CN105860416A - Anti-corrosion and anti-aging composite reinforced plastic inspection well and preparation method - Google Patents

Anti-corrosion and anti-aging composite reinforced plastic inspection well and preparation method Download PDF

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Publication number
CN105860416A
CN105860416A CN201610281041.1A CN201610281041A CN105860416A CN 105860416 A CN105860416 A CN 105860416A CN 201610281041 A CN201610281041 A CN 201610281041A CN 105860416 A CN105860416 A CN 105860416A
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parts
corrosion
resistant
composite reinforced
poly
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郭良来
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Shang Yang
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Moulding By Coating Moulds (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

The invention discloses an anti-corrosion and anti-aging composite reinforced plastic inspection well and a preparation method. The inspection well is prepared from polyvinylchloride resin, ABS resin, polyamide resin-610, high styrene rubbere QBS860, European polyethylene wax-691, polytetrafluoroethylene, a compound stabilizer, DCP, carbon fibers, poly-amino aldehyde, filler and metal fibers. The inspection well overcomes the defects in the prior art; through reasonable preparation of pipe raw material ingredients, the corrosion resistance and aging resistance of the inspection well are greatly improved, and the inspection well can better adapt to a severe underground environment. The preparation method is convenient, efficient and suitable for large-scale industrial popularization.

Description

A kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft and preparation method
Technical field
The present invention relates to plastic well field, be specifically related to a kind of corrosion-resistant ageing-resistant composite strengthening and mould Material inspection shaft and preparation method.
Background technology
In recent years, plastic inspection well is widely used, a large amount of plastic inspection well manufacturing enterprises also with Occur like the mushrooms after rain.Main cause is that China firmly builds portion's emphasis and promotes the use of plastics inspection Well, places restrictions on brick inspection shaft, effectively controls groundwater resources and pollutes.From 2007 time, the whole nation is only 2~3 are had to produce plastic inspection well enterprise, and to existing more than 50 enterprise in whole nation today of 2013 Industry, in these 50 many enterprises, go up in advance is to use Shooting Technique to produce, but in the recent period Producer's great majority of this project upper use rotational molding technique to produce inspection shaft.
According to plastic inspection well standard, material prescription comprises: polyvinyl chloride resin, impact modifying agent, Stabilizer, modifier, filler, colorant and external lubricant etc..The master of plastic inspection well Wanting composition is polrvinyl chloride or polypropylene, it is possible to additionally incorporate other composition to strengthen its thermostability, tough Property, ductility etc..Plastic inspection well is mainly used in plumbing, drainage project.Existing plastics are examined Looking into its surface corrosion resistance of well and ageing resistace is poor, service life is short, is not suitable with severe ring Border uses.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of corrosion-resistant ageing-resistant composite strengthening Plastic inspection well and preparation method so that the plastic well ruggedness produced is strong.
For realizing object above, the present invention is achieved by the following technical programs:
The invention provides a kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, by following heavy The raw material composition of amount number: Corvic: 20-50 part, ABS resin: 20-50 part, Polyamide-610:5-12 part, high styrene rubber QBS860:1-9 part, European poly-second Alkene wax-691:1-8 part, politef: 2-6 part, complex stabilizer: 2-8 part, DCP: 3-5 part, carbon fiber: 2-10 part, poly-ammonium aldehyde: 2-10 part, filler: 2-8 part, metal fibre Dimension: 3-10 part.
Preferably, it is made up of the raw material of following parts by weight: Corvic: 25-45 part, ABS resin: 25-45 part, polyamide-610:6-11 part, high styrene rubber QBS860: 2-8 part, European polyethylene wax-691:2-6 part, politef 4-5 part, complex stabilizer: 3-6 part, DCP:3-5 part, carbon fiber: 3-9 part, poly-ammonium aldehyde: 4-8 part, filler: 3-5 Part, metallic fiber: 6-8 part.
Preferably, it is made up of the raw material of following parts by weight: Corvic: 25 parts, ABS Resin: 30 parts, polyamide-610:6 part, high styrene rubber QBS860:3 part, European polyethylene wax-691:4 part, politef 4 parts, complex stabilizer: 3 parts, DCP: 3 parts, carbon fiber: 3 parts, poly-ammonium aldehyde: 4 parts, filler: 4 parts, metallic fiber: 6 parts.
Preferably, it is made up of the raw material of following parts by weight: Corvic: 30 parts, ABS Resin: 40 parts, polyamide-610:10 part, high styrene rubber QBS860:5 part, European polyethylene wax-691:4 part, politef: 4 parts, complex stabilizer: 3 parts, DCP: 3 parts, carbon fiber: 4 parts, poly-ammonium aldehyde: 6 parts, filler: 3 parts, metallic fiber: 6 parts.
The preparation method of a kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, including following step Rapid:
(1) batch mixing: weigh raw material the most by weight, in being subsequently poured into blender, mixing is all Even stirring 20-30min, is dried 1-2h under conditions of 90-100 DEG C, has been dried after stirring Injection machine it is transported to after Biing;
(2) plasticizing injection: compound is placed in heating plasticizing in the heating cylinder in injection machine 40-50min, is then entered melted compound in mould by screw barrel vasopressing injection;
(3) molding: after the melted compound cooling 5-10h in mould, be shaped to plastics inspection Look into well shape, after completing inspection, enter warehouse for finished product.
Preferably, the pressure of the pressurization described in step (2) is 50-100Mpa.
The method have the benefit that
The present invention, with polrvinyl chloride as primary raw material, coordinates other raw materials combining with reinforced plastics well Close performance, wherein ABS resin is antiacid, alkali, salt corrosion ability stronger, organic solvent-resistant Dissolubility is also preferable, and has good mouldability, can strengthen it corrosion-resistant in addition plastic well Property, increasing the life-span of plastic well, polyamide-610 is the thermoplastic of a kind of good mechanical performance Property engineering plastics, have good mechanical property, thermostability, mar proof, resistance to chemical attack Property and self lubricity, and coefficient of friction is low, has certain anti-flammability, it is easy to processing, adds this Can strengthen the combination property in its plastic well in invention, high styrene rubber QBS860 can increase Ageing-resistant, the hardness of strong plastic well and rigidity, mechanical strength and tearing strength etc., European poly-second Alkene wax with reinforced plastics well plasticizing rate, can improve toughness and surface flatness, the DCP of plastic well It is the industrial macromolecular material auxiliary agent being widely used, in plastic well is processed, adds this thing Matter, can make its pliability strengthen, and is easily worked molding, and instant component proportioning is scientific and reasonable, Safely and effectively, manufacture method is easily operated, is suitable for industrially large-scale promotion.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below will knot Close embodiments of the invention, the technical scheme in the embodiment of the present invention is carried out clearly and completely Describe.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creation The every other embodiment obtained under property work premise, broadly falls into the scope of protection of the invention.
Embodiment 1:
A kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, by the raw material of following parts by weight Composition: Corvic: 25 parts, ABS resin: 30 parts, polyamide-610:6 Part, high styrene rubber QBS860:3 part, European polyethylene wax-691:4 part, polytetrafluoro Ethylene 4 parts, complex stabilizer: 3 parts, DCP:3 part, carbon fiber: 3 parts, poly-ammonium aldehyde: 4 Part, filler: 4 parts, metallic fiber: 6 parts.
The preparation method of a kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, including following step Rapid:
(1) batch mixing: weigh raw material the most by weight, in being subsequently poured into blender, mixing is all Even stirring 20min, is dried 1h under conditions of 90 DEG C, carries after being dried after stirring To injection machine;
(2) plasticizing injection: compound is placed in heating plasticizing in the heating cylinder in injection machine 40min, then enters the pressure injection that melted compound applies 50Mpa by screw barrel In mould;
(3) molding: after the melted compound cooling 5h in mould, be shaped to plastics inspection Well shape, enters warehouse for finished product after completing inspection.
Embodiment 2:
A kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, by the raw material of following parts by weight Composition: Corvic: 30 parts, ABS resin: 40 parts, polyamide-610:10 Part, high styrene rubber QBS860:5 part, European polyethylene wax-691:4 part, polytetrafluoro Ethylene: 4 parts, DCP:3 part, carbon fiber: 5 parts, poly-ammonium aldehyde: 5 parts, filler: 3 Part, metallic fiber: 6 parts.
The preparation method of a kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, including following step Rapid:
(1) batch mixing: weigh raw material the most by weight, in being subsequently poured into blender, mixing is all Even stirring 30min, is dried 2h under conditions of 100 DEG C, carries after being dried after stirring To injection machine;
(2) plasticizing injection: compound is placed in heating plasticizing in the heating cylinder in injection machine 40min, then enters the pressure injection that melted compound applies 60Mpa by screw barrel In mould;
(3) molding: after the melted compound cooling 6h in mould, be shaped to plastics inspection Well shape, enters warehouse for finished product after completing inspection.
Embodiment 3:
A kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, by the raw material of following parts by weight Composition:
Corvic: 25 parts, ABS resin: 30 parts, polyamide-610:6 part, High styrene rubber QBS860:3 part, European polyethylene wax-691:4 part, politef 4 Part, complex stabilizer: 3 parts, DCP:3 part, carbon fiber: 3 parts, poly-ammonium aldehyde: 4 parts, Filler: 4 parts, metallic fiber: 6 parts.
The preparation method of a kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, including following step Rapid:
(1) batch mixing: weigh raw material the most by weight, in being subsequently poured into blender, mixing is all Even stirring 25min, is dried 1h under conditions of 90 DEG C, carries after being dried after stirring To injection machine;
(2) plasticizing injection: compound is placed in heating plasticizing in the heating cylinder in injection machine 40min, then enters the pressure injection that melted compound applies 70Mpa by screw barrel In mould;
(3) molding: after the melted compound cooling 6h in mould, be shaped to plastics inspection Well shape, enters warehouse for finished product after completing inspection.
Embodiment 4:
A kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, by the raw material of following parts by weight Composition:
Corvic: 33 parts, ABS resin: 36 parts, polyamide-610:8 part, High styrene rubber QBS860:4 part, European polyethylene wax-691:5 part, politef: 4 parts, complex stabilizer: 4 parts, DCP:5 part, carbon fiber: 6 parts, poly-ammonium aldehyde: 7 parts, Filler: 5 parts, metallic fiber: 8 parts.
The preparation method of a kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, including following step Rapid:
(1) batch mixing: weigh raw material the most by weight, in being subsequently poured into blender, mixing is all Even stirring 30min, is dried 2h under conditions of 100 DEG C, carries after being dried after stirring To injection machine;
(2) plasticizing injection: compound is placed in heating plasticizing in the heating cylinder in injection machine 40min, then enters the pressure injection that melted compound applies 60Mpa by screw barrel In mould;
(3) molding: after the melted compound cooling 6h in mould, be shaped to plastics inspection Well shape, enters warehouse for finished product after completing inspection.
Embodiment 5:
A kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, by the raw material of following parts by weight Composition:
Corvic: 33 parts, ABS resin: 36 parts, polyamide-610:10 Part, high styrene rubber QBS860:4 part, European polyethylene wax-691:3 part, polytetrafluoro Ethylene: 4 parts, complex stabilizer: 5 parts, DCP:4 part, carbon fiber: 6 parts, poly-ammonium aldehyde: 6 parts, filler: 5 parts, metallic fiber: 8 parts.
The preparation method of a kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, including following step Rapid:
(1) batch mixing: weigh raw material the most by weight, in being subsequently poured into blender, mixing is all Even stirring 30min, is dried 2h under conditions of 100 DEG C, carries after being dried after stirring To injection machine;
(2) plasticizing injection: compound is placed in heating plasticizing in the heating cylinder in injection machine 45min, then enters the pressure injection that melted compound applies 70Mpa by screw barrel In mould;
(3) molding: after the melted compound cooling 7h in mould, be shaped to plastics inspection Well shape, enters warehouse for finished product after completing inspection.
Embodiment 6:
A kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, by the raw material of following parts by weight Composition: Corvic: 40 parts, ABS resin: 38 parts, polyamide-610:9 Part, high styrene rubber QBS860:8 part, European polyethylene wax-691:5 part, polytetrafluoro Ethylene: 5 parts, complex stabilizer: 5 parts, DCP:4 part, carbon fiber: 5 parts, poly-ammonium aldehyde: 6 parts, filler: 4 parts, metallic fiber: 6 parts.
The preparation method of a kind of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, including following step Rapid:
(1) batch mixing: weigh raw material the most by weight, in being subsequently poured into blender, mixing is all Even stirring 30min, is dried 2h under conditions of 100 DEG C, carries after being dried after stirring To injection machine;
(2) plasticizing injection: compound is placed in heating plasticizing in the heating cylinder in injection machine 50min, then enters the pressure injection that melted compound applies 80Mpa by screw barrel In mould;
(3) molding: after the melted compound cooling 8h in mould, be shaped to plastics inspection Well shape, enters warehouse for finished product after completing inspection.
Above example only in order to technical scheme to be described, is not intended to limit;Although With reference to previous embodiment, the present invention is described in detail, those of ordinary skill in the art It is understood that the technical scheme described in foregoing embodiments still can be modified by it, Or wherein portion of techniques feature is carried out equivalent;And these amendments or replacement, not The essence making appropriate technical solution departs from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (6)

1. a corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft, it is characterised in that by following heavy The raw material composition of amount number: Corvic: 20-50 part, ABS resin: 20-50 part, Polyamide-610:5-12 part, high styrene rubber QBS860:1-9 part, European poly-second Alkene wax-691:1-8 part, politef: 2-6 part, complex stabilizer: 2-8 part, DCP: 3-5 part, carbon fiber: 2-10 part, poly-ammonium aldehyde: 2-10 part, filler: 2-8 part, metal fibre Dimension: 3-10 part.
Corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft the most as claimed in claim 1, it is special Levy and be, be made up of the raw material of following parts by weight: Corvic: 25-45 part, ABS Resin: 25-45 part, polyamide-610:6-11 part, high styrene rubber QBS860: 2-8 part, European polyethylene wax-691:2-6 part, politef: 4-5 part, complex stabilizer: 3-6 part, DCP:3-5 part, carbon fiber: 3-9 part, poly-ammonium aldehyde: 4-8 part, filler: 3-5 Part, metallic fiber: 6-8 part.
Corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft the most as claimed in claim 2, it is special Levy and be, be made up of the raw material of following parts by weight: Corvic: 25 parts, ABS tree Fat: 30 parts, polyamide-610:6 part, high styrene rubber QBS860:3 part, Europe Continent Tissuemat E-691:4 part, politef: 4 parts, complex stabilizer: 3 parts, DCP: 3 parts, carbon fiber: 3 parts, poly-ammonium aldehyde: 4 parts, filler: 4 parts, metallic fiber: 6 parts.
Corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft the most as claimed in claim 2, its feature It is, is made up of the raw material of following parts by weight: Corvic: 30 parts, ABS resin: 40 parts, polyamide-610:10 part, high styrene rubber QBS860:5 part, Europe poly- Ethylene waxes-691:4 part, politef: 4 parts, complex stabilizer: 3 parts, DCP:3 Part, carbon fiber: 4 parts, poly-ammonium aldehyde: 6 parts, filler: 3 parts, metallic fiber: 6 parts.
5. the corrosion-resistant ageing-resistant composite reinforced plastics inspection as described in claim 1-4 is arbitrary The preparation method of well, it is characterised in that comprise the following steps:
(1) batch mixing: weigh raw material the most by weight, in being subsequently poured into blender, mixing is all Even stirring 20-30min, is dried 1-2h under conditions of 90-100 DEG C, has been dried after stirring Injection machine it is transported to after Biing;
(2) plasticizing injection: compound is placed in heating plasticizing in the heating cylinder in injection machine 40-50min, is then entered melted compound in mould by screw barrel vasopressing injection;
(3) molding: after the melted compound cooling 5-10h in mould, be shaped to plastics inspection Look into well shape, after completing inspection, enter warehouse for finished product.
The preparation of corrosion-resistant ageing-resistant composite reinforced plastics inspection shaft the most as claimed in claim 5 Method, it is characterised in that the pressure of the pressurization described in step (2) is 50-100Mpa.
CN201610281041.1A 2016-04-27 2016-04-27 Anti-corrosion and anti-aging composite reinforced plastic inspection well and preparation method Pending CN105860416A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106893244A (en) * 2017-03-17 2017-06-27 四会市恒星智能科技有限公司 A kind of composite plastic inspection shaft and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1786049A (en) * 2005-12-06 2006-06-14 河北工业大学 Nylon 6/ poly methylene imine molecular composite material and its preparation method
CN102417671A (en) * 2010-09-27 2012-04-18 上海远洲管业有限公司 Preparation technology of high strength PVC non-excavation pipe fitting
CN104292690A (en) * 2014-09-15 2015-01-21 合肥瑞瑶环保建材科技有限公司 Impact-resistant plastic manhole

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN1786049A (en) * 2005-12-06 2006-06-14 河北工业大学 Nylon 6/ poly methylene imine molecular composite material and its preparation method
CN102417671A (en) * 2010-09-27 2012-04-18 上海远洲管业有限公司 Preparation technology of high strength PVC non-excavation pipe fitting
CN104292690A (en) * 2014-09-15 2015-01-21 合肥瑞瑶环保建材科技有限公司 Impact-resistant plastic manhole

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106893244A (en) * 2017-03-17 2017-06-27 四会市恒星智能科技有限公司 A kind of composite plastic inspection shaft and preparation method thereof

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