CN105860705A - Antirust paint - Google Patents

Antirust paint Download PDF

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Publication number
CN105860705A
CN105860705A CN201610263362.9A CN201610263362A CN105860705A CN 105860705 A CN105860705 A CN 105860705A CN 201610263362 A CN201610263362 A CN 201610263362A CN 105860705 A CN105860705 A CN 105860705A
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CN
China
Prior art keywords
parts
antirust paint
minutes
water
aluminium
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610263362.9A
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Chinese (zh)
Inventor
朱保瑞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI KANGRUIXIN ELECTRONIC TECHNOLOGY Co Ltd
Original Assignee
ANHUI KANGRUIXIN ELECTRONIC TECHNOLOGY Co Ltd
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Application filed by ANHUI KANGRUIXIN ELECTRONIC TECHNOLOGY Co Ltd filed Critical ANHUI KANGRUIXIN ELECTRONIC TECHNOLOGY Co Ltd
Priority to CN201610263362.9A priority Critical patent/CN105860705A/en
Publication of CN105860705A publication Critical patent/CN105860705A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an antirust paint which is prepared from a water-based acrylic resin, water, inositol phosphate, sodium aluminosilicate, sodium stearate, glyceryl tristearate, an acrylic emulsion, sodium lignosulfonate, polyvinylpyrrolidone, pentaerythritol, a Torilis anthriscus extract and aids. The water-based antirust paint disclosed by the invention is low in raw material cost, is free of benzenes or other volatile matters when in use, can not generate any side effect on the body of the user, has higher antirust paint and low shedding tendency under the synergistic actions among the components, and has the advantages of higher drying speed and favorable leveling property when in use. By adding the Torilis anthriscus extract and aids, the paint film is smooth and uniform. The service life of the antirust paint is prolonged by 20%. The antirust paint has very high fixation effect, and can not lose the original color when being subjected to long-term high-temperature and harsh environments.

Description

A kind of antirust paint
Technical field
The present invention relates to paint field, particularly relate to a kind of antirust paint.
Background technology
Antirust paint substantially oiliness and aqueous two kinds.Oily antirust varniss makes material surface greasy removal difficulty, is rarely employed.Oily antirust varniss is easy to use, cheap, but because containing the noxious substance such as nitrite, chromate, relatively big to operator's harm, country has limited use, and these type of properties of product are single, it is impossible to meet the antirust requirement of magnetic alloy material.Along with antirust paint industry and application develop to low stainization, aqueous antirust paint rises the most day by day.Therefore, develop waterborne anti-rust antirust paint to come into one's own.Antirust paint in the market mostly is aqueous antirust paint, although has reached certain rust-proof effect, but has been easy to, by extraneous environmental effect, lose original color and luster.
Summary of the invention
In order to overcome above-mentioned deficiency, the invention provides a kind of antirust paint.
The present invention is achieved through the following technical solutions:
A kind of antirust paint, is made up of following components: 25 parts of water-borne acrylic resins, 35 parts of water, 16 parts of cyclohexanhexanol phosphate esters, 2 parts of lagoriolites, 5 parts of sodium stearates, 5 parts of glyceryl tristearates, 15 parts of acrylic emulsions, 3 parts of sodium lignin sulfonates, 6 parts of polyvinylpyrrolidones, 4 parts of tetramethylolmethanes, 0.3 part of hemlock chervil extract, 1 part of adjuvant by weight;Described adjuvant is by weight percentage: 35% Colophonium, 5% aluminium-hydroxide powder, 60% isopropanol;Described hemlock chervil method for preparing extractive is: will pulverize after hemlock chervil cleaning-drying;Then the hemlock chervil after pulverizing is put in the alcoholic solution of its weight 20 times, mix homogeneously;Being subsequently placed in ultrasonic extraction tank, the ultrasound wave of employing 32kHZ, 35kHZ frequency substitutes circulation for every 6 minutes successively to carry out extracting operation to it, obtains extracting solution after 30 minutes;Gained extracting solution is carried out alcohol recycling, remaining solution is carried out process of anhydrating, obtain hemlock chervil extract.
Further, described water-borne acrylic resin is through pretreatment: by weight is acrylic resin 3.75% nano aluminium oxide and acrylic resin mixing after under 4.5MPa pressure, be heated to 165 DEG C, be incubated 30 minutes;The granularity of nano aluminium oxide is 28-30nm.
Further, the granularity of the aluminium-hydroxide powder in described adjuvant is 300-350 mesh, and aluminium-hydroxide powder is through pretreatment, is put into by aluminium-hydroxide powder in the caprylic acid solution that mass fraction is 0.75%, after soaking 15 minutes, filters, is dried;The preparation method of described adjuvant is: put into homogenizing 20 minutes in homogenizer by after Colophonium, aluminium-hydroxide powder, isopropanol mix homogeneously,;The adjuvant of configuration can greatly increase the wearability of paint of the present invention.
The preparation method of a kind of antirust paint, is made up of following steps:
1) by weight by water-borne acrylic resin, water, cyclohexanhexanol phosphate ester, lagoriolite, sodium stearate, glyceryl tristearate, acrylic emulsion, the most admixed together, stir 30 minutes with the speed of 500 revs/min;
2) until 1) in raw material stirring after 30 minutes, add sodium lignin sulfonate, polyvinylpyrrolidone, tetramethylolmethane, hemlock chervil extract, adjuvant, after stirring 30 minutes with the speed of 1000 revs/min, be ground, until fineness≤30 μm,. The invention has the beneficial effects as follows: a kind of antirust paint cost of material that the present invention provides is low, use aqueous antirust paint, in antirust paint and use be free from the volatile material such as benzene, user health will not be had side effects, between each composition, mutual synergism makes this antirust paint adhesion higher, antirust paint difficult drop-off, and it is dried more quickly when using, good leveling property;Making paint film even uniform by adding hemlock chervil extract with adjuvant, the life-span of antirust paint improves 20%, has the strongest colour fixation, under the influence of it is by long term high temperature and adverse circumstances, still will not lose original color and luster.
Detailed description of the invention
A kind of antirust paint, is made up of following components: 25 parts of water-borne acrylic resins, 35 parts of water, 16 parts of cyclohexanhexanol phosphate esters, 2 parts of lagoriolites, 5 parts of sodium stearates, 5 parts of glyceryl tristearates, 15 parts of acrylic emulsions, 3 parts of sodium lignin sulfonates, 6 parts of polyvinylpyrrolidones, 4 parts of tetramethylolmethanes, 0.3 part of hemlock chervil extract, 1 part of adjuvant by weight;Described adjuvant is by weight percentage: 35% Colophonium, 5% aluminium-hydroxide powder, 60% isopropanol;Described hemlock chervil method for preparing extractive is: will pulverize after hemlock chervil cleaning-drying;Then the hemlock chervil after pulverizing is put in the alcoholic solution of its weight 20 times, mix homogeneously;Being subsequently placed in ultrasonic extraction tank, the ultrasound wave of employing 32kHZ, 35kHZ frequency substitutes circulation for every 6 minutes successively to carry out extracting operation to it, obtains extracting solution after 30 minutes;Gained extracting solution is carried out alcohol recycling, remaining solution is carried out process of anhydrating, obtain hemlock chervil extract.
Further, described water-borne acrylic resin is through pretreatment: by weight is acrylic resin 3.75% nano aluminium oxide and acrylic resin mixing after under 4.5MPa pressure, be heated to 165 DEG C, be incubated 30 minutes;The granularity of nano aluminium oxide is 28-30nm.
Further, the granularity of the aluminium-hydroxide powder in described adjuvant is 300-350 mesh, and aluminium-hydroxide powder is through pretreatment, is put into by aluminium-hydroxide powder in the caprylic acid solution that mass fraction is 0.75%, after soaking 15 minutes, filters, is dried;The preparation method of described adjuvant is: put into homogenizing 20 minutes in homogenizer by after Colophonium, aluminium-hydroxide powder, isopropanol mix homogeneously,.
The preparation method of a kind of antirust paint, is made up of following steps:
1) by weight by water-borne acrylic resin, water, cyclohexanhexanol phosphate ester, lagoriolite, sodium stearate, glyceryl tristearate, acrylic emulsion, the most admixed together, stir 30 minutes with the speed of 500 revs/min;
2) until 1) in raw material stirring after 30 minutes, add sodium lignin sulfonate, polyvinylpyrrolidone, tetramethylolmethane, hemlock chervil extract, adjuvant, after stirring 30 minutes with the speed of 1000 revs/min, be ground, until fineness≤30 μm,.

Claims (4)

1. an antirust paint, it is characterized in that, be made up of following components by weight: 25 parts of water-borne acrylic resins, 35 parts of water, 16 parts of cyclohexanhexanol phosphate esters, 2 parts of lagoriolites, 5 parts of sodium stearates, 5 parts of glyceryl tristearates, 15 parts of acrylic emulsions, 3 parts of sodium lignin sulfonates, 6 parts of polyvinylpyrrolidones, 4 parts of tetramethylolmethanes, 0.3 part of hemlock chervil extract, 1 part of adjuvant;Described adjuvant is by weight percentage: 35% Colophonium, 5% aluminium-hydroxide powder, 60% isopropanol;Described hemlock chervil method for preparing extractive is: will pulverize after hemlock chervil cleaning-drying;Then the hemlock chervil after pulverizing is put in the alcoholic solution of its weight 20 times, mix homogeneously;Being subsequently placed in ultrasonic extraction tank, the ultrasound wave of employing 32kHZ, 35kHZ frequency substitutes circulation for every 6 minutes successively to carry out extracting operation to it, obtains extracting solution after 30 minutes;Gained extracting solution is carried out alcohol recycling, remaining solution is carried out process of anhydrating, obtain hemlock chervil extract.
A kind of antirust paint the most according to claim 1, it is characterized in that, described water-borne acrylic resin is through pretreatment: by weight is acrylic resin 3.75% nano aluminium oxide and acrylic resin mixing after under 4.5MPa pressure, be heated to 165 DEG C, be incubated 30 minutes;The granularity of nano aluminium oxide is 28-30nm.
A kind of antirust paint the most according to claim 1, it is characterized in that, the granularity of the aluminium-hydroxide powder in described adjuvant is 300-350 mesh, and aluminium-hydroxide powder is through pretreatment, aluminium-hydroxide powder is put in the caprylic acid solution that mass fraction is 0.75%, after soaking 15 minutes, filter, be dried;The preparation method of described adjuvant is: put into homogenizing 20 minutes in homogenizer by after Colophonium, aluminium-hydroxide powder, isopropanol mix homogeneously,.
4. according to the preparation method of a kind of antirust paint described in any one of claim 1-3, it is characterised in that be made up of following steps:
1) by weight by water-borne acrylic resin, water, cyclohexanhexanol phosphate ester, lagoriolite, sodium stearate, glyceryl tristearate, acrylic emulsion, the most admixed together, stir 30 minutes with the speed of 500 revs/min;
2) until 1) in raw material stirring after 30 minutes, add sodium lignin sulfonate, polyvinylpyrrolidone, tetramethylolmethane, hemlock chervil extract, adjuvant, after stirring 30 minutes with the speed of 1000 revs/min, be ground, until fineness≤30 μm,.
CN201610263362.9A 2016-04-26 2016-04-26 Antirust paint Pending CN105860705A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610263362.9A CN105860705A (en) 2016-04-26 2016-04-26 Antirust paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610263362.9A CN105860705A (en) 2016-04-26 2016-04-26 Antirust paint

Publications (1)

Publication Number Publication Date
CN105860705A true CN105860705A (en) 2016-08-17

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142023A (en) * 2017-06-28 2017-09-08 扬中市第蝶阀厂有限公司 A kind of antirust paint used for expansion joint
CN109370284A (en) * 2018-10-17 2019-02-22 安徽省含山县华平铸造厂(普通合伙) A kind of corrosion-resistant protection paint formula of ironcasting

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774499A (en) * 2015-04-29 2015-07-15 韦利束 Metal printing ink resistant to corrosion and preparation method thereof
CN104927516A (en) * 2015-05-29 2015-09-23 阜南县猛发工艺品有限公司 Willow weaving paint
CN104945972A (en) * 2015-06-15 2015-09-30 蚌埠市阳光粉沫涂料有限责任公司 Nanometer aluminium oxide-modified acrylic resin type powder coating
CN105331214A (en) * 2015-10-31 2016-02-17 阜南县黄岗镇工艺柳编厂 Anti-corrosion paint for wickerwork made of purple willow

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774499A (en) * 2015-04-29 2015-07-15 韦利束 Metal printing ink resistant to corrosion and preparation method thereof
CN104927516A (en) * 2015-05-29 2015-09-23 阜南县猛发工艺品有限公司 Willow weaving paint
CN104945972A (en) * 2015-06-15 2015-09-30 蚌埠市阳光粉沫涂料有限责任公司 Nanometer aluminium oxide-modified acrylic resin type powder coating
CN105331214A (en) * 2015-10-31 2016-02-17 阜南县黄岗镇工艺柳编厂 Anti-corrosion paint for wickerwork made of purple willow

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
朱庆英等: "异辛酸稀土的合成及其在粉体材料改性中的应用", 《广东化工》 *
牛丽红: "原位表面修饰放法制备油溶性氢氧化铝纳米微粒及其表征", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 *
龙玲等: "纳米Al2O3改性水性木器漆耐磨性和硬度的研究", 《林业科学》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142023A (en) * 2017-06-28 2017-09-08 扬中市第蝶阀厂有限公司 A kind of antirust paint used for expansion joint
CN109370284A (en) * 2018-10-17 2019-02-22 安徽省含山县华平铸造厂(普通合伙) A kind of corrosion-resistant protection paint formula of ironcasting

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Application publication date: 20160817