CN105845763A - Frameless crystalline silicon cell completely-PID-resistant light assembly and cell panel - Google Patents

Frameless crystalline silicon cell completely-PID-resistant light assembly and cell panel Download PDF

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Publication number
CN105845763A
CN105845763A CN201610235691.2A CN201610235691A CN105845763A CN 105845763 A CN105845763 A CN 105845763A CN 201610235691 A CN201610235691 A CN 201610235691A CN 105845763 A CN105845763 A CN 105845763A
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pid
crystal silicon
light components
type crystal
silicon battery
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董友强
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0488Double glass encapsulation, e.g. photovoltaic cells arranged between front and rear glass sheets
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/049Protective back sheets
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Photovoltaic Devices (AREA)

Abstract

The invention discloses a frameless crystalline silicon cell completely-PID-resistant light assembly and a cell panel. The frameless crystalline silicon cell completely-PID-resistant light assembly comprises front board glass, cell slices, a backboard and a wiring box, wherein the cell slices are arranged between the front board glass and the backboard; the front board glass is photovoltaic ultra-white figured glass with thickness of 4.0-5.0mm, a nano titanium dioxide coating film is attached to the surface of the front board glass, packaging material layers are arranged between the cell slices and the front board glass as well as between the cell slices and the backboard, the packaging material layers are prepared by polyolefin, the wiring box is electrically connected with the cell slices, the packaging material layers are mixed with a wavelength conversion agent, and the wavelength conversion agent can shift an ineffective or low-efficiency sunlight wavelength to an effective wavelength. The frameless crystalline silicon cell completely-PID-resistant light assembly eliminates an aluminum frame, satisfies a load requirement of 5400pa without installing the frame, is completely resistant to PID, and is decreased in weight, thickness, and production cost.

Description

A kind of rimless type crystal silicon battery the most anti-PID light components and cell panel
Technical field
The present invention relates to a kind of crystalline silicon photovoltaic module, particularly relate to a kind of rimless type crystal silicon battery The most anti-PID light components and cell panel.
Background technology
Crystalline silicon is divided into monocrystalline silicon, polysilicon and non-crystalline silicon.Wherein, mono-crystalline silicon solar electricity Pond is a kind of solar cell currently developing the fastest, and its structure and production technology are the most fixed Type, product is widely used in space and ground.
Above-mentioned crystalline silicon can be used for making Crystalline Silicon PV Module, and research shows, is present in crystal The high voltage between circuit and its grounded metal frame in silicon photovoltaic module, can cause assembly The continuous decrement of photovoltaic performance.It is many for causing this type of mechanism decayed, such as above-mentioned Under high-tension effect, the encapsulating material of assembly battery and assembly upper surface layer and undersurface layer The Ion transfer phenomenon occurred in material;The hot carrier phenomenon occurred in battery;Electric charge is again Distribution reduces the active layer of battery;Relevant circuit is corroded etc..
The above-mentioned mechanism causing decay is referred to as electromotive force induction decay, polarity, electrolytic etching And electrochemical corrosion.Conventional anti-PID (induce by Potential Induced Degradation electromotive force Decay), after assembly uses 3-5, component power decay is substantially, during assembly life-span, power Too much, assembly life-span shortens, and causes power station generated energy to be decreased obviously in decay.Additionally solar energy The structure of photovoltaic assembly mainly includes upper cover plate, binding agent, cell piece, backboard, frame and wiring Box.Packaged photovoltaic module needs outdoor placement, the dust in air after use a period of time Particulate matter can adsorb on the cover plate of photovoltaic module, forms light blocking dust cover layer, thus reduces The optoelectronic transformation efficiency of photovoltaic module, the light tight pollutant of bulk covers and also can produce hot spot effect simultaneously Should, cause photovoltaic module localized regions of elevated temperature until burning and scrapping.As can be seen here, photovoltaic group The natural resistance of part is poor, is chronically exposed in air and there will be efficiency decay, surface sediment one-tenth ash After the problem such as be difficult to clean off, thus the electricity conversion of existing photovoltaic module is relatively low, use Life-span the most not can exceed that 20 years.
Meanwhile, existing conventional crystalline silicon lightweight packages is about about 20kg.The weight of assembly itself Amount, limits its range of application, in the projects such as the roof that weight capacity is more weak, it is impossible to meet Actual demand.Further, conventional crystalline silicon assembly is heavy, causes it to be inconvenient to carry and transport.
Therefore, for above-mentioned technical problem, it is necessary to further solution.
Summary of the invention
In view of this, it is an object of the invention to provide a kind of rimless type crystal silicon battery the most anti- PID light components and cell panel, to overcome defect present in existing Crystalline Silicon PV Module.
To achieve these goals, the technical scheme that the embodiment of the present invention provides is as follows:
The rimless type crystal silicon battery the most anti-PID light components of the present invention includes: front glass sheet, Cell piece, backboard and terminal box, described cell piece is between described front glass sheet and backboard;
Described front glass sheet is the photovoltaic energy ultrawhite figured glass that 4.0-5.0mm is thick, described header board glass Glass surface have nano titanium oxide film, between described cell piece and described front glass sheet, electricity Being respectively arranged with encapsulation material material layer between pond sheet and described backboard, described encapsulating material layer is poly- Alkene, described terminal box is electrically connected with cell piece, is mixed with wavelength and turns in encapsulating material layer Changing agent, invalid or poor efficiency sunlight wavelength can be migrated to significant wave by described wavelength-shifting agent Long.
Described backboard includes basic unit, outer layer and fluorine-containing coat the most successively from center, described outside Layer surface is through plasma treatment;Described outer layer is BMC layer or SMC layer;Described basic unit is PET keriotheca;Described PET keriotheca is by the thickest soft folder of folder in the middle of upper and lower panel one Core is constituted;The surface of described fluorine-containing coat is through plasma treatment.
As the improvement of the rimless type crystal silicon battery the most anti-PID light components of the present invention, described The thickness of the encapsulating material layer of cell piece either side is 0.25-0.8mm.
As the improvement of the rimless type crystal silicon battery the most anti-PID light components of the present invention, described The thickness of rimless type crystal silicon battery the most anti-PID light components is less than 1cm, and weight is 8-12kg.
As the improvement of the rimless type crystal silicon battery the most anti-PID light components of the present invention, described Rimless type crystal silicon battery the most anti-PID light components also includes that welding, described welding are arranged at institute Stating the front of cell piece, described terminal box is electrically connected with described welding.
As the improvement of the rimless type crystal silicon battery the most anti-PID light components of the present invention, described Polyolefin is heat curing-type or thermoplastics type.
As the improvement of the rimless type crystal silicon battery the most anti-PID light components of the present invention, described Terminal box is that the back of the body connects formula terminal box, and it is installed on the back side of described cell piece.
To achieve these goals, the technical scheme that the embodiment of the present invention provides is as follows:
The cell panel of the present invention includes rimless type crystal silicon battery as above the most anti-PID lightweight Assembly, the quantity of described assembly is multiple, is electrically connected with between the plurality of assembly.
Compared with prior art, the invention has the beneficial effects as follows: the rimless type crystal silicon electricity of the present invention Pond the most anti-PID light components abandons aluminium frame, and assembly just can meet 5400pa without framing up Loading demands;And the most anti-PID of assembly, and reduce lightweight packages, reduce component thickness, Reduce manufacturing cost.Thus, it is greatly prolonged assembly service life, reduces during assembly uses Power attenuation, extend the range of application of crystalline silicon component, and improve crystalline silicon component Convenience and rodability.Solving crystalline silicon component quality weight, thickness is thick, transports and uses The problems such as inconvenience;
Meanwhile, the light transmission rate of the rimless type crystal silicon battery the most anti-PID light components of the present invention Reach more than 92%, add the generated energy of assembly, and do not reduce rigidity and the machine of assembly Tool load-carrying ability;
The rimless type crystal silicon battery the most anti-PID light components water vapor transmittance of the present invention is low, increases Having added the anti-PID performance of assembly, making assembly is the most anti-PID assembly, during assembly life-span Do not have PID phenomenon.
Accompanying drawing explanation
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, below The accompanying drawing used required in embodiment or description of the prior art will be briefly described, aobvious and Easily insight, the accompanying drawing in describing below is only some embodiments described in the present invention, for From the point of view of those of ordinary skill in the art, on the premise of not paying creative work, it is also possible to root Other accompanying drawing is obtained according to these accompanying drawings.
Fig. 1 is rimless type crystal silicon battery of the present invention the most anti-PID light components one specific embodiment party The floor map of formula.
Fig. 2 is the structural representation of backboard of the present invention.
Wherein, front glass sheet-10, cell piece-20, backboard-30, terminal box-40, encapsulation material Material layer-50, welding-60.
Detailed description of the invention
For the technical scheme making those skilled in the art be more fully understood that in the present invention, below The accompanying drawing in the embodiment of the present invention will be combined, the technical scheme in the embodiment of the present invention will be carried out clearly Chu, it is fully described by, it is clear that described embodiment is only a part of embodiment of the present invention, Rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art The every other embodiment obtained under not making creative work premise, all should belong to The scope of protection of the invention.
As it is shown in figure 1, the rimless type crystal silicon battery the most anti-PID light components 100 of the present invention Including: front glass sheet 10, cell piece 20, backboard 30 and terminal box 40, described battery Sheet 20 is between described front glass sheet 10 and backboard 30.
Wherein, described front glass sheet is the photovoltaic energy ultrawhite figured glass that 4.0-5.0mm is thick, described Header board glass surface has nano titanium oxide film, thus, can be easy to increase passing through of assembly Rate, makes transmitance reach more than 92%, thus adds the generated energy of assembly, and will not Reduce rigidity and the mechanical load capability of assembly.
Between described cell piece 20 and described front glass sheet 10, cell piece 20 and described backboard Being respectively arranged with encapsulation material material layer 50 between 30, this encapsulating material layer is used for pond sheet 20 and institute State the connection between front glass sheet 10, between cell piece 20 and described backboard 30.The described back of the body Ban Cong center includes basic unit, outer layer and fluorine-containing coat the most successively, and described superficies pass through Plasma treatment;Described outer layer is BMC layer or SMC layer;Described basic unit is PET keriotheca; Described PET keriotheca is to be made up of the thickest soft sandwich of folder in the middle of upper and lower panel one;Institute State the surface of fluorine-containing coat through plasma treatment.
In present embodiment, described encapsulating material layer 50 is polyolefin, and this polyolefin can be Heat curing-type or thermoplastics type, be mixed with wavelength-shifting agent, described wavelength-shifting agent energy in encapsulating material layer Enough invalid or poor efficiency sunlight wavelength is migrated to EWL.It is arranged such, it is possible to decrease water Vapour transmitance, increases the anti-PID performance of assembly, and making assembly is the most anti-PID assembly, in group PID phenomenon is not had during the part life-span.Preferably, the envelope of wantonly 20 sides of described cell piece The thickness of package material layer is 0.25-0.8mm.Thus so that described rimless type crystal silicon battery is complete The thickness of complete anti-PID light components is less than 1cm.
As shown in Fig. 2 institute, the embodiment of a kind of backboard that the present invention is given, including basic unit 1, Described basic unit 1 is the PET keriotheca formed after cellular technology processes.Described keriotheca form Basic unit be to be made up of the thickest soft sandwich of folder in the middle of upper and lower panel one, honeycomb interlayer is tied Structure has the mechanical property of similar I-beam, has high rigidity, high intensity, high impact resistance, with Other sandwich material is compared, and when intensity is identical, its weight is light.Use PET keriotheca As basic unit, PET material wet and heat ageing resistant, tear-resistant, dimensionally stable, Yi Jia can be played The advantage of work, can utilize again the high rigidity of honeycomb style interlayer, high intensity, high impact resistance, The design feature that thermal diffusivity is good, can fully meet the demand of solar cell backboard.The present invention Casting technique is used to be cast out SMC or BMC resin on two surfaces of basic unit 1, respectively shape Become outer layer 2.SMC refers to that sheet molding compound, BMC refer to BMC, and it has excellent Decay resistance, stronger rigidity, its mechanical performance can match in excellence or beauty with part metals material. Outer surface at two outer layers 2 also has fluorine-containing coat 3.Fluorine-containing coat 3 has the most resistance to Hou Xing, resistance to water, oxygen barrier performance, and have self-cleaning property, it is especially suitable for doing the solar cell back of the body The outermost layer of plate.
Additionally, due to use thicker front glass sheet and the preferable polyolefin of block-water performance, thus The load of 5400pa just can be met without framing up with the aluminium frame edge sealing of abandoning tradition, assembly Requirement, meanwhile, also mitigates the weight of assembly, it is simple to the transport of assembly.The present invention without frame The weight of type crystal silicon battery the most anti-PID light components is 8-12kg, and its weight is significantly lower than existing Some crystalline silicon components.
Described rimless type crystal silicon battery the most anti-PID light components 100 also includes welding 60, Described welding 60 is arranged at the front of described cell piece 20, and the quantity of welding 60 can be according to need Being set to multiple, welding 60 forms the pin of cell piece 20, and described terminal box 40 is passed through Welding 60 realizes the electric connection with cell piece 20.The terminal box of the present invention can be that the back of the body connects formula Terminal box, it is installed on the back side of described cell piece 20.
When the rimless type crystal silicon battery the most anti-PID light components 100 of the present invention makes, will be poly- Alkene is evenly applied on the fitting surface of front glass sheet and backboard respectively, and by welding by welding Mode is welded on the front of cell piece, after welding, is fixed by polyolefin by cell piece On between front glass sheet and backboard, and keep just arranging of cell piece facing to header board glass, The back of the body connects formula terminal box again be fixed on the back side of cell piece, and the back of the body is connect extraction in formula terminal box Connecting line be electrically connected with welding.
Additionally, based on identical inventive concept, the present invention also provides for a kind of cell panel, this battery Plate includes rimless type crystal silicon battery as above the most anti-PID light components, described assembly Quantity is multiple, is electrically connected with between the plurality of assembly, thus by multiple present invention Rimless type crystal silicon battery the most anti-PID light components bigger electricity can be provided to export, meet The needs of different occasion production and processings.
Shown in sum up, the rimless type crystal silicon battery the most anti-PID light components of the present invention abandons aluminium Frame, assembly just can meet the loading demands of 5400pa without framing up;And the most anti-PID of assembly, And reduce lightweight packages, reduce component thickness, reduce manufacturing cost.Thus, it is greatly prolonged Assembly service life, reduce the power attenuation during assembly uses, extend crystalline silicon component Range of application, and improve convenience and the rodability of crystalline silicon component.Solve crystal Silicon assembly quality weight, thickness is thick, transport and in-convenience in use etc. problem;
Meanwhile, the light transmission rate of the rimless type crystal silicon battery the most anti-PID light components of the present invention Reach more than 92%, add the generated energy of assembly, and do not reduce rigidity and the machine of assembly Tool load-carrying ability;
The rimless type crystal silicon battery the most anti-PID light components water vapor transmittance of the present invention is low, increases Having added the anti-PID performance of assembly, making assembly is the most anti-PID assembly, during assembly life-span Do not have PID phenomenon.
It is obvious to a person skilled in the art that the invention is not restricted to above-mentioned one exemplary embodiment Details, and without departing from the spirit or essential characteristics of the present invention, it is possible to it His concrete form realizes the present invention.Therefore, no matter from the point of view of which point, all should be by embodiment Regarding exemplary as, and be nonrestrictive, the scope of the present invention is by claims Rather than described above limit, it is intended that by fall claim equivalency implication and In the range of all changes include in the present invention.Should be by any accompanying drawing mark in claim Note is considered as limiting involved claim.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, but not Each embodiment only comprises an independent technical scheme, and this narrating mode of specification is only Being only for clarity sake, those skilled in the art should be using specification as an entirety, respectively Technical scheme in embodiment can also be through appropriately combined, and forming those skilled in the art can manage Other embodiments solved.

Claims (7)

1. a rimless type crystal silicon battery the most anti-PID light components, it is characterised in that institute State rimless type crystal silicon battery the most anti-PID light components to include: front glass sheet, cell piece, the back of the body Plate and terminal box, described cell piece is between described front glass sheet and backboard;
Described front glass sheet is the photovoltaic energy ultrawhite figured glass that 4.0-5.0mm is thick, described header board glass Glass surface has nano titanium oxide film;
Between described cell piece and described front glass sheet, set respectively between cell piece and described backboard Being equipped with encapsulation material material layer, described encapsulating material layer is polyolefin, described terminal box and cell piece Being electrically connected with, be mixed with wavelength-shifting agent in encapsulating material layer, described wavelength-shifting agent can Invalid or poor efficiency sunlight wavelength is migrated to EWL;
Described backboard includes basic unit, outer layer and fluorine-containing coat the most successively from center, described outside Layer surface is through plasma treatment;Described outer layer is BMC layer or SMC layer;Described basic unit is PET keriotheca;Described PET keriotheca is by the thickest soft folder of folder in the middle of upper and lower panel one Core is constituted;The surface of described fluorine-containing coat is through plasma treatment.
Rimless type crystal silicon battery the most according to claim 1 the most anti-PID light components, It is characterized in that, the thickness of the encapsulating material layer of described cell piece either side is 0.25-0.8mm.
Rimless type crystal silicon battery the most according to claim 1 the most anti-PID light components, It is characterized in that, the thickness of described rimless type crystal silicon battery the most anti-PID light components is less than 1cm, weight is 8-12kg.
Rimless type crystal silicon battery the most according to claim 1 the most anti-PID light components, It is characterized in that, described rimless type crystal silicon battery the most anti-PID light components also includes welding, Described welding is arranged at the front of described cell piece, and described terminal box and described welding are carried out electrically Connect.
Rimless type crystal silicon battery the most according to claim 1 the most anti-PID light components, It is characterized in that, described polyolefin is heat curing-type or thermoplastics type.
Rimless type crystal silicon battery the most according to claim 1 the most anti-PID light components, It is characterized in that, described terminal box is that the back of the body connects formula terminal box, and it is installed on the back of the body of described cell piece Face.
7. a cell panel, it is characterised in that described cell panel includes such as claim 1-6 Rimless type crystal silicon battery the most anti-PID light components described in any one, the quantity of described assembly For multiple, it is electrically connected with between the plurality of assembly.
CN201610235691.2A 2016-04-14 2016-04-14 Frameless crystalline silicon cell completely-PID-resistant light assembly and cell panel Pending CN105845763A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106449824A (en) * 2016-11-30 2017-02-22 庞倩桃 Crystal silicon battery PID (potential induced degradation) resistant light-weight assembly and battery panel
CN106601845A (en) * 2016-11-29 2017-04-26 梁结平 Frameless photovoltaic module and solar panel
CN108231916A (en) * 2017-12-07 2018-06-29 青海黄河上游水电开发有限责任公司光伏产业技术分公司 A kind of photovoltaic module of resisting potential induced degradation
CN111574064A (en) * 2020-06-09 2020-08-25 中节能太阳能科技(镇江)有限公司 anti-PID grid glass and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103187471A (en) * 2011-12-30 2013-07-03 苏州中来光伏新材股份有限公司 Rigid solar battery rear panel and processing technology thereof
CN203859125U (en) * 2014-02-26 2014-10-01 浙江正欣光电科技有限公司 Anti-PID crystalline silicon solar cell assembly
CN204289480U (en) * 2014-11-24 2015-04-22 中利腾晖光伏科技有限公司 The completely anti-PID light components of rimless type crystal silicon battery and cell panel
CN104766899A (en) * 2015-03-23 2015-07-08 赛维Ldk太阳能高科技(南昌)有限公司 Packaging material for solar cell module and solar cell module

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103187471A (en) * 2011-12-30 2013-07-03 苏州中来光伏新材股份有限公司 Rigid solar battery rear panel and processing technology thereof
CN203859125U (en) * 2014-02-26 2014-10-01 浙江正欣光电科技有限公司 Anti-PID crystalline silicon solar cell assembly
CN204289480U (en) * 2014-11-24 2015-04-22 中利腾晖光伏科技有限公司 The completely anti-PID light components of rimless type crystal silicon battery and cell panel
CN104766899A (en) * 2015-03-23 2015-07-08 赛维Ldk太阳能高科技(南昌)有限公司 Packaging material for solar cell module and solar cell module

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106601845A (en) * 2016-11-29 2017-04-26 梁结平 Frameless photovoltaic module and solar panel
CN106449824A (en) * 2016-11-30 2017-02-22 庞倩桃 Crystal silicon battery PID (potential induced degradation) resistant light-weight assembly and battery panel
CN108231916A (en) * 2017-12-07 2018-06-29 青海黄河上游水电开发有限责任公司光伏产业技术分公司 A kind of photovoltaic module of resisting potential induced degradation
CN108231916B (en) * 2017-12-07 2023-11-10 青海黄河上游水电开发有限责任公司光伏产业技术分公司 Photovoltaic module resistant to potential induction attenuation
CN111574064A (en) * 2020-06-09 2020-08-25 中节能太阳能科技(镇江)有限公司 anti-PID grid glass and preparation method thereof
CN111574064B (en) * 2020-06-09 2022-08-02 中节能太阳能科技(镇江)有限公司 anti-PID grid glass and preparation method thereof

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Application publication date: 20160810