CN106751670A - Antiviral PC cups of a kind of fungus-resistant and preparation method thereof - Google Patents
Antiviral PC cups of a kind of fungus-resistant and preparation method thereof Download PDFInfo
- Publication number
- CN106751670A CN106751670A CN201611181650.6A CN201611181650A CN106751670A CN 106751670 A CN106751670 A CN 106751670A CN 201611181650 A CN201611181650 A CN 201611181650A CN 106751670 A CN106751670 A CN 106751670A
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- Prior art keywords
- antiviral
- fungus
- resistant
- cups
- antibacterial
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
Abstract
The present invention relates to antiviral PC cups of a kind of fungus-resistant and preparation method thereof, including following percentage by weight raw material：85%~92% makrolon, 7%~10% macromolecule antimildew and antibacterial polymeric material, 0.5%~2% color masterbatch, macromolecule antimildew and antibacterial polymeric material is polyamine and guanidine salt polymer.Mix a certain proportion of polyamine in makrolon with guanidine salt polymer as macromolecule antimildew and antibacterial polymeric material, it has excellent heat resistance, its decomposition temperature will not be decomposed more than 360 DEG C in the processing of general polymerization thing；In addition also have reactivity higher, can easily be combined with vistanex by melting, solution, solid phase grafting, reach antibacterial, can contaminate, anlistatig function.The antiviral PC cups of fungus-resistant of the invention are safe to the human body and with long-term antibacterial, and its antibiotic rate to staphylococcus aureus and ETEC is equal>99%, anti-common cold virus is efficient to be more than 99%.
Description
Technical field
The present invention relates to cup field, more particularly to a kind of antiviral PC cups of fungus-resistant and preparation method thereof.
Background technology
At present, in use, after water contact more long, easy breed bacteria produces satiny feel to cup, causes tight
The germ contamination of weight.Existing antimicrobial technology typically uses nano-antibacterial and silver-ion antibiotic, actually adds metal ion
It is added in cup and reaches certain anti-microbial property.These methods can produce certain antibacterial effect, but there are two aspects
Subject matter：1st, anti-microbial property index is relatively low, and typically between 70%~90%, and the speed of growing of bacterium is simply to split
What change mode was carried out, so, the bacterium of residual can increase rapidly in a short time.2nd, it is metal ion due to what is added, with water
Cup cannot be perfectly combined, and these metal ions are separated out due to the effect of water, cause antibacterial action progressively to go down and to human body
Cause metallic pollution..
The content of the invention
The invention provides antiviral PC cups of a kind of fungus-resistant and preparation method thereof, asked with solving above-mentioned technology
Topic.
In order to achieve the above object, the technical proposal of the invention is realized in this way：A kind of antiviral PC of fungus-resistant
Cup, including following percentage by weight raw material：85%~92% makrolon, 7%~12% macromolecule antimildew and antibacterial
Polymeric material, 0.001%~2% color masterbatch, macromolecule antimildew and antibacterial polymeric material be polyamine and guanidine salt polymer, its
Feature structure is：
Wherein：N=2-20, m=2-300；Y is Cl-, Br-, NO3 -, HCO3 -Or H2PO4 -In one kind；X is containing active group
The C of group's acid anhydrides, isocyanates, epoxy or oxazoline5-C100Acyl group, amide groups, alkyl or amino group, Z is H or X.
Further, the antiviral PC cups of the fungus-resistant include the raw material of following percentage by weight：87.999%
Makrolon, 12% macromolecule antimildew and antibacterial polymeric material, 0.001% color masterbatch.
Further, guanidinesalt is the guanidinesalt of inorganic acid；The polyamine be ethylenediamine, propane diamine, 1,6- hexamethylene diamines, 1,
10- certain herbaceous plants with big flowers diamines, hexamethylenetetramine, triethylenediamine, diethylenetriamine, N-hydroxyethyl-ethylenediamine, 3- dimethylaminos third
One or several combination in amine.
Further, the antiviral PC cups of the fungus-resistant also raw material including following percentage by weight：Nano-silica
Change titanium 5~8%, shitosan 5~8%, terpenic oil 2~5%, eucalyptus oil 1~3%, caryophyllus oil 3~6%, barium sulfate 1~2%,
Diformazan diallyl phthalate 2~5%, methyl methacrylate 1~3%, borax 1~2%, phthalic acid fat 1~2%, peroxide
Change butylene tert-butyl acrylate 2~5%, propanediol polyoxypropylene 1~2%, APEO 1~2%, in suberic acid 1~2% one
Plant or several combinations.
A kind of preparation method of the antiviral PC cups of above-mentioned fungus-resistant, comprises the following steps：(1) by above-mentioned weight hundred
The raw material of ratio is divided to be well mixed；
(2) raw material that will be mixed in step (1) is preheated 2~3 hours in 80 DEG C~85 DEG C；
(3) raw material that preheating in step (2) is finished is heated to 200 DEG C~220 DEG C machine-shapings.
Compared with prior art, the advantage of the invention is that：Mix a certain proportion of polyamine and guanidine in makrolon
Used as macromolecule antimildew and antibacterial polymeric material, its molecular weight ranges contains 1-5 work to salt polymer between 300-50000
Property double bond, with excellent heat resistance, its decomposition temperature more than 360 DEG C, general polymerization thing processing in will not decompose；In addition
Also there is reactivity higher, can easily be combined with vistanex by melting, solution, solid phase grafting, reach anti-
Bacterium, can contaminate, anlistatig function.The antiviral PC cups of fungus-resistant of the invention are safe to the human body and with long-term antibacterial,
Its antibiotic rate to staphylococcus aureus and ETEC is equal>99%, anti-common cold virus is efficient to be more than 99%.
Specific embodiment
Clear, complete description will be carried out to the technical scheme of various embodiments of the present invention below, it is clear that described implementation
Example is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is general
The resulting all other embodiment on the premise of creative work is not made of logical technical staff, belongs to the present invention and is protected
The scope of shield.
The present invention is described in further detail below by specific embodiment.
Embodiment 1
The embodiment of the present invention 1 is related to a kind of antiviral PC cups of fungus-resistant, including following percentage by weight raw material：
85%~92% makrolon, 7%~12% macromolecule antimildew and antibacterial polymeric material, 0.001%~2% color masterbatch,
Macromolecule antimildew and antibacterial polymeric material is polyamine and guanidine salt polymer, and its feature structure is：
Wherein：N=2-20, m=2-300；Y is Cl-, Br-, NO3 -, HCO3 -Or H2PO4 -In one kind；X is containing active group
The C of group's acid anhydrides, isocyanates, epoxy or oxazoline5-C100Acyl group, amide groups, alkyl or amino group, Z is H or X.
Mix a certain proportion of polyamine in makrolon with guanidine salt polymer as macromolecule antimildew and antibacterial polymer
Material, between 300-50000, containing 1-5 activity double key, with excellent heat resistance, it decomposes temperature to its molecular weight ranges
Degree will not be decomposed more than 360 DEG C in the processing of general polymerization thing；Also there is reactivity higher in addition, can be by molten
Melt, solution, solid phase grafting, easily combined with vistanex, reach antibacterial, can contaminate, anlistatig function.It is of the invention anti-
Mould inhibitory anti-virus PC cups are safe to the human body and with long-term antibacterial, and it is to staphylococcus aureus and ETEC
Antibiotic rate it is equal>99%, anti-common cold virus is efficient to be more than 99%.Macromolecule antimildew and antibacterial polymeric material is by neat including antibacterial
Polymers is polymerized in interior various ingredients, and component includes：The percentage by weight of the monomer with unsaturated double-bond is 30%-
99.5%th, the percentage by weight of the antibacterial oligomer with unsaturated double-bond is 0.01%-50%, the weight percent of hydrophilic monomer
Than the percentage by weight for 0-10%, polymerization initiator be 0.01%-5.0% and the percentage by weight of filler is 0-80%.
Preferably, guanidinesalt is the guanidinesalt of inorganic acid；The polyamine is ethylenediamine, propane diamine, 1,6- hexamethylene diamines, 1,10-
In certain herbaceous plants with big flowers diamines, hexamethylenetetramine, triethylenediamine, diethylenetriamine, N-hydroxyethyl-ethylenediamine, 3- dimethylaminopropylamines
One or several combination.
A kind of preparation method of the antiviral PC cups of the present embodiment fungus-resistant, comprises the following steps：(1) will be above-mentioned heavy
The raw material for measuring percentage is well mixed；
(2) raw material that will be mixed in step (1) is preheated 2~3 hours in 80 DEG C~85 DEG C；
(3) raw material that preheating in step (2) is finished is heated to 200 DEG C~220 DEG C machine-shapings.
Embodiment 2
The embodiment of the present invention 2 is related to a kind of antiviral PC cups of fungus-resistant, including following percentage by weight raw material：
87.999% makrolon, 12% macromolecule antimildew and antibacterial polymeric material, 0.001% color masterbatch, macromolecule is mould proof anti-
Bacterium polymeric material is polyamine and guanidine salt polymer, and its feature structure is：
Wherein：N=2-20, m=2-300；Y is Cl-, Br-, NO3 -, HCO3 -Or H2PO4 -In one kind；X is containing active group
The C of group's acid anhydrides, isocyanates, epoxy or oxazoline5-C100Acyl group, amide groups, alkyl or amino group, Z is H or X.
Mix a certain proportion of polyamine in makrolon with guanidine salt polymer as macromolecule antimildew and antibacterial polymer
Material, between 300-50000, containing 1-5 activity double key, with excellent heat resistance, it decomposes temperature to its molecular weight ranges
Degree will not be decomposed more than 360 DEG C in the processing of general polymerization thing；Also there is reactivity higher in addition, can be by molten
Melt, solution, solid phase grafting, easily combined with vistanex, reach antibacterial, can contaminate, anlistatig function.It is of the invention anti-
Mould inhibitory anti-virus PC cups are safe to the human body and with long-term antibacterial, and it is to staphylococcus aureus and ETEC
Antibiotic rate it is equal>99%, anti-common cold virus is efficient to be more than 99%.Macromolecule antimildew and antibacterial polymeric material is by neat including antibacterial
Polymers is polymerized in interior various ingredients, and component includes：The percentage by weight of the monomer with unsaturated double-bond is 30%-
99.5%th, the percentage by weight of the antibacterial oligomer with unsaturated double-bond is 0.01%-50%, the weight percent of hydrophilic monomer
Than the percentage by weight for 0-10%, polymerization initiator be 0.01%-5.0% and the percentage by weight of filler is 0-80%.
A kind of preparation method of the antiviral PC cups of the present embodiment fungus-resistant, comprises the following steps：(1) will be above-mentioned heavy
The raw material for measuring percentage is well mixed；
(2) raw material that will be mixed in step (1) is preheated 2~3 hours in 80 DEG C~85 DEG C；
(3) raw material that preheating in step (2) is finished is heated to 200 DEG C~220 DEG C machine-shapings.
Embodiment 3
The embodiment of the present invention 3 is related to a kind of antiviral PC cups of fungus-resistant, including following percentage by weight raw material：
85%~92% makrolon, 7%~12% macromolecule antimildew and antibacterial polymeric material, 0.001%~2% color masterbatch,
Macromolecule antimildew and antibacterial polymeric material is polyamine and guanidine salt polymer, and its feature structure is：
Wherein：N=2-20, m=2-300；Y is Cl-, Br-, NO3 -, HCO3 -Or H2PO4 -In one kind；X is containing active group
The C of group's acid anhydrides, isocyanates, epoxy or oxazoline5-C100Acyl group, amide groups, alkyl or amino group, Z is H or X.
Mix a certain proportion of polyamine in makrolon with guanidine salt polymer as macromolecule antimildew and antibacterial polymer
Material, between 300-50000, containing 1-5 activity double key, with excellent heat resistance, it decomposes temperature to its molecular weight ranges
Degree will not be decomposed more than 360 DEG C in the processing of general polymerization thing；Also there is reactivity higher in addition, can be by molten
Melt, solution, solid phase grafting, easily combined with vistanex, reach antibacterial, can contaminate, anlistatig function.It is of the invention anti-
Mould inhibitory anti-virus PC cups are safe to the human body and with long-term antibacterial, and it is to staphylococcus aureus and ETEC
Antibiotic rate it is equal>99%, anti-common cold virus is efficient to be more than 99%.Macromolecule antimildew and antibacterial polymeric material is by neat including antibacterial
Polymers is polymerized in interior various ingredients, and component includes：The percentage by weight of the monomer with unsaturated double-bond is 30%-
99.5%th, the percentage by weight of the antibacterial oligomer with unsaturated double-bond is 0.01%-50%, the weight percent of hydrophilic monomer
Than the percentage by weight for 0-10%, polymerization initiator be 0.01%-5.0% and the percentage by weight of filler is 0-80%.
Preferably, guanidinesalt is the guanidinesalt of inorganic acid；The polyamine is ethylenediamine, propane diamine, 1,6- hexamethylene diamines, 1,10-
In certain herbaceous plants with big flowers diamines, hexamethylenetetramine, triethylenediamine, diethylenetriamine, N-hydroxyethyl-ethylenediamine, 3- dimethylaminopropylamines
One or several combination.
Preferably, the antiviral PC cups of the fungus-resistant also raw material including following percentage by weight：Nanometer titanium dioxide
Titanium 5~8%, shitosan 5~8%, terpenic oil 2~5%, eucalyptus oil 1~3%, caryophyllus oil 3~6%, barium sulfate 1~2%, two
Formic acid diallyl 2~5%, methyl methacrylate 1~3%, borax 1~2%, phthalic acid fat 1~2%, peroxidating
Butylene tert-butyl acrylate 2~5%, propanediol polyoxypropylene 1~2%, APEO 1~2%, the one kind in suberic acid 1~2%
Or several combinations.
A kind of preparation method of the antiviral PC cups of the present embodiment fungus-resistant, comprises the following steps：(1) will be above-mentioned heavy
The raw material for measuring percentage is well mixed；
(2) raw material that will be mixed in step (1) is preheated 2~3 hours in 80 DEG C~85 DEG C；
(3) raw material that preheating in step (2) is finished is heated to 200 DEG C~220 DEG C machine-shapings.
The above, is only presently preferred embodiments of the present invention, and any formal limitation is not made to the present invention, is appointed
What those skilled in the art, without departing from the scope of the present invention, when in the technology using the disclosure above
Appearance is made a little change or is modified to the Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention,
Any simple modification, equivalent variations and the modification made to above example according to technical spirit of the invention, still fall within this
In the range of inventive technique scheme.
Claims (5)
1. a kind of antiviral PC cups of fungus-resistant, it is characterised in that the raw material including following percentage by weight：85%~
92% makrolon, 7%~12% macromolecule antimildew and antibacterial polymeric material, 0.001%~2% color masterbatch, the height
Molecule antimildew and antibacterial polymeric material is polyamine and guanidine salt polymer, and its feature structure is：
Wherein：N=2-20, m=2-300；Y is Cl-, Br-, NO3 -, HCO3 -Or H2PO4 -In one kind；X is containing active group acid
The C of acid anhydride, isocyanates, epoxy or oxazoline5-C100Acyl group, amide groups, alkyl or amino group；Z is H or X.
2. antiviral PC cups of fungus-resistant as claimed in claim 1, it is characterised in that：The antiviral PC of the fungus-resistant
Cup includes the raw material of following percentage by weight：87.999% makrolon, 12% macromolecule antimildew and antibacterial polymeric material
Material, 0.001% color masterbatch.
3. antiviral PC cups of fungus-resistant as claimed in claim 1, it is characterised in that：The guanidinesalt is the guanidine of inorganic acid
Salt；The polyamine is ethylenediamine, propane diamine, 1,6- hexamethylene diamines, 1,10- certain herbaceous plants with big flowers diamines, hexamethylenetetramine, triethylene two
One or several combination in amine, diethylenetriamine, N-hydroxyethyl-ethylenediamine, 3- dimethylaminopropylamines.
4. antiviral PC cups of fungus-resistant as claimed in claim 1, it is characterised in that：The antiviral PC of the fungus-resistant
The cup also raw material including following percentage by weight：Nano titanium oxide 5~8%, shitosan 5~8%, terpenic oil 2~5%,
Eucalyptus oil 1~3%, caryophyllus oil 3~6%, barium sulfate 1~2%, diformazan diallyl phthalate 2~5%, methyl methacrylate 1~
3%, borax 1~2%, phthalic acid fat 1~2%, peroxide acid tert-butyl 2~5%, propanediol polyoxypropylene 1~
2%, APEO 1~2%, one or several the combination in suberic acid 1~2%.
5. the antiviral PC cups of fungus-resistant as described in Claims 1 to 4 is any, it is characterised in that：Comprise the following steps：
(1) raw material of above-mentioned percentage by weight is well mixed；
(2) raw material that will be mixed in step (1) is preheated 2~3 hours in 80 DEG C~85 DEG C；
(3) raw material that preheating in step (2) is finished is heated to 200 DEG C~220 DEG C machine-shapings.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611181650.6A CN106751670A (en) | 2016-12-20 | 2016-12-20 | Antiviral PC cups of a kind of fungus-resistant and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611181650.6A CN106751670A (en) | 2016-12-20 | 2016-12-20 | Antiviral PC cups of a kind of fungus-resistant and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN106751670A true CN106751670A (en) | 2017-05-31 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611181650.6A Pending CN106751670A (en) | 2016-12-20 | 2016-12-20 | Antiviral PC cups of a kind of fungus-resistant and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112778739A (en) * | 2021-01-07 | 2021-05-11 | 华东理工大学 | Concentrated long-acting antibacterial anti-fouling PC master batch and preparation method thereof |
| CN112852043A (en) * | 2021-01-11 | 2021-05-28 | 华东理工大学 | Concentrated long-acting antibacterial anti-fouling polyolefin master batch and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1454932A (en) * | 2002-04-29 | 2003-11-12 | 上海理维纳米新材料有限公司 | Food-level antibacterial polycarbonate plastic and manufacturing method thereof |
| CN101812160A (en) * | 2009-02-23 | 2010-08-25 | 上海富元塑胶科技有限公司 | Polyolefin functional master batch, preparation method thereof and use thereof |
| CN105837940A (en) * | 2016-05-09 | 2016-08-10 | 湖州健塑塑业科技有限公司 | Mould preventing, bacterium inhibiting and virus resisting plastic product and preparation method thereof |
-
2016
- 2016-12-20 CN CN201611181650.6A patent/CN106751670A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1454932A (en) * | 2002-04-29 | 2003-11-12 | 上海理维纳米新材料有限公司 | Food-level antibacterial polycarbonate plastic and manufacturing method thereof |
| CN101812160A (en) * | 2009-02-23 | 2010-08-25 | 上海富元塑胶科技有限公司 | Polyolefin functional master batch, preparation method thereof and use thereof |
| CN105837940A (en) * | 2016-05-09 | 2016-08-10 | 湖州健塑塑业科技有限公司 | Mould preventing, bacterium inhibiting and virus resisting plastic product and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112778739A (en) * | 2021-01-07 | 2021-05-11 | 华东理工大学 | Concentrated long-acting antibacterial anti-fouling PC master batch and preparation method thereof |
| CN112852043A (en) * | 2021-01-11 | 2021-05-28 | 华东理工大学 | Concentrated long-acting antibacterial anti-fouling polyolefin master batch and preparation method thereof |
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Application publication date: 20170531 |