CN105766911A - Insecticidal composition containing spiro tetronic acids compound and monosultap - Google Patents
Insecticidal composition containing spiro tetronic acids compound and monosultap Download PDFInfo
- Publication number
- CN105766911A CN105766911A CN201610195517.XA CN201610195517A CN105766911A CN 105766911 A CN105766911 A CN 105766911A CN 201610195517 A CN201610195517 A CN 201610195517A CN 105766911 A CN105766911 A CN 105766911A
- Authority
- CN
- China
- Prior art keywords
- cupric sulfate
- tetronic acid
- acid compounds
- pesticidal combination
- spirocyclic tetronic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
Abstract
The invention relates to an insecticidal composition containing a spiro tetronic acids compound and monosultap. Active ingredients in the insecticidal composition comprise the spiro tetronic acids compound and the monosultap, wherein the weight ratio of the spiro tetronic acids compound to the monosultap ranges from (100:1) to (1:100). According to the insecticidal composition, the two effective ingredients are combined so that the insecticidal spectrum is expanded and the effect of treating a plurality of types of insects is realized; the resistance of the insects is alleviated and the insecticidal effect is remarkable; the insecticidal composition can be used for effectively preventing and treating diseases and insect pests of crops; and furthermore, compared with single dosages of the spiro tetronic acids compound and the monosultap, the insecticidal composition has the advantages that the production cost and the utilization cost are reduced, and the pesticide utilization cost of farmers is saved.
Description
Technical field
The present invention relates to agrochemical field, containing spirocyclic tetronic acid compounds and kill particularly to one
The Pesticidal combination that worm is single.
Background technology
The resistance problem of agricultural pests is a global problem, and always agricultural science and technology worker is closed
The emphasis problem of note.Continuity year in year out, the increasing of Pesticide use amount along with Chemical Control of Harmful Insects
Adding and not scientifical use pesticide, pest resistance is day by day serious, and the pest species producing resistance constantly increases
Many.
Tetronic acid is present in multiple natural goods in a large number, has a lot of particularly biological medicine activity, its
In, tetronic acid derivatives also has antibacterial, antiviral, Insecticiding-miticiding, weeding and plant growth regulating
Isoreactivity.In recent years, spirocyclic tetronic acid compounds is due to its novel structure, high-efficiency low-toxicity, nothing friendship
The advantages such as fork drug dependence, it has also become one of hot fields of current pesticides discovery research.Spirocyclic tetronic acid
The Insecticiding-miticiding machine matter of compounds is totally different from existing various insecticidal/acaricidal agent, is by suppression
Insect or evil demodicid mite body in lipid synthesis, destroy acarid energy metabolism activity, finally kill off the insect pests or
Evil demodicid mite.
Cupric sulfate, molecular formula is C5H12NNaO6S4, chemical name is 1-thiosulfonic acid sodio-2-diformazan
Amino-3-thiosulfo propane.Cupric sulfate is the analog of the nereistoxin of synthetic, enters elder brother
Nereistoxin or Dihydronereistoxin element it is quickly converted in polypide.This medicine is acetylcholine competitive inhibition
Agent, have stronger tag, stomach toxicity and Uptake and translocation effect, the larva of lepidoptera pest is had preferably
Prevention effect.Belong to bionic-type pesticide, little on natural enemy impact, non-resistant, free from environmental pollution, it is mesh
The front comparatively ideal medicament of comprehensive control insect pest.
Insecticide variety containing single component often existing defects in pesticide Pest control: use continuously
Easily developing immunity to drugs, insecticidal spectrum is narrow, it is impossible to for as providing comprehensively protection, peasant's drug cost
High.Above-mentioned lacking can be overcome to a certain extent by the combination of two or more various active component
Point.There is the combination mixture of two or more active component of potentiation, preventive effect can be improved,
Reduce effective ingredient ground consumption, save peasant's drug cost, slow down pest resistance and occur, and can expand
Preventing and treating spectrum, plays the double effect controlled of many worms.
Summary of the invention
For solving the problem of above-mentioned existence, it is an object of the invention to provide a kind of class Han spirocyclic tetronic acid
Compound and the Pesticidal combination of Cupric sulfate.Described Pesticidal combination, two kinds of combination of active principles use,
Expand insecticidal spectrum, play the double effect controlled of many worms, slow down pest resistance and occur, and insecticidal effect shows
Write, it is possible to effectively prevent and treat diseases and pests of agronomic crop；Additionally, with spirocyclic tetronic acid compounds and Cupric sulfate
Single dose is compared, and produces and use cost reduces, save peasant's drug cost.
For reaching above-mentioned purpose, the technical scheme is that
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and Cupric sulfate, described spirocyclic tetronic acid compounds
It is 100:1-1:100 with the weight ratio of Cupric sulfate.
Further, the weight ratio of described spirocyclic tetronic acid compounds and Cupric sulfate is 30:1-1:30.
Further, the weight ratio of described spirocyclic tetronic acid compounds and Cupric sulfate is 5:1.
Further, described Pesticidal combination is possibly together with dispersant, stabilizer, solvent, emulsifying agent, thickening
One or more in agent.
And, described spirocyclic tetronic acid compounds and Cupric sulfate account for described Pesticidal combination gross weight altogether
10%-80%.
Further, described spirocyclic tetronic acid compounds and Cupric sulfate account for described Pesticidal combination altogether
The 20%-50% of gross weight.
Meanwhile, described Pesticidal combination is applied to aphid in agricultural production, mythimna separata, black bean aphid, rice fly
The preventing and treating of louse, cotten aphid and bollworm.
The beneficial effects of the present invention is:
(1) what the present invention provided is a kind of containing spirocyclic tetronic acid compounds with the Insecticidal combinations of Cupric sulfate
Thing, two kinds of combination of active principles use, and expand insecticidal spectrum, play the double effect controlled of many worms, slow down
Pest resistance occurs, and insecticidal effect is notable, it is possible to effectively prevent and treat diseases and pests of agronomic crop；
(2) what the present invention provided is a kind of containing spirocyclic tetronic acid compounds with the Insecticidal combinations of Cupric sulfate
Thing, compared with spirocyclic tetronic acid compounds and Cupric sulfate single dose, produces and use cost reduces, joint
About peasant's drug cost.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with enforcement
Example further describes.
Embodiment 1
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and Cupric sulfate, its content is: spirocyclic tetronic acid class
Compound: 10%；Cupric sulfate: 0.1%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Emulsifying agent, thickening agent.
Embodiment 2
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and Cupric sulfate, its content is: spirocyclic tetronic acid class
Compound: 20%；Cupric sulfate: 0.4%；Pesticidal combination possibly together with dispersant, solvent, emulsifying agent,
Thickening agent.
Embodiment 3
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and Cupric sulfate, its content is: spirocyclic tetronic acid class
Compound: 30%；Cupric sulfate: 1%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Thickening agent.
Embodiment 4
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and Cupric sulfate, its content is: spirocyclic tetronic acid class
Compound: 10%；Cupric sulfate: 1%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Emulsifying agent, thickening agent.
Embodiment 5
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and Cupric sulfate, its content is: spirocyclic tetronic acid class
Compound: 40%；Cupric sulfate: 40%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Emulsifying agent, thickening agent.
Embodiment 6
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and Cupric sulfate, its content is: spirocyclic tetronic acid class
Compound: 3%；Cupric sulfate: 30%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Thickening agent.
Embodiment 7
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and Cupric sulfate, its content is: spirocyclic tetronic acid class
Compound: 2%；Cupric sulfate: 60%；Pesticidal combination possibly together with dispersant, solvent, emulsifying agent,
Thickening agent.
Embodiment 8
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and Cupric sulfate, its content is: spirocyclic tetronic acid class
Compound: 1%；Cupric sulfate: 50%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Emulsifying agent, thickening agent.
Embodiment 9
A kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, described Pesticidal combination
In active component be spirocyclic tetronic acid compounds and Cupric sulfate, its content is: spirocyclic tetronic acid class
Compound: 0.2%；Cupric sulfate: 20%；Pesticidal combination possibly together with dispersant, stabilizer, solvent,
Emulsifying agent, thickening agent.
In order to the effect of Pesticidal combination in embodiment 1-5 is tested, it is used for killing planthopper, medicine
Effect result of the test is as shown in table 1.
Drug effect calculates as follows:
Table 1: embodiment 1-5 prevents and treats the field control effectiveness test result of planthopper with comparative example 1-2
Wherein: comparative example 1: spirocyclic tetronic acid compounds mu effective ingredient: 15 × 10%=1.5
Gram；Comparative example 2: Cupric sulfate mu effective ingredient: 60 × 10%=6 gram.
Being found out by table 1 result of the test, described Pesticidal combination, two kinds of combination of active principles use,
Insecticidal effect is notable, compared with spirocyclic tetronic acid compounds and Cupric sulfate single dose, plays potentiation,
And produce and use cost reduction, save peasant's drug cost.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted.
Although being described in detail the present invention with reference to preferred embodiment, those of ordinary skill in the art should
Work as understanding, the technical scheme of invention can be modified or equivalent, without deviating from the present invention
The scope of technical scheme, it all should be contained in scope of the presently claimed invention.
Claims (7)
1. one kind contains spirocyclic tetronic acid compounds and the Pesticidal combination of Cupric sulfate, it is characterized in that, active component in described Pesticidal combination is spirocyclic tetronic acid compounds and Cupric sulfate, and the weight ratio of described spirocyclic tetronic acid compounds and Cupric sulfate is 100:1-1:100.
The most according to claim 1 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, it is characterised in that the weight ratio of described spirocyclic tetronic acid compounds and Cupric sulfate is 30:1-1:30.
The most according to claim 1 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, it is characterised in that the weight ratio of described spirocyclic tetronic acid compounds and Cupric sulfate is 5:1.
4. according to a kind of according to any one of claim 1-3 containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, it is characterised in that described Pesticidal combination is possibly together with one or more in dispersant, stabilizer, solvent, emulsifying agent, thickening agent.
The most according to claim 1 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, it is characterised in that described spirocyclic tetronic acid compounds and Cupric sulfate account for the 10%-80% of described Pesticidal combination gross weight altogether.
The most according to claim 5 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, it is characterised in that described spirocyclic tetronic acid compounds and Cupric sulfate account for the 20%-50% of described Pesticidal combination gross weight altogether.
The most according to claim 1 a kind of containing spirocyclic tetronic acid compounds with the Pesticidal combination of Cupric sulfate, it is characterised in that described Pesticidal combination is applied to the preventing and treating of aphid in agricultural production, mythimna separata, black bean aphid, planthopper, cotten aphid and bollworm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610195517.XA CN105766911A (en) | 2016-03-31 | 2016-03-31 | Insecticidal composition containing spiro tetronic acids compound and monosultap |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610195517.XA CN105766911A (en) | 2016-03-31 | 2016-03-31 | Insecticidal composition containing spiro tetronic acids compound and monosultap |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105766911A true CN105766911A (en) | 2016-07-20 |
Family
ID=56395425
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610195517.XA Pending CN105766911A (en) | 2016-03-31 | 2016-03-31 | Insecticidal composition containing spiro tetronic acids compound and monosultap |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105766911A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1635834A (en) * | 2000-03-21 | 2005-07-06 | 拜尔公司 | Combinations of active ingredients with insecticidal and acaricidal properties |
| EP2446742A1 (en) * | 2010-10-28 | 2012-05-02 | Bayer CropScience AG | Insecticide or acaricide compositions containing mono- or disaccharides as activity enhancers |
| CN103250716A (en) * | 2012-02-21 | 2013-08-21 | 陕西美邦农药有限公司 | Insecticidal composition comprising spirotetramat and nereistoxin |
| CN103651363A (en) * | 2012-09-06 | 2014-03-26 | 陕西美邦农药有限公司 | Pesticidal composition containing spiromesifen and nereistoxin |
-
2016
- 2016-03-31 CN CN201610195517.XA patent/CN105766911A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1635834A (en) * | 2000-03-21 | 2005-07-06 | 拜尔公司 | Combinations of active ingredients with insecticidal and acaricidal properties |
| EP2446742A1 (en) * | 2010-10-28 | 2012-05-02 | Bayer CropScience AG | Insecticide or acaricide compositions containing mono- or disaccharides as activity enhancers |
| CN103250716A (en) * | 2012-02-21 | 2013-08-21 | 陕西美邦农药有限公司 | Insecticidal composition comprising spirotetramat and nereistoxin |
| CN103651363A (en) * | 2012-09-06 | 2014-03-26 | 陕西美邦农药有限公司 | Pesticidal composition containing spiromesifen and nereistoxin |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100362918C (en) | Pyrethroid and organic phosphorus composite synergic pesticide and its application | |
| CN103053569A (en) | Tolfenpyrad-containing insecticidal composition | |
| CN101124912A (en) | Multi-reactive insecticide | |
| CN103598182B (en) | Prevention and control agent for banded sclerotial blight of crops | |
| CN105766911A (en) | Insecticidal composition containing spiro tetronic acids compound and monosultap | |
| WO2011092721A9 (en) | A botanical pesticide for agriculture/horticulture crops | |
| CN105766910A (en) | Insecticide composition containing spiro-cyclohexanone acid compounds and dimehypo | |
| CN105831118A (en) | Insecticidal composition containing spirocyclic tetronic acid compound and thiocyclam | |
| CN105746570A (en) | Insecticidal composition containing spirocyclic tetronic acid compound and transfluthrin | |
| CN102726439A (en) | Complex insecticide containing acetamiprid | |
| CN105145617B (en) | A kind of composite synergistic pesticide | |
| CN104304350A (en) | Low toxicity and high efficiency pesticide | |
| CN104285951A (en) | Compound insecticide | |
| CN104273142A (en) | Abamectin-containing emulsion in water and application | |
| CN103936699B (en) | There is γ-benzylidene-gamma butyrolactone derivant and the application of antibacterial action | |
| Bhattacharjee et al. | Efficacy of some biopesticides against rice hispa, Dicladispa armigera (Olivier)(Coleoptera: Chrysomelidae) | |
| CN101897340B (en) | Disinfestation composite containing thiacloprid and carbosulfan | |
| CN102986713A (en) | Thiacloprid and tefluthrin insecticidal active substance combination | |
| CN106070257A (en) | A kind of insecticide for Cruciferae | |
| CN1335065A (en) | Insecticide compounded with nimbin and nereistoxin | |
| CN103749524A (en) | Pesticide | |
| CN103222473A (en) | Imidacloprid and buprofezin compound pesticide | |
| CN116250541A (en) | Medicament for preventing and treating areca-nut coconut leaf beetles and application thereof | |
| Berin Pathrose et al. | Validation and Popularization of Fish Extract for the Management of Gundhi bug, Leptocorisa acuta | |
| Sinha et al. | Impact of insecticide mixtures on aphid population and fruit borer of Tomato |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160720 |
|
| RJ01 | Rejection of invention patent application after publication |