CN105831118A - Insecticidal composition containing spirocyclic tetronic acid compound and thiocyclam - Google Patents
Insecticidal composition containing spirocyclic tetronic acid compound and thiocyclam Download PDFInfo
- Publication number
- CN105831118A CN105831118A CN201610196513.3A CN201610196513A CN105831118A CN 105831118 A CN105831118 A CN 105831118A CN 201610196513 A CN201610196513 A CN 201610196513A CN 105831118 A CN105831118 A CN 105831118A
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- CN
- China
- Prior art keywords
- thiocyclam
- tetronic acid
- acid compounds
- spirocyclic tetronic
- pesticidal combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides an insecticidal composition containing a spirocyclic tetronic acid compound and thiocyclam. The insecticidal composition is characterized in that the active components of the insecticidal composition are the spirocyclic tetronic acid compound and thiocyclam and a weight ratio of the spirocyclic tetronic acid compound to thiocyclam is 90: 1 to 1: 90. The insecticidal composition integrates the two active components, so an insecticidal spectrum is broadened, a plurality of insects can be treated at the same time, resistance of insects is alleviated, substantial insecticidal effect is obtained, and the insecticidal composition can prevent and treat diseases and insect pests attacking crops; moreover, compared with the individual spirocyclic tetronic acid compound or individual thiocyclam, the insecticidal composition is reduced in production and usage cost, so cost of peasants for pesticides is reduced.
Description
Technical field
The present invention relates to agrochemical field, containing spirocyclic tetronic acid compounds and kill particularly to one
The Pesticidal combination of worm ring.
Background technology
The resistance problem of agricultural pests is a global problem, and always agricultural science and technology worker is closed
The emphasis problem of note.Continuity year in year out, the increasing of Pesticide use amount along with Chemical Control of Harmful Insects
Adding and not scientifical use pesticide, pest resistance is day by day serious, and the pest species producing resistance constantly increases
Many.
Tetronic acid is present in multiple natural goods in a large number, has a lot of particularly biological medicine activity, its
In, tetronic acid derivatives also has antibacterial, antiviral, Insecticiding-miticiding, weeding and plant growth regulating
Isoreactivity.In recent years, spirocyclic tetronic acid compounds is due to its novel structure, high-efficiency low-toxicity, nothing friendship
The advantages such as fork drug dependence, it has also become one of hot fields of current pesticides discovery research.Spirocyclic tetronic acid
The Insecticiding-miticiding machine matter of compounds is totally different from existing various insecticidal/acaricidal agent, is by suppression
Insect or evil demodicid mite body in lipid synthesis, destroy acarid energy metabolism activity, finally kill off the insect pests or
Evil demodicid mite.
Thiocyclam, chemical name is N, N-dimethyl-1,2,3-tri-thia hex-5-amine, have another name called thiocyclarn,
SAN-155I, thiocyclam is selective insecticide, have stronger tag, stomach toxicity and Uptake and translocation effect,
The larva of lepidoptera pest there is preferable prevention effect, it is possible to weaving parasitic nematode, as Oryza sativa L. is the sharpest
Nematicide, rust and dead ears disease to some crops also have certain prevention effect, can also prevent and treat three changes in addition
The insects such as snout moth's larva, rice leaf roller, striped rice borer, plant hopper, black peach aphid, apple aphid, pear leaf worm.Belong to imitative
Raw type pesticide, little on natural enemy impact, non-resistant, free from environmental pollution, be current comprehensive control insect pest relatively
Preferably medicament.
Insecticide variety containing single component often existing defects in pesticide Pest control: use continuously
Easily developing immunity to drugs, insecticidal spectrum is narrow, it is impossible to for as providing comprehensively protection, peasant's drug cost
High.Above-mentioned lacking can be overcome to a certain extent by the combination of two or more various active component
Point.There is the combination mixture of two or more active component of potentiation, preventive effect can be improved,
Reduce effective ingredient ground consumption, save peasant's drug cost, slow down pest resistance and occur, and can expand
Preventing and treating spectrum, plays the double effect controlled of many worms.
Summary of the invention
For solving the problem of above-mentioned existence, it is an object of the invention to provide a kind of class Han spirocyclic tetronic acid
Compound and the Pesticidal combination of thiocyclam.Described Pesticidal combination, two kinds of combination of active principles use,
Expand insecticidal spectrum, play the double effect controlled of many worms, slow down pest resistance and occur, and insecticidal effect shows
Write, it is possible to effectively prevent and treat diseases and pests of agronomic crop；Additionally, with spirocyclic tetronic acid compounds and thiocyclam
Single dose is compared, and produces and use cost reduces, save peasant's drug cost.
For reaching above-mentioned purpose, the technical scheme is that
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and thiocyclam, described spirocyclic tetronic acid compounds
It is 90:1-1:90 with the weight ratio of thiocyclam.
Further, the weight ratio of described spirocyclic tetronic acid compounds and thiocyclam is 15:1-1:15.
Further, the weight ratio of described spirocyclic tetronic acid compounds and thiocyclam is 6:1.
And have, described Pesticidal combination is possibly together with dispersant, stabilizer, solvent, emulsifying agent, thickening
One or more in agent.
Separately, described spirocyclic tetronic acid compounds and thiocyclam account for described Pesticidal combination gross weight altogether
10%-60%.
Further, described spirocyclic tetronic acid compounds and thiocyclam account for described Pesticidal combination altogether
The 20%-40% of gross weight.
Meanwhile, described Pesticidal combination is applied to aphid in agricultural production, mythimna separata, black bean aphid, rice fly
The preventing and treating of louse, cotten aphid and bollworm.
The beneficial effects of the present invention is:
(1) what the present invention provided is a kind of containing spirocyclic tetronic acid compounds with the Insecticidal combinations of thiocyclam
Thing, two kinds of combination of active principles use, and expand insecticidal spectrum, play the double effect controlled of many worms, slow down
Pest resistance occurs, and insecticidal effect is notable, it is possible to effectively prevent and treat diseases and pests of agronomic crop；
(2) what the present invention provided is a kind of containing spirocyclic tetronic acid compounds with the Insecticidal combinations of thiocyclam
Thing, compared with spirocyclic tetronic acid compounds and thiocyclam single dose, produces and use cost reduces, joint
About peasant's drug cost.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with enforcement
Example further describes.
Embodiment 1
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and thiocyclam, its content is: spirocyclic tetronic acid class
Compound: 10%；Thiocyclam: 0.11%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Emulsifying agent, thickening agent.
Embodiment 2
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and thiocyclam, its content is: spirocyclic tetronic acid class
Compound: 25%；Thiocyclam: 0.5%；Pesticidal combination possibly together with dispersant, solvent, emulsifying agent,
Thickening agent.
Embodiment 3
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and thiocyclam, its content is: spirocyclic tetronic acid class
Compound: 30%；Thiocyclam: 1%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Thickening agent.
Embodiment 4
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and thiocyclam, its content is: spirocyclic tetronic acid class
Compound: 10%；Thiocyclam: 1%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Emulsifying agent, thickening agent.
Embodiment 5
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and thiocyclam, its content is: spirocyclic tetronic acid class
Compound: 30%；Thiocyclam: 30%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Emulsifying agent, thickening agent.
Embodiment 6
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and thiocyclam, its content is: spirocyclic tetronic acid class
Compound: 3%；Thiocyclam: 30%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Thickening agent.
Embodiment 7
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and thiocyclam, its content is: spirocyclic tetronic acid class
Compound: 1.5%；Thiocyclam: 45%；Pesticidal combination possibly together with dispersant, solvent, emulsifying agent,
Thickening agent.
Embodiment 8
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and thiocyclam, its content is: spirocyclic tetronic acid class
Compound: 1%；Thiocyclam: 50%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Emulsifying agent, thickening agent.
Embodiment 9
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and thiocyclam, its content is: spirocyclic tetronic acid class
Compound: 0.2%；Thiocyclam: 18%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Emulsifying agent, thickening agent.
In order to the effect of Pesticidal combination in embodiment 1-5 is tested, it is used for killing bollworm, medicine
Effect result of the test is as shown in table 1.
Drug effect calculates as follows:
Table 1: embodiment 1-5 prevents and treats the field control effectiveness test result of bollworm with comparative example 1-2
Wherein: comparative example 1: spirocyclic tetronic acid compounds mu effective ingredient: 15 × 10%=1.5
Gram；Comparative example 2: thiocyclam mu effective ingredient: 60 × 10%=6 gram.
Being found out by table 1 result of the test, described Pesticidal combination, two kinds of combination of active principles use,
Insecticidal effect is notable, compared with spirocyclic tetronic acid compounds and thiocyclam single dose, plays potentiation,
And produce and use cost reduction, save peasant's drug cost.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted.
Although being described in detail the present invention with reference to preferred embodiment, those of ordinary skill in the art should
Work as understanding, the technical scheme of invention can be modified or equivalent, without deviating from the present invention
The scope of technical scheme, it all should be contained in scope of the presently claimed invention.
Claims (7)
1. one kind contains spirocyclic tetronic acid compounds and the Pesticidal combination of thiocyclam, it is characterized in that, active component in described Pesticidal combination is spirocyclic tetronic acid compounds and thiocyclam, and the weight ratio of described spirocyclic tetronic acid compounds and thiocyclam is 90:1-1:90.
The most according to claim 1 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, it is characterised in that the weight ratio of described spirocyclic tetronic acid compounds and thiocyclam is 15:1-1:15.
The most according to claim 1 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, it is characterised in that the weight ratio of described spirocyclic tetronic acid compounds and thiocyclam is 6:1.
4. according to a kind of according to any one of claim 1-3 containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, it is characterised in that described Pesticidal combination is possibly together with one or more in dispersant, stabilizer, solvent, emulsifying agent, thickening agent.
The most according to claim 1 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, it is characterised in that described spirocyclic tetronic acid compounds and thiocyclam account for the 10%-60% of described Pesticidal combination gross weight altogether.
The most according to claim 5 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, it is characterised in that described spirocyclic tetronic acid compounds and thiocyclam account for the 20%-40% of described Pesticidal combination gross weight altogether.
The most according to claim 1 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of thiocyclam, it is characterised in that described Pesticidal combination is applied to the preventing and treating of aphid in agricultural production, mythimna separata, black bean aphid, planthopper, cotten aphid and bollworm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610196513.3A CN105831118A (en) | 2016-03-31 | 2016-03-31 | Insecticidal composition containing spirocyclic tetronic acid compound and thiocyclam |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610196513.3A CN105831118A (en) | 2016-03-31 | 2016-03-31 | Insecticidal composition containing spirocyclic tetronic acid compound and thiocyclam |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105831118A true CN105831118A (en) | 2016-08-10 |
Family
ID=56596411
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610196513.3A Pending CN105831118A (en) | 2016-03-31 | 2016-03-31 | Insecticidal composition containing spirocyclic tetronic acid compound and thiocyclam |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105831118A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1400864A (en) * | 2000-02-18 | 2003-03-05 | 拜尔公司 | Active substance combinations comprising insecticidal and acaricidal properties |
| EP2446742A1 (en) * | 2010-10-28 | 2012-05-02 | Bayer CropScience AG | Insecticide or acaricide compositions containing mono- or disaccharides as activity enhancers |
| CN103250716A (en) * | 2012-02-21 | 2013-08-21 | 陕西美邦农药有限公司 | Insecticidal composition comprising spirotetramat and nereistoxin |
| CN103651363A (en) * | 2012-09-06 | 2014-03-26 | 陕西美邦农药有限公司 | Pesticidal composition containing spiromesifen and nereistoxin |
-
2016
- 2016-03-31 CN CN201610196513.3A patent/CN105831118A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1400864A (en) * | 2000-02-18 | 2003-03-05 | 拜尔公司 | Active substance combinations comprising insecticidal and acaricidal properties |
| EP2446742A1 (en) * | 2010-10-28 | 2012-05-02 | Bayer CropScience AG | Insecticide or acaricide compositions containing mono- or disaccharides as activity enhancers |
| CN103250716A (en) * | 2012-02-21 | 2013-08-21 | 陕西美邦农药有限公司 | Insecticidal composition comprising spirotetramat and nereistoxin |
| CN103651363A (en) * | 2012-09-06 | 2014-03-26 | 陕西美邦农药有限公司 | Pesticidal composition containing spiromesifen and nereistoxin |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160810 |
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| RJ01 | Rejection of invention patent application after publication |