CN105837179B - 一种硅铝陶瓷质研磨石及其制备方法 - Google Patents

一种硅铝陶瓷质研磨石及其制备方法 Download PDF

Info

Publication number
CN105837179B
CN105837179B CN201610173188.9A CN201610173188A CN105837179B CN 105837179 B CN105837179 B CN 105837179B CN 201610173188 A CN201610173188 A CN 201610173188A CN 105837179 B CN105837179 B CN 105837179B
Authority
CN
China
Prior art keywords
parts
sio
grinding stone
silica
alumina ceramic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201610173188.9A
Other languages
English (en)
Other versions
CN105837179A (zh
Inventor
沈丽华
王林丹
沈川江
吕阿琴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huzhou Hua Tong Grinder Manufacturing Co Ltd
Original Assignee
Huzhou Hua Tong Grinder Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huzhou Hua Tong Grinder Manufacturing Co Ltd filed Critical Huzhou Hua Tong Grinder Manufacturing Co Ltd
Priority to CN201610173188.9A priority Critical patent/CN105837179B/zh
Publication of CN105837179A publication Critical patent/CN105837179A/zh
Application granted granted Critical
Publication of CN105837179B publication Critical patent/CN105837179B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B24—GRINDING; POLISHING
    • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/6303—Inorganic additives
    • C04B35/6316—Binders based on silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3201—Alkali metal oxides or oxide-forming salts thereof
    • C04B2235/3203—Lithium oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74—Physical characteristics
    • C04B2235/77—Density
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

本发明公开了一种硅铝陶瓷质研磨石，其重量组成为Al2O3 20‑30份、SiO2 20‑30份、云石25‑35份、稀土金属氧化物12‑18份、K2O 4‑6份、Na2SiO3 3‑4份、TiCl4 0.4‑0.6份；使用Na2SiO3水溶液与TiCl4反应形成一种均匀的胶体，替代传统的高分子材料作为粘结剂，减少了制备过程中脱脂（脱粘结剂）步骤；由于使用Na2SiO3与TiCl4水解物形成钛硅酸盐胶体作为无机粘结剂，使用研磨石内部结构更加致密，同时加入稀土金属氧化物，这样提高了产品的抗折强度，抗折强度提高了5‑10MPa，提高了研磨石密度，密度为2.5‑2.8g/cm3，能够用于硬金属的切削加工，使得构件粗磨去毛刺功能大大增强耐磨度比常规磨石提高20%以上。

Description

一种硅铝陶瓷质研磨石及其制备方法
技术领域
本发明涉陶瓷制备技术领域，具体地说是一种硅铝陶瓷质研磨石及其制备方法。
背景技术
磨削既是一种古老的加工方法，又是一个崭新的技术领域。它在世界范围内被广泛使用，尤其在机械制造业的精密加工方面,磨削对许多部门产生着不可忽视的影响。
我国是世界上最早应用磨削方法的国家,进入21世纪后,磨料生产进入一个迅速发展的时期,产量增长很快,这一增长标志着机械制造业中精密加工部分的增加,但也反映出磨料的非磨削应用比例的大幅度增加。这主要是用于国防及制造精细陶瓷而使用的Al2O3和SiC微粉,其用量已达总产的40％。
目前市场上，针对零件表面处理的研磨抛光材料主要有棕刚玉(白刚玉)材质的研磨石、树脂材质的塑胶研磨石、高铝瓷(高频瓷)抛光石、振动抛光钢珠、各类研磨剂、各类光亮剂等，这些研磨抛光材料的主要功能如下表所示：
研磨介质包括研磨石、抛光石、研磨剂、光泽剂等研磨抛光材料，每种材料都有自己的应用范围，如塑胶研磨石用于材质较软的材料，如铝、锌、铜、塑料等；陶瓷类研磨石用于材质较硬的材料，如铁、不锈钢、白铁、钢材等；抛光材质为铁的零件，需要用到铁光泽剂，抛光材质为铜的零件，需要用到铜光泽剂，手工具切削剂用于各类扳手、套筒、批咀去黑膜、去氧化皮，如果用于其他零件，将可能会腐蚀、破坏零件。
陶瓷研磨石主要用于铝合金、锌合金、铜、树脂(塑料)等材质较软的产品表面抛光，电镀前细磨，常用于家私五金(如拉手、锁具等)及箱包(如皮带扣、箱包扣、鞋扣等)，主要有园形、三角形、斜三角形、园柱形、斜园柱形。
陶瓷研磨石主要组成有氧化铝、氧化锆、氧化镁、氧化钙、氧化硅、氧化钛、氧化铁的氧化物类陶瓷；诸如氮化铝、氮化硅、氮化钛的氮化物类陶瓷；诸如碳化硅、碳化钛、碳化钨的碳化物类陶瓷；诸如硼化锆、硼化钛的硼化物类陶瓷等。
作为陶瓷研磨石粘结剂，例如，可以为聚乙烯、聚丙烯、乙烯-醋酸乙烯共聚物等聚烯烃；聚甲基丙烯酸甲酯、聚甲基丙烯酸丁酯等丙烯酸类树脂；聚苯乙烯等苯乙烯类树脂；聚氯乙烯、聚偏氯乙烯、聚酰胺、聚对苯二甲酸乙二酯、聚对苯二甲酸丁二酯等聚酯；聚醚；聚乙烯醇；它们的共聚物等各种树脂；各种蜡；石蜡；高级脂肪酸(例如硬脂酸)；高级醇；高级脂肪酸酯；高级脂肪酸酰胺等各种有机粘结剂。
使用高分子材料作为粘结剂，这就要求对成型实体进行脱脂处理(脱粘结剂处理)，一般是加热成型体，从而从成型体中除去粘结剂。而且使用高分子材料作粘结剂，成型产品表面粗糙度大，研磨力不高，长期使用研磨力下降；并且产品硬度低，密度低，难以用于加工硬金属。
发明内容
本发明目的在于提供一种密度高、切削效率高、适用于加工硬金属的研磨石及其制造方法。
实现上述发明目的技术方案：
一种硅铝陶瓷质研磨石，其重量组成为Al2O3 20-30份、SiO220-30份、云石25-35份、稀土金属氧化物12-18份、K2O 4-6份、Na2SiO3 3-4份、TiCl4 0.4-0.6份；
其制备步骤如下：
(1)根据配比进行计量称重；
(2)混料，将Al2O3、SiO220-30、云石、稀土金属氧化物、K2O通过搅拌和研磨混合均匀
(3)Na2SiO3和TiCl4加入，先将Na2SiO3配成重量浓度为5-10％水溶液，逐步加入TiCl4，加入过程中保持搅拌，形成一种均匀体系；
(4)将步骤2和步骤3的物料混合在一起，加水搅拌混合均匀；
(5)根据产品的要求，选择相应的模具，进行压铸成型；
(6)将压铸成型的产品烘干；
(7)将烘干后产品烧结成型。
其优选的配比为：Al2O3 25份、SiO225份、云石30份、稀土金属氧化物15份、K2O 5份、Na2SiO3 4份、TiCl4 0.5份。
稀土金属氧化物是指氧化钪、氧化铈、氧化钆、氧化钇等。
压铸成型压力为300MPa-400MPa。
烘干温度为300-350℃。
烧结成型温度1280℃-1350℃。
本发明的特点及效果
使用Na2SiO3水溶液与TiCl4反应形成一种均匀的胶体，替代传统的高分子材料作为粘结剂，减少了制备过程中脱脂(脱粘结剂)步骤；由于使用无机粘结剂，使用研磨石内部结构更加致密，Na2SiO3与TiCl4水解物形成钛硅酸盐胶体，提高了产品的抗折强度，抗折强度提高了5-10MPa，由于使用了稀土金属氧化物，降低了产品密度，密度为2.5-2.8g/cm3，能够用于硬金属的切削加工，提高切削效率15-20％。
具体实施方式
下面结合实施例进一步描述本发明，但并不限制本发明的保护范围。
实施例1
按总重量为20kg，组成为Al2O3 25份、SiO225份、云石30份、稀土金属氧化物15份、K2O 5份、Na2SiO3 4份、TiCl4 0.5份分别计量称重；将称量好的Al2O3、SiO2、云石、稀土金属氧化物、K2O搅拌后，再研磨混合均匀；
粘结剂钛硅酸盐均匀盐的制备：先将Na2SiO3配成重量浓度为5％溶液，逐步加入TiCl4，加入过程中保持搅拌，形成一种均匀体系。
将研磨均匀的物料和上步制备的均匀胶体混合在一起，加水搅拌混合均匀；
选择底面直径5cm，高度为10cm模具进行压铸成型，压力为350MPa；
将压铸成型的产品在300℃烘干；
将烘干后产品在1450℃烧结成型。
制备产品抗折强度为170MPa，密度为2.8g/cm3，用于不锈钢等硬金属切削，切削效率比用高分子材料作粘结剂的高20％。
实施例2
按总重量为20kg，组成为Al2O3 30份、SiO220份、云石30份、稀土金属氧化物15份、K2O 5份、Na2SiO3 4份、TiCl4 0.5份分别计量称重；将称量好的Al2O3、SiO2、云石、稀土金属氧化物、K2O搅拌后，再研磨混合均匀；
粘结剂钛硅酸盐均匀盐的制备：先将Na2SiO3配成重量浓度为8％溶液，逐步加入TiCl4，加入过程中保持搅拌，形成一种均匀体系。
将研磨均匀的物料和上步制备的均匀胶体混合在一起，加水搅拌混合均匀；
选择底面直径10cm，高度为20cm模具进行压铸成型，压力为400MPa；
将压铸成型的产品在350℃烘干；
将烘干后产品在1500℃烧结成型。
制备产品抗折强度为165MPa，密度为2.6g/cm3，用于不锈钢等硬金属切削，切削效率比用高分子材料作粘结剂的高15％。

Claims (6)

1.一种硅铝陶瓷质研磨石，其重量组成为Al2O3 20-30份、SiO220-30份、云石25-35份、稀土金属氧化物12-18份、K2O 4-6份、Na2SiO3 3-4份、TiCl4 0.4-0.6份；
其制备步骤如下：
（1）根据配比进行计量称重；
（2）混料，将Al2O3、SiO220-30、云石、稀土金属氧化物、K2O通过搅拌和研磨混合均匀
（3）Na2SiO3和TiCl4 加入，先将Na2SiO3配成重量浓度为5-10%水溶液，逐步加入TiCl4，加入过程中保持搅拌，形成一种均匀体系；
（4）将步骤2和步骤3的物料混合在一起，加水搅拌混合均匀；
（5）根据产品的要求，选择相应的模具，进行压铸成型；
（6）将压铸成型的产品烘干；
（7）将烘干后产品烧结成型。
2.根据权利要求1硅铝陶瓷质研磨石，其特征为：Al2O3 25份、SiO225份、云石30份、稀土金属氧化物15份、K2O 5份、Na2SiO3 4份、TiCl4 0.5份。
3.根据权利要求1硅铝陶瓷质研磨石，其特征在于稀土金属氧化物是指氧化钪、氧化铈、氧化钆、氧化钇中的一种或几种。
4.根据权利要求1硅铝陶瓷质研磨石，其特征在于压铸成型压力为300MPa-400MPa。
5.根据权利要求1硅铝陶瓷质研磨石，其特征在于烘干温度为300-350℃。
6.根据权利要求1硅铝陶瓷质研磨石，其特征在于烧结成型温度1280°C-1350°C。
CN201610173188.9A 2016-03-24 2016-03-24 一种硅铝陶瓷质研磨石及其制备方法 Active CN105837179B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610173188.9A CN105837179B (zh) 2016-03-24 2016-03-24 一种硅铝陶瓷质研磨石及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610173188.9A CN105837179B (zh) 2016-03-24 2016-03-24 一种硅铝陶瓷质研磨石及其制备方法

Publications (2)

Publication Number Publication Date
CN105837179A CN105837179A (zh) 2016-08-10
CN105837179B true CN105837179B (zh) 2018-05-25

Family

ID=56584218

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610173188.9A Active CN105837179B (zh) 2016-03-24 2016-03-24 一种硅铝陶瓷质研磨石及其制备方法

Country Status (1)

Country Link
CN (1) CN105837179B (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110923719A (zh) * 2019-12-13 2020-03-27 湖州市漾西电化有限公司 一种铝合金的表面抛光工艺
CN112266768A (zh) * 2020-09-30 2021-01-26 湖州华通研磨制造有限公司 石墨烯改性高铝瓷磨料及其制备方法
CN112266767A (zh) * 2020-09-30 2021-01-26 湖州华通研磨制造有限公司 石墨烯改性高频瓷磨料及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104254429A (zh) * 2012-04-04 2014-12-31 3M创新有限公司 磨料颗粒、制备磨料颗粒的方法以及磨料制品

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002020994A (ja) * 2000-07-05 2002-01-23 Tomoji Tanaka 電磁波吸収体とその応用加工品

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104254429A (zh) * 2012-04-04 2014-12-31 3M创新有限公司 磨料颗粒、制备磨料颗粒的方法以及磨料制品

Also Published As

Publication number Publication date
CN105837179A (zh) 2016-08-10

Similar Documents

Publication Publication Date Title
CN101862226B (zh) 氧化锆陶瓷义齿坯体的制作方法
CN105837179B (zh) 一种硅铝陶瓷质研磨石及其制备方法
CN105252427B (zh) 一种硬质砂轮以及其制备方法
CN104149038B (zh) 一种陶瓷结合剂金刚石砂轮
JP2016523799A (ja) 射出成形組成物用バインダ
CN100532324C (zh) 粉红色钇锆结构陶瓷及其制备方法
CN104630529B (zh) B4C作为弥散强化添加剂的细晶WC‑Co硬质合金及其制备方法
CN104149037B (zh) 一种树脂陶瓷结合剂金刚石砂轮
CN108439996A (zh) 一种氮化硅-碳化硅复合材料材料及其制备方法
CN108383532A (zh) 一种致密化氮化硅陶瓷材料及其制备方法
CN102992778B (zh) 一种具有玉石质地的精密陶瓷及其制作方法
CN108789187A (zh) 一种青铜基金刚石砂轮及其制备方法
CN105837207B (zh) 一种锆铝陶瓷质研磨石及其制备方法
JPH01172270A (ja) 高強度立方晶窒化ホウ素焼結体
CN106078486A (zh) 一种用于加工钢质薄壁镀铬缸套的珩磨油石
CN104446582A (zh) 一种高耐磨性切削陶瓷及其制备方法
CN108789188A (zh) 一种超硬金刚石砂轮及其制备方法
CN110948407B (zh) 一种磨具的制备方法
US5366524A (en) Ceramic-bonded abrasive grinding tools
CN105837184B (zh) 特重铝镁陶瓷质研磨石
JP3910850B2 (ja) 導電性砥石及びその製造方法
CN106631035A (zh) 一种复合陶瓷及其制备方法
JP2980301B2 (ja) フェライト合金焼結体の製造方法
JP2820476B2 (ja) スリップキャスティング用鋳型およびスリップキャスティング方法
CN104341167B (zh) 镁渣耐磨耐火浇注料

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: A silicon aluminum ceramic grinding stone and its preparation method

Effective date of registration: 20221019

Granted publication date: 20180525

Pledgee: Nanxun Zhejiang rural commercial bank Limited by Share Ltd. and Fu sub branch

Pledgor: HUZHOU HUA TONG GRINDER MANUFACTURING Co.,Ltd.

Registration number: Y2022330002591

PE01 Entry into force of the registration of the contract for pledge of patent right