CN105820450A - Stable-coloring color tire - Google Patents
Stable-coloring color tire Download PDFInfo
- Publication number
- CN105820450A CN105820450A CN201610276840.XA CN201610276840A CN105820450A CN 105820450 A CN105820450 A CN 105820450A CN 201610276840 A CN201610276840 A CN 201610276840A CN 105820450 A CN105820450 A CN 105820450A
- Authority
- CN
- China
- Prior art keywords
- parts
- color
- base
- color tyre
- ramulus uncariae
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0025—Compositions of the sidewalls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Abstract
The invention discloses a stable-coloring color tire. Based on 100 parts of matrix rubber by weight, the sidewall part is added with 2.5-6.5 parts of dibutyltin oxide and 10-20 parts of magnesium stearate. The color tire disclosed by the invention has stable coloring under the conditions of high humidity and strong sunlight illumination.
Description
Technical field
The present invention relates to a kind of coloring stabilized color tyre.
Background technology
Conventional tire is all black or single color, it is impossible to meet user to beautiful demand, it is impossible to show user personality.Existing
In the exploitation having some companies to carry out colored sidewall, but all there is variable color in various degree in the color tyre of these early developments
The colored tire of phenomenon, especially light color, in the sun according to solarization, uses early stage metachromatism especially prominent, colored tire color after variable color
There is significant change, affect the attractive in appearance of tire, it is impossible to fully meet the needs of user.
Summary of the invention
It is an object of the invention to provide a kind of coloring stabilized color tyre.
Technical scheme
A kind of coloring stabilized color tyre, by weight, side wall portion, on the basis of base rubber 100 parts, adds Ramulus Uncariae Cum Uncis base
Stannum oxide 2.5-6.5 part, magnesium stearate 10-20 part.
Present invention additionally comprises following preferred scheme:
Preferably in scheme, by weight, side wall portion, on the basis of base rubber 100 parts, adds Ramulus Uncariae Cum Uncis base stannum oxide 3.0-
6.0 parts, magnesium stearate 12-18 part.
Preferably in scheme, by weight, in side wall portion, base rubber 100 parts, white carbon 20-50 part, paraffin oil
4-8 part, silane coupler 3-5 part, vulcanizing agent 1-2 part, vulcanization accelerator 3-5 part, coloring agent 3-6 part, antistatic additive 5-
8 parts, age resistor 4-8 part, Ramulus Uncariae Cum Uncis base stannum oxide 3.0-5.5 part, magnesium stearate 13-17 part.
Preferably in scheme, by weight, in side wall portion, base rubber 100 parts, white carbon 30-40 part, paraffin oil
5-7 part, silane coupler 4-5 part, vulcanizing agent 1-2 part, vulcanization accelerator 3-4 part, coloring agent 3-5 part, antistatic additive 5-
6 parts, age resistor 4-7 part, Ramulus Uncariae Cum Uncis base stannum oxide 4.0-5.0 part, magnesium stearate 14-16 part.
Preferably in scheme, described Ramulus Uncariae Cum Uncis base stannum oxide 4.0-4.8 part.
Preferably in scheme, described coloring agent is white carbon black, AZOpigments, phthalocyanine, which ketone, isoindolone, anthraquinone, sulfur of quinoline
One or more in indigo.
Preferably in scheme, described silane coupler is liquid Si-75.
Preferably in scheme, described vulcanizing agent is sulfur.
Preferably in scheme, described antistatic additive is ethoxylation tristearin phthalein amine.
Preferably in scheme, described age resistor is p phenylenediamine type antioxidant;Described vulcanization accelerator is guanidines;
Described base rubber is selected from least one of natural rubber and butyl rubber.
The present invention is further included in other components conventional in the tire preparation of prior art.
Beneficial effects of the present invention
The color tyre of the present invention has the discoloration-resistant performance of excellence.The sidewall tire of the present invention is in strong illumination and damp and hot
Not having metachromatism under environment, moreover, the tire of the present invention has a high tear-resistant performance simultaneously, good resistance to subdue anti-tired
Labor and ageing-resistant performance.
The color tyre of the present invention is coloring stabilized under conditions of high humidity and strong illumination.
Each component coordinated in the present invention, it is thus achieved that good resultant effect.
Detailed description of the invention
Following example are intended to that the invention will be further described, but the present invention is not limited to following embodiment.
Embodiment 1
In side wall portion, in parts by weight,
Butyl rubber 100 parts
White carbon 20 parts
Paraffin oil 4 parts
Liquid Si-75 5 parts
1 part of sulfur
Diphenylguanidine 3 parts
Thioindigo 3 parts
Ethoxylation tristearin phthalein amine 8 parts
N-phenyl-N`-cyclohexyl p-phenylenediamine 8 parts
Ramulus Uncariae Cum Uncis base stannum oxide 6.5 parts
Magnesium stearate 10 parts.
Embodiment 2
In side wall portion, in parts by weight,
Natural rubber 100 parts
White carbon 30 parts
Paraffin oil 7 parts
Liquid Si-75 5 parts
2 parts of sulfur
O-tolyl-biguanide 3 parts
White carbon black 3 parts
Ethoxylation tristearin phthalein amine 6 parts
N-phenyl-N`-cyclohexyl p-phenylenediamine 6 parts
Ramulus Uncariae Cum Uncis base stannum oxide 5.5 parts
Magnesium stearate 18 parts.
Embodiment 3
In side wall portion, in parts by weight,
Natural rubber 100 parts
White carbon 40 parts
Paraffin oil 7 parts
Liquid Si-75 5 parts
1 part of sulfur
Di-o-tolylguanidine 3 parts
Isoindolone 4 parts
Ethoxylation tristearin phthalein amine 6 parts
N-phenyl-N`-cyclohexyl p-phenylenediamine 8 parts
Ramulus Uncariae Cum Uncis base stannum oxide 4.8 parts
Magnesium stearate 15 parts.
Comparative example 1
In side wall portion, in parts by weight,
Natural rubber 100 parts
White carbon 10 parts
Paraffin oil 7 parts
Liquid Si-75 2 parts
1 part of sulfur
Di-o-tolylguanidine 3 parts
Isoindolone 4 parts
Ethoxylation tristearin phthalein amine 6 parts
N-phenyl-N`-cyclohexyl p-phenylenediamine 8 parts
Ramulus Uncariae Cum Uncis base stannum oxide 1.0 parts
Magnesium stearate 25 parts.
Comparative example 2
In side wall portion, in parts by weight,
Natural rubber 100 parts
White carbon 10 parts
Paraffin oil 7 parts
Liquid Si-75 2 parts
1 part of sulfur
Di-o-tolylguanidine 3 parts
Isoindolone 4 parts
Ethoxylation tristearin phthalein amine 6 parts
N-phenyl-N`-cyclohexyl p-phenylenediamine 8 parts
Ramulus Uncariae Cum Uncis base stannum oxide 7.0 parts
Magnesium stearate 8 parts.
Comparative example 3
In side wall portion, in parts by weight,
Natural rubber 100 parts
White carbon 10 parts
Paraffin oil 7 parts
Liquid Si-75 2 parts
1 part of sulfur
Di-o-tolylguanidine 3 parts
Isoindolone 4 parts
Ethoxylation tristearin phthalein amine 6 parts
N-phenyl-N`-cyclohexyl p-phenylenediamine 8 parts.
Comparative example 4
In side wall portion, in parts by weight,
Natural rubber 100 parts
White carbon 10 parts
Paraffin oil 7 parts
Liquid Si-75 2 parts
1 part of sulfur
Di-o-tolylguanidine 3 parts
Isoindolone 4 parts
Ethoxylation tristearin phthalein amine 6 parts.
According to above formula, prepare color tyre by conventional method.
The properties of table 1 embodiment and comparative example compares
Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 | |
Hot strength/MPa | 11.6 | 11.7 | 12.7 | 10.1 | 8.9 | 8.9 | 8.0 |
Elongation at break/% | 821 | 824 | 826 | 782 | 776 | 756 | 723 |
Resilience/% | 29 | 33 | 36 | 21 | 21 | 25 | 24 |
Persistent radiation one star under strong illumination Phase | Color keeps, existing without variable color As | Color keeps, existing without variable color As | Color keeps, existing without variable color As | Color substantially becomes Shallow | Color substantially becomes Shallow | Color substantially becomes Shallow | Color substantially shoals |
A week is processed under high humidity | Color keeps, existing without variable color As | Color keeps, existing without variable color As | Color keeps, existing without variable color As | Color substantially becomes Shallow | Color substantially becomes Shallow | Color substantially becomes Shallow | Color substantially shoals |
A star is irradiated under high humidity, strong illumination Phase | Color keeps, existing without variable color As | Color keeps, existing without variable color As | Color keeps, existing without variable color As | Color substantially becomes Shallow | Color substantially becomes Shallow | Color substantially becomes Shallow | Color substantially shoals |
Claims (10)
1. a coloring stabilized color tyre, it is characterised in that by weight, side wall portion is with base rubber 100 parts as base
Standard, adds Ramulus Uncariae Cum Uncis base stannum oxide 2.5-6.5 part, magnesium stearate 10-20 part.
Color tyre the most according to claim 1, it is characterised in that by weight, side wall portion is with base rubber 100
On the basis of Fen, add Ramulus Uncariae Cum Uncis base stannum oxide 3.0-6.0 part, magnesium stearate 12-18 part.
Color tyre the most according to claim 1, it is characterised in that by weight, in side wall portion, base rubber 100
Part, white carbon 20-50 part, paraffin oil 4-8 part, silane coupler 3-5 part, vulcanizing agent 1-2 part, vulcanization accelerator 3-5
Part, coloring agent 3-6 part, antistatic additive 5-8 part, age resistor 4-8 part, Ramulus Uncariae Cum Uncis base stannum oxide 3.0-5.5 part, magnesium stearate 13-
17 parts.
Color tyre the most according to claim 1, it is characterised in that by weight, in side wall portion, base rubber 100
Part, white carbon 30-40 part, paraffin oil 5-7 part, silane coupler 4-5 part, vulcanizing agent 1-2 part, vulcanization accelerator 3-4
Part, coloring agent 3-5 part, antistatic additive 5-6 part, age resistor 4-7 part, Ramulus Uncariae Cum Uncis base stannum oxide 4.0-5.0 part, magnesium stearate 14-
16 parts.
5. according to the color tyre described in any one of claim 1-4, it is characterised in that described Ramulus Uncariae Cum Uncis base stannum oxide 4.0-4.8
Part.
6. according to the color tyre described in any one of claim 1-4, it is characterised in that described coloring agent is white carbon black, azo face
One or more in which ketone, isoindolone, anthraquinone, thioindigo of material, phthalocyanine, quinoline.
7. according to the color tyre described in any one of claim 1-4, it is characterised in that described silane coupler is liquid Si-
75。
8. according to the color tyre described in any one of claim 1-4, it is characterised in that described vulcanizing agent is sulfur.
9. according to the color tyre described in any one of claim 1-4, it is characterised in that described antistatic additive is that ethoxylation is hard
Fat phthalein amine.
10. according to the color tyre described in any one of claim 1-4, it is characterised in that described age resistor is p-phenylenediamine class
Age resistor;Described vulcanization accelerator is guanidines;Described base rubber is selected from natural rubber and at least the one of butyl rubber
Kind.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610276840.XA CN105820450A (en) | 2016-04-29 | 2016-04-29 | Stable-coloring color tire |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610276840.XA CN105820450A (en) | 2016-04-29 | 2016-04-29 | Stable-coloring color tire |
Publications (1)
Publication Number | Publication Date |
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CN105820450A true CN105820450A (en) | 2016-08-03 |
Family
ID=56528757
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201610276840.XA Pending CN105820450A (en) | 2016-04-29 | 2016-04-29 | Stable-coloring color tire |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1294986A (en) * | 1999-11-05 | 2001-05-16 | 马鞍山海天橡胶工业有限公司 | Color motorcycle tyre and its production process |
CN101465090A (en) * | 2008-07-11 | 2009-06-24 | 谭伟林 | Colourful noctilucent tyre trade label and method of manufacturing the same |
CN102532619A (en) * | 2012-02-10 | 2012-07-04 | 青岛双星轮胎工业有限公司 | Rubber composite for sidewall of colored truck radial tire |
CN102528962A (en) * | 2010-12-22 | 2012-07-04 | 罗门哈斯公司 | Method to produce polymer modified ground tire rubber |
CN106084496A (en) * | 2016-06-20 | 2016-11-09 | 安徽海容电缆有限公司 | A kind of corrosion-resistant heat conduction cable material |
-
2016
- 2016-04-29 CN CN201610276840.XA patent/CN105820450A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1294986A (en) * | 1999-11-05 | 2001-05-16 | 马鞍山海天橡胶工业有限公司 | Color motorcycle tyre and its production process |
CN101465090A (en) * | 2008-07-11 | 2009-06-24 | 谭伟林 | Colourful noctilucent tyre trade label and method of manufacturing the same |
CN102528962A (en) * | 2010-12-22 | 2012-07-04 | 罗门哈斯公司 | Method to produce polymer modified ground tire rubber |
CN102532619A (en) * | 2012-02-10 | 2012-07-04 | 青岛双星轮胎工业有限公司 | Rubber composite for sidewall of colored truck radial tire |
CN106084496A (en) * | 2016-06-20 | 2016-11-09 | 安徽海容电缆有限公司 | A kind of corrosion-resistant heat conduction cable material |
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Application publication date: 20160803 |