CN105802551A - Fluorescent lamp modulator tube end cap bonding technology - Google Patents
Fluorescent lamp modulator tube end cap bonding technology Download PDFInfo
- Publication number
- CN105802551A CN105802551A CN201610176161.5A CN201610176161A CN105802551A CN 105802551 A CN105802551 A CN 105802551A CN 201610176161 A CN201610176161 A CN 201610176161A CN 105802551 A CN105802551 A CN 105802551A
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- China
- Prior art keywords
- fluorescent lamp
- technique according
- end cap
- modulator tube
- accelerator
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/06—Vinyl aromatic monomers and methacrylates as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Dental Preparations (AREA)
Abstract
The invention discloses a fluorescent lamp modulator tube end cap bonding technology.The fluorescent lamp modulator tube end cap bonding technology comprises the specific following steps that firstly, acrylate monomers, an initiator, a reinforcing agent and a stabilizing agent are mixed evenly, and the mixture is smeared on a metal or plastic end cap; secondly, an accelerator, a cure activating agent and a solvent are mixed evenly, and the mixture is smeared at the tail end of a fluorescent lamp modulator tube; thirdly, the fluorescent lamp modulator tube and the end cap are connected in an abutting mode, and standing and curing at the room temperature are carried out.By means of the technology, quick positioning of the fluorescent lamp modulator tube and the end cap can be achieved in 3-5 min, usable strength can be reached in 15-30 min, the bonding strength is high, the technology is simple, operability is good, the glue dosage is only 1/5-1/3 that in a traditional technology, the activity of the accelerator printed on the modulator tube can be maintained for around 2 h, and thus sufficient time is available for gluing the end cap.
Description
Technical field
The present invention relates to a kind of fluorescent lamp pipe plug bonding process.
Background technology
Fluorescent lamp pipe plug bonding is a highly important operation in Fluorescent lamp production process, two kinds of adhesive and glue-applying technique is mainly had: 1 in current industry) with two component epoxy for adhesive, need special mixing apparatus or double cylinder packaging, it is positioned to fast, therefore easily blocking up syringe needle, automatization is more difficult, the easy xanthochromia of epoxy glue, the glue consumption of single plug bonding is big, and cost is high；2) with one-component addition curing silicone rubber for adhesive, it is necessary to special firing equipment carrys out solidified glue, and the bulk strength of silicone rubber is low, bond having a big risk unsuccessfully.
Therefore, the exploitation bonding process that a kind of locating speed is fast, adhesion strength is high, process operability is good is needed badly.
Summary of the invention
It is an object of the invention to provide a kind of fluorescent lamp pipe plug bonding process.
The technical solution used in the present invention is:
A kind of fluorescent lamp pipe plug bonding process, concrete operation step is as follows:
1) by acrylic ester monomer, initiator, reinforcing agent and stabilizer mix homogeneously, it is coated on metal or Plastic cap；
2) by accelerator, kicker and solvent mix homogeneously, it is coated in fluorescent lamp tube tail end；
3) dock by fluorescent lamp tube and plug, stand, cold curing.
Described acrylic ester monomer, initiator, reinforcing agent, stabilizer, accelerator, kicker, solvent mass ratio be 100:(2～5): (15～25): (0.005～0.01): (1～5): (0.2～0.7): (30～50).
Described acrylic ester monomer is at least one in methyl methacrylate, ethyl methacrylate, butyl methacrylate, glycidyl methacrylate, methacrylic acid-2-Octyl Nitrite, methacrylic acid-beta-hydroxy ethyl ester, methacrylic acid-β-hydroxypropyl acrylate.
Described initiator is at least one in dibenzoyl peroxide, dilauroyl peroxide, isopropyl benzene hydroperoxide, tert-butyl hydroperoxide, methyl ethyl ketone peroxide.
Described reinforcing agent is at least one in ABS, MBS, PMMA.
Described stabilizer is at least one in hydroquinone, resorcinol, 1,4-benzoquinone, p-tert-butyl catechol, hydroquinone dimethyl ether, thiophene piperazine, 2,6 ditertiary butyl p cresol.
Described accelerator is at least one in NA-22, ethylenediamine, triethylamine, DMA, vanadium acetylacetonate, acetylacetone,2,4-pentanedione, triphenylphosphine, BAA, benzyl dimethylamine tetramethyl thiourea, vinylthiourea.
Described kicker is at least one in cobalt naphthenate, iron oleate, manganese naphthenate.
Described solvent is at least one in ethanol, acetone, butanone.
The time of cold curing described in step 3) is 15～30 minutes.
The invention has the beneficial effects as follows: the technique of the present invention can realize the quick location of fluorescent lamp tube and plug for 3～5 minutes, within 15～30 minutes, namely reaching can working strength, adhesion strength is high, technique is simple, good operability, glue consumption is only the 1/5～1/3 of traditional handicraft, and brush accelerator on fluorescent tube can keep the activity of about 2 hours, has grace time to carry out plug point glue.
Detailed description of the invention
A kind of fluorescent lamp pipe plug bonding process, concrete operation step is as follows:
1) by acrylic ester monomer, initiator, reinforcing agent and stabilizer mix homogeneously, it is coated on metal or Plastic cap；
2) by accelerator, kicker and solvent mix homogeneously, it is coated in fluorescent lamp tube tail end；
3) dock by fluorescent lamp tube and plug, stand, cold curing.
Preferably, described acrylic ester monomer, initiator, reinforcing agent, stabilizer, accelerator, kicker, solvent mass ratio be 100:(2～5): (15～25): (0.005～0.01): (1～5): (0.2～0.7): (30～50).
Preferably, preferably, described acrylic ester monomer is at least one in methyl methacrylate, ethyl methacrylate, butyl methacrylate, glycidyl methacrylate, methacrylic acid-2-Octyl Nitrite, methacrylic acid-beta-hydroxy ethyl ester, methacrylic acid-β-hydroxypropyl acrylate.
Preferably, described initiator is at least one in dibenzoyl peroxide, dilauroyl peroxide, isopropyl benzene hydroperoxide, tert-butyl hydroperoxide, methyl ethyl ketone peroxide.
Preferably, described reinforcing agent is at least one in ABS, MBS, PMMA.
Preferably, described stabilizer is at least one in hydroquinone, resorcinol, 1,4-benzoquinone, p-tert-butyl catechol, hydroquinone dimethyl ether, thiophene piperazine, 2,6 ditertiary butyl p cresol.
Preferably, described accelerator is at least one in NA-22, ethylenediamine, triethylamine, DMA, vanadium acetylacetonate, acetylacetone,2,4-pentanedione, triphenylphosphine, BAA, benzyl dimethylamine tetramethyl thiourea, vinylthiourea.
Preferably, described kicker is at least one in cobalt naphthenate, iron oleate, manganese naphthenate.
Preferably, described solvent is at least one in ethanol, acetone, butanone.
Preferably, the time of cold curing described in step 3) is 15～30 minutes.
Below in conjunction with specific embodiment, the present invention is made further explanation and description.
Embodiment 1:
1) by the methyl methacrylate of 100 mass parts, the dibenzoyl peroxide of 2 mass parts, 15 mass parts the hydroquinone mix homogeneously of ABS and 0.005 mass parts, be coated on metal plug；
2) by the ethanol mix homogeneously of the ethylenediamine of 1 mass parts, the cobalt naphthenate of 0.2 mass parts and 30 mass parts, it is coated in fluorescent lamp tube tail end；
3) dock by fluorescent lamp tube and plug, stand, cold curing 15 minutes.
Embodiment 2:
1) by the ethyl methacrylate of 100 mass parts, the dibenzoyl peroxide of 3 mass parts, 20 mass parts the hydroquinone dimethyl ether mix homogeneously of MBS and 0.007 mass parts, be coated on metal plug；
2) by the ethanol mix homogeneously of the DMA of 3 mass parts, the cobalt naphthenate of 0.5 mass parts and 40 mass parts, it is coated in fluorescent lamp tube tail end；
3) dock by fluorescent lamp tube and plug, stand, cold curing 30 minutes.
Embodiment 3:
1) by the glycidyl methacrylate of 100 mass parts, the isopropyl benzene hydroperoxide of 5 mass parts, 25 mass parts the 1,4-benzoquinone mix homogeneously of ABS and 0.01 mass parts, be coated on Plastic cap；
2) by the acetone mix homogeneously of the triphenylphosphine of 5 mass parts, the iron oleate of 0.7 mass parts and 50 mass parts, it is coated in fluorescent lamp tube tail end；
3) dock by fluorescent lamp tube and plug, stand, cold curing 20 minutes.
Embodiment 4:
1) by the methacrylic acid-beta-hydroxy ethyl ester of 100 mass parts, the methyl ethyl ketone peroxide of 4 mass parts, 20 mass parts the hydroquinone mix homogeneously of PMMA and 0.01 mass parts, be coated on Plastic cap；
2) by the acetone mix homogeneously of the benzyl dimethylamine tetramethyl thiourea of 2 mass parts, the manganese naphthenate of 0.3 mass parts and 35 mass parts, it is coated in fluorescent lamp tube tail end；
3) dock by fluorescent lamp tube and plug, stand, cold curing 25 minutes.
The measure of merit of the bonding process of table 1 embodiment 1～4
Note:
In table, outward appearance refers to the outward appearance of the adhesive layer after solidification.
Ageing-resistant test: fluorescent lamp tube energising being lighted, continuous firing detects lighting tube plug adhesive layer with or without degumming or variable color after 48 hours；
High-temp resisting high-humidity resisting test: fluorescent tube is placed in 85 DEG C, air humidity be 85% environment under, after 120 hours detect lighting tube plug adhesive layer with or without degumming or variable color；
Cold-hot shock-testing: fluorescent tube is placed in 30min under the environment of-20 DEG C, then fluorescent tube is placed in 30min under the environment of 120 DEG C, repeats aforesaid operations, detects lighting tube plug adhesive layer with or without degumming or variable color after 120 hours.
Above-described embodiment is the present invention preferably embodiment; but embodiments of the present invention are also not restricted to the described embodiments; the change made under other any spirit without departing from the present invention and principle, modification, replacement, combination, simplification; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (10)
1. a fluorescent lamp pipe plug bonding process, it is characterised in that: concrete operation step is as follows:
1) by acrylic ester monomer, initiator, reinforcing agent and stabilizer mix homogeneously, it is coated on metal or Plastic cap；
2) by accelerator, kicker and solvent mix homogeneously, it is coated in fluorescent lamp tube tail end；
3) dock by fluorescent lamp tube and plug, stand, cold curing.
2. technique according to claim 1, it is characterised in that: described acrylic ester monomer, initiator, reinforcing agent, stabilizer, accelerator, kicker, solvent mass ratio be 100:(2～5): (15～25): (0.005～0.01): (1～5): (0.2～0.7): (30～50).
3. technique according to claim 1 and 2, it is characterised in that: described acrylic ester monomer is at least one in methyl methacrylate, ethyl methacrylate, butyl methacrylate, glycidyl methacrylate, methacrylic acid-2-Octyl Nitrite, methacrylic acid-beta-hydroxy ethyl ester, methacrylic acid-β-hydroxypropyl acrylate.
4. technique according to claim 3, it is characterised in that: described initiator is at least one in dibenzoyl peroxide, dilauroyl peroxide, isopropyl benzene hydroperoxide, tert-butyl hydroperoxide, methyl ethyl ketone peroxide.
5. technique according to claim 4, it is characterised in that: described reinforcing agent is at least one in ABS, MBS, PMMA.
6. technique according to claim 5, it is characterised in that: described stabilizer is at least one in hydroquinone, resorcinol, 1,4-benzoquinone, p-tert-butyl catechol, hydroquinone dimethyl ether, thiophene piperazine, 2,6 ditertiary butyl p cresol.
7. technique according to claim 6, it is characterized in that: described accelerator is at least one in NA-22, ethylenediamine, triethylamine, DMA, vanadium acetylacetonate, acetylacetone,2,4-pentanedione, triphenylphosphine, BAA, benzyl dimethylamine tetramethyl thiourea, vinylthiourea.
8. technique according to claim 7, it is characterised in that: described kicker is at least one in cobalt naphthenate, iron oleate, manganese naphthenate.
9. technique according to claim 8, it is characterised in that: described solvent is at least one in ethanol, acetone, butanone.
10. technique according to claim 9, it is characterised in that: the time of cold curing described in step 3) is 15～30 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610176161.5A CN105802551A (en) | 2016-03-24 | 2016-03-24 | Fluorescent lamp modulator tube end cap bonding technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610176161.5A CN105802551A (en) | 2016-03-24 | 2016-03-24 | Fluorescent lamp modulator tube end cap bonding technology |
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| Publication Number | Publication Date |
|---|---|
| CN105802551A true CN105802551A (en) | 2016-07-27 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610176161.5A Pending CN105802551A (en) | 2016-03-24 | 2016-03-24 | Fluorescent lamp modulator tube end cap bonding technology |
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| CN (1) | CN105802551A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102587A (en) * | 2016-11-24 | 2018-06-01 | 中航贵州飞机有限责任公司 | It is not added with the preparation method of glycidyl methacrylate modified acrylic ester adhesion agent |
| CN113105848A (en) * | 2021-03-26 | 2021-07-13 | 湖南浩森胶业有限公司 | Preparation method of flexible glue |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1360001A (en) * | 2000-12-20 | 2002-07-24 | 杭州国森化学工业有限公司 | (Methyl) acrylate adhesive |
| CN101463235A (en) * | 2007-12-18 | 2009-06-24 | 湖北回天胶业股份有限公司 | High elongation rate acrylic ester adhesive |
-
2016
- 2016-03-24 CN CN201610176161.5A patent/CN105802551A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1360001A (en) * | 2000-12-20 | 2002-07-24 | 杭州国森化学工业有限公司 | (Methyl) acrylate adhesive |
| CN101463235A (en) * | 2007-12-18 | 2009-06-24 | 湖北回天胶业股份有限公司 | High elongation rate acrylic ester adhesive |
Non-Patent Citations (3)
| Title |
|---|
| 周学良 主编: "《精细化工产品手册 胶粘剂》", 31 May 2002, 化学工业出版社 精细化工出版中心 * |
| 李和平: "《胶黏剂配方工艺手册》", 28 February 2006, 化学工业出版社 化学与应用化学出版中心 * |
| 杜瑞奎等: "常温固化聚丙烯酸酯胶粘剂", 《山西化工》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102587A (en) * | 2016-11-24 | 2018-06-01 | 中航贵州飞机有限责任公司 | It is not added with the preparation method of glycidyl methacrylate modified acrylic ester adhesion agent |
| CN113105848A (en) * | 2021-03-26 | 2021-07-13 | 湖南浩森胶业有限公司 | Preparation method of flexible glue |
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Application publication date: 20160727 |
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