CN104130882A - Oil-gas transmission pipeline cleaning agent and preparation method thereof - Google Patents

Oil-gas transmission pipeline cleaning agent and preparation method thereof Download PDF

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Publication number
CN104130882A
CN104130882A CN201410373989.0A CN201410373989A CN104130882A CN 104130882 A CN104130882 A CN 104130882A CN 201410373989 A CN201410373989 A CN 201410373989A CN 104130882 A CN104130882 A CN 104130882A
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parts
honey locust
chinese honey
preparation
extracting solution
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CN201410373989.0A
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李瑞国
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Qingdao Flourishing Petro-Technology Services Co Ltd
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Qingdao Flourishing Petro-Technology Services Co Ltd
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Abstract

The invention relates to an oil-gas transmission pipeline cleaning agent and a preparation method thereof. The oil-gas transmission pipeline cleaning agent comprises the following components by weight: 28-36 parts of a Gleditsia Sinensis Lam extracted solution, 5-7 parts of polydimethylsiloxane, 6-9 parts of sodium carboxymethylcellulose, 10-16 parts of alkylphenol polyoxyethylene, 8-12 parts of ethylene glycol monobutyl ether, 15-20 parts of sodium chloride, 5-10 parts of citric acid, 4-8 parts of polyepoxysuccinic acid, 2-6 parts of potassium bitartrate, 5-12 parts of cetanol, 30-45 parts of ethanol, and 48-50 parts of water. The cleaning agent and the preparation method provided by the invention have the advantages that: 1. the cleaning agent provided by the invention has an excellent cleaning effect on pipelines, and can reach a clearance rate of 95% on dust and dirt in pipelines; 2. the raw materials involved in the invention are environment friendly and non-toxic, and have wide sources and low price; and 3. the preparation method provided by the invention is simple and feasible, and is convenient to implement, and the cleaning agent prepared by the method have stable properties and can be stored for a long time.

Description

Pipe-line clean-out system and preparation method thereof
Technical field
The invention belongs to industrial cleaning agent technical field, be specifically related to a kind of pipe-line clean-out system and preparation method thereof.
Background technology
Current, along with going from strength to strength of China's oil industry, people's pair industry relevant to oil also does much research on.Current, China's oil long-distance transportation still be take pipeline transportation as main, and wherein most of pipelines have moved for many years, and the economic environmental protection of pipeline transportation is with the obvious advantage.But because the safe operation of the phenomenons such as wax deposition and contamination precipitation to pipeline makes a big impact and hidden danger, oil pipeline cleans its normal operation significant in time, so the cleaning of pipe-line is very important together operation in oil gas course of conveying.The mode that at present mainly adopts matting and physical cleaning method to combine to the cleaning of pipe-line.
And existing chemical is stronger to the corrodibility of pipeline, and cleaning performance is not good, the industrial chemical having, adopts the organic solvent that some toxic side effect are larger, although better to pipeline cleaning effect, the waste liquid after cleaning has caused very big pollution to environment.
In sum, develop a kind of cleaning performance good and human body and eco-friendly pipe-line clean-out system have been become to this area technical problem urgently to be resolved hurrily.
Summary of the invention
The present invention, in order to solve the deficiencies in the prior art, provides a kind of pipe-line clean-out system and preparation method thereof, and this clean-out system cleaning performance is excellent and to human body and environmental friendliness.
The technical solution used in the present invention is as follows:
Pipe-line clean-out system, comprise the following component according to parts by weight meter: Chinese honey locust extracting solution 28-36 part, polydimethylsiloxane 5-7 part, Xylo-Mucine 6-9 part, alkylphenol polyoxyethylene 10-16 part, butyl glycol ether 8-12 part, sodium-chlor 15-20 part, citric acid 5-10 part, poly-epoxy succinic acid 4-8 part, tartarus 2-6 part, hexadecanol 5-12 part, ethanol 30-45 part, water 48-50 part, wherein, the preparation method of Chinese honey locust extracting solution: spaonin powder is broken to 100-200 order, the water that adds 2 times of equivalents, be warming up to 55-65 ℃, continue to stir 2h, the ethanol that adds 2 times of equivalents of Chinese honey locust weight, stir after 30min, be cooled to 40 ℃, standing 6h, filter, get filtrate and obtain Chinese honey locust extracting solution.
Described pipe-line clean-out system, comprise the following component according to parts by weight meter: Chinese honey locust extracting solution 28-30 part, polydimethylsiloxane 5-6 part, Xylo-Mucine 6-8 part, alkylphenol polyoxyethylene 10-14 part, butyl glycol ether 8-10 part, sodium-chlor 15-18 part, citric acid 5-8 part, poly-epoxy succinic acid 4-6 part, tartarus 2-5 part, hexadecanol 5-10 part, ethanol 30-40 part, water 48-49 part, wherein, the preparation method of Chinese honey locust extracting solution: spaonin powder is broken to 100-200 order, the water that adds 2 times of equivalents, be warming up to 55-65 ℃, continue to stir 2h, the ethanol that adds 2 times of equivalents of Chinese honey locust weight, stir after 30min, be cooled to 40 ℃, standing 6h, filter, get filtrate and obtain Chinese honey locust extracting solution.
Described pipe-line clean-out system, comprise the following component according to parts by weight meter: 30 parts of Chinese honey locust extracting solutions, 6 parts of polydimethylsiloxanes, 8 parts of Xylo-Mucines, 14 parts of alkylphenol polyoxyethylene, 10 parts of butyl glycol ethers, 18 parts, sodium-chlor, 8 parts of citric acids, 6 parts of poly-epoxy succinic acids, 5 parts of tartaruss, 10 parts of hexadecanols, 40 parts of ethanol, 49 parts, water, wherein, the preparation method of Chinese honey locust extracting solution: spaonin powder is broken to 100-200 order, the water that adds 2 times of equivalents, be warming up to 55-65 ℃, continue to stir 2h, the ethanol that adds 2 times of equivalents of Chinese honey locust weight, stir after 30min, be cooled to 40 ℃, standing 6h, filter, get filtrate and obtain Chinese honey locust extracting solution.
The preparation method of pipe-line clean-out system, comprises the steps:
The first step, is added to the water ethanol, Chinese honey locust extracting solution successively, stirs 10min, after add successively polydimethylsiloxane, Xylo-Mucine, alkylphenol polyoxyethylene, butyl glycol ether, sodium-chlor, citric acid, be warming up to 60-70 ℃, continue to stir 1h, obtain mixture A;
Second step, adds poly-epoxy succinic acid, tartarus, hexadecanol in step 1 gained mixture A successively, stirs 30min, is cooled to 35-40 ℃, and constant temperature stirs 40min, obtains.
The preparation method of described pipe-line clean-out system, wherein, the stirring velocity in step 1 and step 2 is 150-200r/min.
compared with prior art, its beneficial effect is in the present invention:the first, clean-out system of the present invention is excellent to the cleaning performance of pipeline, to the clearance rate of dust and dirt in pipeline, can reach 95%; The second, the present invention's each raw material environment-protecting asepsis used, wide material sources are cheap; The 3rd, preparation method of the present invention is simple, and it is convenient to implement, and the clean-out system stable in properties making according to the method, can long storage time.
Embodiment
Below in conjunction with embodiment, further set forth the present invention.
Embodiment 1
Pipe-line clean-out system, comprise the following component according to parts by weight meter: 28 parts of Chinese honey locust extracting solutions, 5 parts of polydimethylsiloxanes, 6 parts of Xylo-Mucines, 10 parts of alkylphenol polyoxyethylene, 8 parts of butyl glycol ethers, 15 parts, sodium-chlor, 5 parts of citric acids, 4 parts of poly-epoxy succinic acids, 2 parts of tartaruss, 5 parts of hexadecanols, 30 parts of ethanol, 48 parts, water, wherein, the preparation method of Chinese honey locust extracting solution: spaonin powder is broken to 100 orders, the water that adds 2 times of equivalents, be warming up to 55 ℃, continue to stir 2h, the ethanol that adds 2 times of equivalents of Chinese honey locust weight, stir after 30min, be cooled to 40 ℃, standing 6h, filter, get filtrate and obtain Chinese honey locust extracting solution.
The preparation method of the present embodiment, comprises the steps:
The first step, is added to the water ethanol, Chinese honey locust extracting solution successively, stirs 10min, after add successively polydimethylsiloxane, Xylo-Mucine, alkylphenol polyoxyethylene, butyl glycol ether, sodium-chlor, citric acid, be warming up to 60 ℃, continue to stir 1h, obtain mixture A;
Second step, adds poly-epoxy succinic acid, tartarus, hexadecanol in step 1 gained mixture A successively, stirs 30min, is cooled to 35 ℃, and constant temperature stirs 40min, obtains.
Wherein, the stirring velocity in step 1 and step 2 is 150r/min.
Embodiment 2
Pipe-line clean-out system, comprise the following component according to parts by weight meter: 36 parts of Chinese honey locust extracting solutions, 7 parts of polydimethylsiloxanes, 9 parts of Xylo-Mucines, 16 parts of alkylphenol polyoxyethylene, 12 parts of butyl glycol ethers, 20 parts, sodium-chlor, 10 parts of citric acids, 8 parts of poly-epoxy succinic acids, 6 parts of tartaruss, 12 parts of hexadecanols, 45 parts of ethanol, 50 parts, water, wherein, the preparation method of Chinese honey locust extracting solution: spaonin powder is broken to 200 orders, the water that adds 2 times of equivalents, be warming up to 65 ℃, continue to stir 2h, the ethanol that adds 2 times of equivalents of Chinese honey locust weight, stir after 30min, be cooled to 40 ℃, standing 6h, filter, get filtrate and obtain Chinese honey locust extracting solution.
The preparation method of the present embodiment, comprises the steps:
The first step, is added to the water ethanol, Chinese honey locust extracting solution successively, stirs 10min, after add successively polydimethylsiloxane, Xylo-Mucine, alkylphenol polyoxyethylene, butyl glycol ether, sodium-chlor, citric acid, be warming up to 70 ℃, continue to stir 1h, obtain mixture A;
Second step, adds poly-epoxy succinic acid, tartarus, hexadecanol in step 1 gained mixture A successively, stirs 30min, is cooled to 40 ℃, and constant temperature stirs 40min, obtains.
Wherein, the stirring velocity in step 1 and step 2 is 200r/min.
Embodiment 3
Pipe-line clean-out system, comprise the following component according to parts by weight meter: 30 parts of Chinese honey locust extracting solutions, 6 parts of polydimethylsiloxanes, 8 parts of Xylo-Mucines, 14 parts of alkylphenol polyoxyethylene, 10 parts of butyl glycol ethers, 18 parts, sodium-chlor, 8 parts of citric acids, 6 parts of poly-epoxy succinic acids, 5 parts of tartaruss, 10 parts of hexadecanols, 40 parts of ethanol, 49 parts, water, wherein, the preparation method of Chinese honey locust extracting solution: spaonin powder is broken to 200 orders, the water that adds 2 times of equivalents, be warming up to 65 ℃, continue to stir 2h, the ethanol that adds 2 times of equivalents of Chinese honey locust weight, stir after 30min, be cooled to 40 ℃, standing 6h, filter, get filtrate and obtain Chinese honey locust extracting solution.
The preparation method of the present embodiment, comprises the steps:
The first step, is added to the water ethanol, Chinese honey locust extracting solution successively, stirs 10min, after add successively polydimethylsiloxane, Xylo-Mucine, alkylphenol polyoxyethylene, butyl glycol ether, sodium-chlor, citric acid, be warming up to 60 ℃, continue to stir 1h, obtain mixture A;
Second step, adds poly-epoxy succinic acid, tartarus, hexadecanol in step 1 gained mixture A successively, stirs 30min, is cooled to 35 ℃, and constant temperature stirs 40min, obtains.
Wherein, the stirring velocity in step 1 and step 2 is 150r/min.
Embodiment 4
Pipe-line clean-out system, comprise the following component according to parts by weight meter: 29 parts of Chinese honey locust extracting solutions, 5 parts of polydimethylsiloxanes, 8 parts of Xylo-Mucines, 12 parts of alkylphenol polyoxyethylene, 9 parts of butyl glycol ethers, 16 parts, sodium-chlor, 6 parts of citric acids, 5 parts of poly-epoxy succinic acids, 3 parts of tartaruss, 8 parts of hexadecanols, 38 parts of ethanol, 48 parts, water, wherein, the preparation method of Chinese honey locust extracting solution: spaonin powder is broken to 200 orders, the water that adds 2 times of equivalents, be warming up to 65 ℃, continue to stir 2h, the ethanol that adds 2 times of equivalents of Chinese honey locust weight, stir after 30min, be cooled to 40 ℃, standing 6h, filter, get filtrate and obtain Chinese honey locust extracting solution.
The preparation method of the present embodiment, comprises the steps:
The first step, is added to the water ethanol, Chinese honey locust extracting solution successively, stirs 10min, after add successively polydimethylsiloxane, Xylo-Mucine, alkylphenol polyoxyethylene, butyl glycol ether, sodium-chlor, citric acid, be warming up to 60 ℃, continue to stir 1h, obtain mixture A;
Second step, adds poly-epoxy succinic acid, tartarus, hexadecanol in step 1 gained mixture A successively, stirs 30min, is cooled to 38 ℃, and constant temperature stirs 40min, obtains.
Wherein, the stirring velocity in step 1 and step 2 is 200r/min.
Reference examples 1
Be with the difference of embodiment 3: do not add citric acid.
Pipe-line clean-out system, comprise the following component according to parts by weight meter: 30 parts of Chinese honey locust extracting solutions, 6 parts of polydimethylsiloxanes, 8 parts of Xylo-Mucines, 14 parts of alkylphenol polyoxyethylene, 10 parts of butyl glycol ethers, 18 parts, sodium-chlor, 6 parts of poly-epoxy succinic acids, 5 parts of tartaruss, 10 parts of hexadecanols, 40 parts of ethanol, 49 parts, water, wherein, the preparation method of Chinese honey locust extracting solution: spaonin powder is broken to 200 orders, the water that adds 2 times of equivalents, be warming up to 65 ℃, continue to stir 2h, the ethanol that adds 2 times of equivalents of Chinese honey locust weight, stir after 30min, be cooled to 40 ℃, standing 6h, filter, get filtrate and obtain Chinese honey locust extracting solution.
The preparation method of the present embodiment, comprises the steps:
The first step, is added to the water ethanol, Chinese honey locust extracting solution successively, stirs 10min, after add successively polydimethylsiloxane, Xylo-Mucine, alkylphenol polyoxyethylene, butyl glycol ether, sodium-chlor, be warming up to 60 ℃, continue to stir 1h, obtain mixture A;
Second step, adds poly-epoxy succinic acid, tartarus, hexadecanol in step 1 gained mixture A successively, stirs 30min, is cooled to 35 ℃, and constant temperature stirs 40min, obtains.
Wherein, the stirring velocity in step 1 and step 2 is 150r/min.
Reference examples 2
Be with the difference of embodiment 3: do not add butyl glycol ether and citric acid.
Pipe-line clean-out system, comprise the following component according to parts by weight meter: 30 parts of Chinese honey locust extracting solutions, 6 parts of polydimethylsiloxanes, 8 parts of Xylo-Mucines, 14 parts of alkylphenol polyoxyethylene, 18 parts, sodium-chlor, 6 parts of poly-epoxy succinic acids, 5 parts of tartaruss, 10 parts of hexadecanols, 40 parts of ethanol, 49 parts, water, wherein, the preparation method of Chinese honey locust extracting solution: spaonin powder is broken to 200 orders, the water that adds 2 times of equivalents, be warming up to 65 ℃, continue to stir 2h, the ethanol that adds 2 times of equivalents of Chinese honey locust weight, stir after 30min, be cooled to 40 ℃, standing 6h, filter, get filtrate and obtain Chinese honey locust extracting solution.
The preparation method of the present embodiment, comprises the steps:
The first step, is added to the water ethanol, Chinese honey locust extracting solution successively, stirs 10min, after add successively polydimethylsiloxane, Xylo-Mucine, alkylphenol polyoxyethylene, sodium-chlor, be warming up to 60 ℃, continue to stir 1h, obtain mixture A;
Second step, adds poly-epoxy succinic acid, tartarus, hexadecanol in step 1 gained mixture A successively, stirs 30min, is cooled to 35 ℃, and constant temperature stirs 40min, obtains.
Wherein, the stirring velocity in step 1 and step 2 is 150r/min.
performance Detection:
The embodiment of the present invention 1 to 4 gained finished product and reference examples 1 to 2 gained finished product, the oil pipeline of 3 years ' operation is cleaned, by 500g water dilution for 400g clean-out system, be used for cleaning one square metre of oil pipeline, with placement, after 100 days, have or not precipitation to evaluate its stability, excellent without being precipitated as, every 500g clean-out system precipitation capacity 1-3g is good, every 500g clean-out system precipitation capacity is greater than during 3g is, result is as follows:
Table 1
? Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Reference examples 1 Reference examples 2
Stability Excellent Excellent Excellent Excellent Good In
Except dust and dirt rate, % 99 99.2 99.5 99.4 80 85
As can be seen from the table, in embodiment 1 to 4, embodiment 3 gained finished product best results, are considered as most preferred embodiment; Embodiment 3 is more visible with reference examples 1 and reference examples 2, adding of butyl glycol ether and citric acid can significantly improve the stability of finished product and remove dust and dirt rate, under the acting in conjunction of butyl glycol ether and citric acid and other each components, make clean-out system of the present invention there is excellent stability and the good dust and dirt rate of removing.

Claims (5)

1. pipe-line clean-out system, it is characterized in that, comprise the following component according to parts by weight meter: Chinese honey locust extracting solution 28-36 part, polydimethylsiloxane 5-7 part, Xylo-Mucine 6-9 part, alkylphenol polyoxyethylene 10-16 part, butyl glycol ether 8-12 part, sodium-chlor 15-20 part, citric acid 5-10 part, poly-epoxy succinic acid 4-8 part, tartarus 2-6 part, hexadecanol 5-12 part, ethanol 30-45 part, water 48-50 part, wherein, the preparation method of Chinese honey locust extracting solution: spaonin powder is broken to 100-200 order, the water that adds 2 times of equivalents, be warming up to 55-65 ℃, continue to stir 2h, the ethanol that adds 2 times of equivalents of Chinese honey locust weight, stir after 30min, be cooled to 40 ℃, standing 6h, filter, get filtrate and obtain Chinese honey locust extracting solution.
2. pipe-line clean-out system according to claim 1, it is characterized in that, comprise the following component according to parts by weight meter: Chinese honey locust extracting solution 28-30 part, polydimethylsiloxane 5-6 part, Xylo-Mucine 6-8 part, alkylphenol polyoxyethylene 10-14 part, butyl glycol ether 8-10 part, sodium-chlor 15-18 part, citric acid 5-8 part, poly-epoxy succinic acid 4-6 part, tartarus 2-5 part, hexadecanol 5-10 part, ethanol 30-40 part, water 48-49 part, wherein, the preparation method of Chinese honey locust extracting solution: spaonin powder is broken to 100-200 order, the water that adds 2 times of equivalents, be warming up to 55-65 ℃, continue to stir 2h, the ethanol that adds 2 times of equivalents of Chinese honey locust weight, stir after 30min, be cooled to 40 ℃, standing 6h, filter, get filtrate and obtain Chinese honey locust extracting solution.
3. pipe-line clean-out system according to claim 1, it is characterized in that, comprise the following component according to parts by weight meter: 30 parts of Chinese honey locust extracting solutions, 6 parts of polydimethylsiloxanes, 8 parts of Xylo-Mucines, 14 parts of alkylphenol polyoxyethylene, 10 parts of butyl glycol ethers, 18 parts, sodium-chlor, 8 parts of citric acids, 6 parts of poly-epoxy succinic acids, 5 parts of tartaruss, 10 parts of hexadecanols, 40 parts of ethanol, 49 parts, water, wherein, the preparation method of Chinese honey locust extracting solution: spaonin powder is broken to 100-200 order, the water that adds 2 times of equivalents, be warming up to 55-65 ℃, continue to stir 2h, the ethanol that adds 2 times of equivalents of Chinese honey locust weight, stir after 30min, be cooled to 40 ℃, standing 6h, filter, get filtrate and obtain Chinese honey locust extracting solution.
4. the preparation method of pipe-line clean-out system claimed in claim 1, is characterized in that, comprises the steps:
The first step, is added to the water ethanol, Chinese honey locust extracting solution successively, stirs 10min, after add successively polydimethylsiloxane, Xylo-Mucine, alkylphenol polyoxyethylene, butyl glycol ether, sodium-chlor, citric acid, be warming up to 60-70 ℃, continue to stir 1h, obtain mixture A;
Second step, adds poly-epoxy succinic acid, tartarus, hexadecanol in step 1 gained mixture A successively, stirs 30min, is cooled to 35-40 ℃, and constant temperature stirs 40min, obtains.
5. the preparation method of pipe-line clean-out system according to claim 4, is characterized in that, the stirring velocity in step 1 and step 2 is 150-200r/min.
CN201410373989.0A 2014-08-01 2014-08-01 Oil-gas transmission pipeline cleaning agent and preparation method thereof Pending CN104130882A (en)

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CN104531378A (en) * 2014-12-29 2015-04-22 江苏健神生物农化有限公司 Heavy-oil delivery pipeline cleaning agent and preparation method thereof
CN105695127A (en) * 2016-03-16 2016-06-22 安徽海德石油化工有限公司 High-viscosity petroleum product conveying pipeline cleaning agent
CN105779161A (en) * 2016-03-14 2016-07-20 宁波江东索雷斯电子科技有限公司 Preparation method of paraffin remover
CN105838527A (en) * 2016-04-19 2016-08-10 王维娜 Household water pipeline cleaning agent and preparation method thereof
CN105838513A (en) * 2016-05-18 2016-08-10 大连和田科技有限公司 Preparation method of high-solid content heavy-oil cleaning agent
CN107162227A (en) * 2017-07-08 2017-09-15 安徽雪雨洁具有限公司 A kind of toilet seat water tank scale preventative and preparation method thereof
CN107384660A (en) * 2017-08-10 2017-11-24 安徽钰丰电子科技有限公司 A kind of brewage process of cortex acanthopanacis health-preserving beer
CN114369451A (en) * 2022-01-13 2022-04-19 陕西科技大学 Nano imbibition agent and preparation method and application thereof

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104531378A (en) * 2014-12-29 2015-04-22 江苏健神生物农化有限公司 Heavy-oil delivery pipeline cleaning agent and preparation method thereof
CN105779161A (en) * 2016-03-14 2016-07-20 宁波江东索雷斯电子科技有限公司 Preparation method of paraffin remover
CN105695127A (en) * 2016-03-16 2016-06-22 安徽海德石油化工有限公司 High-viscosity petroleum product conveying pipeline cleaning agent
CN105838527A (en) * 2016-04-19 2016-08-10 王维娜 Household water pipeline cleaning agent and preparation method thereof
CN105838513A (en) * 2016-05-18 2016-08-10 大连和田科技有限公司 Preparation method of high-solid content heavy-oil cleaning agent
CN107162227A (en) * 2017-07-08 2017-09-15 安徽雪雨洁具有限公司 A kind of toilet seat water tank scale preventative and preparation method thereof
CN107384660A (en) * 2017-08-10 2017-11-24 安徽钰丰电子科技有限公司 A kind of brewage process of cortex acanthopanacis health-preserving beer
CN114369451A (en) * 2022-01-13 2022-04-19 陕西科技大学 Nano imbibition agent and preparation method and application thereof
CN114369451B (en) * 2022-01-13 2022-11-29 甘肃智仑新材料科技有限公司 Nano imbibition agent and preparation method and application thereof

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