CN105833833A - Bentonite raw ore particles and preparation method thereof - Google Patents

Bentonite raw ore particles and preparation method thereof Download PDF

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Publication number
CN105833833A
CN105833833A CN201610223640.8A CN201610223640A CN105833833A CN 105833833 A CN105833833 A CN 105833833A CN 201610223640 A CN201610223640 A CN 201610223640A CN 105833833 A CN105833833 A CN 105833833A
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bentonite
raw ore
granule
raw material
powder
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张兴华
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12Naturally occurring clays or bleaching earth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/043Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016Particle form

Abstract

The invention discloses bentonite raw ore particles and a preparation method thereof. The raw materials of the bentonite raw ore particles include bentonite powder, and based on the 100% mass of the bentonite powder 0.02-0.05% of carbonate and 0.02-0.05% of silicate. The bentonite raw ore particles comprise active carbon, and the bentonite raw ore particles become multiaperture because of addition of active carbon, so that the specific surface area of the particles is increased, and the bentonite raw ore particles have good adsorption capacity.

Description

Bentonite raw ore granule and preparation method thereof
Technical field
The present invention relates to bentonitic technical field, in particular to bentonite raw ore granule and Preparation method.
Background technology
Bentonite is the nonmetallic minerals with montmorillonite as main mineral constituent, and bentonite is a kind of clay Rock, also known as smectite clay rock, normal bentonite bentonite, containing a small amount of illite, kaolinite, Ai Luo Stone, chlorite, zeolite, quartz, Anhydrite, calcite etc.;Typically exhibit white, faint yellow, because of Iron-holder change again in light gray, red, brick red, grey black etc. light green, pink, brown;Have wax-like, native Shape or greasy luster;It is loose as native that bentonite has, and the densification also having is hard.Main chemical compositions is Silicon dioxide, aluminium sesquioxide and water, possibly together with elements such as ferrum, magnesium, calcium, sodium, potassium, Na2O and Bentonitic physicochemical properties and process technology performance are affected the biggest by CaO content.Montmorillonite mineral Belong to monoclinic system, generally in earthy block, white, sometimes carry isochrome pale red, light green, yellowish.Light Pool is dim.Hardness 1~2, density 2~3g/cm3.By kind, the content of montmorillonite exchangeable cations With interlayer charge size, bentonite can be divided into sodium bentonite (alkaline soil), calcium-base bentonite (alkaline earth Soil), natural bleaching soil (acid soil or Emathlite), wherein calcium-base bentonite includes again calcium sodio and calcium Magnesio etc..Bentonite has strong hygroscopicity and dilatancy, adsorbable 8~15 times of own vols The water yield, volumetric expansion is up to several times to 30 times;As a form of gel and suspension can be dispersed in aqueous medium, This medium solution has certain viscosity, thixotropy and lubricity;Stronger cation is had to exchange Ability;Various gases, liquid, organic substance are had certain absorbability, and maximal absorptive capacity is up to 5 Times self weight;It has plasticity and cohesiveness with the admixture of water, mud or fine sand;Have Surface activity acid bleaching soil (active hargil, natural bleaching soil-Emathlite) can adsorb coloured from Son.Granule bentonite adsorption is preferable, the most extensively applies in building and other field.
In prior art, bentonite raw ore granule is little due to specific surface area, and viscosity is inadequate, causes absorption Power is poor.
Summary of the invention
In view of this, one aspect of the present invention is to provide a kind of bentonite raw ore granule, this bentonite origin Ore deposit granule has preferable absorption affinity.
A kind of bentonite raw ore granule, its raw material comprises bentonite in powder, and accounts for bentonite in powder quality It is 100% meter, 0.02~0.05% carbonate, 0.02~0.05% silicate.
Further, the granularity of described bentonite in powder is 100~200 mesh.
Further, described carbonate is sodium carbonate and/or potassium carbonate.
Further, described silicate is sodium silicate and/or potassium silicate.
Further, its raw material also comprises water.
Further, the consumption of described water is 10~15%, is in terms of 100% by bentonite in powder quality.
Another aspect of the present invention is to provide a kind of preparation method for bentonite, this preparation method obtain Bentonite there is preferable absorption affinity.
The preparation method of a kind of such as above-mentioned bentonite origin ore deposit granule, comprises the following steps:
Mix described raw material;
The raw material of described mixing is dried molding.
Further, described drying and moulding uses dehydrator, and described drying to moisture is 10% Below.
Further, after described drying and moulding also include pulverize, the granularity of described pulverizing be 1~ 4mm。
The bentonite raw ore granule of the present invention comprises activated carbon, and the addition of activated carbon can make bentonite origin There is porous in ore deposit granule, improves the specific surface area of granule, to make it have preferable absorption affinity.
Detailed description of the invention
For the ease of understanding the present invention, close embodiment below and further illustrate the technical side of the present invention Case.
The bentonite raw ore granule of the present invention, its raw material comprises bentonite in powder, and with bentonite opaque Amount is 100% meter, 0.02~0.05% carbonate, 0.02~0.05% silicate.Such as, with swollen Profit soil opaque amount is 100% meter, the quality of carbonate is 0.02%, 0.025%, 0.03%, 0.035%, 0.04%, 0.045%, 0.048% or 0.05%;The quality of silicate is 0.02%, 0.025%, 0.03%, 0.035%, 0.04%, 0.045%, 0.048% or 0.05%.
Above-mentioned bentonite in powder refers to the bentonite of powder, it should be appreciated that the granularity of powder is little In graininess.The granularity of bentonite in powder is not made by the present invention limit the most harshly, but swollen in order to make In the preparation of profit soil raw ore granule, bentonite in powder can be preferably with other stock dispersion, and can be selected for granularity is The bentonite in powder of 100~200 mesh, such as its granularity be 100 mesh, 110 mesh, 120 mesh, 150 mesh, 180 mesh, 190 mesh or 200 mesh.Need explanation, mesh i.e. measurement unit at this, refer to every square Eyelet number on inch screen, mesh number is the highest, and granularity is the least.100~200 mesh be scaled 74~ 165 microns.The present invention density requirement the most especially to bentonite in powder, can use 2~3g/cm3
The kind of above-mentioned bentonite in powder does not make the most harsh restriction, can use bentonite well known in the art Powder, can be sodium bentonite in powder, calcium-base bentonite powder, hydrogen-based bentonite, organobentonite etc..Sodium Base bentonite powder refers to that interlayer cation is Na+;Calcium-base bentonite powder refers to that interlayer cation is Ca2+;Have Machine bentonite refers to that interlayer cation is organic cation;Hydrogen-based bentonite refers to that interlayer cation is H+, Active hargil, natural bleaching soil.Active hargil is to be raw material with clay (mainly bentonite), Process through inorganic acidifying, then through water rinsing, the dry adsorbent made, outward appearance is off-white powder. Natural bleaching soil refers to natural output, be with montmorillonite, albite, the quartz white as key component, White gray clay.Organobentonite is a kind of inorganic mineral/organic ammonium complex, is former with bentonite Material, utilize montmorillonite in bentonite lamellar structure and can swelling dispersion in water or organic solvent Become colloid cosmid characteristic, insert organic coverture by ion exchange technique and make.
The effect of above-mentioned carbonate is to produce carbon dioxide, to carry by the hydrolysis of carbanion The porous of high bentonite raw ore granule.Carbonate can be water soluble carbonate, such as potassium carbonate, Sodium carbonate and combinations thereof, it is also possible to for water insoluble carbonate, such as magnesium carbonate, aluminium carbonate etc., preferably For potassium carbonate and/or sodium carbonate.
Above-mentioned silicate plays a part bonding.Silicate can be for water-soluble silicate, such as silicic acid Potassium, sodium silicate and combinations thereof, can be also water-insoluble silicate, such as magnesium silicate, aluminium silicate etc., excellent Elect potassium silicate and/or sodium silicate as.
The bentonitic raw material of the present invention also can comprise water, and the effect of water is at bentonite raw ore granule Preparation plays scattered effect.It is the referring to property of content of water 10~15%, with profit soil opaque amount It is 100% meter, such as 10%, 11%, 12%, 12.5%, 13%, 14%, 14.5% or 15%.
Of course for the dispersibility improved in the preparation of bentonite raw ore granule, alcoholic solvent also can be added.Alcohol Solvent can be C1~4Alcoholic solvent, such as ethanol, isopropanol etc..
The bentonitic raw material of the present invention, except above-mentioned property powdered carbon, carbonate, silicate, water, also may be used With other component below adding.
In order to improve the viscosity of bentonite raw ore granule, known thickening agent can be added, have cellulose ether, Such as methylcellulose, hydroxypropyl methyl cellulose, sodium carboxymethyl cellulose, hydroxyethyl cellulose.My god So macromolecule and derivant thereof, such as starch, gelatin, sodium alginate, casein, guar gum, carapace Amine, Radix Acaciae senegalis, xanthan gum, soybean glue, natural rubber, lanoline, agar etc., have Synthesis macromolecule, as polyacrylamide, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol oxide, Modified paraffin resin, carbomer, polyacrylic acid, Polyacrylate Emulsion, butadiene rubber, fourth Benzene rubber, polyurethane, modified polyurea, low-molecular polyethylene wax etc., have solvay-type Organometallic compounds Thing, such as amino alcohol solvay-type titanate esters.Consumption as thickening agent can be according to the selection of actual thickening agent Adjust, no longer limit at this.
In order to improve the dispersibility in the preparation of bentonite raw ore granule, known surfactant can be added. Surfactant refers to add the material of the interface state generation significant change that can make its solution system on a small quantity. There is fixing hydrophilic and oleophilic group, can align on the surface of solution.The molecule of surfactant Structure has amphipathic: one end is hydrophilic group, and the other end is hydrophobic group.Surfactant can be adopted Use known kind, can be anion surfactant, have the salt of higher fatty acids, have hydrosulphate RO-SO3-M, such as sodium lauryl sulphate, Turkey red oils, or has azochlorosulfonate acid compound R-SO3-M, Such as dioctyl succinate disulfonate acid (A Luosuo-OT), dodecylbenzene sodium sulfonate, sodium glycocholate, or Or ground can be cationic surfactant, such as quaternary ammonium compound, Dodecyl trimethyl ammonium chloride, Or ground, can be also amphoteric surfactant, such as amino acid pattern and betaine type;Certainly can be also non- Ionic surface active agent, has the fatty glyceride with glyceryl monostearate as representative, has with poly-second Glycol is the polyhydric alcohol of representative, has the polyoxyethanyl class with OP-10, NP-10 as representative, has with poly- Oxygen ethylene-poiyoxypropylene copolymer.Consumption as surfactant can be according to its kind selected actual Adjust, no longer limit at this.
In order to improve the dispersibility in the preparation of bentonite raw ore granule, coupling agent also can be added.Coupling agent Being the class material with two heterogeneity functional groups, the maximum feature of its molecular structure is to contain in molecule Having two groups that chemical property is different, one is the group of parent's inorganic matter, easily rises with mineral surfaces Chemical reaction;Another is organophilic group, can be with synthetic resin or other polymer Learn reaction or generation hydrogen bond is dissolved in wherein.Coupling agent can be organochromium complexes, silanes, metatitanic acid Esters and aluminated compound.Organochromium complexes is formed by unsaturated organic acid and trivalent chromic ion Crome metal complex;The formula of silane coupling agent silane coupler is RSiX3, in formula, R represents ammonia The groups such as base, sulfydryl, vinyl, epoxy radicals, cyano group and methacryloxy, these groups and Different matrix resins is respectively provided with stronger respond, and X represents the alkoxyl that can hydrolyze (such as first Epoxide, ethyoxyl etc.), such as KH550, KH560, KH570, KH792, DL602, DL171 Deng.Titante coupling agent can be monoalkoxy type, monoalkoxy pyrophosphoric acid ester type, chelating type, join Position build etc..
In order to improve the adsorptivity of bentonite raw ore granule further, modification infusorial earth can be added.? This can list the mode of a kind of modification infusorial earth, the such as modification infusorial earth raw material by following weight portion Make: kieselguhr 50~60 parts, Linesless charcoal 4~7 parts, sodium lignin sulfonate 3~5 parts, stearic acid 2~ 4 parts, liquor-saturated 4~6 parts of maleic acid, lauryl vinegar 4~7 parts, melamino-formaldehyde Resin 5~7 parts, sodium tripolyphosphate 4~5 parts, water 50~60 parts, its preparation method is to be firstly added Kieselguhr, Linesless charcoal, lauryl methacrylate, water stir, and form suspension, add along fourth Enedioic acid acid anhydride, melamine resin, sodium tripolyphosphate mix and blend 25~35 minutes, then add Enter remaining residual components, stir under the conditions of 1200~1500rpm, dry at 50~60 DEG C, powder It is broken into 200~400 mesh powder and get final product.
In order to improve the adsorptivity of bentonite raw ore granule, Ludox can be added.Ludox refers to nanometer The silica dioxide granule of level dispersion liquid in water or in solvent.Owing to the SiO2 in Ludox contains Substantial amounts of water and hydroxyl, therefore Ludox can also be expressed as SiO2.nH2O.Ludox is by silicic acid molecule It is polymerized generation voluntarily, the most also can be polymerized generation gel further and settle out from solution To come. when being used alone Ludox absorption, it understands self. polymerization, ' particle growth. surface reduces. absorbability Decline.Additionally it is while Liquidity limit bores, and micelle surface charge is neutralized. the most quickly coalesce And separate out. this is probably another reason that Ludox absorbability is the highest.Electronegative Ludox can adsorb On the bentonite clay particle crystal layer end face of positively charged.Adsorbed Ludox grain can not carry out Blang again Motion, decreases collision polymerization and grows up chance. and be distributed affected by the end face lotus locational space that powers on, that It is the least that this combines chance of growing up, and this makes the sol particle granularity of absorption on end face less, remains Bigger absorption surface.In the plane and end face of granule crystal layer, all there is suction in swelling after Ludox process Attached cation capacity.The Liquidity limit ability just making it is both high, also than the raw material bentonite not processed Higher than Ludox.You need to add is that, Ludox can be used known method to make by oneself by sodium silicate, Do not repeat them here.
The preparation method of the bentonite raw ore granule of the present invention, comprises the following steps: mix described raw material; And the raw material of described mixing is dried molding.
Above-mentioned mixing can use mixing apparatus well known in the art, such as blender, turning as stirring Speed can be not particularly limited, and can carry out conventional setting according to the power of agitator of actual mixing plant.
Above-mentioned drying and moulding refers under desiccation so that mixed raw material is shaped to graininess.Dry Dry molding can use dehydrator, described drying to moisture to be less than 10%.Except this, can be also true Empty dry.
After being mixed by raw material, can carry out being squeezed into cake by mixed raw material employing cooked flake wrapping machine.
Also including after above-mentioned drying and moulding pulverizing, the granularity of described pulverizing is 1~4mm, such as 1mm, 1.2mm, 1.5mm, 2mm, 2.5mm, 3mm, 3.5mm, 3.8mm or 4mm. Known means, such as ball milling, grinding etc. can be used as the means pulverized.
Embodiment 1
It is first according to quality than proportioning raw material: i.e. 100 mesh bentonite in powder, and accounts for bentonite opaque Amount is 100% meter, 0.02% sodium carbonate, 0.02% sodium silicate.
Use blender to add 10% water raw material good for said ratio, use cooked flake wrapping machine extruded.
Entering dehydrator by conveyer, the bentonite activated carbon granule moisture after then drying reaches Less than 10%, screen 1mm granule.
Embodiment 2
It is first according to quality than proportioning raw material: i.e. 100 mesh bentonite in powder, and accounts for bentonite opaque Amount is 100% meter, 0.05% sodium carbonate, 0.05% sodium silicate.
Use blender to add 10% water raw material good for said ratio, use cooked flake wrapping machine extruded.
Entering dehydrator by conveyer, the bentonite activated carbon granule moisture after then drying reaches Less than 10%, screen 1mm granule.
Embodiment 3
It is first according to quality than proportioning raw material: i.e. 200 mesh bentonite in powder, and accounts for bentonite opaque Amount is 100% meter, 0.05% sodium carbonate, 0.05% sodium silicate.
Use blender to add 15% water raw material good for said ratio, use cooked flake wrapping machine extruded.
Entering dehydrator by conveyer, the bentonite activated carbon granule moisture after then drying reaches Less than 10%, screen 4mm granule.
Embodiment 4
It is first according to quality than proportioning raw material: i.e. 200 mesh bentonite in powder, and accounts for bentonite opaque Amount is 100% meter, 0.02% sodium carbonate, 0.02% sodium silicate.
Raw material good for said ratio is used blender addition 10~15% water, uses cooked flake wrapping machine to be squeezed into Type.
Entering dehydrator by conveyer, the bentonite activated carbon granule moisture after then drying reaches Less than 10%, screen 1~4mm granule.
Embodiment 5
It is first according to quality than proportioning raw material: i.e. 150 mesh bentonite in powder, and accounts for bentonite opaque Amount is 100% meter, 0.02% sodium carbonate, 0.05% sodium silicate.
Use blender to add 10% water raw material good for said ratio, use cooked flake wrapping machine extruded.
Entering dehydrator by conveyer, the bentonite activated carbon granule moisture after then drying reaches Less than 10%, screen 3mm granule.
Embodiment 6
It is first according to quality than proportioning raw material: i.e. 150 mesh bentonite in powder, and accounts for bentonite opaque Amount is 100% meter, 0.05% sodium carbonate, 0.02% sodium silicate.
Use blender to add 15% water raw material good for said ratio, use cooked flake wrapping machine extruded.
Entering dehydrator by conveyer, the bentonite activated carbon granule moisture after then drying reaches Less than 10%, screen 3mm granule.
Embodiment 7
It is first according to quality than proportioning raw material: i.e. 150 mesh bentonite in powder, and accounts for bentonite opaque Amount is 100% meter, 0.035% sodium carbonate, 0.035% sodium silicate.
Use blender to add 12% water raw material good for said ratio, use cooked flake wrapping machine extruded.
Entering dehydrator by conveyer, the bentonite activated carbon granule moisture after then drying reaches Less than 10%, screen 3mm granule.
Embodiment 8
It is first according to quality than proportioning raw material: i.e. 150 mesh bentonite in powder, and accounts for bentonite opaque Amount is 100% meter, 0.035% sodium carbonate, 0.035% sodium silicate.
Use blender to add 12% water raw material good for said ratio, use cooked flake wrapping machine extruded.
Entering dehydrator by conveyer, the bentonite activated carbon granule moisture after then drying reaches Less than 10%, screen 3mm granule.
Comparative example
In this example, its raw material does not comprise activated carbon powder, and other is with embodiment 8.
Use known means to the bentonite raw ore granule prepared by embodiment 1-8 and comparative example Adsorptivity is tested, and test shows that the adsorptivity of comparative example is less than embodiment example.
The natural moisture that bentonite raw ore granule of the present invention makes full use of bentonite original ore soil carries out extruding and dries Dry, products obtained therefrom have glittering and translucent, bright, granule is limpid, adsorptivity is strong, conglomeration is firm, no Easy to fall off point of quarrel etc..(this bentonite ore soil dries, dry after pulverizing select granule again, intensity is big, crystal Color and luster is good, the most muddy).
Owing to the numerical range of each technological parameter involved in the present invention is the most impossible All embody, as long as but those skilled in the art is the most envisioned falls into this numerical range above-mentioned In any numerical value all can implement the present invention, the most also include appointing of occurrence in the range of some numerical value Meaning combination.Herein, for the consideration of length, eliminate and provide tool in certain one or more numerical range The embodiment of body value, this is not to be construed as the insufficient disclosure of technical scheme.
Applicant state, the present invention by above-described embodiment illustrate the present invention detailed process equipment and Technological process, but the invention is not limited in above-mentioned detailed process equipment and technological process, i.e. it is not intended that The present invention and have to rely on above-mentioned detailed process equipment and technological process could be implemented.Art Technical staff it will be clearly understood that any improvement in the present invention, the equivalence of raw material each to product of the present invention Replace and the interpolation of auxiliary element, concrete mode selection etc., be within the scope of the present invention.

Claims (9)

1. a bentonite raw ore granule, it is characterised in that its raw material comprises bentonite in powder, and Account for by bentonite in powder quality be in terms of 100%, 0.02~0.05% carbonate, 0.02~0.05% silicate.
Bentonite raw ore granule the most according to claim 1, it is characterised in that described swelling The granularity of soil powder is 100~200 mesh.
Bentonite raw ore granule the most according to claim 1, it is characterised in that described carbonic acid Salt is sodium carbonate and/or potassium carbonate.
Bentonite raw ore granule the most according to claim 1, it is characterised in that described silicic acid Salt is sodium silicate and/or potassium silicate.
Bentonite raw ore granule the most according to claim 1, it is characterised in that its raw material is also Comprise water.
Bentonite raw ore granule the most according to claim 5, it is characterised in that described water Consumption is 10~15%, is in terms of 100% by bentonite in powder quality.
7. the preparation method of a bentonite raw ore granule as claimed in claim 1, it is characterised in that Comprise the following steps:
Mix described raw material;
The raw material of described mixing is dried molding.
Preparation method the most according to claim 8, it is characterised in that described drying and moulding uses Dehydrator, described drying to moisture is less than 10%.
Preparation method the most according to claim 1, it is characterised in that described drying and moulding it After also include pulverize, the granularity of described pulverizing is 1~4mm.
CN201610223640.8A 2016-04-11 2016-04-11 Bentonite raw ore particles and preparation method thereof Pending CN105833833A (en)

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CN107096356A (en) * 2017-05-22 2017-08-29 句容康泰膨润土有限公司 A kind of bentonite drier and preparation method thereof
CN108467121A (en) * 2018-05-14 2018-08-31 胡敏 A kind of microorganism sewage water processing method being inoculated with flora using activated sludge
CN109248659A (en) * 2018-10-26 2019-01-22 芜湖飞尚非金属材料有限公司 A kind of refuse landfill bentonite base inorganic agent and preparation method thereof
CN109821517A (en) * 2019-04-09 2019-05-31 乐清市智格电子科技有限公司 A kind of particle nanomicroporous material and preparation method thereof

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CN108467121B (en) * 2018-05-14 2020-11-10 金涛 Microbial sewage treatment method adopting activated sludge to inoculate flora
CN109248659A (en) * 2018-10-26 2019-01-22 芜湖飞尚非金属材料有限公司 A kind of refuse landfill bentonite base inorganic agent and preparation method thereof
CN109821517A (en) * 2019-04-09 2019-05-31 乐清市智格电子科技有限公司 A kind of particle nanomicroporous material and preparation method thereof

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