CN105851040B - 一种含烯丙苯噻唑和异菌脲的农药颗粒剂 - Google Patents
一种含烯丙苯噻唑和异菌脲的农药颗粒剂 Download PDFInfo
- Publication number
- CN105851040B CN105851040B CN201610278318.5A CN201610278318A CN105851040B CN 105851040 B CN105851040 B CN 105851040B CN 201610278318 A CN201610278318 A CN 201610278318A CN 105851040 B CN105851040 B CN 105851040B
- Authority
- CN
- China
- Prior art keywords
- iprodione
- probenazole
- granular pesticide
- rice
- seedling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000005867 Iprodione Substances 0.000 title claims abstract description 41
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 title claims abstract description 41
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000000575 pesticide Substances 0.000 title claims abstract description 20
- 241000209094 Oryza Species 0.000 claims abstract description 23
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 22
- 235000009566 rice Nutrition 0.000 claims abstract description 22
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- LJWIAZFZRNWQOL-UHFFFAOYSA-N benzene;1,3-thiazole Chemical compound C1=CSC=N1.C1=CC=CC=C1 LJWIAZFZRNWQOL-UHFFFAOYSA-N 0.000 claims description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims 2
- 208000015220 Febrile disease Diseases 0.000 claims 1
- 125000005336 allyloxy group Chemical group 0.000 claims 1
- 150000003851 azoles Chemical class 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 230000001932 seasonal effect Effects 0.000 claims 1
- 229930192474 thiophene Natural products 0.000 claims 1
- 201000010099 disease Diseases 0.000 abstract description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 6
- 238000012360 testing method Methods 0.000 description 11
- 239000008187 granular material Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000003814 drug Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 3
- 230000000855 fungicidal effect Effects 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 241001330975 Magnaporthe oryzae Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 230000004071 biological effect Effects 0.000 description 2
- 238000013401 experimental design Methods 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- -1 Sodium alkyl sulfate Chemical class 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明涉及一种含烯丙苯噻唑和异菌脲的农药颗粒剂，有效成分由以下重量比的成分组成：烯丙苯噻唑5‑8％，异菌脲2‑3％，其中烯丙苯噻唑和异菌脲的重量比为：5‑8:2‑3。本发明适用于防治旱育秧期的水稻稻瘟病,其配方增效显著，内吸性好,能有效的控制病害，具有省时省工省力的功效。
Description
技术领域
本发明涉及农药技术领域,具体涉及一种含烯丙苯噻唑和异菌脲的农药颗粒剂。
背景技术
烯丙苯噻唑，英文通用名为：probenazole,是日本明治制果药业株式会社开发的一种诱导免疫型杀菌剂，通过激发植物本身对病害的免疫(抗性)反应来实现防病效果，通过植物根部吸收，并较迅速地渗透传导至植物体各部分。烯丙苯噻唑处理水稻，能促进根系吸收，保护作物不受稻瘟病菌和稻白叶枯病菌的侵染。
异菌脲，英文通用名为：iprodione，是一种广谱触杀型保护性杀菌剂，同时具有一定的治疗作用，也可通过根部吸收起内吸作用。适用于防治蔬菜、观赏作物的叶斑病、灰霉病、菌核病、根腐病，对水稻稻瘟病也有较好的防治效果。
现阶段,水稻育秧基本实现从之前的水育秧为主到目前的旱育秧为主，而秧苗病害仍以药剂兑水喷雾法进行防治，比较费时费力。在农村劳力短缺的情况下，省力型防治病虫害的方法越来越受关注，本发明通过有效成分烯丙苯噻唑和异菌脲复配，制成农药颗粒剂，其内吸传导性好,能在育秧作业时或秧苗期施用，具有省时省工的功效。
目前，将烯丙苯噻唑与异菌脲复配的研究未见有相关的报道。
发明内容
本发明要解决的技术问题是，提供一种含烯丙苯噻唑和异菌脲的农药颗粒剂，用于旱育秧期稻瘟病的防治,其配方增效显著，内吸性好,能有效的控制病害，具有省时省工省力的功效。
本发明采取的技术方案是：一种含烯丙苯噻唑和异菌脲的农药颗粒剂，有效成分由烯丙苯噻唑和异菌脲组成，其中烯丙苯噻唑和异菌脲的重量比为：5-8:2-3，优选的，烯丙苯噻唑和异菌脲的重量比为8:2。
所述的烯丙苯噻唑在农药颗粒剂中的重量百分比为5-8％，异菌脲在农药颗粒剂中的重量百分比为2-3％。
本发明的农药颗粒剂加入的辅助剂包括填料、粘结剂、分散剂、润湿剂、崩解剂、着色剂、稳定剂或其它有益于有效成分在制剂中稳定和药效发挥的物质，都是农药制剂领域中常用或允许使用的各种成分。
本发明具有以下优点和显著的技术效果:
(1)烯丙苯噻唑和异菌脲的作用机制不同,相互混配有利于缓解病菌抗性发展。
(2)室内生测结果表明，烯丙苯噻唑和异菌脲按一定的比例复配对稻瘟病菌增效明显，有利于减少农药施用量和降低农药成本。
(3)本发明制备成农药颗粒剂,结合旱育秧作业时或育秧期间施用，减轻了农事操作，有利于节约劳动成本。
具体实施方式
以下结合实施例对本发明的技术方案和有益效果作进一步说明，本发明所述的百分比均为重量百分比。
一、制备实施例
实施例1：8％烯丙苯噻唑·异菌脲颗粒剂(有效成分比6:2)
配方：按重量比称取烯丙苯噻唑6％，异菌脲2％，萘磺酸盐甲醛缩合物4.5％，十二烷基硫酸钠3％，聚乙烯醇3.5％，膨润土补足至100％。
实施例2：9％烯丙苯噻唑·异菌脲颗粒剂(有效成分比6:3)
配方：按重量比称取烯丙苯噻唑7％，异菌脲3％，萘磺酸盐甲醛缩合物3％，十二烷基硫酸钠3.5％，聚乙烯醇3％，凹凸棒土12％，高岭土补足至100％。
实施例3：10％烯丙苯噻唑·异菌脲颗粒剂(有效成分比8:2)
配方：按重量比称取烯丙苯噻唑8％，异菌脲2％，十二烷基硫酸钠2.5％，羧甲基纤维素3.5％，硅藻土15％，膨润土补足至100％。
实施例4：7％烯丙苯噻唑·异菌脲颗粒剂(有效成分比5:2)
配方：按重量比称取烯丙苯噻唑5％，异菌脲2％,萘磺酸盐甲醛缩合物5％，十二烷基硫酸钠2.5％，聚乙烯醇5％，高岭土补足至100％。
制备方法：将上述实施例1-4所述的配方组分混合均匀，粉碎，加水润湿后充分搅拌均匀，再用螺杆挤压造粒机造粒，干燥后过筛即得含烯丙苯噻唑·异菌脲颗粒剂。
二、生物活性试验实施例
本发明的生物活性实施例分为室内毒力测定试验和田间药效试验。
实施例1：烯丙苯噻唑、异菌脲及复配剂对稻瘟病的室内毒力测定。
经预试确定各药剂有效抑制浓度范围后，将烯丙苯噻唑、异菌脲及其混配剂按有效成分含量梯度系列稀释5个浓度，设清水对照。参照《农药室内生物测定试验准则杀菌剂》进行，采用菌丝生长速率法测定药剂对稻瘟病的毒力。72h后用十字交叉法测量菌落直径，计算各处理净生长量、菌丝生长抑制率。
将菌丝生长抑制率换算成机率值(y)，药液浓度(μg/mL)转换成对数值(x)，以最小二乘法求得毒力回归方程(y＝a+bx)，并由此计算出每种药剂的EC50值。
根据孙云沛法的共毒系数法(CTC)来评价药剂混用的增效作用，即CTC≤80为拮抗作用，80<CTC<120为相加作用，CTC≥120为增效作用。统计结果如表1所示：
| 供试药剂 | 配比 | EC<sub>50</sub>(mg/L) | 共毒系数(CTC) |
| 烯丙苯噻唑(A) | / | 2.05 | / |
| 异菌脲(B) | / | 3.15 | / |
| A：B | 5:2 | 1.66 | 137.0 |
| A：B | 6:2 | 1.45 | 155.4 |
| A：B | 7:2 | 1.41 | 158.2 |
| A：B | 8:2 | 1.24 | 177.4 |
| A：B | 5:3 | 1.56 | 151.5 |
| A：B | 6:3 | 1.57 | 148.0 |
| A：B | 7:3 | 1.51 | 151.8 |
| A：B | 8:3 | 1.58 | 143.5 |
| A：B | 1:10 | 3.83 | 78.4 |
测定结果表明，当烯丙苯噻唑和异菌脲的配比为5-8:2-3时,共毒系数(CTC)大于120，增效作用明显。
实施例2：制备实施例3所得的制剂用于防治秧苗稻瘟病的田间药效试验
(1)试验设计:将10％烯丙苯噻唑·异菌脲(8:2)颗粒剂作为试验组1#，施用量为0.1公斤/m2；以8％烯丙苯噻唑颗粒剂为对照组1#,施用量为0.15公斤/m2；以10％异菌脲颗粒剂为对照组2#，施用量为0.2公斤/m2，设置1个空白对照组。
(2)施药方法
在平整育秧畦上放好育秧盘,在秧盘按每孔放入2颗已经催好的牙谷种,在弄好秧盘之后按对应处理的药剂及药量施用,将已经催好芽的谷种栽入土壤中,试验中每个处理3次重复,以4个秧盘作为1个小区面积，按试验设计将试验组1#、对照组1#、对照组2#的对应药剂按规定的用量均匀施于对应的小区上，各小区中保持苗床环境一致。
(3)试验结果
药后10天，结合秧苗稻瘟病高发期结果调查,计算发病率及防治效果，结果表明，试验组1#对秧稻瘟病的防治效果为85.43％，对照组1#对秧稻瘟病的防治效果为72.24％；对照组2#对秧稻瘟病的防治效果为70.57％。从试验中看出，烯丙苯噻唑与异菌脲合理混配后，混配剂对秧稻瘟病增效明显，既减少有效成分的使用量，又表现出优于单剂的田间效果，有助于减少农药使用成本。
Claims (4)
1.一种含烯丙苯噻唑和异菌脲的农药颗粒剂，其特征在于，烯丙苯噻唑和异菌脲的重量比为：5-8:2-3。
2.根据权利要求1所述的含烯丙苯噻唑和异菌脲的农药颗粒剂，其特征在于，烯丙苯噻唑和异菌脲的重量比为8:2。
3.根据权利要求1或2所述的含烯丙苯噻唑和异菌脲的农药颗粒剂，其特征在于，烯丙苯噻唑的重量百分比为5-8％，异菌脲的重量百分比为2-3％。
4.权利要求3所述的含烯丙苯噻唑和异菌脲的农药颗粒剂用于防治旱育秧期的水稻稻瘟病的用途。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610278318.5A CN105851040B (zh) | 2016-04-28 | 2016-04-28 | 一种含烯丙苯噻唑和异菌脲的农药颗粒剂 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610278318.5A CN105851040B (zh) | 2016-04-28 | 2016-04-28 | 一种含烯丙苯噻唑和异菌脲的农药颗粒剂 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105851040A CN105851040A (zh) | 2016-08-17 |
| CN105851040B true CN105851040B (zh) | 2019-01-25 |
Family
ID=56629662
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610278318.5A Expired - Fee Related CN105851040B (zh) | 2016-04-28 | 2016-04-28 | 一种含烯丙苯噻唑和异菌脲的农药颗粒剂 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105851040B (zh) |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3629428A (en) * | 1967-09-07 | 1971-12-21 | Meiji Seika Kaisha | Pesticide for controlling bacterial and fungal diseases of rice plant |
| JP2581917B2 (ja) * | 1987-04-24 | 1997-02-19 | アグロカネシヨウ株式会社 | 農園芸用殺菌剤 |
| CN103238622B (zh) * | 2012-02-10 | 2015-12-16 | 陕西美邦农药有限公司 | 一种含有烯丙苯噻唑的杀菌组合物 |
-
2016
- 2016-04-28 CN CN201610278318.5A patent/CN105851040B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN105851040A (zh) | 2016-08-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104522054A (zh) | 一种生物源增效复配杀虫剂、制备方法及其应用 | |
| CN109303054A (zh) | 一种含春雷霉素和精甲霜灵的杀菌剂 | |
| CN104757006B (zh) | 一种包含噻呋酰胺的农药组合物 | |
| CN106982844B (zh) | 一种包含噁唑菌酮和恶霉灵的农用杀菌组合物 | |
| CN108294014A (zh) | 一种防治根腐病的种衣剂及其制备方法与应用 | |
| CN103120166A (zh) | 含有噁霉灵的杀菌组合物 | |
| CN102972410B (zh) | 一种含丙硫菌唑和甲氧基丙烯酸酯类杀菌剂的农药组合物 | |
| CN105851040B (zh) | 一种含烯丙苯噻唑和异菌脲的农药颗粒剂 | |
| CN105851016B (zh) | 一种含烯丙苯噻唑和甲霜灵的农药颗粒剂 | |
| CN105746519B (zh) | 一种含稻瘟酰胺和香菇多糖的农药组合物 | |
| CN105918325B (zh) | 一种含烯丙苯噻唑和精甲霜灵的农药颗粒剂 | |
| CN104351210B (zh) | 含二氯异氰尿酸钠和噁霉灵的棉籽杀菌配种液的制备方法 | |
| CN104488869B (zh) | 一种2‑氰基‑3‑氨基‑3‑苯基丙烯酸乙酯与蛇床子素的杀菌组合物 | |
| CN105685062A (zh) | 一种含烯丙苯噻唑和噁霉灵的农药颗粒剂 | |
| CN108013077A (zh) | 一种微生物土壤杀菌剂 | |
| CN105935055B (zh) | 一种含烯丙苯噻唑和福美双的农药颗粒剂 | |
| CN108041077A (zh) | 一种土壤杀菌剂 | |
| CN104982453A (zh) | 一种含呋虫胺的杀虫杀菌颗粒剂 | |
| CN106508911B (zh) | 一种含嘧菌环胺和氨基寡糖素的杀菌组合物 | |
| CN115918665B (zh) | 一种防治小麦茎基腐病的小麦拌种剂 | |
| CN107148969A (zh) | 一种含烯丙苯噻唑和茉莉酸甲酯的颗粒剂 | |
| CN105850994A (zh) | 一种含烯丙苯噻唑和黄芪多糖的农药颗粒剂 | |
| CN105831134A (zh) | 一种防治旱育秧水稻稻瘟病的方法 | |
| CN105746535A (zh) | 一种含烯丙苯噻唑和氨基寡糖素的农药颗粒剂 | |
| CN105211106B (zh) | 一种含哈茨木霉菌和腐殖酸的颗粒剂 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20181206 Address after: 462300 Yellow River Plaza Commercial and Trade City, West Section of Yellow River Road, Luohe City, Henan Province Applicant after: Luohe Fupai Agricultural Technology Co.,Ltd. Address before: 530000 room 3106, block C, hang Yang International City, No. 131, National Road, Qingxiu District, Nanning, the Guangxi Zhuang Autonomous Region. Applicant before: GUANGXI NANNING YITU BIOTECHNOLOGY Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190125 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |