 1 | After 10 days, binding agent softens | 10MPa |
| Comparative example 2 | After 10 days, binding agent softens | 8MPa |
Binder Properties test result at 5 250 DEG C of table
| Group | Tolerance time | Shear strength |
| Embodiment 1 | 280 days not softening and sheddings | 18MPa |
| Embodiment 2 | 280 days not softening and sheddings | 19MPa |
| Embodiment 3 | 280 days not softening and sheddings | 18MPa |
| Comparative example 1 | After 3 days, binding agent softens | 4MPa |
| Comparative example 2 | After 3 days, binding agent softens | 3MPa |
The above is the preferred embodiment of the present invention, it is noted that come for those skilled in the art
Saying, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also regard
For protection scope of the present invention.
Claims (10)
- null1. an E-business logistics commodity RFID antifalsification label adhesive，It is characterized in that: be made up of the component of following mass fraction: titanium dioxide 16～20 parts、Wollastonite in powder 18～22 parts、Alumina silicate 14～18 parts、Dimethyl carbonate 12～16 parts、Ethyl acetate 18～22 parts、Dichlorotetra-fluoroethane 14～18 parts、Dibutyl maleate 12～16 parts、Graphite 18～22 parts、To t-Octylphenol formaldehyde resin 14～18 parts、Tricresyl phosphite isooctyl acrylate 12～16 parts、Oyster shell powder 18～22 parts、Sodium humate 14～18 parts、Ethylenediamine 14～18 parts、Iron naphthenate 12～16 parts、Tetraethyl orthosilicate 18～22 parts、Bisphenol A type epoxy resin 14～18 parts、Carboxy modified emulsion 12～16 parts、Humic acid 18～22 parts、Cornstarch 14～18 parts、Lauxite 12～16 parts、Dibasic lead phosphite 18～22 parts.
- nullE-business logistics commodity RFID antifalsification label adhesive the most according to claim 1，It is characterized in that: described E-business logistics commodity RFID antifalsification label adhesive is made up of the component of following mass fraction: titanium dioxide 16 parts、Wollastonite in powder 18 parts、Alumina silicate 14 parts、Dimethyl carbonate 12 parts、Ethyl acetate 18 parts、Dichlorotetra-fluoroethane 14 parts、Dibutyl maleate 12 parts、18 parts of graphite、To t-Octylphenol formaldehyde resin 14 parts、Tricresyl phosphite isooctyl acrylate 12 parts、Oyster shell powder 18 parts、Sodium humate 14 parts、Ethylenediamine 14 parts、Iron naphthenate 12 parts、Tetraethyl orthosilicate 18 parts、Bisphenol A type epoxy resin 14 parts、Carboxy modified emulsion 12 parts、Humic acid 18 parts、Cornstarch 14 parts、Lauxite 12 parts、Dibasic lead phosphite 18 parts.
- nullE-business logistics commodity RFID antifalsification label adhesive the most according to claim 1，It is characterized in that: described E-business logistics commodity RFID antifalsification label adhesive is made up of the component of following mass fraction: titanium dioxide 18 parts、Wollastonite in powder 20 parts、Alumina silicate 16 parts、Dimethyl carbonate 14 parts、Ethyl acetate 20 parts、Dichlorotetra-fluoroethane 16 parts、Dibutyl maleate 14 parts、20 parts of graphite、To t-Octylphenol formaldehyde resin 16 parts、Tricresyl phosphite isooctyl acrylate 14 parts、Oyster shell powder 20 parts、Sodium humate 16 parts、Ethylenediamine 16 parts、Iron naphthenate 14 parts、Tetraethyl orthosilicate 20 parts、Bisphenol A type epoxy resin 16 parts、Carboxy modified emulsion 14 parts、Humic acid 20 parts、Cornstarch 16 parts、Lauxite 14 parts、Dibasic lead phosphite 20 parts.
- nullE-business logistics commodity RFID antifalsification label adhesive the most according to claim 1，It is characterized in that: described E-business logistics commodity RFID antifalsification label adhesive is made up of the component of following mass fraction: titanium dioxide 20 parts、Wollastonite in powder 22 parts、Alumina silicate 18 parts、Dimethyl carbonate 16 parts、Ethyl acetate 22 parts、Dichlorotetra-fluoroethane 18 parts、Dibutyl maleate 16 parts、22 parts of graphite、To t-Octylphenol formaldehyde resin 18 parts、Tricresyl phosphite isooctyl acrylate 16 parts、Oyster shell powder 22 parts、Sodium humate 18 parts、Ethylenediamine 18 parts、Iron naphthenate 16 parts、Tetraethyl orthosilicate 22 parts、Bisphenol A type epoxy resin 18 parts、Carboxy modified emulsion 16 parts、Humic acid 22 parts、Cornstarch 18 parts、Lauxite 16 parts、Dibasic lead phosphite 22 parts.
- 5. according to the E-business logistics commodity RFID antifalsification label adhesive described in claim 1 to 2, it is characterized in that: described wollastonite in powder is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number is respectively 30～50 mesh, 50～80 mesh, 80～100 mesh, and the mixing quality ratio of above-mentioned three kinds of powders is 3～7:4～8:1.
- 6. according to the E-business logistics commodity RFID antifalsification label adhesive described in claims 1 to 3, it is characterized in that: described titanium dioxide is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number is respectively 30～50 mesh, 50～80 mesh, 80～100 mesh, and the mixing quality ratio of above-mentioned three kinds of powders is 3～8:2～8:1.
- 7. according to the E-business logistics commodity RFID antifalsification label adhesive described in Claims 1-4, it is characterised in that: the viscosity of described tetraethyl orthosilicate is about 12000～14000mpa.s at 25 DEG C.
- E-business logistics commodity RFID antifalsification label adhesive the most according to claim 1, it is characterized in that: described oyster shell powder is made up of the powder of three kinds of particle diameter mesh numbers, its particle diameter mesh number is respectively 20～50 mesh, 50～70 mesh, 70～90 mesh, and the mixing quality ratio of above-mentioned three kinds of powders is 2～4:3～5:1.
- E-business logistics commodity RFID antifalsification label adhesive the most according to claim 1, it is characterised in that: the viscosity of described bisphenol A type epoxy resin is about 8000～10000mpa.s at 25 DEG C.
- E-business logistics commodity RFID antifalsification label adhesive the most according to claim 1, it is characterised in that: described E-business logistics commodity RFID antifalsification label adhesive preparation method step is as follows:(1) titanium dioxide of described mass fraction, wollastonite in powder, alumina silicate, dimethyl carbonate, ethyl acetate, dichlorotetra-fluoroethane, dibutyl maleate, oyster shell powder, sodium humate, bisphenol A type epoxy resin, Carboxy modified emulsion, humic acid, cornstarch, Lauxite, dibasic lead phosphite are mixed, it is sequentially added in agitator tank, is sufficiently stirred for about 30 minutes with the speed of 200rpm；(2) add the ethylenediamine of described mass fraction, iron naphthenate, tetraethyl orthosilicate, be sufficiently stirred for about 60 minutes with the speed of 300rpm；(3) add the graphite of described mass fraction, to t-Octylphenol formaldehyde resin, tricresyl phosphite isooctyl acrylate, be sufficiently stirred for about 90 minutes with the speed of 400rpm, obtain binder product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610447610.5A CN105860858A (en) | 2016-06-20 | 2016-06-20 | Electronic commerce physical distribution commercial product RFID (radio frequency identification) anti-counterfeiting label adhesive |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610447610.5A CN105860858A (en) | 2016-06-20 | 2016-06-20 | Electronic commerce physical distribution commercial product RFID (radio frequency identification) anti-counterfeiting label adhesive |
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| CN105860858A true CN105860858A (en) | 2016-08-17 |
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| CN201610447610.5A Pending CN105860858A (en) | 2016-06-20 | 2016-06-20 | Electronic commerce physical distribution commercial product RFID (radio frequency identification) anti-counterfeiting label adhesive |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106281107A (en) * | 2016-08-23 | 2017-01-04 | 广安欧奇仕电子科技有限公司 | Binding agent installed by a kind of motor |
| CN106520013A (en) * | 2016-10-14 | 2017-03-22 | 华蓥市盈胜电子有限公司 | Mobile phone mainboard binder and preparation method thereof |
-
2016
- 2016-06-20 CN CN201610447610.5A patent/CN105860858A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106281107A (en) * | 2016-08-23 | 2017-01-04 | 广安欧奇仕电子科技有限公司 | Binding agent installed by a kind of motor |
| CN106520013A (en) * | 2016-10-14 | 2017-03-22 | 华蓥市盈胜电子有限公司 | Mobile phone mainboard binder and preparation method thereof |
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