CN105837940A - Mould preventing, bacterium inhibiting and virus resisting plastic product and preparation method thereof - Google Patents
Mould preventing, bacterium inhibiting and virus resisting plastic product and preparation method thereof Download PDFInfo
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- CN105837940A CN105837940A CN201610304823.2A CN201610304823A CN105837940A CN 105837940 A CN105837940 A CN 105837940A CN 201610304823 A CN201610304823 A CN 201610304823A CN 105837940 A CN105837940 A CN 105837940A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to a mould preventing, bacterium inhibiting and virus resisting plastic product and a preparation method thereof. The mould preventing, bacterium inhibiting and virus resisting plastic product is prepared from, by weight, 85% to 92% of polypropylene or polyethylene, 7% to 10% of macromolecular mouldproof and anti-microbial polymer material and 0.5% to 2% of color masterbatch, and the macromolecular mouldproof and anti-microbial polymer material is a polyamine and guanidine salt polymer. The polyamine and guanidine salt polymer with a certain proportion is mixed in polypropylene or polyethylene to serve as the macromolecular mouldproof and anti-microbial polymer material. The polymer material has excellent heat resistance, the decomposition temperature of the polymer material is 360 DEG C or above, and the polymer material cannot be decomposed during common polymer processing. In addition, high reaction activity is achieved, the polymer material can be combined with polyolefin resin conveniently through fusion, a solution and solid phase grafting, and the functions of resisting bacteria, being dyeable and resisting static electricity are achieved. The mould preventing, bacterium inhibiting and virus resisting plastic product is safe to the human body and has a long antibacterial property, the antibacterial rate of the plastic product to staphylococcus aureus and escherichia coli is higher than 99%, and the common cold virus resisting effective rate is larger than 99%.
Description
Technical field
The present invention relates to field of plastic products, particularly relate to a kind of fungus-resistant antiviral plastic and
Preparation method.
Background technology
At present, plastic conduit and other plastic in use, longer with water contact after, easily grow
Endophytic bacteria, produces satiny feel, causes serious germ contamination.Existing plastic antimicrobial technology is typically adopted
With nano-antibacterial and silver-ion antibiotic, actually metal ion is added to and in plastic, reach certain
Anti-microbial property.These methods can produce certain antibacterial effect, but there is the subject matter of two aspects:
1, anti-microbial property index is on the low side, and typically between 70%～90%, and the speed of growing of antibacterial is with simply
Fission mode is carried out, so, the antibacterial of residual can increase rapidly at short notice.2, due to add it is
Metal ion, cannot be perfectly combined with plastics, and these metal ions separate out due to the effect of water, causes anti-
Bacterium effect is progressively gone down and human body is caused metallic pollution.This formula is that the macromolecule antimildew and antibacterial added resists
Antiviral polymeric, can combine together completely with the raw material of plastic, and makes plastic itself become completely
Become antibacterial main body.Solve metal to add problem and antimildew and antibacterial effect and progressively go down problem.
Summary of the invention
The invention provides plastic of a kind of fungus-resistant antiviral and preparation method thereof, above-mentioned to solve
Technical problem.
In order to achieve the above object, the technical scheme is that and be achieved in that: a kind of fungus-resistant is disease-resistant
The plastic of poison, including the raw material of following percentage by weight: the polypropylene of 85%～92% or polyethylene,
The macromolecule antimildew and antibacterial polymeric material of 7%～10%, the color masterbatch of 0.5%～2%, macromolecule antimildew and antibacterial gathers
Laminate material is polyamine and guanidine salt polymer, and its feature structure is:
Wherein: n=2-20, m=2-300；Y is Cl-, Br-, NO3 -, HCO3 -Or H2PO4 -In one；
X is the C containing active group anhydride, isocyanates, epoxy or oxazoline5-C100Acyl group, amide groups, alkane
Base or amino group, Z is H or X.
Further, the plastic of this fungus-resistant antiviral includes the raw material of following percentage by weight:
The polypropylene of 90%～91.5% or polyethylene, the macromolecule antimildew and antibacterial polymeric material of 8%, 0.5%～2%
Color masterbatch.
Further, guanidinesalt is the guanidinesalt of mineral acid；Described polyamine be ethylenediamine, propane diamine, 1,6-oneself two
Amine, 1,10-certain herbaceous plants with big flowers diamidogen, hexamethylenetetramine, triethylenediamine, diethylenetriamine, N-ethoxy second
One or several combination in diamidogen, 3-dimethylaminopropylamine.
Further, the plastic of this fungus-resistant antiviral also includes the raw material of following percentage by weight:
Nano titanium oxide 5～8%, chitosan 5～8%, terpenic oil 2～5%, Eucalyptus oil 1～3%, Oleum Caryophylli 3～6%,
Barium sulfate 1～2%, dioctyl phthalate diallyl 2～5%, methyl methacrylate 1～3%, Borax 1～2%, adjacent
Phthalic acid fat 1～2%, peroxide acid tert-butyl 2～5%, propanediol polyoxypropylene 1～2%, polyoxy
Vinyl Ether 1～2%, one or several the combination in suberic acid 1～2%.
The preparation method of the plastic of a kind of above-mentioned fungus-resistant antiviral, comprises the following steps: (1) will
The raw material mix homogeneously of above-mentioned percentage by weight；
(2) raw material mixed in step (1) is preheated 2～3 hours in 80 DEG C～85 DEG C；
(3) it is heated to 200 DEG C～220 DEG C of machine-shapings by step (2) preheats complete raw material.
Compared with prior art, it is an advantage of the current invention that: in polypropylene or polyethylene, mix a definite proportion
The polyamine of example and guanidine salt polymer exist as macromolecule antimildew and antibacterial polymeric material, its molecular weight ranges
Between 300-50000, containing 1-5 activity double key, having excellent thermostability, its decomposition temperature is at 360 DEG C
Above, will not decompose in general polymerization thing is processed；The most also there is higher reactivity, can pass through
Melted, solution, solid phase grafting, be combined with vistanex easily, reaches antibacterial, can contaminate, antistatic
Function.The fungus-resistant antiviral plastic of the present invention is safe to the human body and has long-term antibacterial, and it is right
The antibiotic rate of staphylococcus aureus and colon bacillus is equal > 99%, anti-cold virus effective percentage is more than
99%.
Detailed description of the invention
The technical scheme of various embodiments of the present invention will be carried out clear, complete description below, it is clear that retouched
The embodiment stated is only a part of embodiment of the present invention rather than whole embodiments.Based on the present invention
In embodiment, those of ordinary skill in the art on the premise of not making creative work obtained by institute
There is other embodiments, broadly fall into the scope that the present invention is protected.
Below by specific embodiment, the present invention is described in further detail.
Embodiment 1
The embodiment of the present invention 1 relates to the plastic of a kind of fungus-resistant antiviral, including following weight percent
The raw material of ratio: the polypropylene of 85%～92% or polyethylene, the macromolecule antimildew and antibacterial polymeric material of 7%～10%
Material, the color masterbatch of 0.5%～2%, macromolecule antimildew and antibacterial polymeric material is polyamine and guanidine salt polymer, its
Feature structure is:
Wherein: n=2-20, m=2-300；Y is Cl-, Br-, NO3 -, HCO3 -Or H2PO4 -In one；
X is the C containing active group anhydride, isocyanates, epoxy or oxazoline5-C100Acyl group, amide groups, alkane
Base or amino group, Z is H or X.
In polypropylene or polyethylene, mix a certain proportion of polyamine prevent as macromolecule with guanidine salt polymer
Mould antibiotic polymer material, its molecular weight ranges is between 300-50000, containing 1-5 activity double key,
Having excellent thermostability, its decomposition temperature, more than 360 DEG C, will not be decomposed in general polymerization thing is processed；
The most also there is higher reactivity, can be by melted, solution, solid phase grafting, easily with polyene
Hydrocarbon resin combines, and reaches antibacterial, can contaminate, anlistatig function.The fungus-resistant antiviral plastics of the present invention
Goods are safe to the human body and have long-term antibacterial, and staphylococcus aureus and colon bacillus are resisted by it
Bacterium rate is equal > 99%, anti-cold virus effective percentage is more than 99%.Macromolecule antimildew and antibacterial polymeric material is by including
Antibacterial oligomer is polymerized in interior various ingredients, and component includes: the weight of the monomer of band unsaturated double-bond
Percentage ratio is 30%-99.5%, the percentage by weight of the antibacterial oligomer of band unsaturated double-bond is 0.01%-50%,
The percentage by weight of hydrophilic monomer is 0-10%, the percentage by weight of polymerization initiator is 0.01%-5.0% and
The percentage by weight of filler is 0-80%.
Preferably, guanidinesalt is the guanidinesalt of mineral acid；Described polyamine be ethylenediamine, propane diamine, 1,6-hexamethylene diamine,
1,10-certain herbaceous plants with big flowers diamidogen, hexamethylenetetramine, triethylenediamine, diethylenetriamine, N-hydroxyethyl-ethylenediamine,
One or several combination in 3-dimethylaminopropylamine.
The preparation method of the plastic of a kind of the present embodiment fungus-resistant antiviral, comprises the following steps: (1)
By the raw material mix homogeneously of above-mentioned percentage by weight；
(2) raw material mixed in step (1) is preheated 2～3 hours in 80 DEG C～85 DEG C；
(3) it is heated to 200 DEG C～220 DEG C of machine-shapings by step (2) preheats complete raw material.
Embodiment 2
The embodiment of the present invention 2 relates to the plastic of a kind of fungus-resistant antiviral, including following weight percent
The raw material of ratio: the polypropylene of 90%～91.5% or polyethylene, the macromolecule antimildew and antibacterial polymeric material of 8%,
The color masterbatch of 0.5%～2%, macromolecule antimildew and antibacterial polymeric material is polyamine and guanidine salt polymer, its feature
Structure is:
Wherein: n=2-20, m=2-300；Y is Cl-, Br-, NO3 -, HCO3 -Or H2PO4 -In one；
X is the C containing active group anhydride, isocyanates, epoxy or oxazoline5-C100Acyl group, amide groups, alkane
Base or amino group, Z is H or X.
In polypropylene or polyethylene, mix a certain proportion of polyamine prevent as macromolecule with guanidine salt polymer
Mould antibiotic polymer material, its molecular weight ranges is between 300-50000, containing 1-5 activity double key,
Having excellent thermostability, its decomposition temperature, more than 360 DEG C, will not be decomposed in general polymerization thing is processed；
The most also there is higher reactivity, can be by melted, solution, solid phase grafting, easily with polyene
Hydrocarbon resin combines, and reaches antibacterial, can contaminate, anlistatig function.The fungus-resistant antiviral plastics of the present invention
Goods are safe to the human body and have long-term antibacterial, and staphylococcus aureus and colon bacillus are resisted by it
Bacterium rate is equal > 99%, anti-cold virus effective percentage is more than 99%.Macromolecule antimildew and antibacterial polymeric material is by including
Antibacterial oligomer is polymerized in interior various ingredients, and component includes: the weight of the monomer of band unsaturated double-bond
Percentage ratio is 30%-99.5%, the percentage by weight of the antibacterial oligomer of band unsaturated double-bond is 0.01%-50%,
The percentage by weight of hydrophilic monomer is 0-10%, the percentage by weight of polymerization initiator is 0.01%-5.0% and
The percentage by weight of filler is 0-80%.
The preparation method of the plastic of a kind of the present embodiment fungus-resistant antiviral, comprises the following steps: (1)
By the raw material mix homogeneously of above-mentioned percentage by weight；
(2) raw material mixed in step (1) is preheated 2～3 hours in 80 DEG C～85 DEG C；
(3) it is heated to 200 DEG C～220 DEG C of machine-shapings by step (2) preheats complete raw material.
Embodiment 3
The embodiment of the present invention 3 relates to the plastic of a kind of fungus-resistant antiviral, including following weight percent
The raw material of ratio: the polypropylene of 85%～92% or polyethylene, the macromolecule antimildew and antibacterial polymeric material of 7%～10%
Material, the color masterbatch of 0.5%～2%, macromolecule antimildew and antibacterial polymeric material is polyamine and guanidine salt polymer, its
Feature structure is:
Wherein: n=2-20, m=2-300；Y is Cl-, Br-, NO3 -, HCO3 -Or H2PO4 -In one；
X is the C containing active group anhydride, isocyanates, epoxy or oxazoline5-C100Acyl group, amide groups, alkane
Base or amino group, Z is H or X.
In polypropylene or polyethylene, mix a certain proportion of polyamine prevent as macromolecule with guanidine salt polymer
Mould antibiotic polymer material, its molecular weight ranges is between 300-50000, containing 1-5 activity double key,
Having excellent thermostability, its decomposition temperature, more than 360 DEG C, will not be decomposed in general polymerization thing is processed；
The most also there is higher reactivity, can be by melted, solution, solid phase grafting, easily with polyene
Hydrocarbon resin combines, and reaches antibacterial, can contaminate, anlistatig function.The fungus-resistant antiviral plastics of the present invention
Goods are safe to the human body and have long-term antibacterial, and staphylococcus aureus and colon bacillus are resisted by it
Bacterium rate is equal > 99%, anti-cold virus effective percentage is more than 99%.Macromolecule antimildew and antibacterial polymeric material is by including
Antibacterial oligomer is polymerized in interior various ingredients, and component includes: the weight of the monomer of band unsaturated double-bond
Percentage ratio is 30%-99.5%, the percentage by weight of the antibacterial oligomer of band unsaturated double-bond is 0.01%-50%,
The percentage by weight of hydrophilic monomer is 0-10%, the percentage by weight of polymerization initiator is 0.01%-5.0% and
The percentage by weight of filler is 0-80%.
Preferably, guanidinesalt is the guanidinesalt of mineral acid；Described polyamine be ethylenediamine, propane diamine, 1,6-hexamethylene diamine,
1,10-certain herbaceous plants with big flowers diamidogen, hexamethylenetetramine, triethylenediamine, diethylenetriamine, N-hydroxyethyl-ethylenediamine,
One or several combination in 3-dimethylaminopropylamine.
Preferably, the plastic of this fungus-resistant antiviral also includes the raw material of following percentage by weight: receive
Rice titanium dioxide 5～8%, chitosan 5～8%, terpenic oil 2～5%, Eucalyptus oil 1～3%, Oleum Caryophylli 3～6%,
Barium sulfate 1～2%, dioctyl phthalate diallyl 2～5%, methyl methacrylate 1～3%, Borax 1～2%, adjacent
Phthalic acid fat 1～2%, peroxide acid tert-butyl 2～5%, propanediol polyoxypropylene 1～2%, polyoxy
Vinyl Ether 1～2%, one or several the combination in suberic acid 1～2%.
The preparation method of the plastic of a kind of the present embodiment fungus-resistant antiviral, comprises the following steps: (1)
By the raw material mix homogeneously of above-mentioned percentage by weight；
(2) raw material mixed in step (1) is preheated 2～3 hours in 80 DEG C～85 DEG C；
(3) it is heated to 200 DEG C～220 DEG C of machine-shapings by step (2) preheats complete raw material.
The above, be only presently preferred embodiments of the present invention, not makees the present invention any pro forma
Limit, any those skilled in the art, in the range of without departing from technical solution of the present invention, when can profit
Make a little change with the technology contents of the disclosure above or be modified to the Equivalent embodiments of equivalent variations, as long as being
Without departing from the content of technical solution of the present invention, according to appointing that above example is made by the technical spirit of the present invention
What simple modification, equivalent variations and modification, all still fall within the range of technical solution of the present invention.
Claims (5)
1. the plastic of a fungus-resistant antiviral, it is characterised in that include following percentage by weight
Raw material: the polypropylene of 85%～92% or polyethylene, the macromolecule antimildew and antibacterial polymeric material of 7%～10%,
The color masterbatch of 0.5%～2%, described macromolecule antimildew and antibacterial polymeric material is polyamine and guanidine salt polymer, its
Feature structure is:
Wherein: n=2-20, m=2-300；Y is Cl-, Br-, NO3 -, HCO3 -Or H2PO4 -In one；
X is the C containing active group anhydride, isocyanates, epoxy or oxazoline5-C100Acyl group, amide groups, alkane
Base or amino group；Z is H or X.
2. the plastic of fungus-resistant antiviral as claimed in claim 1, it is characterised in that: this mildew-resistant
The plastic of inhibitory anti-virus includes the raw material of following percentage by weight: the polypropylene or poly-of 90%～91.5%
Ethylene, the macromolecule antimildew and antibacterial polymeric material of 8%, the color masterbatch of 0.5%～2%.
3. the plastic of fungus-resistant antiviral as claimed in claim 1, it is characterised in that: described guanidine
Salt is the guanidinesalt of mineral acid；Described polyamine be ethylenediamine, propane diamine, 1,6-hexamethylene diamine, 1,10-certain herbaceous plants with big flowers diamidogen,
Hexamethylenetetramine, triethylenediamine, diethylenetriamine, N-hydroxyethyl-ethylenediamine, 3-dimethylamino
One or several combination in propylamine.
4. the plastic of fungus-resistant antiviral as claimed in claim 1, it is characterised in that: this mildew-resistant
The plastic of inhibitory anti-virus also includes the raw material of following percentage by weight: nano titanium oxide 5～8%,
Chitosan 5～8%, terpenic oil 2～5%, Eucalyptus oil 1～3%, Oleum Caryophylli 3～6%, barium sulfate 1～2%, two
Formic acid diallyl 2～5%, methyl methacrylate 1～3%, Borax 1～2%, phthalic acid fat 1～2%,
Peroxide acid tert-butyl 2～5%, propanediol polyoxypropylene 1～2%, polyoxyethylene ether 1～2%, pungent two
One or several combination in acid 1～2%.
5. the plastic of the fungus-resistant antiviral as described in Claims 1 to 4 is arbitrary, it is characterised in that:
Comprise the following steps: (1) is by the raw material mix homogeneously of above-mentioned percentage by weight；
(2) raw material mixed in step (1) is preheated 2～3 hours in 80 DEG C～85 DEG C；
(3) it is heated to 200 DEG C～220 DEG C of machine-shapings by step (2) preheats complete raw material.
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| CN201610304823.2A CN105837940A (en) | 2016-05-09 | 2016-05-09 | Mould preventing, bacterium inhibiting and virus resisting plastic product and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106519401A (en) * | 2016-12-20 | 2017-03-22 | 湖州健塑塑业科技有限公司 | Mold-proof antibacterial and antiviral PE pipeline and preparation method thereof |
| CN106589611A (en) * | 2016-12-20 | 2017-04-26 | 湖州健塑塑业科技有限公司 | Mildew-proof antibacterial antiviral PPR pipeline and preparation method thereof |
| CN106751670A (en) * | 2016-12-20 | 2017-05-31 | 湖州健塑塑业科技有限公司 | Antiviral PC cups of a kind of fungus-resistant and preparation method thereof |
| CN109456537A (en) * | 2018-11-26 | 2019-03-12 | 铜陵熙成塑料制品有限公司 | A kind of antimildew and antibacterial bag material |
| CN112142929A (en) * | 2020-09-16 | 2020-12-29 | 邓天生 | Antibacterial polyethylene material and preparation method thereof |
| FR3123359A1 (en) * | 2021-05-31 | 2022-12-02 | Institut National Des Sciences Et Industries Du Vivant Et De L'environnement | MASTERBATCH WITH BACTERIOSTATIC OR BACTERICIDAL ACTIVITY, METHOD FOR PREPARING IT AND ITS USES |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1569923A (en) * | 2003-07-23 | 2005-01-26 | 上海塑杰科技有限公司 | Polyamine guanidine salt copolymer and its uses in antibiotic polyester and polyamide materials |
| CN101812160A (en) * | 2009-02-23 | 2010-08-25 | 上海富元塑胶科技有限公司 | Polyolefin functional master batch, preparation method thereof and use thereof |
| CN105524355A (en) * | 2016-01-05 | 2016-04-27 | 杭州旺平科技有限公司 | PP-R self-cleaning kitchen and bath pipe and preparation method thereof |
-
2016
- 2016-05-09 CN CN201610304823.2A patent/CN105837940A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1569923A (en) * | 2003-07-23 | 2005-01-26 | 上海塑杰科技有限公司 | Polyamine guanidine salt copolymer and its uses in antibiotic polyester and polyamide materials |
| CN101812160A (en) * | 2009-02-23 | 2010-08-25 | 上海富元塑胶科技有限公司 | Polyolefin functional master batch, preparation method thereof and use thereof |
| CN105524355A (en) * | 2016-01-05 | 2016-04-27 | 杭州旺平科技有限公司 | PP-R self-cleaning kitchen and bath pipe and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106519401A (en) * | 2016-12-20 | 2017-03-22 | 湖州健塑塑业科技有限公司 | Mold-proof antibacterial and antiviral PE pipeline and preparation method thereof |
| CN106589611A (en) * | 2016-12-20 | 2017-04-26 | 湖州健塑塑业科技有限公司 | Mildew-proof antibacterial antiviral PPR pipeline and preparation method thereof |
| CN106751670A (en) * | 2016-12-20 | 2017-05-31 | 湖州健塑塑业科技有限公司 | Antiviral PC cups of a kind of fungus-resistant and preparation method thereof |
| CN109456537A (en) * | 2018-11-26 | 2019-03-12 | 铜陵熙成塑料制品有限公司 | A kind of antimildew and antibacterial bag material |
| CN112142929A (en) * | 2020-09-16 | 2020-12-29 | 邓天生 | Antibacterial polyethylene material and preparation method thereof |
| FR3123359A1 (en) * | 2021-05-31 | 2022-12-02 | Institut National Des Sciences Et Industries Du Vivant Et De L'environnement | MASTERBATCH WITH BACTERIOSTATIC OR BACTERICIDAL ACTIVITY, METHOD FOR PREPARING IT AND ITS USES |
| WO2022254138A1 (en) * | 2021-05-31 | 2022-12-08 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Masterbatch with bacteriostatic or bactericidal activity, production method thereof, and uses of same |
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