CN105842779A - Erbium-doped photonic crystal fiber - Google Patents

Erbium-doped photonic crystal fiber Download PDF

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Publication number
CN105842779A
CN105842779A CN201610392053.1A CN201610392053A CN105842779A CN 105842779 A CN105842779 A CN 105842779A CN 201610392053 A CN201610392053 A CN 201610392053A CN 105842779 A CN105842779 A CN 105842779A
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CN
China
Prior art keywords
photonic crystal
doped
layer
crystal fiber
ring
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Pending
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CN201610392053.1A
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Chinese (zh)
Inventor
罗文勇
杜城
李伟
严垒
陈超
张洁
雷琼
刘承香
赵磊
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Rui Light Communication Technology Co Ltd
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Fiberhome Telecommunication Technologies Co Ltd
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Priority to CN201610392053.1A priority Critical patent/CN105842779A/en
Publication of CN105842779A publication Critical patent/CN105842779A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/02295Microstructured optical fibre
    • G02B6/023Microstructured optical fibre having different index layers arranged around the core for guiding light by reflection, i.e. 1D crystal, e.g. omniguide
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/036Optical fibres with cladding with or without a coating core or cladding comprising multiple layers

Abstract

The invention discloses an erbium-doped photonic crystal fiber and belongs to the photonic crystal fiber field. The erbium-doped photonic crystal fiber includes a quartz fiber core, an air hole layer, a quartz cladding layer and a coating which are sequentially distributed from inside to outside; a plurality of air holes are formed in the air hole layer; the air holes are all distributed along the axial direction of the fiber and are arranged throughout the entire fiber; the air holes are arranged to form a plurality of rings; at least five rings are formed; the size of air holes in each ring is identical; the air holes in each ring are hexagonally arranged with the quartz fiber core adopted as a center; the number of air holes in each ring is equal to the product of the serial number of the corresponding ring and 6; the quartz fiber core includes a doped core layer; and the doped core layer is doped with erbium ions and praseodymium ions. The erbium-doped photonic crystal fiber has excellent radiation resistance and can meet application requirements of the fluorescent light source of an aerospace optical fiber gyroscope and an erbium-doped fiber amplifier (EDFA) for complex environment under special environments.

Description

A kind of er-doped photonic crystal fiber
Technical field
The present invention relates to photonic crystal fiber field, be specifically related to a kind of er-doped photonic crystal light Fine.
Background technology
Under severe nuclear radiation environment, the transmission of optical fiber information is had the biggest by the irradiation damage of optical fiber Impact, particularly in high power pulse radiation field, the transient state induced loss of optical fiber may be up to thousands of dB;Long-term irradiation accumulation under low dose rate environment, also can produce bigger permanent damage. For optical fiber, when wherein containing the coloring ion such as germanium ion, aluminium ion, at gamma-rays Irradiation under, in optical fiber, the own electrons of part is captured by these coloring ions, thus at light Fibre is formed colour center, forms new absorption band, cause the wave band at visible ray that bigger damage occurs Consumption, not even printing opacity.For Er-doped fiber, due to the internal doping of the fibre core of Er-doped fiber There is coloring ion, be will be apparent from by fibre loss after irradiation, it is therefore desirable to carry out targetedly The techniques such as doping process, new irradiation resistant fiber structure design, drawing process, predispersed fiber irradiation Research in terms of means.
Photonic crystal fiber has structure design characteristics flexibly, by entering photonic crystal fiber The structure design that row is certain, it is possible to achieve good radiation-resisting performance.People study various one after another The radiation-resisting performance of photonic crystal fiber and the characteristic of Er-doped fiber are combined by method, are formed There is the er-doped photonic crystal fiber of radiation-resisting performance.But, existing er-doped photonic crystal light Fine anti-radiation performance is poor, it is impossible to meet the space flight fluorescence light source of optical fibre gyro, complicated ring Application demand under the special environments such as the erbium-doped optical fiber amplifier EDFA in border.
Summary of the invention
The invention aims to overcome the deficiency of above-mentioned background technology, it is provided that a kind of er-doped Photonic crystal fiber, this er-doped photonic crystal fiber has excellent anti-radiation performance, it is possible to Meet the space flight fluorescence light source of optical fibre gyro, the erbium-doped optical fiber amplifier EDFA of complex environment Deng the application demand under special environment.
The present invention provides a kind of er-doped photonic crystal fiber, including be arranged in order from the inside to the outside Silica core, have several airports air aperture layer, quartz surrounding layer, coating, institute Stating airport all along optical fiber axial distribution and through whole optical fiber, the arrangement of described airport is formed Multilamellar ring, the number of plies of described ring is at least 5 layers, and the airport size in every layer of ring is equal Identical, the airport in every layer of ring, all centered by silica core, arranges in regular hexagon, The quantity of the airport in every layer of ring=ring number of plies * 6;Described silica core includes the core that adulterates Layer, described doping sandwich layer is mixed with erbium ion, praseodymium ion.
On the basis of technique scheme, described silica core also includes fluorine doped covering, institute State fluorine doped covering and be coated on the outside of described doping sandwich layer.
On the basis of technique scheme, also mixed with a certain amount of boron in described doping sandwich layer Ion.
On the basis of technique scheme, the dutycycle of described air aperture layer hollow pore is 25%~40%.
On the basis of technique scheme, described fluorine doped covering is relative with quartz surrounding layer Refractivity is-0.0%~-1.0%.
On the basis of technique scheme, the ring number of plies in described air aperture layer is 5~9 Layer.
On the basis of technique scheme, the ring number of plies in described air aperture layer is 7 Layer.
On the basis of technique scheme, the spacing of two adjacent described airports is 3.0 μm~6.0 μm.
On the basis of technique scheme, the internal diameter of described airport is 1.0 μm~4.0 μm.
On the basis of technique scheme, described doping sandwich layer a diameter of 3.0 μm~8.0 μm.
Compared with prior art, advantages of the present invention is as follows:
(1) present invention makes full use of the feature of structure flexible design of er-doped photonic crystal fiber, The structure of reasonably optimizing air aperture layer, controls the ring number of plies of airport, effectively realizes photon brilliant The radiation-resisting performance of body optical fiber;Introduce praseodymium ion at the fine layer of doping to be co-doped with erbium ion simultaneously, enter One step improves the radiation-resisting performance of optical fiber.This er-doped photonic crystal fiber has excellent Flouride-resistani acid phesphatase Characteristic, under conditions of irradiation accumulated dose is 100Krad, this er-doped photonic crystal fiber exists Radiation induced loss value added under 1200nm wavelength is less than 0.5dB/m, it is possible to meet space flight With the fluorescence light source of optical fibre gyro, the Special Ring such as erbium-doped optical fiber amplifier EDFA of complex environment Application demand under border.
(2) the fine layer of doping is coated with fluorine doped covering, and the fluorion in fluorine doped covering is on the one hand Reduce the refractive index of covering, be conducive to the logical light of total reflection, be on the other hand also beneficial to the anti-of optical fiber Radiation Characteristics.
(3) fibre core of this er-doped photonic crystal fiber can also mix boron ion simultaneously, it is possible to Resist owing to introducing praseodymium ion and the effects such as darkening in the case of the reunion that brings and power ascension, Thus improve the service behaviour of erbium doped fiber laser based on er-doped photonic crystal fiber.
(4) present invention can reach 5.5dB/m~12dB/m at the absorptance of 980nm, The absorptance of 1550nm can reach 12dB/m~21dB/m, it is possible to meets Erbium-doped fiber amplifier Device EDFA is to the different application demand of er-doped fluorescence light source.This er-doped photonic crystal fiber exists 980nm pump light and 1550nm output light are single mode transport, it is possible to ensure good pumping Efficiency and the beam quality going out light.1550nm mode field diameter can be controlled in 3.0 microns~8.0 micro- Rice, it is possible to meet the use demand of different components design.
(5) present invention is designed with the special airport number of plies and airport dutycycle, makes er-doped Photonic crystal fiber has background loss and the color of optimum at wavelength 1310nm~1550nm wave band Dissipate characteristic, and good gain can be realized, improve light conversion efficiency.By micropore and fibre core The cutoff wavelength of photonic crystal fiber is optimized by optimum organization flexibly such that it is able to control light flexibly Fine zero-dispersion wavelength, is adjusted flexibly between 1310nm and 1550nm according to actual needs.
(6) present invention uses multipole method to design, the structure of reasonably optimizing air aperture layer, controls The ring number of plies of airport, makes er-doped photonic crystal fiber in wavelength 980nm~1550nm scope Interior holding single mode transport.Airport in the present invention is designed as regular hexagon distribution, also helps Compare accurate drawing.
(7) present invention has excellent bending resistance, the minimum under 5mm bending radius Bending added losses are less than 0.2dB.
Accompanying drawing explanation
Fig. 1: the end face structure of the actual er-doped photonic crystal fiber developed in the embodiment of the present invention Figure;
Fig. 2: the toroidal ring structure design drawing of er-doped photonic crystal fiber in the embodiment of the present invention;
The absorption collection of illustrative plates of er-doped photonic crystal fiber in Fig. 3: the embodiment of the present invention 3;
The mode field diameter test figure of er-doped photonic crystal fiber in Fig. 4: the embodiment of the present invention 10.
Reference: 1 silica core, 1a adulterates sandwich layer, 1b fluorine doped covering, and 2 is empty Pore, 3 quartz surrounding layers, 4 coatings.
Detailed description of the invention
Below in conjunction with the accompanying drawings and specific embodiment the present invention is described in further detail.
Seeing shown in Fig. 1, Fig. 2, the embodiment of the present invention provides a kind of er-doped photonic crystal fiber, This optical fiber includes the silica core 1 being arranged in order from the inside to the outside, has several airports 2 Air aperture layer, quartz surrounding layer 3, coating 4, air aperture layer is coated on outside silica core 1 Side, quartz surrounding layer 3 uses pure silicon dioxide to make, and is coated on the outside of air aperture layer, Coating 4 is coated in the outside of quartz surrounding layer 3;Airport 2 is all along optical fiber axial distribution and pass through Being through at whole optical fiber, airport 2 arrangement forms multilamellar ring, and the number of plies of ring is at least 5 Layer, airport 2 size in every layer of ring is the most identical, the airport 2 in every layer of ring all with Centered by silica core 1, arrange in regular hexagon, the quantity of the airport 2 in every layer of ring =ring number of plies * 6;Silica core 1 includes adulterate sandwich layer 1a, fluorine doped covering 1b, and adulterate sandwich layer 1a is mixed with erbium ion, praseodymium ion, and a small amount of aluminium ion and germanium ion, fluorine doped covering 1b It is coated on the outside of doping sandwich layer 1a.
The present invention reduces germanium, aluminum etc. in doping sandwich layer 1a can increase the ion doping of colour center, with Time introduce praseodymium ion be co-doped with, it is achieved radiation-resisting performance.Also mixed with a certain amount of in doping sandwich layer 1a Boron ion, for opposing due to introduce praseodymium ion and in the case of the reunion that brings and power ascension The effect such as darkening.
Preferably, the ring number of plies in air aperture layer is 5~9 layers, typical value include 6 layers, 7 layers, 8 layers, 9 layers etc.;In actual application, the ring number of plies most preferably 7 in air aperture layer Layer.In 1st layer of ring, the quantity of airport 2 is N1=1*6=6, in the 2nd layer of ring The quantity of airport 2 is N2=2*6=12, the like, air in xth layer ring Quantity Nx=x*6 in hole 2.
The dutycycle of air aperture layer hollow pore 2 is 25%~40%, two adjacent airports The spacing of 2 is 3.0 μm~6.0 μm, and the internal diameter of airport 2 is 1.0 μm~4.0 μm.
A diameter of 3.0 μm of doping sandwich layer 1a~8.0 μm, fluorine doped covering 1b's is a diameter of 4.0 μm~10.0 μm.Fluorine doped covering 1b is-0.0% with the refractive index contrast of quartz surrounding layer 3 ~-1.0%, the fluorine doped concentration of fluorine doped covering 1b is with fluorine doped covering 1b and quartz surrounding layer 3 Refractive index contrast determines.A diameter of 80.0 μm of quartz surrounding layer 3~125.0 μm, be coated with A diameter of 135.0 μm of layer 4~245.0 μm.
The coating 4 of the outer coating of quartz surrounding layer 3, for protecting optical fiber.Coating 4 is adopted Material be polyacrylic resin or polyimides, when external environment is severe, operating temperature Time higher, by using resistant to elevated temperatures polyacrylic resin or polyimides, optical fiber can be made to exist Good working order is kept under the conditions of more than 100 degree.The material that coating 4 uses is polypropylene During acid resin, the highest temperature that works long hours of optical fiber can reach 150 degree;Coating 4 uses When material is polyimides, the highest temperature that works long hours of optical fiber is up to 300 degree.Coating 4 Can be single coating, it is also possible to for double coatings.When coating 4 is single coating, the material of employing Material can be polyacrylic resin, it is also possible to for polyimide resin.When coating 4 is double painting During layer, the material of employing can be the polyacrylic resin of two-layer, it is possible to for the polyamides of two-layer Imide resin, or internal layer employing polyacrylic resin, outer layer uses polyimide resin.
Below by 15 specific embodiments, the present invention is described in further detail:
Embodiment 1~15 provides quartz surrounding layer 3 diameter from 80 microns~125 microns not Er-doped photonic crystal fiber with dimensions.
In embodiment 1~5, the ring number of plies of er-doped photonic crystal fiber is 5 layers, and coating material is i.e. Can use polyacrylic resin, it is possible to use polyimide resin, coating 4 can be single painting Layer, it is possible to for double coatings.In embodiment 1~5, the structural parameters of er-doped photonic crystal fiber are such as Shown in table 1:
Table 1, tool are of five storeys the structural parameters of er-doped photonic crystal fiber of ring
As it can be seen from table 1 total at 100Krad of the er-doped photonic crystal fiber of 5 layers of ring Under radiation dose, 1200nm Radiation induced loss value added is 0.2~0.4dB/m, has excellent Anti-radiation performance.The 980nm absorptance of the er-doped photonic crystal fiber of 5 layers of ring is 5.5~5.9dB/m, 1550nm absorptance is 12~13dB/m, uses embodiment 3 to try When testing, the typical absorption of this er-doped photonic crystal fiber is composed as shown in Figure 3.
In embodiment 6~10, the ring number of plies of er-doped photonic crystal fiber is 7 layers, coating material Can use polyacrylic resin, it is possible to use polyimide resin, coating 4 can be single painting Layer, it is possible to for double coatings.When coating material uses resistant to elevated temperatures polyacrylic resin, the highest The temperature that works long hours is up to 150 degree.The knot of er-doped photonic crystal fiber in embodiment 6~10 Structure parameter is as shown in table 2:
Table 2, there are the structural parameters of the er-doped photonic crystal fiber of 7 layers of ring
From table 2 it can be seen that total at 100Krad of the er-doped photonic crystal fiber of 7 layers of ring Under radiation dose, 1200nm Radiation induced loss value added is 0.15~0.4dB/m, has excellent Good anti-radiation performance.The 1550nm mode field diameter of the er-doped photonic crystal fiber of 7 layers of ring It is 3~5 μm, when using embodiment 10 to test, the typical case of this er-doped photonic crystal fiber Mould field test figure is as shown in Figure 4.
In embodiment 11~15, the ring number of plies of er-doped photonic crystal fiber is 9 layers, coating material Can use polyacrylic resin, it is possible to use polyimide resin, coating 4 can be single painting Layer, it is possible to for double coatings.The structural parameters of er-doped photonic crystal fiber in embodiment 11~15 As shown in table 3:
Table 3, there are the structural parameters of the er-doped photonic crystal fiber of 9 layers of ring
From table 3 it can be seen that total at 100Krad of the er-doped photonic crystal fiber of 9 layers of ring Under radiation dose, 1200nm Radiation induced loss value added is 0.1~0.2dB/m, has excellent Anti-radiation performance.
Those skilled in the art can carry out various modifications and variations to the embodiment of the present invention, if If these amendment and modification within the scope of the claims in the present invention and equivalent technologies thereof, then this A little amendments and modification are also within protection scope of the present invention.
The prior art that the content not described in detail in description is known to the skilled person.

Claims (10)

1. an er-doped photonic crystal fiber, this optical fiber includes the stone being arranged in order from the inside to the outside English fibre core (1), have several airports (2) air aperture layer, quartz surrounding layer (3), Coating (4), described airport (2) all along optical fiber axial distribution and through whole optical fiber, It is characterized in that: described airport (2) arrangement forms multilamellar ring, the number of plies of described ring At least 5 layers, airport (2) size in every layer of ring is the most identical, in every layer of ring Airport (2), all centered by silica core (1), arranges in regular hexagon, every layer of ring In quantity=ring number of plies * 6 of airport (2);Described silica core (1) includes doping Sandwich layer (1a), described doping sandwich layer (1a) is mixed with erbium ion, praseodymium ion.
2. er-doped photonic crystal fiber as claimed in claim 1, it is characterised in that: described Silica core (1) also includes that fluorine doped covering (1b), described fluorine doped covering (1b) are coated on institute State the outside of doping sandwich layer (1a).
3. er-doped photonic crystal fiber as claimed in claim 1, it is characterised in that: described Also mixed with a certain amount of boron ion in doping sandwich layer (1a).
4. er-doped photonic crystal fiber as claimed in claim 1, it is characterised in that: described The dutycycle of air aperture layer hollow pore (2) is 25%~40%.
5. er-doped photonic crystal fiber as claimed in claim 2, it is characterised in that: described Fluorine doped covering (1b) is-0.0%~-1.0% with the refractive index contrast of quartz surrounding layer (3).
6. er-doped photonic crystal fiber as claimed in claim 1, it is characterised in that: described The ring number of plies in air aperture layer is 5~9 layers.
7. er-doped photonic crystal fiber as claimed in claim 6, it is characterised in that: described The ring number of plies in air aperture layer is 7 layers.
8. er-doped photonic crystal fiber as claimed in claim 1, it is characterised in that: adjacent The spacing of two described airports (2) be 3.0 μm~6.0 μm.
9. er-doped photonic crystal fiber as claimed in claim 1, it is characterised in that: described The internal diameter of airport (2) is 1.0 μm~4.0 μm.
10. er-doped photonic crystal fiber as claimed in claim 1, it is characterised in that: institute State a diameter of 3.0 μm~8.0 μm of doping sandwich layer (1a).
CN201610392053.1A 2016-06-03 2016-06-03 Erbium-doped photonic crystal fiber Pending CN105842779A (en)

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Cited By (2)

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CN115521079A (en) * 2022-09-29 2022-12-27 长飞光纤光缆股份有限公司 Post-processing method of radiation-resistant optical fiber

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