CN105802113B - A kind of environment-protecting thermoplastic ice face Antiskid sole and preparation method thereof - Google Patents
A kind of environment-protecting thermoplastic ice face Antiskid sole and preparation method thereof Download PDFInfo
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- CN105802113B CN105802113B CN201610264429.0A CN201610264429A CN105802113B CN 105802113 B CN105802113 B CN 105802113B CN 201610264429 A CN201610264429 A CN 201610264429A CN 105802113 B CN105802113 B CN 105802113B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to technical field of polymer materials, there is provided it is a kind of snowfield, frost ice face, dry ice face, wet ice face road surface interface on have fine antiskid effect, low temperature flexibility is good, and environment-protecting thermoplastic ice face Antiskid sole that can be recycled repeatedly and preparation method thereof, the composition of the environment-protecting thermoplastic ice face Antiskid sole include：Epoxidation vinyl benzene butadiene styrene block copolymerization object (ESBS), styreneo-acrylonitrile resin (SAN), chlorinated polyethylene resin, china-hemp fibers, White Mineral Oil, antioxidant, zinc stearate, nano-calcium carbonate, more than component material is premixed 57 minutes in super mixer, then premix is passed through into double screw extruder, it squeezes out, be granulated, finally injection molding obtains the thermoplasticity ice face Antiskid sole at 173 175 DEG C.
Description
Technical field
The invention belongs to technical field of polymer materials, are related to thermoplastic material, more particularly to a kind of environment-protecting thermoplastic
Ice face Antiskid sole and preparation method thereof.
Background technology
102964645 B of patent CN disclose a kind of Ice surface anti-slip rubber sports shoe soles and its manufacturing method, the ice face
Antiskid rubber athletic shoe sole is by butadiene rubber, nitrile rubber, natural rubber, brombutyl, white carbon, stearic acid, oxygen
Change zinc, anti-aging agent, microwax, white smoke active agent, silane coupling agent, rosin resin, aluminium oxide, glass fibre, sulphur, accelerating agent
Composition, on-slip is preferable on the road surface interface of thin ice, snowfield and frozen soil layer.104292554 A of patent CN disclose a kind of ice face
Dynamic Anti-skidding rubber sole and its production method, ice face dynamic Anti-skidding rubber sole composition include：Natural rubber, neoprene rubber
Glue, nano silicon dioxide, plasticiser, anti-aging agent, white smoke active agent, silane coupling agent, china-hemp fibers, gathers brombutyl
Ethylene waxes, zinc oxide, sulphur, vulcanization accelerator, the ice face dynamic Anti-skidding rubber sole being prepared, snowfield, frost ice face,
Dry ice face, wet ice face road surface interface on have good antiskid effect, comprehensive performance stablize, ensure wearer will not be because of ice face
It is wet and slippery and slip.The anti-skidding technology of existing ice face is all using vulcanization rubber, and rubber is a kind of thermosetting property polymerization after vulcanization
Object, since it is during sulfidization molding, molecule interchain forms cross-bond, and it is in spatial network shape structure to make entire molecule, by
The effect of molecule interchain cross-bond, strand can not move, and prevent rubber material from being dissolved in relevant solvent, after heating
It will not melt, it is made to be difficult to recycling molding after use and is utilized.Moreover, waste old has very strong heat resistanceheat resistant, heat
Biology, mechanical resistance, it is difficult to degrade, decades all will not Lock-out fall.Long-term air storage does not only take up a large amount of soils,
And killing propagation disease is easily grown, and easily cause fire, it is known as " black pollution ".
Invention content
The defects of in order to overcome existing patented technology, the present invention provides a kind of environment-protecting thermoplastic ice face Antiskid sole and
Preparation method, the environment-protecting thermoplastic ice face Antiskid sole snowfield, frost ice face, dry ice face, wet ice face road surface circle
There is fine antiskid effect, low temperature flexibility is good, and can recycle repeatedly, economizes on resources on face；And the environmental protection
The preparation method processing step of type thermoplasticity ice face Antiskid sole is simple, easy to operate, is suitble to quantitatively produce and use.
To achieve the above object, the present invention adopts the following technical scheme that：A kind of environment-protecting thermoplastic ice face Antiskid sole, packet
Component material is included：Epoxidized styrene-butadiene-styrene block copolymer (ESBS), styrene-acrylonitrile resin
(SAN), chlorinated polyethylene resin, china-hemp fibers, White Mineral Oil, antioxidant, zinc stearate, nano-calcium carbonate are prepared.
Further, each component material is expressed as by weight：
40 parts of epoxidized styrene-butadiene-styrene block copolymer (ESBS)
25-30 parts of styrene-acrylonitrile resin (SAN)
2-3 parts of chlorinated polyethylene resin
8-12 parts of china-hemp fibers
12-15 parts of White Mineral Oil
0.2-0.3 part of antioxidant
0.5-1 part of zinc stearate
12-15 parts of nano-calcium carbonate.
Further, the parts by weight of each component material are preferably：
40 parts of epoxidized styrene-butadiene-styrene block copolymer (ESBS)
28 parts of styrene-acrylonitrile resin (SAN)
3 parts of chlorinated polyethylene resin
10 parts of china-hemp fibers
15 parts of White Mineral Oil
0.2 part of antioxidant
0.5 part of zinc stearate
12 parts of nano-calcium carbonate.
Further, the epoxidation matter of the epoxidized styrene-butadiene-styrene block copolymer (ESBS)
It measures score and is more than 4%.
Further, the melt index of the styrene-acrylonitrile resin (SAN) is higher than 20g/10min.
Further, the chlorinty of the chlorinated polyethylene resin is more than 30%.
Further, the antioxidant includes at least one kind in antioxidant 1076, antioxidant GM, antioxidant S4P.
A kind of preparation method of environment-protecting thermoplastic ice face Antiskid sole, by component material epoxidized styrene-butadiene-
Styrene block copolymer (ESBS), styrene-acrylonitrile resin (SAN), chlorinated polyethylene resin, china-hemp fibers, White Mineral Oil,
Antioxidant, zinc stearate, nano-calcium carbonate premix 5-7 minutes in super mixer, then squeeze premix by twin-screw
Go out machine, squeeze out, be granulated, finally injection molding obtains the thermoplasticity ice face Antiskid sole at 173-175 DEG C.
By taking preceding solution, the present invention has the advantages that：
1, vulcanize rubber, while retain preferable ice using the environment-protecting thermoplastic material substitution that can be recycled repeatedly
Face non-skid property and comprehensive mechanical property.The thermoplasticity ice face Antiskid sole of the present invention, the leftover pieces in production process can
It recycles, does not generate waste substantially in entire process of producing product, substance is constantly recycled, and realizes money
The mode of sustainable development of source-product-regenerated resources not only saves resource, environmental protection, but also reduces production cost, has
The social economic effect of bigger.
2, the present invention uses the preferable epoxidized styrene-butadiene-styrene block copolymer of wet-sliding resistant performance as base
Body glue by adding polar resin styrene-acrylonitrile resin (SAN) and chlorinated polyethylene resin, increases the polarity of material, carries
The hydrophily of high material, significantly improve material snowfield, frost ice face, dry ice face, wet ice face road surface interface on skid resistance
Energy.
Specific embodiment
In conjunction with specific embodiment, the present invention is further described.
Embodiment 1：
In the present embodiment 1, a kind of environment-protecting thermoplastic ice face Antiskid sole is composed of the following components：
40 parts of epoxidized styrene-butadiene-styrene block copolymer (ESBS)
28 parts of styrene-acrylonitrile resin (SAN) PN-107
3 parts of chlorinated polyethylene resin 135B
10 parts of china-hemp fibers
15 parts of White Mineral Oil
0.2 part of antioxidant GM
0.5 part of zinc stearate
12 parts of nano-calcium carbonate.
More than component material in super mixer is premixed 6 minutes, then squeezes premix by double screw extruder
Go out, be granulated, finally injection molding obtains thermoplasticity ice face Antiskid sole at 173 DEG C.
The above-mentioned environment-protecting thermoplastic ice face Antiskid sole being prepared, the on-slip coefficient of frost ice face be 0.42,
The on-slip coefficient in dry ice face is 0.42, the on-slip coefficient 0.34 in wet ice face.
Embodiment 2：
In the present embodiment 2, a kind of preparation method of environment-protecting thermoplastic ice face Antiskid sole substantially in embodiment 1
Preparation method is identical, except that：
30 parts of styrene-acrylonitrile resin (SAN) PN-107,8 parts of china-hemp fibers, 0.3 part of antioxidant GM, stearic acid
1 part of zinc；
Premix 7 minutes；175 DEG C of injection temperature.
The above-mentioned environment-protecting thermoplastic ice face Antiskid sole being prepared, the on-slip coefficient of frost ice face be 0.39,
The on-slip coefficient in dry ice face is 0.36, the on-slip coefficient 0.30 in wet ice face.
Embodiment 3：
In the present embodiment 3, a kind of preparation method of environment-protecting thermoplastic ice face Antiskid sole substantially in embodiment 1
Preparation method is identical, except that：
It is 25 parts of styrene-acrylonitrile resin (SAN) PN-117,2 parts of haloflex 135B, 12 parts of china-hemp fibers, white
12 parts of dormant oil, 15 parts of nano-calcium carbonate；
The above-mentioned environment-protecting thermoplastic ice face Antiskid sole being prepared, the on-slip coefficient of frost ice face be 0.44,
The on-slip coefficient in dry ice face is 0.42, the on-slip coefficient 0.33 in wet ice face.
After the data preparation of above-described embodiment 1~3, obtain such as the following table 1（Note：According to TM144：2011 methods are surveyed
Examination, uses 603 instruments of STM and ice face instrument of SATRA scientific ＆ technical corporation of Britain, -6 to -8 DEG C of ice surface temperature, after test pattern is
With）：
The ice face dynamic on-slip test parameter table of comparisons of anti-slip sole in table 1, embodiment 1-3
| Embodiment | Frost ice face | Dry ice face | Wet ice face |
| 1 | 0.42 | 0.42 | 0.34 |
| 2 | 0.39 | 0.36 | 0.30 |
| 3 | 0.44 | 0.42 | 0.33 |
In conclusion a kind of environment-protecting thermoplastic ice face Antiskid sole for designing and preparing according to the present invention, preparation method
It is simple and practicable, it is easy to industrialized production, the thermoplasticity ice face Antiskid sole being prepared is in snowfield, frost ice face, dry ice face, wet
There is fine antiskid effect, low temperature flexibility is good, and can recycle repeatedly, and substance obtains not on the road surface interface of ice face
It is disconnected to recycle, it realizes the mode of sustainable development of resource-product-regenerated resources, not only saves resource, environmental protection, but also
Production cost is reduced, the social economic effect with bigger.
The foregoing descriptions are merely the embodiment using this origination techniques content, any those skilled in the art use this wound
Make done modifications and changes, all belong to the scope of the claims of this creation opinion, and be not limited to those disclosed embodiments.
Claims (7)
1. a kind of environment-protecting thermoplastic ice face Antiskid sole, which is characterized in that include following component material：Epoxidation benzene second
Alkene-butadiene-styrene block copolymer (ESBS), styrene-acrylonitrile resin (SAN), chlorinated polyethylene resin, Chinese fiber crops are fine
Dimension, White Mineral Oil, antioxidant, zinc stearate, nano-calcium carbonate are prepared；Each component material is expressed as by weight：
40 parts of epoxidized styrene-butadiene-styrene block copolymer (ESBS)
25-30 parts of styrene-acrylonitrile resin (SAN)
2-3 parts of chlorinated polyethylene resin
8-12 parts of china-hemp fibers
12-15 parts of White Mineral Oil
0.2-0.3 part of antioxidant
0.5-1 part of zinc stearate
12-15 parts of nano-calcium carbonate.
2. environment-protecting thermoplastic ice face Antiskid sole according to claim 1, which is characterized in that each component material is by weight
Part is expressed as：
40 parts of epoxidized styrene-butadiene-styrene block copolymer (ESBS)
28 parts of styrene-acrylonitrile resin (SAN)
3 parts of chlorinated polyethylene resin
10 parts of china-hemp fibers
15 parts of White Mineral Oil
0.2 part of antioxidant
0.5 part of zinc stearate
12 parts of nano-calcium carbonate.
3. environment-protecting thermoplastic ice face Antiskid sole according to claim 1, it is characterised in that：The epoxidation benzene second
The epoxidation mass fraction of alkene-butadiene-styrene block copolymer (ESBS) is more than 4%.
4. environment-protecting thermoplastic ice face Antiskid sole according to claim 1, it is characterised in that：Styrene-acrylonitrile tree
The melt index of fat (SAN) is higher than 20g/10min.
5. environment-protecting thermoplastic ice face Antiskid sole according to claim 1, it is characterised in that：The haloflex
The chlorinty of resin is more than 30%.
6. environment-protecting thermoplastic ice face Antiskid sole according to claim 1, it is characterised in that：The antioxidant is at least
Including one kind in antioxidant 1076, antioxidant GM, antioxidant S4P.
7. a kind of preparation method of environment-protecting thermoplastic ice face Antiskid sole, it is characterised in that：By component material epoxidation benzene second
Alkene-butadiene-styrene block copolymer (ESBS), styrene-acrylonitrile resin (SAN), chlorinated polyethylene resin, Chinese fiber crops are fine
Dimension, White Mineral Oil, antioxidant, zinc stearate, nano-calcium carbonate premix 5-7 minutes in super mixer, then lead to premix
Double screw extruder is crossed, squeezes out, be granulated, finally injection molding obtains the thermoplasticity ice face Antiskid sole at 173-175 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610264429.0A CN105802113B (en) | 2016-04-26 | 2016-04-26 | A kind of environment-protecting thermoplastic ice face Antiskid sole and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610264429.0A CN105802113B (en) | 2016-04-26 | 2016-04-26 | A kind of environment-protecting thermoplastic ice face Antiskid sole and preparation method thereof |
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| CN105802113B true CN105802113B (en) | 2018-07-03 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292554A (en) * | 2014-08-07 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | Ice-surface dynamic anti-slip rubber sole and production method thereof |
| CN104356581A (en) * | 2014-11-13 | 2015-02-18 | 茂泰(福建)鞋材有限公司 | Anti-slip thermoplastic shoe sole and preparation method thereof |
| CN104829884A (en) * | 2015-04-24 | 2015-08-12 | 茂泰(福建)鞋材有限公司 | Antibacterial mildewproof rubber shoe sole and preparation method thereof |
-
2016
- 2016-04-26 CN CN201610264429.0A patent/CN105802113B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292554A (en) * | 2014-08-07 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | Ice-surface dynamic anti-slip rubber sole and production method thereof |
| CN104356581A (en) * | 2014-11-13 | 2015-02-18 | 茂泰(福建)鞋材有限公司 | Anti-slip thermoplastic shoe sole and preparation method thereof |
| CN104829884A (en) * | 2015-04-24 | 2015-08-12 | 茂泰(福建)鞋材有限公司 | Antibacterial mildewproof rubber shoe sole and preparation method thereof |
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| CN105802113A (en) | 2016-07-27 |
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Address after: No. 588, Jinxin Road, Jiangtou Village, Chendai Town, Jinjiang City, Quanzhou City, Fujian Province, 362000 Patentee after: Maotai (Fujian) New Material Technology Co.,Ltd. Address before: 362000 Chen Dai Zhen Jiang tou Cun, Jinjiang City, Quanzhou City, Fujian Province Patentee before: Maotai(Fujian) Soles Co.,Ltd. |