CN105816353B - Low-light, which is treated, refers to coloured silk - Google Patents

Low-light, which is treated, refers to coloured silk Download PDF

Info

Publication number
CN105816353B
CN105816353B CN201510468135.5A CN201510468135A CN105816353B CN 105816353 B CN105816353 B CN 105816353B CN 201510468135 A CN201510468135 A CN 201510468135A CN 105816353 B CN105816353 B CN 105816353B
Authority
CN
China
Prior art keywords
water
ci
present invention
treated
formula
Prior art date
Application number
CN201510468135.5A
Other languages
Chinese (zh)
Other versions
CN105816353A (en
Inventor
赵明
Original Assignee
杭州莱凡网络科技有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 杭州莱凡网络科技有限公司 filed Critical 杭州莱凡网络科技有限公司
Priority to CN201510468135.5A priority Critical patent/CN105816353B/en
Publication of CN105816353A publication Critical patent/CN105816353A/en
Application granted granted Critical
Publication of CN105816353B publication Critical patent/CN105816353B/en

Links

Abstract

Treated the present invention relates to a kind of low-light and refer to coloured silk, it mainly includes the component of following mass parts:Water 40~45, polyurethane 25~29, acrylic acid esters co-polymer 20~25, compound of formula I 0.01~0.05, swelling great soil group thickener 3~5, other auxiliary agents and color stuffing are not essential.There is no photoinitiator, ethereal oil solvent, benzene, formaldehyde, ethyl acetate, DBP class harmful substances in inventive formulation, and there is environmental protection, quick-drying, be not required to illumination, form a film and stablize, a variety of colorfuls can be obtained, and can effectively prevent fungal infection.And since the present invention has the advantages that health, when use, need not carry out base oil protection, the pretreatment before first is applied without protectiveness, and glossiness of the present invention is good, it is not required that use gloss varnish;In other words, the present invention accomplished base oil, gloss varnish it is two-in-one, change script complex steps manicure work.

Description

Low-light, which is treated, refers to coloured silk

Technical field

The present invention relates to a kind of nail polish, more particularly to a kind of low-light to treat nail polish, belongs to water-based nail polish technical field.

Background technology

Nail polish is also known as nail varuish.Its main component is 70% or so volatile solvent, and 15% or so nitrification is fine Dimension element, a small amount of oil-based solvent, camphor, titanium dioxide and the molten pigment of oil.Nail polish, which is applied to after nail, forms film, strong and have There is the gloss moderately coloured, not only protect nail, but also assign a kind of aesthetic feeling of nail.

In General nail oil, in order to achieve the purpose that nail polish is quickly parched, a large amount of acetone, ethyl acetate are added The characteristics of component, both components is highly volatile, so nail polish can be killed quickly.But acetone, ethyl acetate belong to danger Dangerous chemicals, they are inflammable and explosive, volatilization when generation make us dazzling dizzy penetrating odor, to room air produce stain, In the case of long-term suction, to nervous system there may be harm, also there is strong and stimulating to mucous membrane.If have baby's in family Words, it is just more dangerous to contact this constituents.These organic solvents also have a harm, are exactly in nail in multiple Reusability Afterwards, nail can be made to change colour, becomes fragile, turns white, caused " manicure does not ruin first into counter ".

As health is increasingly paid attention to, people propose nail polish new requirement.People are also made that new nail Oil product, to solve the pollution problem of volatile solvent.

Such as the Chinese invention patent application of Application No. 201410252815.9, a kind of UV photocurings red nail is disclosed Oil, it is using oligomer such as urethane acrylate, epoxy acrylates in the UV lamp and in condition existing for photoinitiator Lower carry out cross-linked polymeric, so as to generate paint film, is free of volatile solvent, does not produce pollution substantially in product.But the product needs To be cured under uv lamps, limit use scope.The Chinese invention patent of Application No. 201210270409.6 for another example Application, discloses a kind of light efficiency gel, this kind of light efficiency gel is mainly containing acrylic monomers, acrylate oligomer and light-initiated Agent, it can be achieved with curing under LED light, and hardening time is short.The product still has photoinitiator, still needs to cure by light source, Equally limit use scope;And it is nail gels, based on semi-solid, more thick and heavy fingernail is produced during smearing Film, causes it to use limited.

The content of the invention

The invention solves above-mentioned technical problem, there is provided a kind of film forming is fast, is not required to illumination, without the micro- of ethereal oil solvent Phototherapy refers to coloured silk.

Technical proposal that the invention solves the above-mentioned problems is as follows:(in terms of mass parts)

Its compounds of formula I is shown below:

In above-mentioned technical proposal of the present invention, for water as the decentralized medium being entirely formulated, it is not only that polyurethane latex is micro- The decentralized medium of grain, and as the decentralized medium of color stuffing.Since the surface tension of water is more much higher than organic solvent, this just leads The problem of causing to color stuffing and poor nail wetting.Need to add exhibiting high surface activating agent for this to reduce surface tension.And table The problem of addition of face activating agent frequently can lead to produce bubble, so that formula complicates.In addition, water-based nail polish forms a film Afterwards, surfactant is left in nail film, is had a negative impact to the water resistance of nail film so that nail polish is easily flooded It is soaked and rises and influence to use.

And in the present invention, almost without traditional surfactant is used, this is because polyurethane -10 and esters of acrylic acid Copolymer has the dispersiveness of height in water;That is since sorting is scientific and reasonable, avoid and largely use surface-active The problem of agent.And surfactant is the concept of a broad sense, can reduce surface tension can be referred to as surface Activating agent, so some materials for being used not as surfactant, also have certain surface-active action when in use, Such as the wetting agent in the present invention, propane diols or glycerine, its own is with good water solubility, after it is distributed in water, Also the surface tension of water can be reduced, instead of the effect of surfactant to a certain extent.But glycerine or propane diols exist In inventive formulation, use mainly or as wetting agent, it enables to the other materials such as color stuffing to be spontaneously wet out by water.It is actual On, it can be spontaneously wet out by water, its essence is exactly the change of surface tension.

In the present invention, when water starts evaporation, that is, coating on nail starts to form a film.Decentralized medium is waved during film forming Hair, in the case where capillary force and surface tension promote, the emulsion particle that is stably dispersed in graininess in decentralized medium water Generation is tightly packed, and deforms upon, the rupture of particle shell, and the interface between particle is faded away, polymer molecular chain phase Mutually infiltration and winding, so as to form continuous homogeneous film.

In the present invention, the addition of glycerine or propane diols, can not only cause color stuffing to be accelerated wetting and increase wetting journey Degree, it is also possible that they have anti-settling ability;In addition, the addition of glycerine or propane diols, can also improve first film with referring to The adhesive force of first.

It is well known that water evaporation is except related in relation to factors such as the degree of drying also with environment, wind speed with environment temperature.Cause This, illumination, temperature are no longer unique factors main in other words, this, which allows for the present invention, to be consolidated without ancillary equipment It is melted into film.Also, water-based nail polish, when moisture evaporates on a small quantity, the coating on nail is formed the film more consolidated, at this time Normally referred to as surface drying, also referred to as touches and does, i.e., at this time, gently pressed with finger and it will not be impacted, it will not be inhaled The foreign matter in follower ring border, such as dust.When water further evaporates, can develop into tack-free, do to can touch, do something in disregard of obstacles, parch, do to It can recoat.And be usually developed to do to can touch and just can be considered that nail is carried out, this period is very short, the several seconds to several minutes not Deng this is related with factors such as temperature, ambient humidity, wind speed.

Water-based nail polish, compared with conventional nail polish, its auxiliary agent species is more, this is also a difficulty in R&D process Point.Although auxiliary agent content is few, only a few percent even some thousandths of, its production technology to water-based nail polish, production Quality, stable storage, easy to use etc., which have, to be significantly affected.Auxiliary agent in water-based nail polish, except above-mentioned surface (surface tension of water is reduced outside activating agent so that emulsion particle is easier to be distributed in water with other auxiliary agents), is also soaked Agent dispersant, defoamer, thickener, coalescents;There can also be color stuffing etc. in water-based nail polish.Color stuffing is added to finger Nail polish brings huge economic value, but also because of that, the destabilizing factor of bigger is brought to formula design.Conventional art In, the addition of filler often simply reduces cost, and now also in the effect of research other side, such as:Prevent pigment sedimentation, The mobility and levelability of influence water-based nail polish, the removing for influencing the gloss of film forming, contributing to film surface pollution, influence film Scrub resistance;Some fillers can also oil suction.It is inorganic such as aluminium powder organically such as PET using the filler of two-component in the present invention. The present inventor has taken into full account above-mentioned factor, have finally chosen PET and aluminium powder, they be used in conjunction with not only can effectively prevent Pigment sedimentation, can also bring gloss to water-based nail polish, and cause water-based nail polish to become prone to clear pollution and anti-scratch Wash, there is outstanding feature, it is deep to be liked by consumer.

In the present invention, glycerine has very strong water solubility, is a kind of cosolvent, it is not necessary to very much, it is only necessary to little by little Major ingredient and other auxiliary agents can be helped fully dispersed into water, also them can be helped fully to be soaked by water, also therefore, in water-based finger Nail polish field, also referred to as wetting agent on some books.

As the preferred of above-mentioned technical proposal, the swelling great soil group thickener is specially to take charge of to draw oronain bentonite.

As the preferred of above-mentioned technical proposal, the wetting agent is selected from one or both of glycerine or propane diols.

As the preferred of above-mentioned technical proposal, the pigment is selected from CI 77891, CI 19140, CI 15850, CI 77510th, CI 77019, CI 77499, CI 77491, CI 77742, CI 15880, one kind in CI45410, CI77000 or It is a variety of.

As the preferred of above-mentioned technical proposal, the low-light treats that to refer to coloured silk be water-base resin nail water, without toluene, formaldehyde, Ethyl acetate, DBP class harmful substances.

The invention has the advantages that:

1st, the present invention be using water as dispersant, using polyurethane as emulsion particle, based on the water-based nail polish that is formed;This The membrane formation mechanism of invention is as follows:Decentralized medium volatilizees, and in the case where capillary force and surface tension promote, is stablized with graininess The emulsion particle generation being dispersed in decentralized medium water is tightly packed, and deforms upon, the rupture of particle shell, between particle Interface is faded away, and polymer molecular chain is interpenetrated and wound, so as to form continuous homogeneous film;That is, work as water When fraction evaporates, significant changes occur for the interfacial tension between the emulsion particle of resinous coat therein, and fade away, Coating is caused to shrink, surface desiccation, forms water-based nail polish film, treats that water is evaporated part, be usually only necessary to several seconds time, Surface drying is just can reach, that is, is touched dry;

2nd, in this formula, the filler of PET and aluminium powder as two-component, they be used in conjunction with not only can effectively prevent face Material sedimentation, can also bring gloss to water-based nail polish, and cause water-based nail polish to become prone to clear pollution and scrubbing resistance, It is deep to be liked by consumer with outstanding feature;

3rd, to sum up, there is no photoinitiator in inventive formulation, there is no ethereal oil solvent, without benzene, formaldehyde, acetic acid second yet Ester, DBP class harmful substances, and there is environmental protection, quick-drying, be not required to illumination, form a film and stablize, and the portion in inventive formulation It is divided into point and ratio can arbitrarily adjusts according to personal like and can obtain a variety of colorfuls, such as the dosage of the species of adjustment pigment And the dosage of pearl powder, filler etc., obtain a variety of homogeneous colors such as light gold, ochre red, tender powder, naked powder, black, transparent;

4th, the present invention is due to having the advantages that health, by being adjusted to color filters type and its dosage, so as to obtain A variety of colorfuls;And since the present invention has the advantages that health, and glossiness of the present invention is good, it is easier to divests;The present invention is done Arrived base oil, gloss varnish it is two-in-one, change script complex steps manicure work.

5th, it with the addition of the compound of formula I extracted from ginkgo leaf in inventive formulation, can effectively prevent nail fungi Generation.

Embodiment

Below by embodiment, the invention will be further described.It should be understood that the method for the embodiment of the present invention It is only used for the explanation present invention, rather than limitation of the present invention, to preparation side of the invention under the concept thereof of the present invention The simple modifications of method belong to the scope of protection of present invention.All raw materials, solvent and the strain used in embodiment are purchased From Sigma Biochemical and Organic Compounds for Research and Diagnostic Clinical Reagents companies.

The preparation embodiment of compound of formula I:

Using Folium Ginkgo as raw material, crushed and soaked and extracted 2~4 times with ethanol, each 12h~72h, will extract Liquid merges, filters and the ginkgo biloba p.e medicinal extract is obtained after concentrating;Wherein ethanol:Ginkgo leaf=3~4:1, weight ratio.

By 60~120 mesh after above-mentioned ginkgo biloba p.e medicinal extract acetone solution with 2~5 times of weight for the medicinal extract Dry column-packing after silica gel mixing, is then followed successively by 9 with volume ratio:1、8:2、7:3、6:4、5:5 grade chloroform-methanol solution into Row gradient elution, it is 9 to collect wherein with volume ratio:The eluent obtained during 1 chloroform-methanol elution, is known as first and washes De- liquid;Above-mentioned first eluent silica gel column chromatography is continued to separate, 15 are followed successively by with volume ratio:1、10:1、5:1、2:1 chlorine Imitative-acetone soln carries out gradient elution, will volume be wherein 10:The eluent obtained during 1 chloroform-acetone solution elution is known as Second eluent.Above-mentioned second eluent silica gel column chromatography is continued to separate, 9 are followed successively by with volume ratio:1、8:2、7:3、6: 4、5:5 petroleum ether-ethyl acetate solution carries out gradient elution, will volume ratio be wherein 7:3 petroleum ether-ethyl acetate elution When obtained eluent be known as the 3rd eluent.

Above-mentioned 3rd eluent is passed through high pressure liquid chromatography (reversed-phase preparative chromatography of the pressure in 5-15Mpa) to be separated Purifying, the high pressure liquid chromatography use 21.2mm × 250mm, 5 μm of C18Chromatographic column, mobile phase are that the methanol of 60wt% is water-soluble Liquid, flow rate of mobile phase 12mL/min, UV detector Detection wavelength are 374nm, each 60~150 μ of Jin Yang of the 3rd eluent L, collects eluent corresponding when chromatographic peak retention time after each sample introduction is 31min, up to the Formulas I after removing solvent Compound

After obtaining above-mentioned compound of formula I, methanol solution can be again dissolved in, and using methanol solution as mobile phase, by solidifying Rubber column gel column carries out chromatography, can further purify the compound of formula I.

Formula Compound I is yellow powder;Following ultraviolet spectras, infrared spectrum and hydrogen for listing compound of formula I The key structural feature peak of nuclear-magnetism.

Ultraviolet spectra (solvent is methanol):λmax(log ε) 210 (4.36), 266 (3.82), 374 (3.68) nm;

Infrared spectrum (pressing potassium bromide troche):vmax3452,2924,2615,1668,1612,1516,1437,1316,1247, 1182,1083,1022,868,722cm-1

1H NMR(500MHz,CDCl3,ppm)δ:10.7(s-OH),9.48(s-OH)6.28-7.52(d,-CH 5H), 6.57(s,1H),6.18(s 1H),3.27(d,-CH2),1.99-3.81(d,-CH39H).

Embodiment one:

A kind of water-based nail polish of weak golden, it includes the component of following mass parts:

Oronain draws in water 42.73, polyurethane -10 24.99, acrylic acid esters co-polymer 16.43, compound of formula I 0.01, department Bentonite 4.19, glycerine 0.09, pigment (CI 77891) 0.33, high-speed stirred is uniformly mixed after the mixing of above component.

Embodiment two:

A kind of water-based nail polish of ochre red, it includes the component of following mass parts:

Oronain draws in water 43.72, polyurethane -10 26.47, acrylic acid esters co-polymer 23.12, compound of formula I 0.02, department Bentonite 4.85, glycerine 0.99, pigment (CI 77,891 0.83, CI 11,710 0.01, CI 12,490 0.01) 0.85, the above High-speed stirred is uniformly mixed after component mixing.

Embodiment three:

A kind of water-based nail polish of naked pink colour, it includes the component of following mass parts:

Oronain draws in water 44.17, polyurethane -10 20.78, acrylic acid esters co-polymer 22.43, compound of formula I 0.03, department Bentonite 4.35, glycerine 0.97, pigment (CI 77,891 0.92, CI 12,490 0.07) 0.99, after the mixing of above component at a high speed It is uniformly mixed.

Example IV:

A kind of water-based nail polish of tender pink colour, it includes the component of following mass parts:

Oronain draws in water 44.09, polyurethane -10 26.54, acrylic acid esters co-polymer 23.25, compound of formula I 0.04, department Bentonite 3.72, glycerine 1.01, pigment (CI 77,891 1.31, CI 12,490 0.08) 1.39, after the mixing of above component at a high speed It is uniformly mixed.

Embodiment five:

A kind of water-based nail polish of pearly-lustre blueness, it includes the component of following mass parts:

Oronain draws in water 41.66, polyurethane -10 28.62, acrylic acid esters co-polymer 23.27, compound of formula I 0.05, department Bentonite 4.72, glycerine 0.95, pigment (CI 77,266 0.01, CI 74,160 0.77) 0.78, after the mixing of above component at a high speed It is uniformly mixed.

Embodiment six:

A kind of pink water-based nail polish, it includes the component of following mass parts:

Oronain draws in water 43.55, polyurethane -10 26.34, acrylic acid esters co-polymer 24.18, compound of formula I 0.06, department Bentonite 3.65, glycerine 1.13, pigment (CI 77,891 0.93, CI 12,490 0.22) 1.15, after the mixing of above component at a high speed It is uniformly mixed.

Embodiment seven:

A kind of water-based nail polish of purple, it includes the component of following mass parts:

Oronain draws in water 44.98, polyurethane -10 26.17, acrylic acid esters co-polymer 23.03, compound of formula I 0.02, department Bentonite 4.58, glycerine 0.78, pigment (CI 12,490 0.12, CI 77,266 0.34) 0.46, after the mixing of above component at a high speed It is uniformly mixed.

Embodiment eight:

A kind of water-based nail polish of black, it includes the component of following mass parts:

Oronain draws in water 44.31, polyurethane -10 25.78, acrylic acid esters co-polymer 22.64, compound of formula I 0.03, department Bentonite 3.57, glycerine 1.43, pigment (CI 77266) 2.27, high-speed stirred is uniformly mixed after the mixing of above component.

Embodiment nine:

A kind of water-based nail polish of rose, it includes the component of following mass parts:

Oronain draws in water 40.97, polyurethane -10 22.82, acrylic acid esters co-polymer 25.67, compound of formula I 0.04, department Bentonite 4.28, glycerine 1.05, pigment (CI 77,891 4.17, CI 12,490 0.04) 5.21, after the mixing of above component at a high speed It is uniformly mixed.

Embodiment ten:

A kind of water-based nail polish of shallow cameo brown, it includes the component of following mass parts:

Water 51.38, polyurethane (polyurethane -35) 24.21, acrylic acid/VP cross-linked polymers 16.36, compound of formula I 0.05th, hydroxypropyl methyl cellulose 4.21, triethanolamine 0.99, laureth (laureth -21) 0.76, glycerine 0.42nd, pigment (CI 77,891 1.64, CI 11,710 0.01, CI 12,490 0.01, CI 77,266 0.01) 1.67, the above into High-speed stirred is uniformly mixed after dividing mixing.

Embodiment 11:

A kind of caesious water-based nail polish, it includes the component of following mass parts:

Water 48.72, polyurethane (polyurethane -35) 22.53, acrylic acid/VP cross-linked polymers 16.38, compound of formula I 0.01st, hydroxypropyl methyl cellulose 4.21, triethanolamine 0.99, laureth (laureth -21) 0.76, glycerine 1.28th, pigment (CI 77,891 5.12, CI 77,266 0.01) 5.13, high-speed stirred is uniformly mixed i.e. after the mixing of above component Can.

Embodiment 12:

A kind of water-based nail polish of transparent water colour, it includes the component of following mass parts:

Water 52.36, polyurethane (polyurethane -35) 27.41, acrylic acid/VP cross-linked polymers 16.41, compound of formula I 0.03rd, laureth (laureth -21) 0.82, high-speed stirred is uniformly mixed after the mixing of above component.

Activity experiment:

1st, compound of formula I activity experiment

Bacterium (Trichophyton rubrum, trichophyton gypseum and Epidermophvton trichophyta) is suspended in MH culture mediums, is disperseed Concentration is about 105Cfu ﹒ mL-1, bacterium solution is added on 96 orifice plates and (adds 100 μ L of bacterium solution per hole), using culture medium as blank control, Tested material is replaced as negative control using DMSO, with Itraconazole (Xian-Janssen Pharmaceutical Ltd.) for positive control.By Formulas I Compound is dissolved in DMSO is made into 800,400,200,100,50,25 μ g ﹒ mL respectively-1Solution is (for MIC50Less than 5 μ g ﹒ mL-1 , when carrying out step experiment, the concentration gradient of preparation is 50,25,12.5,6.25,3.1,1.5 μ g ﹒ mL-1), with every 11 μ L's of hole Amount is added on 96 orifice plates【The ultimate density of liquid is respectively 80,40,20,10,5,2.5 μ gmL-1(be 5 for the latter, 2.5,1.25,0.63,0.31 and 0.15 μ gmL-1)】, each concentration gradient does four parallel laboratory tests.96 orifice plates are put into 37 DEG C Incubator in cultivate 24h, PBSs of the 25 μ L per mL MTT containing 4mg is then added per hole, then 4h is cultivated under similarity condition, often Hole adds 100 μ LSDS lysates (95mL tri-distilled water+10gSDS+5mL isopropanol+0.1mL concentrated hydrochloric acids) and cultivates 12h afterwards.With enzyme mark Instrument measures OD values under 570nm, and percent inhibition is calculated as follows:

The height of activity is with semi-inhibit rate MIC50To represent, MIC50It is smaller, compound activity it is higher, as a result for:Formulas I Compound is to Trichophyton rubrum, trichophyton gypseum and Epidermophvton trichophyta semi-inhibit rate MIC50Respectively 0.63,0.60 and 0.82;Itraconazole is to Trichophyton rubrum, trichophyton gypseum and Epidermophvton trichophyta semi-inhibit rate MIC50Respectively 0.63, 0.70 and 0.65.

2nd, agent activity is tested:

Using preparation described in embodiment 1-5, the activity experiment being discussed below:

About 0.5mm thickness is cut from the corner of ox horn, the small pieces of 1.5 × 3cm sizes are simultaneously handled half with embodiment 1-5 preparations Side, once a day, continuous five days.Then the piece is fixed on to about 0.5cm above the aqueous agar surface of a moisture chamber It is processed half side face-down on metal column.The whole side of ox horn upward is inoculated with small point of trichophyton mentagrophytes in dots Raw spore suspension.Then, bacterium colony form is stored 10 days at 28 DEG C.

Allergenic is prevented 5 times using the pretreatment of the preparation of 1-5 of the embodiment of the present invention at half of the back side of ox horn Son germinates in whole top surface.Even after 90 days, still vaccination cannot be observed in whole top surface under the microscope.Therefore, Embodiment 1-5 preparations containing compound of formula I wherein can effectively pre- anti-fungal growth.

According to the method described above, control experiment is carried out, difference lies in being all free of compound of formula I in preparation described in embodiment 1-5, Fungi has a small number of growing points on processed ox horn side, but another half on piece observed the good growth of fungi.

The blank that invention formulation is handled is not used after inoculation, and fungi fully grows on ox horn surface.

Claims (4)

1. low-light, which is treated, refers to coloured silk, it is made of the component of following mass parts:
Its compounds of formula I is shown below:
2. low-light according to claim 1, which is treated, refers to coloured silk, it is characterised in that:The swelling great soil group thickener is specially to take charge of to draw chlorine Ammonium bentonite.
3. low-light according to claim 1 or 2, which is treated, refers to coloured silk, it is characterised in that:The wetting agent is selected from glycerine or the third two One or both of alcohol.
4. low-light according to claim 1 or 2, which is treated, refers to coloured silk, it is characterised in that:The pigment is selected from CI 77891, CI 19140、CI 15850、CI 77510、CI 77019、CI 77499、CI 77491、CI 77742、CI 15880、CI45410、 One or more in CI77000.
CN201510468135.5A 2015-08-03 2015-08-03 Low-light, which is treated, refers to coloured silk CN105816353B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510468135.5A CN105816353B (en) 2015-08-03 2015-08-03 Low-light, which is treated, refers to coloured silk

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510468135.5A CN105816353B (en) 2015-08-03 2015-08-03 Low-light, which is treated, refers to coloured silk

Publications (2)

Publication Number Publication Date
CN105816353A CN105816353A (en) 2016-08-03
CN105816353B true CN105816353B (en) 2018-04-24

Family

ID=56514459

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510468135.5A CN105816353B (en) 2015-08-03 2015-08-03 Low-light, which is treated, refers to coloured silk

Country Status (1)

Country Link
CN (1) CN105816353B (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030064044A1 (en) * 2001-04-16 2003-04-03 Chen Shih-Ruey T. Cosmetic compositions containing water-soluble polymer complexes
CN102228411A (en) * 2011-06-23 2011-11-02 谭卓华 Two-in-one water-soluble nail painting and protecting membrane solution
CN104758195A (en) * 2014-01-06 2015-07-08 万华化学(广东)有限公司 Waterborne nail polish based on aqueous polyurethane dispersion
CN104800125A (en) * 2015-05-04 2015-07-29 上海零玖科技有限公司 Nail polish and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030064044A1 (en) * 2001-04-16 2003-04-03 Chen Shih-Ruey T. Cosmetic compositions containing water-soluble polymer complexes
CN102228411A (en) * 2011-06-23 2011-11-02 谭卓华 Two-in-one water-soluble nail painting and protecting membrane solution
CN104758195A (en) * 2014-01-06 2015-07-08 万华化学(广东)有限公司 Waterborne nail polish based on aqueous polyurethane dispersion
CN104800125A (en) * 2015-05-04 2015-07-29 上海零玖科技有限公司 Nail polish and preparation method thereof

Also Published As

Publication number Publication date
CN105816353A (en) 2016-08-03

Similar Documents

Publication Publication Date Title
Gettens et al. Painting materials: a short encyclopaedia
Hsu et al. Antioxidant activity of extract from Polygonum cuspidatum
JP5980774B2 (en) Fragrance preparation, method for producing the same, and article containing the same
US20030035917A1 (en) Image making medium
US5676935A (en) Cosmetic composition containing an epoxidized oil as plasticizer
Tangen et al. Observations on pigments and morphology of Gyrodinium aureolum Hulburt, a marine dinoflagellate containing 19′-hexanoyloxyfucoxanthin as the main carotenoid
EP1060223B1 (en) Photochromic coating compound and substrate coated with same
FR2767699A1 (en) Film-forming composition thickened
BR0314370A (en) Effect pigments having surface modified with lcst and / or ucst polymers
TW200502700A (en) Colored composition, method of manufacturing color filter, and method of manufacturing black matrix
TW200417579A (en) Inorganic spherical absorption pigments
CA2145596C (en) Composition applied on nails for nail care
CN102639578A (en) Removable protective topcoat for artificial nail coatings and methods therefore
WO2003043567A3 (en) Organosilicon treated cosmetic powders, their production and use
Seth Trees and their economic importance
Vogel et al. Antioxidant properties and TLC characterization of four Chilean Haplopappus-species known as bailahuén
EP1469041A3 (en) Silverpigments
Ryu et al. Inhibition of mast cell degranulation by tanshinones from the roots of Salvia miltiorrhiza
EP2168633A3 (en) Use of a cosmetic composition comprising organic derivatives of silicium containing at least a basic moiety as pre-treatment before a composition comprising a film-forming hydrophobic polymer, a pigment and a solvent
US5340386A (en) Silicone containing artists' media
WO1992006668A1 (en) Scented nail enamels
CN101974292A (en) Hard wax oil and preparation method thereof
KR20060083892A (en) Intensely coloured red effect pigments
Maffei et al. Glandular trichomes and essential oils of developing leaves in Mentha viridis lavanduliodora
TW200615692A (en) Radiation sensitive composition and method for the preparation of the same

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information
CB02 Change of applicant information

Address after: Hangzhou City, Zhejiang province 310000 Jianggan District Jiuhua Road No. 1 Building 2 building 301 room 3

Applicant after: Hangzhou Lai Fan network technology Co., Ltd

Address before: Xihu District city of Hangzhou in West Zhejiang province 310012 No. 522 Building 9 unit 8 Room 201

Applicant before: Hangzhou Lai Fan network technology Co., Ltd

GR01 Patent grant
GR01 Patent grant