CN105838300A - Special sealant for ordinary batteries and preparation process thereof - Google Patents

Special sealant for ordinary batteries and preparation process thereof Download PDF

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Publication number
CN105838300A
CN105838300A CN201610248732.1A CN201610248732A CN105838300A CN 105838300 A CN105838300 A CN 105838300A CN 201610248732 A CN201610248732 A CN 201610248732A CN 105838300 A CN105838300 A CN 105838300A
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China
Prior art keywords
adds
parts
reactor
add
root
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Inventor
翟恩宏
邱昌炯
陈同吾
官仕朝
李家梅
郑学柱
尹德义
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ANHUI INNOVATION NEW ENERGY Co Ltd
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ANHUI INNOVATION NEW ENERGY Co Ltd
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Priority to CN201610248732.1A priority Critical patent/CN105838300A/en
Publication of CN105838300A publication Critical patent/CN105838300A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J161/00Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G16/00Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
    • C08G16/02Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
    • C08G16/0212Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds
    • C08G16/0218Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen
    • C08G16/0231Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/206Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention provides a special sealant for ordinary batteries and a preparation method thereof. The sealant is prepared from the following components: vegetable oil, potassium permanganate, methanol, ethylene glycol, pentaerythritol, sulfolane, alkylphenol ethoxylates, ethanolamine, zinc naphthenate, low grade ether, epoxy organosilicone, a toughening agent, a coupling agent, a curing agent, ethyl cyanoacetate, solid formaldehyde, piperidine, cyclohexane, ethyl acetate, phosphorus pentoxide, sulfur dioxide, hydroquinone, E-42 epoxy resin, a phenolic aldehyde-nitrile-butadiene rubber copolymer, acetone, ethylenediamine, pepperweed seed, cassia twig, white paeony root, dried ginger, Chinese ephedra, pinellia tuber, bulb of thunberg fritillary, manchurian wildginger herb, Chinese magnoliavine fruit, liquorice root and scented tea. When used for sealing plastic surfaces, the sealant has an insulating function on the one hand and a sealing function on the other hand. The sealant prepared by utilizing the method is non-toxic and harmless, furthest ensures leakage of harmful substances of batteries, is also simple in process and low in cost and has excellent properties, a wide range of application, good stability, strong waterproofness, high bonding strength and strong practicability.

Description

Common batteries special seal gum and preparation technology thereof
Technical field:
The present invention designs a kind of battery auxiliary material preparation technology, is specifically related to a kind of common batteries special seal gum and preparation thereof Technique.
Background technology:
Chemical industry is to develop the most rapid mainstay of the national economy industry modern times, and fine chemistry industry tail gas important set Becoming part, obtained the development advanced by leaps and bounds in 20th century, the clothing, food, lodging and transportion--basic necessities of life of the unresolved mankind and the energy, resource and environment are asked Topic makes significant contribution;
Need specialty glue for battery parcel glue, glue is development of modern industry and human living standard improve essential Important materials, adhesive and bonding technology are with the incomparable special warfare of other connected modes, in modern economy, modern state Anti-, modern science and technology plays great effect.
Summary of the invention:
The technical problem to be solved is to overcome the defect of prior art, it is provided that a kind of common batteries is special close Sealing and preparation technology thereof.
The technical problem to be solved realizes by the following technical solutions.
Common batteries special seal gum, it is characterised in that: it is prepared from the following components, vegetable oil 36-44 part, permanganic acid Potassium 4-6 part, methyl alcohol 9-11 part, ethylene glycol 9-11 part, pentaerythrite 4-6 part, sulfolane 9-11 part, APES 4- 6 parts, monoethanolamine 9-11 part, zinc naphthenate 19-21 part, rudimentary ether 6-10 part, epoxy organosilicon 50-60 part, toughener 10-15 Part, coupling agent 1-2 part, curing agent 2-3 part, ethyl cyanoacetate 100-150 part, solid formaldehyde 50-60 part, piperidines 2-3 part, hexamethylene Alkane 2-5 part, ethyl acetate 1-3 part, phosphorus pentoxide 2-5 part, sulfur dioxide 1-2 part, hydroquinones 1-3 part, E-42 asphalt mixtures modified by epoxy resin Fat 89-99 part, phenolic aldehyde-nitrile rubber copolymer 89-99 part, acetone 66-75 part, ethylenediamine 10-15 part, Roripa montana 4-5 part, cassia twig 10-12 part, root of herbaceous peony 10-12 part, rhizoma zingiberis 10-12 part, Chinese ephedra 8-10 part, tuber of pinellia 8-10 part, fritillaria thunbergii 5-8 part, root of Chinese wild ginger 3-5 part, Fruit of Chinese magnoliavine 10-15 part, Radix Glycyrrhizae 8-10 part, jasmine tea 4-5 grain.
Common batteries special seal gum comprises the following steps and is prepared from:
1) selection one is with the reactor of agitator, then adds important vegetable oil in formula in reactor and opens Open stirring;
2) by the potassium permanganate in raw material, sulfolane, APES, monoethanolamine, zinc naphthenate and rudimentary ether, All add in reactor, after being stirred and heated to 60-80 DEG C, isothermal reaction 2-4h;
3) until above-mentioned steps reaction terminate after, reactor is cooled to 20-25 DEG C, by the pentaerythrite in raw material, methyl alcohol and Ethylene glycol is added thereto, and stands 5-10h, obtain auxiliary material one after stirring;
4) E-42 epoxy resin and acetone are mixed;
5) mixed solvent and phenolic aldehyde-nitrile rubber copolymer are joined in bottle, stirring;
6) it is heated to 81-86 DEG C, adds MMA, continue stirring 1 hour;
7) intermixture is mixed in the ratio of 30:1 in the environment of ethylenediamine early-60 DEG C to 60 DEG C, be sufficiently stirred for Uniformly;
8) cool to room temperature again, obtain auxiliary material two;
9) take epoxy organosilicon, toughener, coupling agent mixing be completely dissolved after, add curing agent make semi-finished product glue;
10) take solid formaldehyde, piperidines adds in a flask, heating simultaneously, and stirring is dissolved, then put into reactor In, reactor is warming up to 90 DEG C, adds ethyl cyanoacetate, heat 2 hours, then recycling design methyl alcohol, to temperature 120 DEG C, Stopping heating, add hexamethylene, ethyl acetate mixing, reflux dewatering, temperature rises to 125 DEG C, and discharging obtains condensation polymer;
11) condensation polymer and semi-finished product glue being mixed, proportion is 100:20-50, adds 5-10 part accelerator, is warming up to 90 DEG C, heating duration i.e. can get copolymerization adhesive in 1 hour;
12) take 1-2 part phosphorus pentoxide and add copolymerization adhesive, be heated under 190 DEG C-200 DEG C, vacuum 0.1MPa entering Row cracking, obtains crude monomer;
13) in crude monomer, add remaining phosphorus pentoxide, hydroquinones, sulfur dioxide, stir in reactor, temperature Degree control 80-100 DEG C, vacuum be under 0.1MPa collect cut be the product of 70-80 DEG C, obtain essence monomer;
14) take essence monomer and add the mixing that mass fraction is the dioctyl phthalate of 1%-2%, lucite powder Thing, obtains moment adhesive;
15) by the Roripa montana in constitutive material, cassia twig, the root of herbaceous peony, rhizoma zingiberis, Chinese ephedra, the tuber of pinellia, fritillaria thunbergii, the root of Chinese wild ginger, the fruit of Chinese magnoliavine and sweet Grass, puts in cucurbit, adds the clear water of 5 times, boiling, and the water to cucurbit is evaporated, and collects steam, steam liquid again Change;Being put into by jasmine tea in boiling water simultaneously and soak, the water yield is 300ml, soaks 5-8 minute, crosses drainage, obtains jasmine tea water;To receive again The steam of collection mixes with jasmine tea water, obtains mixed liquor;
16) taking 20% auxiliary material one to mix with 40% mixed liquor, the moment adhesive taking twice 20% adds mixing, is heated to 60 DEG C, heating duration 10 minutes, during then cooling is placed in the auxiliary material two of 60%;
17) moment adhesive with 80% mixes the most again, cooling, obtains fluid sealant.
The invention has the beneficial effects as follows: the glue of cell sealing, for sealed plastic surface, on the one hand play insulating effect, Another plays the effect of sealing, and the fluid sealant utilizing this law to prepare is nontoxic, at utmost ensure that battery harmful substance Revealing, technique is simple simultaneously, and property favorable rates is honest and clean, of many uses, good stability, and water-resistance is strong, and adhesion strength is high, practical.
Detailed description of the invention:
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot Close specific embodiment, the present invention is expanded on further.
Specific embodiment 1: common batteries special seal gum, is prepared from the following components, vegetable oil 36 parts, potassium permanganate 4 parts, methyl alcohol 9 parts, ethylene glycol 9 parts, pentaerythrite 4 parts, sulfolane 9 parts, APES 4 parts, monoethanolamine 9 parts, ring 19 parts of alkanoic acid zinc, 6 parts of rudimentary ether, epoxy organosilicon 50 parts, toughener 10 parts, coupling agent 1 part, 2 parts of curing agent, ethyl cyanoacetate 100 parts, solid formaldehyde 50 parts, piperidines 2 parts, hexamethylene 2 parts, 1 part of ethyl acetate, phosphorus pentoxide 2 parts, sulfur dioxide 1 part, right Benzenediol 1 part, E-42 epoxy resin 89 parts, phenolic aldehyde-nitrile rubber copolymer 89 parts, 66 parts of acetone, ethylenediamine 10 parts, Roripa montana 4 Part, cassia twig 10 parts, the root of herbaceous peony 10 parts, rhizoma zingiberis 10 parts, 8 parts of Chinese ephedra, the tuber of pinellia 8 parts, fritillaria thunbergii 5 parts, the root of Chinese wild ginger 3 parts, 10 parts of the fruit of Chinese magnoliavine, sweet Grass 8 parts, jasmine tea 4.
Specific embodiment 2: common batteries special seal gum, is prepared from the following components, vegetable oil 44 parts, potassium permanganate 6 parts, methyl alcohol 11 parts, ethylene glycol 11 parts, pentaerythrite 6 parts, sulfolane 11 parts, APES 6 parts, monoethanolamine 11 Part, zinc naphthenate 21 parts, 10 parts of rudimentary ether, epoxy organosilicon 60 parts, toughener 15 parts, coupling agent 2 parts, 3 parts of curing agent, cyanogen second Acetoacetic ester 150 parts, solid formaldehyde 60 parts, piperidines 3 parts, hexamethylene 5 parts, 3 parts of ethyl acetate, phosphorus pentoxide 5 parts, sulfur dioxide 2 parts, hydroquinones 3 parts, E-42 epoxy resin 99 parts, phenolic aldehyde-nitrile rubber copolymer 99 parts, 75 parts of acetone, ethylenediamine 15 parts, Roripa montana 5 parts, cassia twig 12 parts, the root of herbaceous peony 12 parts, rhizoma zingiberis 12 parts, 10 parts of Chinese ephedra, the tuber of pinellia 10 parts, fritillaria thunbergii 8 parts, the root of Chinese wild ginger 5 parts, the fruit of Chinese magnoliavine 15 parts, 10 parts of Radix Glycyrrhizae, jasmine tea 5.
Its preparation method includes:
1) selection one is with the reactor of agitator, then adds important vegetable oil in formula in reactor and opens Open stirring;
2) by the potassium permanganate in raw material, sulfolane, APES, monoethanolamine, zinc naphthenate and rudimentary ether, All add in reactor, after being stirred and heated to 60-80 DEG C, isothermal reaction 2-4h;
3) until above-mentioned steps reaction terminate after, reactor is cooled to 20-25 DEG C, by the pentaerythrite in raw material, methyl alcohol and Ethylene glycol is added thereto, and stands 5-10h, obtain auxiliary material one after stirring;
4) E-42 epoxy resin and acetone are mixed;
5) mixed solvent and phenolic aldehyde-nitrile rubber copolymer are joined in bottle, stirring;
6) it is heated to 81-86 DEG C, adds MMA, continue stirring 1 hour;
7) intermixture is mixed in the ratio of 30:1 in the environment of ethylenediamine early-60 DEG C to 60 DEG C, be sufficiently stirred for Uniformly;
8) cool to room temperature again, obtain auxiliary material two;
9) take epoxy organosilicon, toughener, coupling agent mixing be completely dissolved after, add curing agent make semi-finished product glue;
10) take solid formaldehyde, piperidines adds in a flask, heating simultaneously, and stirring is dissolved, then put into reactor In, reactor is warming up to 90 DEG C, adds ethyl cyanoacetate, heat 2 hours, then recycling design methyl alcohol, to temperature 120 DEG C, Stopping heating, add hexamethylene, ethyl acetate mixing, reflux dewatering, temperature rises to 125 DEG C, and discharging obtains condensation polymer;
11) condensation polymer and semi-finished product glue being mixed, proportion is 100:20-50, adds 5-10 part accelerator, is warming up to 90 DEG C, heating duration i.e. can get copolymerization adhesive in 1 hour;
12) take 1-2 part phosphorus pentoxide and add copolymerization adhesive, be heated under 190 DEG C-200 DEG C, vacuum 0.1MPa entering Row cracking, obtains crude monomer;
13) in crude monomer, add remaining phosphorus pentoxide, hydroquinones, sulfur dioxide, stir in reactor, temperature Degree control 80-100 DEG C, vacuum be under 0.1MPa collect cut be the product of 70-80 DEG C, obtain essence monomer;
14) take essence monomer and add the mixing that mass fraction is the dioctyl phthalate of 1%-2%, lucite powder Thing, obtains moment adhesive;
15) by the Roripa montana in constitutive material, cassia twig, the root of herbaceous peony, rhizoma zingiberis, Chinese ephedra, the tuber of pinellia, fritillaria thunbergii, the root of Chinese wild ginger, the fruit of Chinese magnoliavine and sweet Grass, puts in cucurbit, adds the clear water of 5 times, boiling, and the water to cucurbit is evaporated, and collects steam, steam liquid again Change;Being put into by jasmine tea in boiling water simultaneously and soak, the water yield is 300ml, soaks 5-8 minute, crosses drainage, obtains jasmine tea water;To receive again The steam of collection mixes with jasmine tea water, obtains mixed liquor;
16) taking 20% auxiliary material one to mix with 40% mixed liquor, the moment adhesive taking twice 20% adds mixing, is heated to 60 DEG C, heating duration 10 minutes, during then cooling is placed in the auxiliary material two of 60%;
17) moment adhesive with 80% mixes the most again, cooling, obtains fluid sealant.
The general principle of the present invention, principal character and advantages of the present invention have more than been shown and described.The technology of the industry Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and specification The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and Equivalent defines.

Claims (2)

1. common batteries special seal gum, it is characterised in that: it is prepared from the following components, vegetable oil 36-44 part, potassium permanganate 4-6 part, methyl alcohol 9-11 part, ethylene glycol 9-11 part, pentaerythrite 4-6 part, sulfolane 9-11 part, APES 4-6 Part, monoethanolamine 9-11 part, zinc naphthenate 19-21 part, rudimentary ether 6-10 part, epoxy organosilicon 50-60 part, toughener 10-15 part, Coupling agent 1-2 part, curing agent 2-3 part, ethyl cyanoacetate 100-150 part, solid formaldehyde 50-60 part, piperidines 2-3 part, hexamethylene 2-5 part, ethyl acetate 1-3 part, phosphorus pentoxide 2-5 part, sulfur dioxide 1-2 part, hydroquinones 1-3 part, E-42 epoxy resin 89-99 part, phenolic aldehyde-nitrile rubber copolymer 89-99 part, acetone 66-75 part, ethylenediamine 10-15 part, Roripa montana 4-5 part, cassia twig 10-12 part, root of herbaceous peony 10-12 part, rhizoma zingiberis 10-12 part, Chinese ephedra 8-10 part, tuber of pinellia 8-10 part, fritillaria thunbergii 5-8 part, root of Chinese wild ginger 3-5 part, Fruit of Chinese magnoliavine 10-15 part, Radix Glycyrrhizae 8-10 part, jasmine tea 4-5 grain.
2. according to the common batteries special seal gum described in claim 1, it is characterised in that: comprise the following steps and be prepared from:
1) selection one is with the reactor of agitator, then adds vegetable oil unlatching important in formula in reactor and stirs Mix;
2) by the potassium permanganate in raw material, sulfolane, APES, monoethanolamine, zinc naphthenate and rudimentary ether, all Add in reactor, after being stirred and heated to 60-80 DEG C, isothermal reaction 2-4h;
3) after above-mentioned steps reaction terminates, reactor is cooled to 20-25 DEG C, by the pentaerythrite in raw material, methyl alcohol and second two Alcohol is added thereto, and stands 5-10h, obtain auxiliary material one after stirring;
4) E-42 epoxy resin and acetone are mixed;
5) mixed solvent and phenolic aldehyde-nitrile rubber copolymer are joined in bottle, stirring;
6) it is heated to 81-86 DEG C, adds MMA, continue stirring 1 hour;
7) intermixture is mixed in the ratio of 30:1 in the environment of ethylenediamine early-60 DEG C to 60 DEG C, stir;
8) cool to room temperature again, obtain auxiliary material two;
9) take epoxy organosilicon, toughener, coupling agent mixing be completely dissolved after, add curing agent make semi-finished product glue;
10) take solid formaldehyde, piperidines adds in a flask, heating simultaneously, and stirring is dissolved, then put in reactor, will Reactor is warming up to 90 DEG C, adds ethyl cyanoacetate, heats 2 hours, then recycling design methyl alcohol, to temperature 120 DEG C, stop adding Heat, adds hexamethylene, ethyl acetate mixing, and reflux dewatering, temperature rises to 125 DEG C, and discharging obtains condensation polymer;
11) condensation polymer and semi-finished product glue being mixed, proportion is 100:20-50, adds 5-10 part accelerator, is warming up to 90 DEG C, adds Hot duration i.e. can get copolymerization adhesive in 1 hour;
12) take 1-2 part phosphorus pentoxide and add copolymerization adhesive, be heated under 190 DEG C-200 DEG C, vacuum 0.1MPa splitting Solve, obtain crude monomer;
13) in crude monomer, add remaining phosphorus pentoxide, hydroquinones, sulfur dioxide, stir in reactor, temperature control Make 80-100 DEG C, vacuum be under 0.1MPa collect cut be the product of 70-80 DEG C, obtain essence monomer;
14) take essence monomer and add the mixture that mass fraction is the dioctyl phthalate of 1%-2%, lucite powder, To moment adhesive;
15) by the Roripa montana in constitutive material, cassia twig, the root of herbaceous peony, rhizoma zingiberis, Chinese ephedra, the tuber of pinellia, fritillaria thunbergii, the root of Chinese wild ginger, the fruit of Chinese magnoliavine and Radix Glycyrrhizae, Putting in cucurbit, add the clear water of 5 times, boiling, the water to cucurbit is evaporated, and collects steam, and steam liquefies again; Being put into by jasmine tea in boiling water simultaneously and soak, the water yield is 300ml, soaks 5-8 minute, crosses drainage, obtains jasmine tea water;Again by collection Steam mixes with jasmine tea water, obtains mixed liquor;
16) taking 20% auxiliary material one to mix with 40% mixed liquor, the moment adhesive taking twice 20% adds mixing, is heated to 60 DEG C, heating duration 10 minutes, during then cooling is placed in the auxiliary material two of 60%;
17) moment adhesive with 80% mixes the most again, cooling, obtains fluid sealant.
CN201610248732.1A 2016-04-19 2016-04-19 Special sealant for ordinary batteries and preparation process thereof Pending CN105838300A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201610248732.1A CN105838300A (en) 2016-04-19 2016-04-19 Special sealant for ordinary batteries and preparation process thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106218056A (en) * 2016-08-31 2016-12-14 阜南县天亿工艺品有限公司 A kind of ferrum skill artware packaging thermal insulation board preparation method
CN107159989A (en) * 2017-06-09 2017-09-15 天长市天峰机电科技有限公司 A kind of overall soldering process of armature

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103947790A (en) * 2014-04-09 2014-07-30 郎溪县黄香茶叶有限公司 Tea drink formula beneficial to lung warming and cold dispelling and preparation method thereof
CN104073198A (en) * 2014-06-26 2014-10-01 安徽神舟飞船胶业有限公司 Formula and preparation process of non-toxic epoxy resin adhesive
CN104194715A (en) * 2014-08-26 2014-12-10 安徽神舟飞船胶业有限公司 Formula and preparation process of instant organic silicon adhesive
CN104711043A (en) * 2015-01-30 2015-06-17 安徽海德石油化工有限公司 Novel burner plant oil and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103947790A (en) * 2014-04-09 2014-07-30 郎溪县黄香茶叶有限公司 Tea drink formula beneficial to lung warming and cold dispelling and preparation method thereof
CN104073198A (en) * 2014-06-26 2014-10-01 安徽神舟飞船胶业有限公司 Formula and preparation process of non-toxic epoxy resin adhesive
CN104194715A (en) * 2014-08-26 2014-12-10 安徽神舟飞船胶业有限公司 Formula and preparation process of instant organic silicon adhesive
CN104711043A (en) * 2015-01-30 2015-06-17 安徽海德石油化工有限公司 Novel burner plant oil and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106218056A (en) * 2016-08-31 2016-12-14 阜南县天亿工艺品有限公司 A kind of ferrum skill artware packaging thermal insulation board preparation method
CN107159989A (en) * 2017-06-09 2017-09-15 天长市天峰机电科技有限公司 A kind of overall soldering process of armature

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Application publication date: 20160810