CN105816353A - Microphototherapy nail polish - Google Patents
Microphototherapy nail polish Download PDFInfo
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- CN105816353A CN105816353A CN201510468135.5A CN201510468135A CN105816353A CN 105816353 A CN105816353 A CN 105816353A CN 201510468135 A CN201510468135 A CN 201510468135A CN 105816353 A CN105816353 A CN 105816353A
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Abstract
The invention relates to a microphototherapy nail polish. The microphototherapy nail polish mainly comprises, by mass, 40 to 45 parts of water, 25 to 29 parts of polyurethane, 20 to 25 parts of an acrylate copolymer, 0.01 to 0.05 part of a compound as shown in a formula I, 3 to 5 parts of a bentonite thickening agent, and other auxiliary agents, pigments and fillers which may or may not be included. The formula for the microphototherapy nail polish is free of a photoinitiator, a volatile oil solvent, benzene, formaldehyde, ethyl acetate and DBP harmful substances, has the advantages of environment friendliness, quick drying, no need for illumination and stable film formation, can present a plurality of dazzling colors and is capable of effectively preventing and treating fungal infection; the microphototherapy nail polish is healthy; base oil protection is not needed in usage of the microphototherapy nail polish, and protective pretreatment is not needed before smearing of nails with the nail polish; the nail polish has good glossiness, so brightening oil is not needed; so the nail polish realizes integration of base oil and brightening oil, so conventional tedious nail beautifying steps are changed.
Description
Technical field
The present invention relates to a kind of nial polish, particularly relate to a kind of low-light and treat nail polish, belong to water-based nail polish technical field.
Background technology
Nial polish is also known as nail varuish.It is mainly composed of about 70% volatile solvent, the nitrocellulose of about 15%, a small amount of oil-based solvent, Camphora, titanium dioxide and oil soluble pigment.Nial polish is applied to after fingernail be formed thin film, strong and have the gloss of appropriateness coloring, had both protected fingernail, and had given again fingernail one aesthetic feeling.
In General nail oil, in order to reach the purpose making nial polish quickly parch, adding a large amount of acetone, ethyl acetate composition, the feature of both compositions is highly volatile, so nial polish can quickly be killed.But acetone, ethyl acetate belong to hazardous chemical, and they are inflammable and explosive, when volatilization, generation is made us dazzling dizzy penetrating odor, produces room air and stains, and in the case of long-term suction, nervous system may be produced harm, also mucosa is had strong and stimulating.If family has baby, contact this constituents the most dangerous.These organic solvents also have a harm, it is simply that at repeatedly Reusability after fingernail, can make fingernail variable color, become fragile, turn white, and cause " manicure does not become counter and ruins first ".
Along with health is increasingly paid attention to, people propose new requirement to nial polish.People are also made that new nail polish products, solve the pollution problem of volatile solvent.
Chinese invention patent application such as Application No. 201410252815.9, disclose a kind of UV photocuring red nail polish, it utilizes the oligomer such as urethane acrylate, epoxy acrylate under uviol lamp and carries out cross-linked polymeric under conditions of light trigger exists, thus generate paint film, without volatile solvent in product, the most do not produce pollution.But this product needed solidifies under uv lamps, limits range.The Chinese invention patent application of Application No. 201210270409.6 for another example, discloses a kind of light efficiency gel, and this kind of light efficiency gel is mainly containing acrylic monomers, acrylate oligomer and light trigger, and it can be achieved with solidification under LED, and hardening time is short.This product still has light trigger, still needs to, by light source curing, limit range equally；And it is nail gels, based on semi-solid, produce the most thick and heavy fingernail shell membrane when smearing, cause its use limited.
Summary of the invention
The invention solves the problems that above-mentioned technical problem, it is provided that a kind of film forming is fast, be not required to illumination, low-light without ethereal oil solvent is treated and referred to coloured silk.
The technical scheme that the present invention solves the problems referred to above is as follows: (in terms of mass parts)
Its compounds of formula I is shown below:
In technique scheme of the present invention, water is as the disperse medium of whole formula, and it is not only the disperse medium of polyurethane latex microgranule, and as the disperse medium of color stuffing.Owing to the surface tension of water is more much higher than organic solvent, this results in the problem poor to color stuffing and fingernail moistening.Need for this to add exhibiting high surface activating agent to reduce surface tension.And the addition of surfactant frequently can lead to produce the problem of bubble, so that formula complicates.It addition, after water-based nail polish film forming, surfactant is left in nail film, the resistance to water of nail film is had a negative impact so that nial polish is easily flooded steep raising and rises and affect use.
And in the present invention, almost without using traditional surfactant, this is because polyurethane-10 and acrylic acid esters co-polymer have the dispersibility of height in water；That is scientific and reasonable owing to selecting materials, it is to avoid the problem of a large amount of use surfactants.And surfactant is the concept of a broad sense, i.e. can reduce and capillary can be referred to as surfactant, so some materials used not as surfactant, the most also there is certain surface-active action, such as, wetting agent in the present invention, propylene glycol or glycerol, himself have good water solublity, after it is distributed in water, also can reduce the surface tension of water, instead of the effect of surfactant to a certain extent.But glycerol or propylene glycol are in inventive formulation, mainly or using as wetting agent, it enables to other materials such as color stuffing and is spontaneously wet out by water.Can it practice, be spontaneously wet out by water, its essence be exactly capillary change.
In the present invention, when water starts to evaporate, namely the coating on fingernail starts film forming.Disperse medium volatilization during film forming, under capillary force and surface tension promote, occur tightly packed with the emulsion particle that graininess is stably dispersed in disperse medium water, and deform upon, particle shell ruptures, fading away in interface between particle, polymer molecular chain interpenetrates and is wound around, thus forms the most homogeneous film.
In the present invention, glycerol or the interpolation of propylene glycol, it is possible not only to strengthen wetness degree so that color stuffing is accelerated moistening, it is also possible to make them have anti-settling ability；It addition, glycerol or the interpolation of propylene glycol, it is also possible to improve the adhesive force of first film and fingernail.
It is known that water evaporation except with ambient temperature about also relevant with the factor such as the degree of drying of environment, wind speed.Therefore, illumination, temperature are no longer main factors, and this allows for the present invention can carry out film-forming without auxiliary equipment.Further, water-based nail polish is when moisture evaporates on a small quantity, and the coating on fingernail is the formation of the film more consolidated, now it is normally referred to as surface drying, also referred to as touches dry, the most now, gently pressing with finger and will not impact it, it also will not adsorb the foreign body of environment, such as dust.When water evaporates further, tack-free can be developed into, do to touching, do something in disregard of obstacles, parch, do to recoating.And be generally developed to do to can touch and just can be considered that fingernail is carried out, the shortest, in the several seconds to several minutes, this is relevant with factors such as temperature, ambient humidity, wind speed.
Water-based nail polish, compared with conventional nial polish, its auxiliary agent kind is many, and this is also a difficult point in R&D process.Although auxiliary agent content is few, only a few percent even some thousandths of, but it on production technology, the product quality of water-based nail polish, stably store, facilitate the aspects such as use to have appreciable impact.Auxiliary agent in water-based nail polish, (reduces the surface tension of water so that emulsion particle and other auxiliary agent are easier to be distributed in water), also wetting agent dispersant, defoamer, thickening agent, coalescents in addition to above-mentioned surfactant；Water-based nail polish can also have color stuffing etc..The nial polish that is added to of color stuffing brings huge economic worth, but also because of that, bring bigger unstable factor to formula design.In conventional art, the interpolation of filler the most simply reduces cost, and now the most also in the effect of research other side, such as: prevent pigment sedimentation, the mobility affecting water-based nail polish and levelability, affect the gloss of film forming, contribute to the removing of film surface contamination, affect the scrub resistance of film；Some filler also can oil suction.In the present invention, use the filler of double-component, organically such as PET, inorganic such as aluminium powder.The present inventor has taken into full account above-mentioned factor, have finally chosen PET and aluminium powder, they are used in conjunction with not only can effectively preventing pigment sedimentation, gloss can also be brought to water-based nail polish, and make water-based nail polish become prone to understand pollution and scrubbing resistance, there is outstanding feature, deeply liked by consumer.
In the present invention, glycerol has the strongest water solublity, is a kind of cosolvent, need not a lot, it is only necessary to major ingredient and other auxiliary agent little by little just can be helped fully dispersed in water, them also can be helped by the abundant moistening of water, the most therefore, in water-based nail polish field, some book is also referred to as wetting agent.
Preferred as technique scheme, oronain bentonite draws in described swelling great soil group thickening agent specially department.
Preferred as technique scheme, one or both in glycerol or propylene glycol of described wetting agent.
Preferred as technique scheme, one or more in CI77891, CI19140, CI15850, CI77510, CI77019, CI77499, CI77491, CI77742, CI15880, CI45410, CI77000 of described pigment.
Preferred as technique scheme, described low-light treat refer to color for water-base resin fingernail water, without toluene, formaldehyde, ethyl acetate, DBP class harmful substance.
The method have the advantages that
1, the present invention is using water as dispersant, with polyurethane as emulsion particle, based on formed water-based nail polish；The membrane formation mechanism of the present invention is as follows: disperse medium volatilizees, under capillary force and surface tension promote, occur tightly packed with the emulsion particle that graininess is stably dispersed in disperse medium water, and deform upon, particle shell ruptures, fading away in interface between particle, polymer molecular chain interpenetrates and is wound around, thus forms the most homogeneous film；That is, when water fraction evaporates, there is notable change in the interfacial tension between the emulsion particle of resinous coat therein, and fades away, and causes coating to shrink, surface mummification, form water-based nail polish film, treat that water is evaporated part, the most only need several seconds time, just can reach surface drying, i.e. touch dry；
2, in this formula, PET and aluminium powder are as the filler of double-component, and they are used in conjunction with not only can effectively preventing pigment sedimentation, gloss can also be brought to water-based nail polish, and make water-based nail polish become prone to understand pollution and scrubbing resistance, there is outstanding feature, deeply liked by consumer；
3, to sum up, inventive formulation does not has light trigger, there is no ethereal oil solvent, there is no benzene, formaldehyde, ethyl acetate, DBP class harmful substance yet, and have environmental protection, quick-drying, be not required to illumination, advantage that film forming is stable, and fractions and ratio in inventive formulation can arbitrarily adjust according to personal like and be obtained in that multiple colorful, such as adjust the consumption of the kind of pigment and the consumption of pearl essence, filler etc., it is thus achieved that light gold, ochre red, tender powder, naked powder, black, the multiple homogeneous color such as transparent；
4, due to the fact that there is healthy advantage, by color filters type and consumption thereof are adjusted, thus obtain multiple colorful；And owing to the present invention has the advantage of health, and glossiness of the present invention is good, it is easier to divest；The present invention accomplished base oil, gloss varnish two-in-one, change the manicure work of originally complex steps.
5, inventive formulation with the addition of the compound of formula I extracted from Folium Ginkgo, can effectively prevent the generation of nail fungi.
Embodiment
Below by embodiment, the invention will be further described.The method described in the embodiment of the present invention that it should be understood that is only used for the present invention rather than limitation of the present invention are described, under the concept thereof of the present invention, the simple modifications of preparation method of the present invention is broadly fallen into the scope of protection of present invention.All raw materials, solvent and the strain used in embodiment is purchased from SigmaBiochemicalandOrganicCompoundsforResearchandDiagnos ticClinicalReagents company.
The preparation embodiment of compound of formula I:
With Folium Ginkgo as raw material, pulverized and by soak with ethanol and extract 2～4 times, each 12h～72h, after being merged, filter and concentrate by extracting solution, obtained described Folium Ginkgo extract extractum；Wherein ethanol: Folium Ginkgo=3～4:1, weight ratio.
Dry column-packing after 60～120 mesh silica gel with 2～5 times of weight for described extractum after above-mentioned Folium Ginkgo extract extractum acetone solution are mixed, then it is followed successively by the grade chloroform-methanol solution of 9:1,8:2,7:3,6:4,5:5 by volume ratio and carries out gradient elution, the eluent obtained when collecting wherein with the chloroform-methanol eluting that volume ratio is 9:1, the referred to as first eluent；Continue to separate by above-mentioned first eluent silica gel column chromatography, the chloroform-acetone solution being followed successively by 15:1,10:1,5:1,2:1 by volume ratio carries out gradient elution, and the eluent obtained during by chloroform-acetone solution eluting that wherein volume is 10:1 is referred to as the second eluent.Continue to separate by above-mentioned second eluent silica gel column chromatography, the petroleum ether-ethyl acetate solution being followed successively by 9:1,8:2,7:3,6:4,5:5 by volume ratio carries out gradient elution, and the eluent obtained during by petroleum ether-ethyl acetate eluting that wherein volume ratio is 7:3 is referred to as the 3rd eluent.
Above-mentioned 3rd eluent being passed through high pressure liquid chromatography (pressure is at the reversed-phase preparative chromatography of 5-15Mpa) and carries out isolated and purified, this high pressure liquid chromatography uses 21.2mm × 250mm, the C of 5 μm18Chromatographic column, flowing is the methanol aqueous solution of 60wt% mutually, flow rate of mobile phase is 12mL/min, UV-detector detection wavelength is 374nm, 3rd each Jin Yang of eluent 60～150 μ L, collect eluent corresponding when chromatographic peak retention time after each sample introduction is 31min, after desolvation, i.e. obtain described compound of formula I
After obtaining above-mentioned compound of formula I, methanol solution can be again dissolved in, and with methanol solution for flowing phase, carry out chromatography by gel column, described compound of formula I can be purified further.
Formula I is yellow powder；The following key structural feature peak listing the ultraviolet spectra of compound of formula I, infrared spectrum and proton magnetic.
Ultraviolet spectra (solvent is methanol): λmax(log ε) 210 (4.36), 266 (3.82), 374 (3.68) nm；
Infrared spectrum (pressing potassium bromide troche): vmax3452,2924,2615,1668,1612,1516,1437,1316,1247,1182,1083,1022,868,722cm-1；
1HNMR(500MHz,CDCl3,ppm)δ:10.7(s-OH),9.48(s-OH)6.28-7.52(d,-CH5H),6.57(s,1H),6.18(s1H),3.27(d,-CH2),1.99-3.81(d,-CH39H).
Embodiment one:
A kind of water-based nail polish of weak golden, it comprises the component of following mass parts:
Oronain bentonite 4.19, glycerol 0.09, pigment (CI77891) 0.33, high-speed stirred mix homogeneously after the mixing of above composition draw in water 42.73, polyurethane-1024.99, acrylic acid esters co-polymer 16.43, compound of formula I 0.01, department.
Embodiment two:
A kind of water-based nail polish of ochre red, it comprises the component of following mass parts:
Oronain bentonite 4.85, glycerol 0.99, pigment (CI778910.83, CI117100.01, CI124900.01) 0.85, high-speed stirred mix homogeneously after the mixing of above composition draw in water 43.72, polyurethane-1026.47, acrylic acid esters co-polymer 23.12, compound of formula I 0.02, department.
Embodiment three:
A kind of water-based nail polish of naked pink colour, it comprises the component of following mass parts:
Oronain bentonite 4.35, glycerol 0.97, pigment (CI778910.92, CI124900.07) 0.99, high-speed stirred mix homogeneously after the mixing of above composition draw in water 44.17, polyurethane-1020.78, acrylic acid esters co-polymer 22.43, compound of formula I 0.03, department.
Embodiment four:
A kind of water-based nail polish of tender pink colour, it comprises the component of following mass parts:
Oronain bentonite 3.72, glycerol 1.01, pigment (CI778911.31, CI124900.08) 1.39, high-speed stirred mix homogeneously after the mixing of above composition draw in water 44.09, polyurethane-1026.54, acrylic acid esters co-polymer 23.25, compound of formula I 0.04, department.
Embodiment five:
The water-based nail polish that a kind of pearly-lustre is blue, it comprises the component of following mass parts:
Oronain bentonite 4.72, glycerol 0.95, pigment (CI772660.01, CI741600.77) 0.78, high-speed stirred mix homogeneously after the mixing of above composition draw in water 41.66, polyurethane-1028.62, acrylic acid esters co-polymer 23.27, compound of formula I 0.05, department.
Embodiment six:
A kind of pinkish water-based nail polish, it comprises the component of following mass parts:
Oronain bentonite 3.65, glycerol 1.13, pigment (CI778910.93, CI124900.22) 1.15, high-speed stirred mix homogeneously after the mixing of above composition draw in water 43.55, polyurethane-1026.34, acrylic acid esters co-polymer 24.18, compound of formula I 0.06, department.
Embodiment seven:
A kind of water-based nail polish of purple, it comprises the component of following mass parts:
Oronain bentonite 4.58, glycerol 0.78, pigment (CI124900.12, CI772660.34) 0.46, high-speed stirred mix homogeneously after the mixing of above composition draw in water 44.98, polyurethane-1026.17, acrylic acid esters co-polymer 23.03, compound of formula I 0.02, department.
Embodiment eight:
A kind of water-based nail polish of black, it comprises the component of following mass parts:
Oronain bentonite 3.57, glycerol 1.43, pigment (CI77266) 2.27, high-speed stirred mix homogeneously after the mixing of above composition draw in water 44.31, polyurethane-1025.78, acrylic acid esters co-polymer 22.64, compound of formula I 0.03, department.
Embodiment nine:
A kind of water-based nail polish of rose, it comprises the component of following mass parts:
Oronain bentonite 4.28, glycerol 1.05, pigment (CI778914.17, CI124900.04) 5.21, high-speed stirred mix homogeneously after the mixing of above composition draw in water 40.97, polyurethane-1022.82, acrylic acid esters co-polymer 25.67, compound of formula I 0.04, department.
Embodiment ten:
A kind of water-based nail polish of shallow cameo brown, it comprises the component of following mass parts:
Water 51.38, polyurethane (polyurethane-35) 24.21, acrylic acid/VP cross linked polymer 16.36, compound of formula I 0.05, hydroxypropyl methyl cellulose 4.21, triethanolamine 0.99, laureth (laureth-21) 0.76, glycerol 0.42, pigment (CI778911.64, CI117100.01, CI124900.01, CI772660.01) 1.67, high-speed stirred mix homogeneously after the mixing of above composition.
Embodiment 11:
A kind of caesious water-based nail polish, it comprises the component of following mass parts:
Water 48.72, polyurethane (polyurethane-35) 22.53, acrylic acid/VP cross linked polymer 16.38, compound of formula I 0.01, hydroxypropyl methyl cellulose 4.21, triethanolamine 0.99, laureth (laureth-21) 0.76, glycerol 1.28, pigment (CI778915.12, CI772660.01) 5.13, high-speed stirred mix homogeneously after the mixing of above composition.
Embodiment 12:
A kind of water-based nail polish of transparent water colour, it comprises the component of following mass parts:
Water 52.36, polyurethane (polyurethane-35) 27.41, acrylic acid/VP cross linked polymer 16.41, compound of formula I 0.03, laureth (laureth-21) 0.82, high-speed stirred mix homogeneously after the mixing of above composition.
Activity experiment:
1, compound of formula I activity experiment
Being suspended in MH culture medium by antibacterial (trichophyton, trichophyton gypseum and Epidermophvton trichophyton), dispersion concentration is about 105Cfu mL-1, bacterium solution is added on 96 orifice plates (every hole adds bacterium solution 100 μ L), with culture medium as blank, using DMSO replacement tested material as negative control, with itraconazole (Xian-Janssen Pharmaceutical Ltd.) as positive control.Compound of formula I is dissolved in DMSO and is made into 800,400,200,100,50,25 μ g mL respectively-1Solution is (for MIC50Less than 5 μ g mL-1, when carrying out a step experiment, the Concentraton gradient of preparation is 50,25,12.5,6.25,3.1,1.5 μ g mL-1), join on 96 orifice plates with the amount of every hole 11 μ L that [ultimate density of medicinal liquid is respectively 80,40,20,10,5,2.5 μ g mL-1(it is 5,2.5,1.25,0.63,0.31 and 0.15 μ g mL for the latter-1)], each Concentraton gradient does four parallel laboratory tests.96 orifice plates are put into cultivation 24h in the incubator of 37 DEG C, then every hole adds the 25 every mL of the μ L PBS containing 4mgMTT, cultivating 4h again under similarity condition, every hole adds 100 μ LSDS lysates (95mL tri-distilled water+10gSDS+5mL isopropanol+0.1mL concentrated hydrochloric acid) and cultivates 12h afterwards.Measuring OD value under 570nm by microplate reader, percent inhibition is calculated as follows:
The height of activity is with semi-inhibit rate MIC50Represent, MIC50The least, the activity of compound is the highest, and result is: compound of formula I is to trichophyton, trichophyton gypseum and Epidermophvton trichophyton semi-inhibit rate MIC50It is respectively 0.63,0.60 and 0.82；Itraconazole is to trichophyton, trichophyton gypseum and Epidermophvton trichophyton semi-inhibit rate MIC50It is respectively 0.63,0.70 and 0.65.
2, agent activity experiment:
Use preparation described in embodiment 1-5, the activity experiment being discussed below:
Cutting about 0.5mm from the corner of Cornu Bovis seu Bubali thick, the small pieces of 1.5 × 3cm size also process half side, once a day, continuous five days with embodiment 1-5 preparation.Then being fixed on above the aqueous agar surface of a moisture chamber on the metal column of about 0.5cm by this sheet, the half side-view processed is down.The whole side of Cornu Bovis seu Bubali upward inoculates the microgonidium suspension of Trichophyton mentagrophytes in dots.Then, bacterium colony form is stored 10 days at 28 DEG C.
The pretreatment using the preparation of embodiment of the present invention 1-5 at half back side of Cornu Bovis seu Bubali prevents fungal spore for 5 times and germinates at whole end face.The most after 90 days, still vaccination can not be observed at whole apical view under the microscope.Therefore, the embodiment 1-5 preparation containing compound of formula I can the growth of effective pre-anti-fungal.
According to the method described above, carrying out control experiment, difference is in preparation described in embodiment 1-5 all not contain compound of formula I, and fungus has minority growing point on the Cornu Bovis seu Bubali side processed, but observed the good growth of fungus in another half.
Being provided without the blank of invention formulation process after inoculation, fungus fully grows on Cornu Bovis seu Bubali surface.
Claims (4)
1. low-light is treated and is referred to coloured silk, is made up of the component of following mass parts:
Its compounds of formula I is shown below:
Low-light the most according to claim 1 is treated and is referred to coloured silk, it is characterised in that: oronain bentonite draws in described swelling great soil group thickening agent specially department.
Low-light the most according to claim 1 and 2 is treated and is referred to coloured silk, it is characterised in that: described wetting agent is selected from one or both in glycerol or propylene glycol.
Low-light the most according to claim 1 and 2 is treated and is referred to coloured silk, it is characterised in that: one or more in CI77891, CI19140, CI15850, CI77510, CI77019, CI77499, CI77491, CI77742, CI15880, CI45410, CI77000 of described pigment.
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| CN201510468135.5A CN105816353B (en) | 2015-08-03 | 2015-08-03 | Low-light, which is treated, refers to coloured silk |
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| CN201510468135.5A CN105816353B (en) | 2015-08-03 | 2015-08-03 | Low-light, which is treated, refers to coloured silk |
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| CN105816353B CN105816353B (en) | 2018-04-24 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108714113A (en) * | 2018-06-02 | 2018-10-30 | 浙江莱凡化妆品有限公司 | A kind of stamp nail polish and its preparation process and application method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030064044A1 (en) * | 2001-04-16 | 2003-04-03 | Chen Shih-Ruey T. | Cosmetic compositions containing water-soluble polymer complexes |
| CN102228411A (en) * | 2011-06-23 | 2011-11-02 | 谭卓华 | Two-in-one water-soluble nail painting and protecting membrane solution |
| CN104758195A (en) * | 2014-01-06 | 2015-07-08 | 万华化学（广东）有限公司 | Waterborne nail polish based on aqueous polyurethane dispersion |
| CN104800125A (en) * | 2015-05-04 | 2015-07-29 | 上海零玖科技有限公司 | Nail polish and preparation method thereof |
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2015
- 2015-08-03 CN CN201510468135.5A patent/CN105816353B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030064044A1 (en) * | 2001-04-16 | 2003-04-03 | Chen Shih-Ruey T. | Cosmetic compositions containing water-soluble polymer complexes |
| CN102228411A (en) * | 2011-06-23 | 2011-11-02 | 谭卓华 | Two-in-one water-soluble nail painting and protecting membrane solution |
| CN104758195A (en) * | 2014-01-06 | 2015-07-08 | 万华化学（广东）有限公司 | Waterborne nail polish based on aqueous polyurethane dispersion |
| CN104800125A (en) * | 2015-05-04 | 2015-07-29 | 上海零玖科技有限公司 | Nail polish and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108714113A (en) * | 2018-06-02 | 2018-10-30 | 浙江莱凡化妆品有限公司 | A kind of stamp nail polish and its preparation process and application method |
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