CN105834209A - Method for repairing heavy metal soil through sedum alfredii hance with assistance of alternating current electric field - Google Patents
Method for repairing heavy metal soil through sedum alfredii hance with assistance of alternating current electric field Download PDFInfo
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- CN105834209A CN105834209A CN201610196698.8A CN201610196698A CN105834209A CN 105834209 A CN105834209 A CN 105834209A CN 201610196698 A CN201610196698 A CN 201610196698A CN 105834209 A CN105834209 A CN 105834209A
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- sedum alfredii
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/10—Reclamation of contaminated soil microbiologically, biologically or by using enzymes
- B09C1/105—Reclamation of contaminated soil microbiologically, biologically or by using enzymes using fungi or plants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/08—Reclamation of contaminated soil chemically
- B09C1/085—Reclamation of contaminated soil chemically electrochemically, e.g. by electrokinetics
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C2101/00—In situ
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- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Soil Sciences (AREA)
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- General Health & Medical Sciences (AREA)
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- Molecular Biology (AREA)
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Abstract
The invention discloses a method for repairing heavy metal soil through sedum alfredii hance with the assistance of an alternating current electric field. The method comprises the steps that sedum alfredii hance plants are selected, an organic material serves as a base fertilizer, and the sedum alfredii hance plants are transplanted to the to-be-repaired soil; the organic material comprises, by weight, 100 parts of peat soil, 50-75 parts of soymeal slag, 15-20 parts of coconut coir, 10-15 parts of carbonized rice hulls and 12-16 parts of lees; and an alternating current is applied into the to-be-repaired soil, the voltage strength is 0.4-1.1 V/cm, the energizing time lasts for 15-20 days, and energizing is conducted for 5-8 h every day. According to the method for repairing the heavy metal soil through the sedum alfredii hance with the assistance of the alternating current electric field, the alternating current specific in voltage strength and energizing time is applied into the heavy metal soil and is matched with the specific organic material to assist the sedum alfredii hance plants in repairing the heavy metal soil, the migration efficiency of heavy metal in the soil can be significantly improved, and the amount of the heavy metal accumulated through the over-ground part of the plant can be significantly increased, so that the repairing efficiency of the heavy metal soil is improved.
Description
Technical field
The present invention relates to environmental pollution many technical tie-ups processing technology field, particularly relate to one and utilize AC field auxiliary southeast scape
The method of it remediating heavy metal soil.
Background technology
At present, soil pollution repair method main rationalization repairing method and biological restoration;Such as, traditional soil replacement method, change
Learn drip washing and biological restoration etc..Owing to having that cost is high, easily causing secondary pollution or destroy the defects such as Soil structure, these methods
It is difficult to the reparation of large area heavy-metal contaminated soil.
Phytoremediation, although environmental protection, but the rhizosphere to hyperaccumulative plant that most of heavy metal is difficult to orient moves,
Described, it is difficult to be continuously kept remediation efficiency.Single electromotion repairing technique method, although have remediation efficiency high, convenient post-treatment
Etc. advantage, but, owing to the method is restricted by the factor such as cost and operation, so the application prospect of its reality can be affected.
Electric repairing technique helps speed up the absorption of plant heavy metal element with combining of phytoremediation technology and is transported to plant
Thing overground part, thus realize the raising of remediation efficiency.DC electric field-plant combined repairing method, based on both sides electrode potential
Difference and produce voltage, by applying DC voltage in contaminated soil both sides, thus form electric-force gradient, make the weight in soil
Metal changes, and moves to electrode two ends under electric field action by the way of electromigration, EOF or electrophoresis, in this process
In, plant heavy metal absorbs, thus reaches the purpose of repairing polluted soil.
Application publication number is that the application for a patent for invention document of CN102125927A discloses and a kind of repaired by heavy-metal contaminated soil
Method, has the electrode of a pair insertion soil in the device that the method uses, its insertion depth takes 0.5 meter;To place in-between the electrodes
Plant root apply short interval time change electropolar direct current weak electric field excitation;Described short interval time is 3~5 hours;Institute
Stating direct current weak electric field is 0.1~1mA/cm2;And implement according to the following steps: (1) cultivation rehabilitation plant;(2) contaminated soil is measured
Middle heavy metal concentration, determines heavy metal pollution of soil region;(3) mark need repair soil region, construct reparation band with every
From band;(4) electrode and electrode control system are disposed;(5) plantation rehabilitation plant;(6) electric field is applied;(7) step (6) is repeated;
Until the heavy metal concentration in soil is down to claimed range;(8) isolation strip changes into repairing band, and former reparation band changes isolation strip into;Weight
Multiple step (5)~(7).The method applies feeble field switch polarity in root system of plant region, promotes heavy metal in soil pollutant
Desorbing and migration, promote that plant is to the absorption of pollutant and accumulation.
But, due to the displacement of charged particle, the two poles of the earth meta-acid or meta-alkali can be caused, be unfavorable for plant growing, so,
Processing procedure needs change polarity of electrode.And AC field-plant combined repairing method is unlikely to two because have employed alternating current
Pole meta-acid or the situation of meta-alkali, the beneficially growth of plant ground.
Application publication number is that the application for a patent for invention document of CN103406347A discloses one and can be used for heavy metal in Enriching soil
And organic method, the method forms electric field by building electrokinetic enrichment system in soil, is made by EOF, electromigration
With by the heavy metal accumulation in soil in a certain region, then carry out separating, purifying;Described electrokinetic enrichment system is straight by controllable
Stream power supply, anode chamber, cathode chamber, soil, electrode, cation exchange membrane composition;Anode chamber and anode, cathode chamber and negative electrode
Being positioned at the both sides of faradaic reaction system, soil is positioned at the centre of two electrodes, arranges cation exchange membrane between cathode chamber and soil,
Controllable DC source jointed anode and negative electrode;Electrolyte also need to be prepared at electric field two ends;Described electrolyte be water, acid solution,
One in chemical complexing agent EDTA solution, solution concentration is 0.01~1.0mol/L;Described method is by chemical complexing agent EDTA
Join cathode chamber, as the cathodic control liquid of faradaic reaction.
But, existing electronic-phytoremediation device is mostly confined to laboratory and uses, and again by making expensive, material
The impact of factors such as special (common laboratory all use graphite electrode), is carried out this Technique Popularizing to land for growing field crops, field so more difficult
Experiment.
Therefore, probe into the most simple and feasible a kind of AC field-plant restoration method, thus improve hyperaccumulative plant and administering weight
Effect in terms of technology contaminated soil, becomes hot issue urgently to be resolved hurrily.
Summary of the invention
The invention provides a kind of method utilizing AC field auxiliary Sedum alfredii Hance remediating heavy metal soil, the method can be effective
Improve Sedum alfredii Hance and administer the efficiency of heavy-metal contaminated soil, and be easy to application.
A kind of method utilizing AC field auxiliary Sedum alfredii Hance remediating heavy metal soil, including:
(1) take Sedum alfredii Hance plant, using organic materials as base manure, transplant to soil to be repaired;
In parts by weight, the component of described organic materials is: peat soil 100 parts, bean cake slag 50~75 parts, coconut palm health 15~20
Part, carbonization rice hulls 10~15 parts, schlempe 12~16 parts;
(2) applying alternating current in soil to be repaired, voltage strength is 0.4~1.1V/cm, and conduction time is 15~20 days, often
It energising 5~8h.
As preferably, in parts by weight, the component of described organic materials is: peat soil 100 parts, bean cake slag 60 parts, coconut palm health 16
Part, carbonization rice hulls 12 parts, schlempe 14 parts;The amount of application of described organic materials is 1500~3000kg/ mus.
The reparation of follow-up heavy metal soil is had an impact by the selection-breeding of Sedum alfredii Hance plant, as preferably, in step (1), and described east
The selection of south Herba hylotelephii erythrosticti plant is: chooses the Sedum alfredii Hance branch of length 3~6cm, removes terminal bud, entered by the branch of band blade
Row cuttage cultivate, it is thus achieved that taken root and root length be 3~5cm, plant height be 10~15cm Sedum alfredii Hance plant.
For selecting more excellent Sedum alfredii Hance plant further, to improve the Sedum alfredii Hance absorbability to heavy metal in soil, make
For preferably, the condition that described cuttage is cultivated is: intensity of illumination is 80~85%, and temperature is 20~25 DEG C, and air humidity is 60~65%.
Migration and the absorption of follow-up heavy metal are played an important role by plantlet of transplant to Transplanting Density during heavy metal soil and the degree of depth, as preferably,
In step (1), the density of described plantlet of transplant is 3cm × 5cm, and the plantlet of transplant degree of depth is 5~10cm.
Find through experiment, the plantlet of transplant degree of depth is adjusted, Transplantation depth is set and can improve plant further to a huge sum of money
Belong to accumulation, thus improve remediation efficiency.As preferably, in step (1), adjacent two row's plantlet of transplant degree of depth are different, are respectively
5~6cm and 8~10cm.
As preferably, when applying alternating voltage, electrode insertion depth is 20~30cm, and the spacing of the electrode that is connected is 30~40cm.
As preferably, in step (2), after the voltage strength energising 3~5h of 0.4~0.7V/cm, stop energising 0.5~1h,
Again with 0.8~1.1V/cm voltage strength be energized 2~3h.
Further, in step (2), often energising 3 days, stop being energized 1 day, common electric 25~35 days.
Compared with prior art, the method have the advantages that
The present invention applies specific voltage intensity and the alternating current of conduction time by heavy metal soil, and coordinates specific organic materials
Auxiliary Sedum alfredii Hance plant remediating heavy metal soil, it is possible to significantly improve transport efficiency and the plant above ground portion of heavy metal in soil
The accumulation of heavy metal, thus improve heavy metal soil remediation efficiency.
Detailed description of the invention
Below by case study on implementation, the present invention is further illustrated.
Embodiment 1
1, experiment material and place:
(1) for examination soil: the soil picking up from township surrounded by mountains of Fuyang City of Zhejiang Province a certain small furnace periphery heavy metal severe contamination is (following
It is called for short " Fuyang soil "), fetched earth earth is all the topsoil of 0~20cm, In Shade air-dried, crosses 5mm sieve standby.
This confession examination heavy metal in soil background content is: it is 1183.48mg/kg that full dose content of beary metal is respectively as follows: full Cu, entirely
Zn is 2403.15mg/kg, and full Pb is 817.75mg/kg, and full Cd is 13.15mg/kg, and available heavy metal content is respectively
For: the bio-available Zn concentration of Cu is the bio-available Zn concentration that bio-available Zn concentration is 1140.36mg/kg, Pb of 768.73mg/kg, Zn
Bio-available Zn concentration for 515.01mg/kg, Cd is 2.61mg/kg.
(2) for examination plant: take from the heavy metal hyperaccumulative plant Sedum alfredii Hance (Sedum of the ancient Pb-Zn deposits in Quzhou City of Zhejiang Province one
Alfredii Hance), as material to be tested after artificially breeding;
(3) for examination equipment: be purchased from the TDGC2-0.5KVA AC transformer of Shanghai voltage stabilizing factory.
(4) for ground, examination hall: school district, Zhejiang A & F University East Lake.
2, test preparation and sample collecting
(1) Polluted Soil from somewhere, Hangzhou crossing 5mm sieve is loaded the plastics of a size of 900 × 640 × 480mm
In basin, every basin soil usage amount is 240kg (guaranteeing that soil thickness is more than 20cm, simulation land for growing field crops environment).
(2) by Sedum alfredii Hance plantlet of transplant engagement good for selection-breeding, in growing process, periodically water the every basin soil of guarantee
Moisture content maintain the 60% of field capacity.
(3) alternating voltage control system is installed;
Wherein, alternating voltage control system includes: AC transformer, battery lead plate (iron plate), and battery lead plate is pressed from both sides by wire and wire
It is connected with AC transformer.
(4) plant to be planted Feng Hanghou, carries out the collection of pedotheque and plant sample.
Wherein, pedotheque main herborization rhizosphere soil, the soil sample of collection, after natural air drying, is pulverized, is sieved.For
10 mesh sieves crossed by the sample that available nutrient and pH measure, and other index crosses 100 mesh sieves.After plant sample gathers, with distillation washing
Only, surface water is blotted in absorbent paper, measures fresh weight;It is placed in again at 75 DEG C and dries to constant weight, measure its amount of dry matter, finally use agate
Nao mortar grinds, and crosses 10 mesh sieves and measures for analyzing.
3, the method utilizing AC field auxiliary Sedum alfredii Hance remediating heavy metal soil, specifically comprises the following steps that
(1) choose the Sedum alfredii Hance branch of length 6cm, remove terminal bud, be 80% by the branch of band blade in intensity of illumination,
Temperature is 25 DEG C, and air humidity is to carry out cuttage cultivation under conditions of 65%, it is thus achieved that taken root and root length is 4cm, plant
It it is highly the Sedum alfredii Hance plant of 12cm.
(2) using organic materials as base manure, by described plantlet of transplant to heavy metal soil to be repaired, cultivate;
Wherein, in parts by weight, the component of described organic materials is: peat soil 100 parts, bean cake slag 60 parts, coconut palm health 16
Part, carbonization rice hulls 12 parts, schlempe 14 parts;The amount of application of organic materials is 2500kg/ mu (that is: 3.75kg/m2);
The density of plantlet of transplant is 3cm × 5cm, and adjacent two row's plantlet of transplant degree of depth are different, respectively 6cm and 9cm.
(3) applying alternating voltage in heavy metal soil, when applying alternating voltage, electrode insertion depth is 25cm, adjacent electricity
The spacing of pole is 35cm;After the voltage strength energising 4h of 0.5V/cm, stop energising 1h, then the voltage with 1.0V/cm
Intensity energising 3h;Often energising 3 days, stop being energized 1 day, common electric 30 days.
Embodiment 2
The present embodiment is identical with the content of experiment material in embodiment 1 and place, test preparation and sample collecting, and uses interval
The mode of pressure, it differs only in: after the voltage strength energising 4h of 1V/cm, stop energising 1h, then with 0.8V/cm
Voltage strength energising 3h;Often energising 3 days, stop being energized 1 day, common electric 30 days, total conduction time and embodiment 1 phase
With.
Embodiment 3
The present embodiment is identical with the content of experiment material in embodiment 1 and place, test preparation and sample collecting, and uses interval
The mode of pressure, it differs only in: before and after interval pressure, voltage is constant, is 0.5V/cm, total conduction time and enforcement
Example 1 is identical.
Comparative example 1
This comparative example is identical with the content of experiment material in embodiment 1 and place, test preparation and sample collecting, and its difference only exists
In: do not apply voltage.
Embodiment 4
The present embodiment is identical with the content of experiment material in embodiment 1 and place, test preparation and sample collecting, and its difference only exists
In: use the mode of pressure continuously, it may be assumed that every day is energized with the voltage strength of 1V/cm after 4h, then the voltage with 0.8V/cm
Intensity energising 3h, common electric 30 days, total conduction time was same as in Example 1.
Comparative example 2
This comparative example is identical with the content of experiment material in embodiment 1 and place, test preparation and sample collecting, and its difference only exists
In: do not use above-mentioned organic materials as base manure, and use the inorganic fertilizer in the Sedum alfredii Hance cultivation of routine, it may be assumed that urine
Element;But fertilizer addition is identical.
Result of the test
Measure and use after above-mentioned soil remediation method, the content of heavy metal in soil available state and plant shoot heavy metal dense
Degree.
Result is as follows:
The impact (mg/kg) on heavy metal-polluted soil bio-available Zn concentration of table 1 different disposal
Note: in table, different lower cases represent significant difference between process (P < 0.05), lower same.
Table 2 different disposal plant shoot heavy metal concentration (mg/kg)
Note: in table, different lower cases represent significant difference between process (P < 0.05), lower same.
Claims (9)
1. the method utilizing AC field auxiliary Sedum alfredii Hance remediating heavy metal soil, it is characterised in that including:
(1) take Sedum alfredii Hance plant, using organic materials as base manure, transplant to soil to be repaired;
In parts by weight, the component of described organic materials is: peat soil 100 parts, bean cake slag 50~75 parts, coconut palm health 15~20
Part, carbonization rice hulls 10~15 parts, schlempe 12~16 parts;
(2) applying alternating current in soil to be repaired, voltage strength is 0.4~1.1V/cm, and conduction time is 15~20 days, often
It energising 5~8h.
2. the method for claim 1, it is characterised in that in parts by weight, the component of described organic materials is: peat
100 parts of soil, bean cake slag 60 parts, coconut palm health 16 parts, carbonization rice hulls 12 parts, schlempe 14 parts;Executing of described organic materials
Consumption is 1500~3000kg/ mus.
3. the method for claim 1, it is characterised in that in step (1), the selection-breeding side of described Sedum alfredii Hance plant
Method is: choose the Sedum alfredii Hance branch of length 3~6cm, removes terminal bud, the branch of band blade is carried out cuttage cultivation, it is thus achieved that
Take root and root length be 3~5cm, plant height be 10~15cm Sedum alfredii Hance plant.
4. method as claimed in claim 3, it is characterised in that the condition that described cuttage is cultivated is: intensity of illumination is 80~85%,
Temperature is 20~25 DEG C, and air humidity is 60~65%.
5. the method for claim 1, it is characterised in that in step (1), the density of described plantlet of transplant is 3cm × 5cm,
The plantlet of transplant degree of depth is 5~10cm.
6. method as claimed in claim 5, it is characterised in that in step (1), adjacent two row's plantlet of transplant degree of depth are different,
It is respectively 5~6cm and 8~10cm.
7. the method for claim 1, it is characterised in that in step (2), when applying alternating voltage, electrode inserts
The degree of depth is 20~30cm, and the spacing of adjacent electrode is 30~40cm.
8. the method for claim 1, it is characterised in that in step (2), with the voltage strength of 0.4~0.7V/cm
After energising 3~5h, stop energising 0.5~1h, then the voltage strength energising 2~3h with 0.8~1.1V/cm.
9. method as claimed in claim 8, it is characterised in that in step (2), often energising 3 days, stop energising 1 day,
Common electric 25~35 days.
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CN108541555A (en) * | 2018-04-09 | 2018-09-18 | 华南农业大学 | A kind of the transplanting nutrient matrix and cultivation management method of Sedum alfredii Hance tissue-cultured seedling |
CN108856240A (en) * | 2018-05-31 | 2018-11-23 | 昆明理工大学 | Electromagnetism strengthens the method and device of heavy metal and POPs in removing debirs |
CN109317511A (en) * | 2018-12-06 | 2019-02-12 | 中电建路桥集团有限公司 | The device and method of AC field enhancement microbiological reparation petroleum hydrocarbon contaminated soil |
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CN108541555A (en) * | 2018-04-09 | 2018-09-18 | 华南农业大学 | A kind of the transplanting nutrient matrix and cultivation management method of Sedum alfredii Hance tissue-cultured seedling |
CN108435770A (en) * | 2018-05-07 | 2018-08-24 | 常州大学 | A kind of method of electrodynamics joint Phytoremediation of Soils Contaminated by Heavy Metals |
CN108856240A (en) * | 2018-05-31 | 2018-11-23 | 昆明理工大学 | Electromagnetism strengthens the method and device of heavy metal and POPs in removing debirs |
CN109317511A (en) * | 2018-12-06 | 2019-02-12 | 中电建路桥集团有限公司 | The device and method of AC field enhancement microbiological reparation petroleum hydrocarbon contaminated soil |
CN109772876A (en) * | 2019-03-25 | 2019-05-21 | 北京大学深圳研究生院 | A kind of method that electric power coupling pepper planting repairs arsenic pollution farming land soil |
CN114602114A (en) * | 2022-02-17 | 2022-06-10 | 复旦大学 | Method for treating heavy metal pollution remediation plants through in-situ penetration type current thermal effect |
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