CN105816353B - Low-light, which is treated, refers to coloured silk - Google Patents
Low-light, which is treated, refers to coloured silk Download PDFInfo
- Publication number
- CN105816353B CN105816353B CN201510468135.5A CN201510468135A CN105816353B CN 105816353 B CN105816353 B CN 105816353B CN 201510468135 A CN201510468135 A CN 201510468135A CN 105816353 B CN105816353 B CN 105816353B
- Authority
- CN
- China
- Prior art keywords
- water
- present
- formula
- nail polish
- treated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Cosmetics (AREA)
Abstract
Treated the present invention relates to a kind of low-light and refer to coloured silk, it mainly includes the component of following mass parts：Water 40~45, polyurethane 25~29, acrylic acid esters co-polymer 20~25, compound of formula I 0.01~0.05, swelling great soil group thickener 3~5, other auxiliary agents and color stuffing are not essential.There is no photoinitiator, ethereal oil solvent, benzene, formaldehyde, ethyl acetate, DBP class harmful substances in inventive formulation, and there is environmental protection, quick-drying, be not required to illumination, form a film and stablize, a variety of colorfuls can be obtained, and can effectively prevent fungal infection.And since the present invention has the advantages that health, when use, need not carry out base oil protection, the pretreatment before first is applied without protectiveness, and glossiness of the present invention is good, it is not required that use gloss varnish；In other words, the present invention accomplished base oil, gloss varnish it is two-in-one, change script complex steps manicure work.
Description
Technical field
The present invention relates to a kind of nail polish, more particularly to a kind of low-light to treat nail polish, belongs to water-based nail polish technical field.
Background technology
Nail polish is also known as nail varuish.Its main component is 70% or so volatile solvent, and 15% or so nitrification is fine
Dimension element, a small amount of oil-based solvent, camphor, titanium dioxide and the molten pigment of oil.Nail polish, which is applied to after nail, forms film, strong and have
There is the gloss moderately coloured, not only protect nail, but also assign a kind of aesthetic feeling of nail.
In General nail oil, in order to achieve the purpose that nail polish is quickly parched, a large amount of acetone, ethyl acetate are added
The characteristics of component, both components is highly volatile, so nail polish can be killed quickly.But acetone, ethyl acetate belong to danger
Dangerous chemicals, they are inflammable and explosive, volatilization when generation make us dazzling dizzy penetrating odor, to room air produce stain,
In the case of long-term suction, to nervous system there may be harm, also there is strong and stimulating to mucous membrane.If have baby's in family
Words, it is just more dangerous to contact this constituents.These organic solvents also have a harm, are exactly in nail in multiple Reusability
Afterwards, nail can be made to change colour, becomes fragile, turns white, caused " manicure does not ruin first into counter ".
As health is increasingly paid attention to, people propose nail polish new requirement.People are also made that new nail
Oil product, to solve the pollution problem of volatile solvent.
Such as the Chinese invention patent application of Application No. 201410252815.9, a kind of UV photocurings red nail is disclosed
Oil, it is using oligomer such as urethane acrylate, epoxy acrylates in the UV lamp and in condition existing for photoinitiator
Lower carry out cross-linked polymeric, so as to generate paint film, is free of volatile solvent, does not produce pollution substantially in product.But the product needs
To be cured under uv lamps, limit use scope.The Chinese invention patent of Application No. 201210270409.6 for another example
Application, discloses a kind of light efficiency gel, this kind of light efficiency gel is mainly containing acrylic monomers, acrylate oligomer and light-initiated
Agent, it can be achieved with curing under LED light, and hardening time is short.The product still has photoinitiator, still needs to cure by light source,
Equally limit use scope；And it is nail gels, based on semi-solid, more thick and heavy fingernail is produced during smearing
Film, causes it to use limited.
The content of the invention
The invention solves above-mentioned technical problem, there is provided a kind of film forming is fast, is not required to illumination, without the micro- of ethereal oil solvent
Phototherapy refers to coloured silk.
Technical proposal that the invention solves the above-mentioned problems is as follows：(in terms of mass parts)
Its compounds of formula I is shown below：
In above-mentioned technical proposal of the present invention, for water as the decentralized medium being entirely formulated, it is not only that polyurethane latex is micro-
The decentralized medium of grain, and as the decentralized medium of color stuffing.Since the surface tension of water is more much higher than organic solvent, this just leads
The problem of causing to color stuffing and poor nail wetting.Need to add exhibiting high surface activating agent for this to reduce surface tension.And table
The problem of addition of face activating agent frequently can lead to produce bubble, so that formula complicates.In addition, water-based nail polish forms a film
Afterwards, surfactant is left in nail film, is had a negative impact to the water resistance of nail film so that nail polish is easily flooded
It is soaked and rises and influence to use.
And in the present invention, almost without traditional surfactant is used, this is because polyurethane -10 and esters of acrylic acid
Copolymer has the dispersiveness of height in water；That is since sorting is scientific and reasonable, avoid and largely use surface-active
The problem of agent.And surfactant is the concept of a broad sense, can reduce surface tension can be referred to as surface
Activating agent, so some materials for being used not as surfactant, also have certain surface-active action when in use,
Such as the wetting agent in the present invention, propane diols or glycerine, its own is with good water solubility, after it is distributed in water,
Also the surface tension of water can be reduced, instead of the effect of surfactant to a certain extent.But glycerine or propane diols exist
In inventive formulation, use mainly or as wetting agent, it enables to the other materials such as color stuffing to be spontaneously wet out by water.It is actual
On, it can be spontaneously wet out by water, its essence is exactly the change of surface tension.
In the present invention, when water starts evaporation, that is, coating on nail starts to form a film.Decentralized medium is waved during film forming
Hair, in the case where capillary force and surface tension promote, the emulsion particle that is stably dispersed in graininess in decentralized medium water
Generation is tightly packed, and deforms upon, the rupture of particle shell, and the interface between particle is faded away, polymer molecular chain phase
Mutually infiltration and winding, so as to form continuous homogeneous film.
In the present invention, the addition of glycerine or propane diols, can not only cause color stuffing to be accelerated wetting and increase wetting journey
Degree, it is also possible that they have anti-settling ability；In addition, the addition of glycerine or propane diols, can also improve first film with referring to
The adhesive force of first.
It is well known that water evaporation is except related in relation to factors such as the degree of drying also with environment, wind speed with environment temperature.Cause
This, illumination, temperature are no longer unique factors main in other words, this, which allows for the present invention, to be consolidated without ancillary equipment
It is melted into film.Also, water-based nail polish, when moisture evaporates on a small quantity, the coating on nail is formed the film more consolidated, at this time
Normally referred to as surface drying, also referred to as touches and does, i.e., at this time, gently pressed with finger and it will not be impacted, it will not be inhaled
The foreign matter in follower ring border, such as dust.When water further evaporates, can develop into tack-free, do to can touch, do something in disregard of obstacles, parch, do to
It can recoat.And be usually developed to do to can touch and just can be considered that nail is carried out, this period is very short, the several seconds to several minutes not
Deng this is related with factors such as temperature, ambient humidity, wind speed.
Water-based nail polish, compared with conventional nail polish, its auxiliary agent species is more, this is also a difficulty in R＆D process
Point.Although auxiliary agent content is few, only a few percent even some thousandths of, its production technology to water-based nail polish, production
Quality, stable storage, easy to use etc., which have, to be significantly affected.Auxiliary agent in water-based nail polish, except above-mentioned surface
(surface tension of water is reduced outside activating agent so that emulsion particle is easier to be distributed in water with other auxiliary agents), is also soaked
Agent dispersant, defoamer, thickener, coalescents；There can also be color stuffing etc. in water-based nail polish.Color stuffing is added to finger
Nail polish brings huge economic value, but also because of that, the destabilizing factor of bigger is brought to formula design.Conventional art
In, the addition of filler often simply reduces cost, and now also in the effect of research other side, such as：Prevent pigment sedimentation,
The mobility and levelability of influence water-based nail polish, the removing for influencing the gloss of film forming, contributing to film surface pollution, influence film
Scrub resistance；Some fillers can also oil suction.It is inorganic such as aluminium powder organically such as PET using the filler of two-component in the present invention.
The present inventor has taken into full account above-mentioned factor, have finally chosen PET and aluminium powder, they be used in conjunction with not only can effectively prevent
Pigment sedimentation, can also bring gloss to water-based nail polish, and cause water-based nail polish to become prone to clear pollution and anti-scratch
Wash, there is outstanding feature, it is deep to be liked by consumer.
In the present invention, glycerine has very strong water solubility, is a kind of cosolvent, it is not necessary to very much, it is only necessary to little by little
Major ingredient and other auxiliary agents can be helped fully dispersed into water, also them can be helped fully to be soaked by water, also therefore, in water-based finger
Nail polish field, also referred to as wetting agent on some books.
As the preferred of above-mentioned technical proposal, the swelling great soil group thickener is specially to take charge of to draw oronain bentonite.
As the preferred of above-mentioned technical proposal, the wetting agent is selected from one or both of glycerine or propane diols.
As the preferred of above-mentioned technical proposal, the pigment is selected from CI 77891, CI 19140, CI 15850, CI
77510th, CI 77019, CI 77499, CI 77491, CI 77742, CI 15880, one kind in CI45410, CI77000 or
It is a variety of.
As the preferred of above-mentioned technical proposal, the low-light treats that to refer to coloured silk be water-base resin nail water, without toluene, formaldehyde,
Ethyl acetate, DBP class harmful substances.
The invention has the advantages that：
1st, the present invention be using water as dispersant, using polyurethane as emulsion particle, based on the water-based nail polish that is formed；This
The membrane formation mechanism of invention is as follows：Decentralized medium volatilizees, and in the case where capillary force and surface tension promote, is stablized with graininess
The emulsion particle generation being dispersed in decentralized medium water is tightly packed, and deforms upon, the rupture of particle shell, between particle
Interface is faded away, and polymer molecular chain is interpenetrated and wound, so as to form continuous homogeneous film；That is, work as water
When fraction evaporates, significant changes occur for the interfacial tension between the emulsion particle of resinous coat therein, and fade away,
Coating is caused to shrink, surface desiccation, forms water-based nail polish film, treats that water is evaporated part, be usually only necessary to several seconds time,
Surface drying is just can reach, that is, is touched dry；
2nd, in this formula, the filler of PET and aluminium powder as two-component, they be used in conjunction with not only can effectively prevent face
Material sedimentation, can also bring gloss to water-based nail polish, and cause water-based nail polish to become prone to clear pollution and scrubbing resistance,
It is deep to be liked by consumer with outstanding feature；
3rd, to sum up, there is no photoinitiator in inventive formulation, there is no ethereal oil solvent, without benzene, formaldehyde, acetic acid second yet
Ester, DBP class harmful substances, and there is environmental protection, quick-drying, be not required to illumination, form a film and stablize, and the portion in inventive formulation
It is divided into point and ratio can arbitrarily adjusts according to personal like and can obtain a variety of colorfuls, such as the dosage of the species of adjustment pigment
And the dosage of pearl powder, filler etc., obtain a variety of homogeneous colors such as light gold, ochre red, tender powder, naked powder, black, transparent；
4th, the present invention is due to having the advantages that health, by being adjusted to color filters type and its dosage, so as to obtain
A variety of colorfuls；And since the present invention has the advantages that health, and glossiness of the present invention is good, it is easier to divests；The present invention is done
Arrived base oil, gloss varnish it is two-in-one, change script complex steps manicure work.
5th, it with the addition of the compound of formula I extracted from ginkgo leaf in inventive formulation, can effectively prevent nail fungi
Generation.
Embodiment
Below by embodiment, the invention will be further described.It should be understood that the method for the embodiment of the present invention
It is only used for the explanation present invention, rather than limitation of the present invention, to preparation side of the invention under the concept thereof of the present invention
The simple modifications of method belong to the scope of protection of present invention.All raw materials, solvent and the strain used in embodiment are purchased
From Sigma Biochemical and Organic Compounds for Research and Diagnostic
Clinical Reagents companies.
The preparation embodiment of compound of formula I：
Using Folium Ginkgo as raw material, crushed and soaked and extracted 2~4 times with ethanol, each 12h~72h, will extract
Liquid merges, filters and the ginkgo biloba p.e medicinal extract is obtained after concentrating；Wherein ethanol:Ginkgo leaf=3~4:1, weight ratio.
By 60~120 mesh after above-mentioned ginkgo biloba p.e medicinal extract acetone solution with 2~5 times of weight for the medicinal extract
Dry column-packing after silica gel mixing, is then followed successively by 9 with volume ratio:1、8:2、7:3、6:4、5:5 grade chloroform-methanol solution into
Row gradient elution, it is 9 to collect wherein with volume ratio:The eluent obtained during 1 chloroform-methanol elution, is known as first and washes
De- liquid；Above-mentioned first eluent silica gel column chromatography is continued to separate, 15 are followed successively by with volume ratio:1、10:1、5:1、2:1 chlorine
Imitative-acetone soln carries out gradient elution, will volume be wherein 10:The eluent obtained during 1 chloroform-acetone solution elution is known as
Second eluent.Above-mentioned second eluent silica gel column chromatography is continued to separate, 9 are followed successively by with volume ratio:1、8:2、7:3、6:
4、5:5 petroleum ether-ethyl acetate solution carries out gradient elution, will volume ratio be wherein 7:3 petroleum ether-ethyl acetate elution
When obtained eluent be known as the 3rd eluent.
Above-mentioned 3rd eluent is passed through high pressure liquid chromatography (reversed-phase preparative chromatography of the pressure in 5-15Mpa) to be separated
Purifying, the high pressure liquid chromatography use 21.2mm × 250mm, 5 μm of C18Chromatographic column, mobile phase are that the methanol of 60wt% is water-soluble
Liquid, flow rate of mobile phase 12mL/min, UV detector Detection wavelength are 374nm, each 60~150 μ of Jin Yang of the 3rd eluent
L, collects eluent corresponding when chromatographic peak retention time after each sample introduction is 31min, up to the Formulas I after removing solvent
Compound
After obtaining above-mentioned compound of formula I, methanol solution can be again dissolved in, and using methanol solution as mobile phase, by solidifying
Rubber column gel column carries out chromatography, can further purify the compound of formula I.
Formula Compound I is yellow powder；Following ultraviolet spectras, infrared spectrum and hydrogen for listing compound of formula I
The key structural feature peak of nuclear-magnetism.
Ultraviolet spectra (solvent is methanol)：λmax(log ε) 210 (4.36), 266 (3.82), 374 (3.68) nm；
Infrared spectrum (pressing potassium bromide troche)：vmax3452,2924,2615,1668,1612,1516,1437,1316,1247,
1182,1083,1022,868,722cm-1；
1H NMR(500MHz,CDCl3,ppm)δ:10.7(s-OH),9.48(s-OH)6.28-7.52(d,-CH 5H),
6.57(s,1H),6.18(s 1H),3.27(d,-CH2),1.99-3.81(d,-CH39H).
Embodiment one：
A kind of water-based nail polish of weak golden, it includes the component of following mass parts：
Oronain draws in water 42.73, polyurethane -10 24.99, acrylic acid esters co-polymer 16.43, compound of formula I 0.01, department
Bentonite 4.19, glycerine 0.09, pigment (CI 77891) 0.33, high-speed stirred is uniformly mixed after the mixing of above component.
Embodiment two：
A kind of water-based nail polish of ochre red, it includes the component of following mass parts：
Oronain draws in water 43.72, polyurethane -10 26.47, acrylic acid esters co-polymer 23.12, compound of formula I 0.02, department
Bentonite 4.85, glycerine 0.99, pigment (CI 77,891 0.83, CI 11,710 0.01, CI 12,490 0.01) 0.85, the above
High-speed stirred is uniformly mixed after component mixing.
Embodiment three：
A kind of water-based nail polish of naked pink colour, it includes the component of following mass parts：
Oronain draws in water 44.17, polyurethane -10 20.78, acrylic acid esters co-polymer 22.43, compound of formula I 0.03, department
Bentonite 4.35, glycerine 0.97, pigment (CI 77,891 0.92, CI 12,490 0.07) 0.99, after the mixing of above component at a high speed
It is uniformly mixed.
Example IV：
A kind of water-based nail polish of tender pink colour, it includes the component of following mass parts：
Oronain draws in water 44.09, polyurethane -10 26.54, acrylic acid esters co-polymer 23.25, compound of formula I 0.04, department
Bentonite 3.72, glycerine 1.01, pigment (CI 77,891 1.31, CI 12,490 0.08) 1.39, after the mixing of above component at a high speed
It is uniformly mixed.
Embodiment five：
A kind of water-based nail polish of pearly-lustre blueness, it includes the component of following mass parts：
Oronain draws in water 41.66, polyurethane -10 28.62, acrylic acid esters co-polymer 23.27, compound of formula I 0.05, department
Bentonite 4.72, glycerine 0.95, pigment (CI 77,266 0.01, CI 74,160 0.77) 0.78, after the mixing of above component at a high speed
It is uniformly mixed.
Embodiment six：
A kind of pink water-based nail polish, it includes the component of following mass parts：
Oronain draws in water 43.55, polyurethane -10 26.34, acrylic acid esters co-polymer 24.18, compound of formula I 0.06, department
Bentonite 3.65, glycerine 1.13, pigment (CI 77,891 0.93, CI 12,490 0.22) 1.15, after the mixing of above component at a high speed
It is uniformly mixed.
Embodiment seven：
A kind of water-based nail polish of purple, it includes the component of following mass parts：
Oronain draws in water 44.98, polyurethane -10 26.17, acrylic acid esters co-polymer 23.03, compound of formula I 0.02, department
Bentonite 4.58, glycerine 0.78, pigment (CI 12,490 0.12, CI 77,266 0.34) 0.46, after the mixing of above component at a high speed
It is uniformly mixed.
Embodiment eight：
A kind of water-based nail polish of black, it includes the component of following mass parts：
Oronain draws in water 44.31, polyurethane -10 25.78, acrylic acid esters co-polymer 22.64, compound of formula I 0.03, department
Bentonite 3.57, glycerine 1.43, pigment (CI 77266) 2.27, high-speed stirred is uniformly mixed after the mixing of above component.
Embodiment nine：
A kind of water-based nail polish of rose, it includes the component of following mass parts：
Oronain draws in water 40.97, polyurethane -10 22.82, acrylic acid esters co-polymer 25.67, compound of formula I 0.04, department
Bentonite 4.28, glycerine 1.05, pigment (CI 77,891 4.17, CI 12,490 0.04) 5.21, after the mixing of above component at a high speed
It is uniformly mixed.
Embodiment ten：
A kind of water-based nail polish of shallow cameo brown, it includes the component of following mass parts：
Water 51.38, polyurethane (polyurethane -35) 24.21, acrylic acid/VP cross-linked polymers 16.36, compound of formula I
0.05th, hydroxypropyl methyl cellulose 4.21, triethanolamine 0.99, laureth (laureth -21) 0.76, glycerine
0.42nd, pigment (CI 77,891 1.64, CI 11,710 0.01, CI 12,490 0.01, CI 77,266 0.01) 1.67, the above into
High-speed stirred is uniformly mixed after dividing mixing.
Embodiment 11：
A kind of caesious water-based nail polish, it includes the component of following mass parts：
Water 48.72, polyurethane (polyurethane -35) 22.53, acrylic acid/VP cross-linked polymers 16.38, compound of formula I
0.01st, hydroxypropyl methyl cellulose 4.21, triethanolamine 0.99, laureth (laureth -21) 0.76, glycerine
1.28th, pigment (CI 77,891 5.12, CI 77,266 0.01) 5.13, high-speed stirred is uniformly mixed i.e. after the mixing of above component
Can.
Embodiment 12：
A kind of water-based nail polish of transparent water colour, it includes the component of following mass parts：
Water 52.36, polyurethane (polyurethane -35) 27.41, acrylic acid/VP cross-linked polymers 16.41, compound of formula I
0.03rd, laureth (laureth -21) 0.82, high-speed stirred is uniformly mixed after the mixing of above component.
Activity experiment：
1st, compound of formula I activity experiment
Bacterium (Trichophyton rubrum, trichophyton gypseum and Epidermophvton trichophyta) is suspended in MH culture mediums, is disperseed
Concentration is about 105Cfu ﹒ mL-1, bacterium solution is added on 96 orifice plates and (adds 100 μ L of bacterium solution per hole), using culture medium as blank control,
Tested material is replaced as negative control using DMSO, with Itraconazole (Xian-Janssen Pharmaceutical Ltd.) for positive control.By Formulas I
Compound is dissolved in DMSO is made into 800,400,200,100,50,25 μ g ﹒ mL respectively-1Solution is (for MIC50Less than 5 μ g ﹒ mL-1
, when carrying out step experiment, the concentration gradient of preparation is 50,25,12.5,6.25,3.1,1.5 μ g ﹒ mL-1), with every 11 μ L's of hole
Amount is added on 96 orifice plates【The ultimate density of liquid is respectively 80,40,20,10,5,2.5 μ gmL-1(be 5 for the latter,
2.5,1.25,0.63,0.31 and 0.15 μ gmL-1)】, each concentration gradient does four parallel laboratory tests.96 orifice plates are put into 37 DEG C
Incubator in cultivate 24h, PBSs of the 25 μ L per mL MTT containing 4mg is then added per hole, then 4h is cultivated under similarity condition, often
Hole adds 100 μ LSDS lysates (95mL tri-distilled water+10gSDS+5mL isopropanol+0.1mL concentrated hydrochloric acids) and cultivates 12h afterwards.With enzyme mark
Instrument measures OD values under 570nm, and percent inhibition is calculated as follows：
The height of activity is with semi-inhibit rate MIC50To represent, MIC50It is smaller, compound activity it is higher, as a result for：Formulas I
Compound is to Trichophyton rubrum, trichophyton gypseum and Epidermophvton trichophyta semi-inhibit rate MIC50Respectively 0.63,0.60 and
0.82；Itraconazole is to Trichophyton rubrum, trichophyton gypseum and Epidermophvton trichophyta semi-inhibit rate MIC50Respectively 0.63,
0.70 and 0.65.
2nd, agent activity is tested：
Using preparation described in embodiment 1-5, the activity experiment being discussed below：
About 0.5mm thickness is cut from the corner of ox horn, the small pieces of 1.5 × 3cm sizes are simultaneously handled half with embodiment 1-5 preparations
Side, once a day, continuous five days.Then the piece is fixed on to about 0.5cm above the aqueous agar surface of a moisture chamber
It is processed half side face-down on metal column.The whole side of ox horn upward is inoculated with small point of trichophyton mentagrophytes in dots
Raw spore suspension.Then, bacterium colony form is stored 10 days at 28 DEG C.
Allergenic is prevented 5 times using the pretreatment of the preparation of 1-5 of the embodiment of the present invention at half of the back side of ox horn
Son germinates in whole top surface.Even after 90 days, still vaccination cannot be observed in whole top surface under the microscope.Therefore,
Embodiment 1-5 preparations containing compound of formula I wherein can effectively pre- anti-fungal growth.
According to the method described above, control experiment is carried out, difference lies in being all free of compound of formula I in preparation described in embodiment 1-5,
Fungi has a small number of growing points on processed ox horn side, but another half on piece observed the good growth of fungi.
The blank that invention formulation is handled is not used after inoculation, and fungi fully grows on ox horn surface.
Claims (4)
1. low-light, which is treated, refers to coloured silk, it is made of the component of following mass parts：
Its compounds of formula I is shown below：
2. low-light according to claim 1, which is treated, refers to coloured silk, it is characterised in that：The swelling great soil group thickener is specially to take charge of to draw chlorine
Ammonium bentonite.
3. low-light according to claim 1 or 2, which is treated, refers to coloured silk, it is characterised in that：The wetting agent is selected from glycerine or the third two
One or both of alcohol.
4. low-light according to claim 1 or 2, which is treated, refers to coloured silk, it is characterised in that：The pigment is selected from CI 77891, CI
19140、CI 15850、CI 77510、CI 77019、CI 77499、CI 77491、CI 77742、CI 15880、CI45410、
One or more in CI77000.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510468135.5A CN105816353B (en) | 2015-08-03 | 2015-08-03 | Low-light, which is treated, refers to coloured silk |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510468135.5A CN105816353B (en) | 2015-08-03 | 2015-08-03 | Low-light, which is treated, refers to coloured silk |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105816353A CN105816353A (en) | 2016-08-03 |
| CN105816353B true CN105816353B (en) | 2018-04-24 |
Family
ID=56514459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510468135.5A Active CN105816353B (en) | 2015-08-03 | 2015-08-03 | Low-light, which is treated, refers to coloured silk |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105816353B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108714113B (en) * | 2018-06-02 | 2021-08-17 | 浙江莱凡化妆品有限公司 | Printing nail polish and preparation process and use method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030064044A1 (en) * | 2001-04-16 | 2003-04-03 | Chen Shih-Ruey T. | Cosmetic compositions containing water-soluble polymer complexes |
| CN102228411A (en) * | 2011-06-23 | 2011-11-02 | 谭卓华 | Two-in-one water-soluble nail painting and protecting membrane solution |
| CN104758195A (en) * | 2014-01-06 | 2015-07-08 | 万华化学（广东）有限公司 | Waterborne nail polish based on aqueous polyurethane dispersion |
| CN104800125A (en) * | 2015-05-04 | 2015-07-29 | 上海零玖科技有限公司 | Nail polish and preparation method thereof |
-
2015
- 2015-08-03 CN CN201510468135.5A patent/CN105816353B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030064044A1 (en) * | 2001-04-16 | 2003-04-03 | Chen Shih-Ruey T. | Cosmetic compositions containing water-soluble polymer complexes |
| CN102228411A (en) * | 2011-06-23 | 2011-11-02 | 谭卓华 | Two-in-one water-soluble nail painting and protecting membrane solution |
| CN104758195A (en) * | 2014-01-06 | 2015-07-08 | 万华化学（广东）有限公司 | Waterborne nail polish based on aqueous polyurethane dispersion |
| CN104800125A (en) * | 2015-05-04 | 2015-07-29 | 上海零玖科技有限公司 | Nail polish and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105816353A (en) | 2016-08-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105250155B (en) | Add calcium armor water | |
| CN103229677B (en) | Agilawood production method | |
| CN103751036B (en) | A kind of UV fingernail phototherapy glue and preparation method thereof | |
| CN106634553B (en) | A kind of environment-friendly water-based woodcare paint of water dispersible and preparation method with desinsection and release anionic property | |
| CN103434309A (en) | Novel reusable water writing paper | |
| KR20110023197A (en) | Natural oil paint compos ite and thereby wood box | |
| KR101214074B1 (en) | Chemical-free synthetic wood using reed and the method of manufacturing thereof | |
| CN105816353B (en) | Low-light, which is treated, refers to coloured silk | |
| US20170035671A1 (en) | Peelable transparent diamond nail-care coat | |
| CN105496814B (en) | A kind of 4D nail polish glue and its application method | |
| CN107141949A (en) | A kind of gardens wooden bridge insect prevention, water-repellent paint and preparation method | |
| CN105816356B (en) | A kind of health refers to coloured silk | |
| KR101238660B1 (en) | Paint using natural pigment and manufacturing method of the paint | |
| Tosti et al. | Occupational airborne contact dermatitis due to ethylene glycol dimethacrylate. | |
| CN110305522A (en) | A kind of slow-release natural plants aromatic function coating | |
| AU2001269732A1 (en) | Fragrance compositions | |
| CN105816347B (en) | A kind of self-service peelable armor glue and its application method | |
| CN108084777A (en) | Environmentally friendly chalk of articles for babies table print and preparation method thereof | |
| EP2819642A1 (en) | Patterned nail varnish composition | |
| Parthasarathy et al. | Garcinia bark exudates–an important phytochemical source | |
| JP6241717B2 (en) | Powdered pseudo hair thickener | |
| CN101368130A (en) | Champignon oil solvent | |
| CN105816355B (en) | A kind of water-base resin refers to coloured silk | |
| Terada et al. | Photopolymerizable golden-varnish in the ancient East-Asian countries, and KOSHIABURA of Japan | |
| CN107281010A (en) | A kind of nail polish glue containing plants essential oil and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: Hangzhou City, Zhejiang province 310000 Jianggan District Jiuhua Road No. 1 Building 2 building 301 room 3 Applicant after: Hangzhou Lai Fan network technology Co., Ltd Address before: Xihu District city of Hangzhou in West Zhejiang province 310012 No. 522 Building 9 unit 8 Room 201 Applicant before: Hangzhou Lai Fan network technology Co., Ltd |
|
| CB02 | Change of applicant information | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |