CN105838527A - Household water pipeline cleaning agent and preparation method thereof - Google Patents

Household water pipeline cleaning agent and preparation method thereof Download PDF

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Publication number
CN105838527A
CN105838527A CN201610248872.9A CN201610248872A CN105838527A CN 105838527 A CN105838527 A CN 105838527A CN 201610248872 A CN201610248872 A CN 201610248872A CN 105838527 A CN105838527 A CN 105838527A
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parts
water
acid
sodium
cleaning agent
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王维娜
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/047Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on cationic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00Special methods for preparing compositions containing mixtures of detergents
    • C11D11/0094Process for making liquid detergent compositions, e.g. slurries, pastes or gels
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0068Deodorant compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/34Derivatives of acids of phosphorus
    • C11D1/342Phosphonates; Phosphinates or phosphonites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a household water pipeline cleaning agent and a preparation method thereof. The household water pipeline cleaning agent comprises a saponin extracting solution, lauryl sodium sulfate, p-aminobenzoic acid, ammonia water, sodium bicarbonate, potassium bitartrate, polyepoxysuccinic acid, sodium sulfite, phosphonic carboxylic acid, a polycarboxylic acid water reducing agent, a phosphoryl carboxylic acid polymer, a Belsperse164 dispersing agent, dimethylcarbinol, amidogen ether betaine, urotropine, stannous octoate, a surfactant, D solvent oil, aluminum naphthenate, sodium chloride, lipase, tetradecyldimethylbenzylammonium chloride, triethanolamine oleate soap, ferric citrate, polyether and water. The raw materials of the household water pipeline cleaning agent have the advantages of environment friendliness, no toxicity, wide sources and low price, and can be stored for a long time. The preparation method is simple, and is easy and convenient to implement. The household water pipeline cleaning agent can not leave beneficial conditions to microbial deposition after cleaning, thoroughly removes biological slime, reproductive fungi and bacteria caused by poor quality of water provided by the heating company, and can implement thorough cleaning.

Description

A kind of Household water pipeline cleaning agent and preparation method thereof
Technical field
The present invention relates to a kind of cleaning agent, specifically a kind of Household water pipeline cleaning agent and preparation method thereof.
Background technology
The application of pipeline is substantial amounts of to be present in our everyday home life, the pipeline of such as heating supply, sewer pipe etc., Now more with relatively difficult cleaning, impurity, do not clean as a example by the life of people being caused than the heating supply pipeline of considerable influence, Prior art and prior art defect to pipeline cleaning are described further.Heating supply has become as a kind of important adopting Warm form, under the promotion of national industrial policies and real estate construction market, China's heating technology is developed rapidly, concentrates Heating system has become basically universal.Heating supply has become as a kind of mode improving people's quality of life, and as consumer Wish to preferably show the superiority of heating system, environmental protection, save the energy, length in service life, save space, The features such as Comfortable health-care are increasingly becoming the target that people pursue.Heating supply as an engineering project, its design, selection, The each side such as installation, completion, engineering after-sale service can be improved and can implement completely, just can be considered an entire flow, and Cleaning of after-sale service, such as pipeline does not the most obtain attention highly as a ring important in flow process.
Heating supply is by mean of circuit line, user's heat exchanger or underground coil pipe, is circulated by water and realizes heating. After whole laying project terminates, just in case heating effect is not complied with one's wishes or needs repairing, it is difficult to deal with.Even if fixing link does not has Problematic, during the use of user, also there will be some specific situations occur, such as coil pipe encrustation, line clogging The hottest serious etc. causing water temperature, it is impossible to normally to use.As inside water collecting and diversifying device connecting tube tube wall in yellow, green, red rust Look, black or use more than two Heating Periods, indoor temperature is substantially lower than in the past.And extensive along with various heating systems Application, these insoluble problems also can be following, more prominent.
It is primarily present problems with the most in the duct and governs heat supply temperature decline, the problem that service life is short:
1, long-term ponding in geothermal tube, has microorganism in water, and hot duct conditional is suitable, and the most a lot of for heat unit Some anti-dehydration agents can be added in water, produce substantial amounts of biological clay, cover in pipe.Heat supply occurrence temperature changes, just It is that the covering of this biological clay is caused at tube wall inwall.And dirt deposition is at pipe surface, underdeposit corrosion can be caused for a long time. Additionally survived in pipeline substantial amounts of bacterium, and the health of user be also result in harm.
2, heat supply pipeline is accomplished by carrying out periodic maintenance and maintenance more than two Heating Periods service life, because heating tube makes Biological clay and impurity, the generation of bacterium is just had, for ensureing the cleaning of geothermal tube inwall with rear.The prolongedly use of heat pipe Life-span, so the periodic maintenance of geothermal pipe line system and maintenance are inevitable.
3, the indoor temperature that user's family is present had substantially declined than former indoor temperature, this is because geothermal tube inwall produces Having given birth to large number of biological foundry loam, dirt, according to relevant statistics, during heating, inside pipe wall often increases 0.1mm incrustation scale, Environment temperature will be made to reduce by 6 degree, not only have impact on normal temperature, also result in energy waste.
4, the water-flowing amount of pipeline substantially feels that this year is less than former years, and this is possible to be that the biological clay in geothermal tube is too much, Geothermal tube is caused local stoppages, block in being continuing with will result in pipe.Only destroy and remove or change pipe-line system, Cause the user property loss and life inconvenience.
5, pipeline-cleaning period before, during and after heating three periods all can be by the biology in pipe because cleaning before heating Foundry loam, impurity are all disposed, thus the normal use during ensureing heating, heating is carried out can experience pipe intuitively Road system is being got rid of the heating effect after biological clay, impurity and is being prevented regeneration and the breeding of bacterium.It is that the heating later stage cleans For important, because the water quality that Running-water Company confesses is the most poor, the inside also has impurity and bacterium, the breeding of bacterium and regeneration Being usually in spring and summer, if it thoroughly not removed, our health will be caused the biggest harm by it.
Summary of the invention
It is an object of the invention to provide a kind of with low cost, environmental protection reliable Household water pipeline cleaning agent and preparation method thereof, With the problem solving to propose in above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of Household water pipeline cleaning agent, includes according to the raw material of weight portion: Chinese honey locust extract 80-90 part, dodecyl sulphur Acid sodium 20-40 part, p-aminobenzoic acid 20-30 part, ammoniacal liquor 10-20 part, sodium acid carbonate 10-20 part, potassium hydrogen tartrate 10-15 part, poly-epoxy succinic acid 10-15 part, sodium sulfite phosphine carboxylic acid 10-15 part, polycarboxylate water-reducer 8-12 part, phosphine Carboxylic acyl polymer 5-10 part, Belsperse164 dispersant 6-8 part, dimethylcarbinol 6-8 part, amidogen ether glycine betaine 6-8 Part, methenamine 4-6 part, stannous octoate 4-6 part, surfactant 3-5 part, D60 solvent naphtha 3-5 part, aluminium napthenate 3-5 part, sodium chloride 3-5 part, lipase 2-4 part, tetradecyl chloride base dimethyl benzyl group ammonium 1-3 part, triethanolamine oleate Soap 1-3 part, ironic citrate 0.5-1 part, polyethers 0.3-0.5 part, water 100-200 part.
As the further scheme of the present invention: described Household water pipeline cleaning agent, include according to the raw material of weight portion: Chinese honey locust carries Take liquid 82-88 part, lauryl sodium sulfate 25-35 part, p-aminobenzoic acid 22-28 part, ammoniacal liquor 12-18 part, bicarbonate Sodium 12-18 part, potassium hydrogen tartrate 11-14 part, poly-epoxy succinic acid 11-14 part, sodium sulfite phosphine carboxylic acid 11-14 part, poly- Carboxylic acid water reducer 9-11 part, phosphono-carboxylic acids polymer 6-9 part, Belsperse164 dispersant 6.5-7.5 part, dimethyl methyl Alcohol 6.5-7.5 part, amidogen ether glycine betaine 6.5-7.5 part, methenamine 4.5-5.5 part, stannous octoate 4.5-5.5 part, surface-active Agent 3.5-4.5 part, D60 solvent naphtha 3.5-4.5 part, aluminium napthenate 3.5-4.5 part, sodium chloride 3.5-4.5 part, lipase 2.5-3.5 Part, tetradecyl chloride base dimethyl benzyl group ammonium 1.5-2.5 part, triethanolamine oleate 1.5-2.5 part, ironic citrate 0.6-0.9 Part, polyethers 0.35-0.45 part, water 120-180 part.
As the further scheme of the present invention: described Household water pipeline cleaning agent, include according to the raw material of weight portion: Chinese honey locust carries Take liquid 85 parts, lauryl sodium sulfate 30 parts, p-aminobenzoic acid 25 parts, ammoniacal liquor 15 parts, sodium acid carbonate 15 parts, Potassium hydrogen tartrate 12 parts, poly-epoxy succinic acid 12 parts, sodium sulfite phosphine carboxylic acid 12 parts, polycarboxylate water-reducer 10 parts, phosphine 8 parts of carboxylic acyl polymer, Belsperse164 dispersant 7 parts, dimethylcarbinol 7 parts, amidogen ether glycine betaine 7 parts, crow Lip river tropine 5 parts, stannous octoate 5 parts, 4 parts of surfactant, D60 solvent naphtha 4 parts, aluminium napthenate 4 parts, sodium chloride 4 parts, 3 parts of lipase, tetradecyl chloride base dimethyl benzyl group ammonium 2 parts, triethanolamine oleate 2 parts, ironic citrate 0.8 Part, polyethers 0.4 part, 150 parts of water.
As the further scheme of the present invention: described polyethers be in secondary alkanol APEO and NPE extremely Few one.
As the present invention further scheme: described surfactant is selected from butyl glycol ether, coco-nut oil fatty acid diethanol One or more in acid amides or sodium sulfate of polyethenoxy ether of fatty alcohol.
The preparation method of described Household water pipeline cleaning agent, specifically comprises the following steps that
(1) each raw material is weighed according to weight portion;
(2) lauryl sodium sulfate, sodium acid carbonate, potassium hydrogen tartrate, amidogen ether glycine betaine, methenamine, stannous octoate, Aluminium napthenate, sodium chloride, lipase, tetradecyl chloride base dimethyl benzyl group ammonium, triethanolamine oleate and ironic citrate grind Wore into the fine powder of 200-300 mesh sieve, mixed standby;
(3) spaonin powder is broken to 100-200 mesh, adds the water of 3-5 times of equivalent, be warming up to 40-60 DEG C, continue stirring 1-2h, Add the ethanol of 2 times of equivalents of Chinese honey locust weight, after stirring 20-40min, be cooled to 35-45 DEG C, stand 6-10h, filter, Take filtrate and i.e. obtain Chinese honey locust extract;
(4) by p-aminobenzoic acid, ammoniacal liquor, poly-epoxy succinic acid, sodium sulfite phosphine carboxylic acid, polycarboxylate water-reducer, phosphine Carboxylic acyl polymer, Belsperse164 dispersant and dimethylcarbinol are added to the water, mixing and stirring;
(5), in the product that product addition to the step (4) step (2) and step (3) obtained obtains, table is added Face activating agent and solvent naphtha polyethers, after being uniformly mixed finished product.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention each raw material environment-protecting asepsis, wide material sources price is low, can long storage time, preparation method is simple, implement Convenient, excellent to the cleaning performance of pipeline, to the clearance rate of dust and dirt in pipeline up to 95%, will not leave behind after cleaning micro-life Thing deposition beneficial conditions, through the present invention clean after pipeline noresidue, up hill and dale remove due to heating company provide water Matter is bad, and the biological clay caused, breeding fungi, bacterium, cleaning thorough, clean.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the technical scheme of this patent is described in more detail.
Embodiment 1
A kind of Household water pipeline cleaning agent, includes according to the raw material of weight portion: Chinese honey locust extract 80 parts, dodecyl sulphate 20 parts of sodium, p-aminobenzoic acid 20 parts, ammoniacal liquor 10 parts, sodium acid carbonate 10 parts, potassium hydrogen tartrate 10 parts, polycyclic oxygen Butanedioic acid 10 parts, sodium sulfite phosphine carboxylic acid 10 parts, polycarboxylate water-reducer 8 parts, 5 parts of phosphono-carboxylic acids polymer, Belsperse164 dispersant 6 parts, dimethylcarbinol 6 parts, amidogen ether glycine betaine 6 parts, methenamine 4 parts, stannous octoate 4 Part, 3 parts of surfactant, D60 solvent naphtha 3 parts, aluminium napthenate 3 parts, 3 parts of sodium chloride, 2 parts of lipase, chlorination Dodecyldimethylamine base benzyl group ammonium 1 part, triethanolamine oleate 1 part, ironic citrate 0.5 part, polyethers 0.3 part, water 100 Part.
The preparation method of described Household water pipeline cleaning agent, specifically comprises the following steps that
(1) each raw material is weighed according to weight portion;
(2) lauryl sodium sulfate, sodium acid carbonate, potassium hydrogen tartrate, amidogen ether glycine betaine, methenamine, stannous octoate, Aluminium napthenate, sodium chloride, lipase, tetradecyl chloride base dimethyl benzyl group ammonium, triethanolamine oleate and ironic citrate grind Wore into the fine powder of 200 mesh sieves, mixed standby;
(3) spaonin powder is broken to 100 mesh, adds the water of 3 times of equivalents, be warming up to 40 DEG C, continue stirring 1h, add soap The ethanol of 2 times of equivalents of angle weight, after stirring 20min, is cooled to 35 DEG C, stands 6h, filter, take filtrate and i.e. obtain Chinese honey locust Extract;
(4) by p-aminobenzoic acid, ammoniacal liquor, poly-epoxy succinic acid, sodium sulfite phosphine carboxylic acid, polycarboxylate water-reducer, phosphine Carboxylic acyl polymer, Belsperse164 dispersant and dimethylcarbinol are added to the water, mixing and stirring;
(5), in the product that product addition to the step (4) step (2) and step (3) obtained obtains, table is added Face activating agent and solvent naphtha polyethers, after being uniformly mixed finished product.
Embodiment 2
A kind of Household water pipeline cleaning agent, includes according to the raw material of weight portion: Chinese honey locust extract 82 parts, dodecyl sulphate 25 parts of sodium, p-aminobenzoic acid 22 parts, ammoniacal liquor 12 parts, sodium acid carbonate 12 parts, potassium hydrogen tartrate 11 parts, polycyclic oxygen Butanedioic acid 11 parts, sodium sulfite phosphine carboxylic acid 11 parts, polycarboxylate water-reducer 9 parts, 6 parts of phosphono-carboxylic acids polymer, Belsperse164 dispersant 6.5 parts, dimethylcarbinol 6.5 parts, amidogen ether glycine betaine 6.5 parts, methenamine 4.5 parts, pungent Acid stannous 4.5 parts, 3.5 parts of surfactant, D60 solvent naphtha 3.5 parts, aluminium napthenate 3.5 parts, 3.5 parts of sodium chloride, 2.5 parts of lipase, tetradecyl chloride base dimethyl benzyl group ammonium 1.5 parts, triethanolamine oleate 1.5 parts, ironic citrate 0.6 Part, polyethers 0.35 part, 120 parts of water.
The preparation method of described Household water pipeline cleaning agent, specifically comprises the following steps that
(1) each raw material is weighed according to weight portion;
(2) lauryl sodium sulfate, sodium acid carbonate, potassium hydrogen tartrate, amidogen ether glycine betaine, methenamine, stannous octoate, Aluminium napthenate, sodium chloride, lipase, tetradecyl chloride base dimethyl benzyl group ammonium, triethanolamine oleate and ironic citrate grind Wore into the fine powder of 200-300 mesh sieve, mixed standby;
(3) spaonin powder is broken to 120 mesh, adds the water of 3.5 times of equivalents, be warming up to 45 DEG C, continue stirring 1.2h, add Enter the ethanol of 2 times of equivalents of Chinese honey locust weight, after stirring 25min, be cooled to 38 DEG C, stand 7h, filter, take filtrate and get final product Chinese honey locust extract;
(4) by p-aminobenzoic acid, ammoniacal liquor, poly-epoxy succinic acid, sodium sulfite phosphine carboxylic acid, polycarboxylate water-reducer, phosphine Carboxylic acyl polymer, Belsperse164 dispersant and dimethylcarbinol are added to the water, mixing and stirring;
(5), in the product that product addition to the step (4) step (2) and step (3) obtained obtains, table is added Face activating agent and solvent naphtha polyethers, after being uniformly mixed finished product.
Embodiment 3
A kind of Household water pipeline cleaning agent, includes according to the raw material of weight portion: Chinese honey locust extract 85 parts, dodecyl sulphate 30 parts of sodium, p-aminobenzoic acid 25 parts, ammoniacal liquor 15 parts, sodium acid carbonate 15 parts, potassium hydrogen tartrate 12 parts, polycyclic oxygen Butanedioic acid 12 parts, sodium sulfite phosphine carboxylic acid 12 parts, polycarboxylate water-reducer 10 parts, 8 parts of phosphono-carboxylic acids polymer, Belsperse164 dispersant 7 parts, dimethylcarbinol 7 parts, amidogen ether glycine betaine 7 parts, methenamine 5 parts, stannous octoate 5 Part, 4 parts of surfactant, D60 solvent naphtha 4 parts, aluminium napthenate 4 parts, 4 parts of sodium chloride, 3 parts of lipase, chlorination Dodecyldimethylamine base benzyl group ammonium 2 parts, triethanolamine oleate 2 parts, ironic citrate 0.8 part, polyethers 0.4 part, water 150 Part.
The preparation method of described Household water pipeline cleaning agent, specifically comprises the following steps that
(1) each raw material is weighed according to weight portion;
(2) lauryl sodium sulfate, sodium acid carbonate, potassium hydrogen tartrate, amidogen ether glycine betaine, methenamine, stannous octoate, Aluminium napthenate, sodium chloride, lipase, tetradecyl chloride base dimethyl benzyl group ammonium, triethanolamine oleate and ironic citrate grind Wore into the fine powder of 250 mesh sieves, mixed standby;
(3) spaonin powder is broken to 150 mesh, adds the water of 4 times of equivalents, be warming up to 50 DEG C, continue stirring 1.5h, add The ethanol of 2 times of equivalents of Chinese honey locust weight, after stirring 30min, is cooled to 40 DEG C, stands 8h, filter, take filtrate and i.e. obtain soap Angle extract;
(4) by p-aminobenzoic acid, ammoniacal liquor, poly-epoxy succinic acid, sodium sulfite phosphine carboxylic acid, polycarboxylate water-reducer, phosphine Carboxylic acyl polymer, Belsperse164 dispersant and dimethylcarbinol are added to the water, mixing and stirring;
(5), in the product that product addition to the step (4) step (2) and step (3) obtained obtains, table is added Face activating agent and solvent naphtha polyethers, after being uniformly mixed finished product.
Embodiment 4
A kind of Household water pipeline cleaning agent, includes according to the raw material of weight portion: Chinese honey locust extract 88 parts, dodecyl sulphate 35 parts of sodium, p-aminobenzoic acid 28 parts, ammoniacal liquor 18 parts, sodium acid carbonate 18 parts, potassium hydrogen tartrate 14 parts, polycyclic oxygen Butanedioic acid 14 parts, sodium sulfite phosphine carboxylic acid 14 parts, polycarboxylate water-reducer 11 parts, 9 parts of phosphono-carboxylic acids polymer, Belsperse164 dispersant 6.7.5 part, dimethylcarbinol 6.7.5 part, amidogen ether glycine betaine 6.7.5 part, methenamine 4.5.5 Part, stannous octoate 4.5.5 part, surfactant 3.4.5 part, D60 solvent naphtha 3.4.5 part, aluminium napthenate 3.4.5 part, chlorine Change sodium 3.4.5 part, lipase 2.3.5 part, tetradecyl chloride base dimethyl benzyl group ammonium 1.2.5 part, triethanolamine oleate 1.2.5 Part, ironic citrate 0.0.9 part, polyethers 0.45 part, 180 parts of water.
The preparation method of described Household water pipeline cleaning agent, specifically comprises the following steps that
(1) each raw material is weighed according to weight portion;
(2) lauryl sodium sulfate, sodium acid carbonate, potassium hydrogen tartrate, amidogen ether glycine betaine, methenamine, stannous octoate, Aluminium napthenate, sodium chloride, lipase, tetradecyl chloride base dimethyl benzyl group ammonium, triethanolamine oleate and ironic citrate grind Wore into the fine powder of 280 mesh sieves, mixed standby;
(3) spaonin powder is broken to 180 mesh, adds the water of 4.5 times of equivalents, be warming up to 55 DEG C, continue stirring 1.8h, add Enter the ethanol of 2 times of equivalents of Chinese honey locust weight, after stirring 35min, be cooled to 42 DEG C, stand 9h, filter, take filtrate and get final product Chinese honey locust extract;
(4) by p-aminobenzoic acid, ammoniacal liquor, poly-epoxy succinic acid, sodium sulfite phosphine carboxylic acid, polycarboxylate water-reducer, phosphine Carboxylic acyl polymer, Belsperse164 dispersant and dimethylcarbinol are added to the water, mixing and stirring;
(5), in the product that product addition to the step (4) step (2) and step (3) obtained obtains, table is added Face activating agent and solvent naphtha polyethers, after being uniformly mixed finished product.
Embodiment 5
A kind of Household water pipeline cleaning agent, includes according to the raw material of weight portion: Chinese honey locust extract 90 parts, dodecyl sulphate 40 parts of sodium, p-aminobenzoic acid 30 parts, ammoniacal liquor 20 parts, sodium acid carbonate 20 parts, potassium hydrogen tartrate 15 parts, polycyclic oxygen Butanedioic acid 15 parts, sodium sulfite phosphine carboxylic acid 15 parts, polycarboxylate water-reducer 12 parts, 10 parts of phosphono-carboxylic acids polymer, Belsperse164 dispersant 8 parts, dimethylcarbinol 8 parts, amidogen ether glycine betaine 8 parts, methenamine 6 parts, stannous octoate 6 Part, 5 parts of surfactant, D60 solvent naphtha 5 parts, aluminium napthenate 5 parts, 5 parts of sodium chloride, 4 parts of lipase, chlorination Dodecyldimethylamine base benzyl group ammonium 3 parts, triethanolamine oleate 3 parts, ironic citrate 0.1 part, polyethers 0.0.5 part, water 200 parts.
The preparation method of described Household water pipeline cleaning agent, specifically comprises the following steps that
(1) each raw material is weighed according to weight portion;
(2) lauryl sodium sulfate, sodium acid carbonate, potassium hydrogen tartrate, amidogen ether glycine betaine, methenamine, stannous octoate, Aluminium napthenate, sodium chloride, lipase, tetradecyl chloride base dimethyl benzyl group ammonium, triethanolamine oleate and ironic citrate grind Wore into the fine powder of 300 mesh sieves, mixed standby;
(3) spaonin powder is broken to 200 mesh, adds the water of 5 times of equivalents, be warming up to 60 DEG C, continue stirring 2h, add soap The ethanol of 2 times of equivalents of angle weight, after stirring 40min, is cooled to 45 DEG C, stands 10h, filter, take filtrate and i.e. obtain Chinese honey locust Extract;
(4) by p-aminobenzoic acid, ammoniacal liquor, poly-epoxy succinic acid, sodium sulfite phosphine carboxylic acid, polycarboxylate water-reducer, phosphine Carboxylic acyl polymer, Belsperse164 dispersant and dimethylcarbinol are added to the water, mixing and stirring;
(5), in the product that product addition to the step (4) step (2) and step (3) obtained obtains, table is added Face activating agent and solvent naphtha polyethers, after being uniformly mixed finished product.
Described polyethers is at least one in secondary alkanol APEO and NPE;Described surfactant selects In butyl glycol ether, cocoanut fatty acid diethanolamide or sodium sulfate of polyethenoxy ether of fatty alcohol one or both with On.
Below in conjunction with experimental data, the effect of the present invention is further elaborated.
1. experimental subjects: the Household water pipeline cleaning agent of the environmental protection sterilization prepared using embodiment 1-5 as 5 groups of experimental group, with Commercially available pipeline cleaning agent is as a control group;
2. experimental technique:
1) respectively 5 groups of experimental group and one group of control group are carried out pipeline washing tests, detect degreasing efficiency respectively, deoil Dirty speed, sterilizing efficiency, antibacterial time, deodorizing time, and record result and compare, result is as shown in table 1:
Table 1 cleaning performance is tested
As shown in Table 1, the cleaning agent of the present invention compared with conventional clean agent, degreasing efficiency more preferably, speed faster, and greatly Improve greatly the sterilization effect of flora in pipeline and antibacterial time, it is ensured that the cleaning ambient in pipeline, and then improve water supply Water quality;Deodorizing effect is more preferable, and in being avoided that pipeline, accumulation of residues causes corrosion and fermentation to produce stench, improves air matter Amount.
2) respectively 5 groups of experimental group and one group of control group are carried out sterilization experiment, measure cleaning agent to Salmonella choleraesuls, Aspergillus niger, geotrichum candidum, staphylococcus aureus, Escherichia coli, enterobacter cloacae, the bactericidal action of bacillus, calculate Experimental group and control group are with 106Sterilizing rate after cfu/ml above-mentioned bacterial classification contact 3h, result is as shown in table 2:
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Comparative example
Enterobacter cloacae (%) 90.52 89.88 90.23 89.74 90.33 90.15
Bacillus (%) 92.10 90.75 91.52 91.08 90.89 73.54
Geotrichum candidum (%) 98.55 98.19 99.23 98.87 98.58 78.00
Aspergillus niger (%) 98.23 98.46 98.02 98.24 98.35 72.84
Escherichia coli (%) 98.40 99.04 99.01 99.11 99.13 86.23
Staphylococcus aureus (%) 89.74 92.59 91.63 91.82 90.99 40.31
Table 2 bactericidal effect is tested
As can be seen from Table 2, the Household water pipeline cleaning agent of the present invention to Salmonella choleraesuls, aspergillus niger, geotrichum candidum, Staphylococcus aureus, Escherichia coli, enterobacter cloacae, the average bactericidal rate of bacillus reach more than 94%, it was demonstrated that this Invention possesses stronger sterilizing ability, and compared with the cleaning agent of prior art, family's water pipe cleaning agent of the present invention is in bactericidal properties It is significantly improved on can, substantially increases sterilizing rate.
Understanding based on above-mentioned experiment, the cleaning agent ability of cleaning greasy dirt of embodiment of the present invention 1-5 is strong, efficiency fast, can kill multiple Bacterial fungus and mould in waterpipe, reach long-acting bacteriostatic deodorizing effect, significantly improves water quality and indoor air environment;Technique Simply, low cost, have broad application prospects.
The present invention each raw material environment-protecting asepsis, wide material sources price is low, can long storage time, preparation method is simple, implement Convenient, excellent to the cleaning performance of pipeline, to the clearance rate of dust and dirt in pipeline up to 95%, will not leave behind after cleaning micro-life Thing deposition beneficial conditions, through the present invention clean after pipeline noresidue, up hill and dale remove due to heating company provide water Matter is bad, and the biological clay caused, breeding fungi, bacterium, cleaning thorough, clean.
Above the better embodiment of this patent is explained in detail, but this patent is not limited to above-mentioned embodiment, In the ken that those of ordinary skill in the art is possessed, it is also possible to make each on the premise of without departing from this patent objective Plant change.

Claims (6)

  1. null1. a Household water pipeline cleaning agent,It is characterized in that,Include according to the raw material of weight portion: Chinese honey locust extract 80-90 part、Lauryl sodium sulfate 20-40 part、P-aminobenzoic acid 20-30 part、Ammoniacal liquor 10-20 part、Sodium acid carbonate 10-20 part、Potassium hydrogen tartrate 10-15 part、Poly-epoxy succinic acid 10-15 part、Sodium sulfite phosphine carboxylic acid 10-15 part、Polycarboxylate water-reducer 8-12 part、Phosphono-carboxylic acids polymer 5-10 part、Belsperse164 dispersant 6-8 part、Dimethylcarbinol 6-8 part、Amidogen ether glycine betaine 6-8 part、Methenamine 4-6 part、Stannous octoate 4-6 part、Surfactant 3-5 part、D60 solvent naphtha 3-5 part、Aluminium napthenate 3-5 part、Sodium chloride 3-5 part、Lipase 2-4 part、Tetradecyl chloride base dimethyl benzyl group ammonium 1-3 part、Triethanolamine oleate 1-3 part、Ironic citrate 0.5-1 part、Polyethers 0.3-0.5 part、Water 100-200 part.
  2. nullHousehold water pipeline cleaning agent the most according to claim 1,It is characterized in that,Include according to the raw material of weight portion: Chinese honey locust extract 82-88 part、Lauryl sodium sulfate 25-35 part、P-aminobenzoic acid 22-28 part、Ammoniacal liquor 12-18 part、Sodium acid carbonate 12-18 part、Potassium hydrogen tartrate 11-14 part、Poly-epoxy succinic acid 11-14 part、Sodium sulfite phosphine carboxylic acid 11-14 part、Polycarboxylate water-reducer 9-11 part、Phosphono-carboxylic acids polymer 6-9 part、Belsperse164 dispersant 6.5-7.5 part、Dimethylcarbinol 6.5-7.5 part、Amidogen ether glycine betaine 6.5-7.5 part、Methenamine 4.5-5.5 part、Stannous octoate 4.5-5.5 part、Surfactant 3.5-4.5 part、D60 solvent naphtha 3.5-4.5 part、Aluminium napthenate 3.5-4.5 part、Sodium chloride 3.5-4.5 part、Lipase 2.5-3.5 part、Tetradecyl chloride base dimethyl benzyl group ammonium 1.5-2.5 part、Triethanolamine oleate 1.5-2.5 part、Ironic citrate 0.6-0.9 part、Polyethers 0.35-0.45 part、Water 120-180 part.
  3. nullHousehold water pipeline cleaning agent the most according to claim 1,It is characterized in that,Include according to the raw material of weight portion: Chinese honey locust extract 85 parts、Lauryl sodium sulfate 30 parts、P-aminobenzoic acid 25 parts、Ammoniacal liquor 15 parts、Sodium acid carbonate 15 parts、Potassium hydrogen tartrate 12 parts、Poly-epoxy succinic acid 12 parts、Sodium sulfite phosphine carboxylic acid 12 parts、Polycarboxylate water-reducer 10 parts、8 parts of phosphono-carboxylic acids polymer、Belsperse164 dispersant 7 parts、Dimethylcarbinol 7 parts、Amidogen ether glycine betaine 7 parts、Methenamine 5 parts、Stannous octoate 5 parts、4 parts of surfactant、D60 solvent naphtha 4 parts、Aluminium napthenate 4 parts、4 parts of sodium chloride、3 parts of lipase、Tetradecyl chloride base dimethyl benzyl group ammonium 2 parts、Triethanolamine oleate 2 parts、Ironic citrate 0.8 part、Polyethers 0.4 part、150 parts of water.
  4. 4. according to the arbitrary described Household water pipeline cleaning agent of claim 1-3, it is characterised in that described polyethers is at least one in secondary alkanol APEO and NPE.
  5. 5. according to the arbitrary described Household water pipeline cleaning agent of claim 1-3, it is characterised in that described surfactant is selected from one or more in butyl glycol ether, cocoanut fatty acid diethanolamide or sodium sulfate of polyethenoxy ether of fatty alcohol.
  6. 6. one kind profit require 1-3 arbitrary as described in the preparation method of Household water pipeline cleaning agent, it is characterised in that specifically comprise the following steps that
    (1) each raw material is weighed according to weight portion;
    (2) lauryl sodium sulfate, sodium acid carbonate, potassium hydrogen tartrate, amidogen ether glycine betaine, methenamine, stannous octoate, aluminium napthenate, sodium chloride, lipase, tetradecyl chloride base dimethyl benzyl group ammonium, triethanolamine oleate and ironic citrate ground to form the fine powder of 200-300 mesh sieve, mixed standby;
    (3) spaonin powder is broken to 100-200 mesh, adds the water of 3-5 times of equivalent, be warming up to 40-60 DEG C, continue stirring 1-2h, add the ethanol of 2 times of equivalents of Chinese honey locust weight, after stirring 20-40min, be cooled to 35-45 DEG C, stand 6-10h, filter, take filtrate and i.e. obtain Chinese honey locust extract;
    (4) p-aminobenzoic acid, ammoniacal liquor, poly-epoxy succinic acid, sodium sulfite phosphine carboxylic acid, polycarboxylate water-reducer, phosphono-carboxylic acids polymer, Belsperse164 dispersant and dimethylcarbinol are added to the water, mixing and stirring;
    (5) product that step (2) and step (3) obtained adds to step (4) in the product obtained, and adds surfactant and solvent naphtha polyethers, after being uniformly mixed finished product.
CN201610248872.9A 2016-04-19 2016-04-19 Household water pipeline cleaning agent and preparation method thereof Pending CN105838527A (en)

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CN107034044A (en) * 2017-04-07 2017-08-11 任国亮 A kind of sewer cleaning agent
CN107513719A (en) * 2017-08-04 2017-12-26 郴州国盛新材科技有限公司 A kind of metal cleaner for adding functional modification graphene and preparation method thereof
CN108124450A (en) * 2017-11-08 2018-06-05 苏州荣能环保科技有限公司 A kind of sewer pipe cleaning agent
CN108707911A (en) * 2018-09-03 2018-10-26 成都长江锅炉热能设备制造有限公司 Cleaning agent for air cooler metal surface
CN111139146A (en) * 2019-12-31 2020-05-12 四川美之家洗化用品有限公司 Pipeline dredging deodorant and preparation method thereof

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CN107034044A (en) * 2017-04-07 2017-08-11 任国亮 A kind of sewer cleaning agent
CN107513719A (en) * 2017-08-04 2017-12-26 郴州国盛新材科技有限公司 A kind of metal cleaner for adding functional modification graphene and preparation method thereof
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CN108707911A (en) * 2018-09-03 2018-10-26 成都长江锅炉热能设备制造有限公司 Cleaning agent for air cooler metal surface
CN111139146A (en) * 2019-12-31 2020-05-12 四川美之家洗化用品有限公司 Pipeline dredging deodorant and preparation method thereof

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Application publication date: 20160810