CN105802113A - Environmentally friendly thermoplastic ice non-slip sole and preparation method thereof - Google Patents
Environmentally friendly thermoplastic ice non-slip sole and preparation method thereof Download PDFInfo
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- CN105802113A CN105802113A CN201610264429.0A CN201610264429A CN105802113A CN 105802113 A CN105802113 A CN 105802113A CN 201610264429 A CN201610264429 A CN 201610264429A CN 105802113 A CN105802113 A CN 105802113A
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- ice face
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the technical field of high polymer materials, and provides an environmentally friendly thermoplastic ice non-slip sole and a preparation method thereof. The environmentally friendly thermoplastic ice non-slip sole has a good non-slip effect on a snowfield, a frost ice surface, a dry ice surface, and a wet ice road surface, and good low temperature flexibility, and can be repeatedly recycled. The environmentally friendly thermoplastic ice non-slip sole is prepared from an epoxidized styrene-butadiene-styrene block copolymer (ESBS), styrene-acrylonitrile resin (SAN), chlorinated polyethylene resin, hemp fiber, white mineral oil, an antioxidant, zinc stearate, and nano calcium carbonate. The materials are premixed in a high speed mixer for 5 to 7 minutes, and then a premix is extruded and granulated by a twin screw extruder; and finally, the thermoplastic ice non-slip sole is obtained by injection molding at a temperature of 173 to 175 DEG C.
Description
Technical field
The invention belongs to technical field of polymer materials, relate to thermoplastic, particularly to a kind of environment-protecting thermoplastic
Ice face Antiskid sole and preparation method thereof.
Background technology
Patent CN 102964645 B discloses a kind of Ice surface anti-slip rubber sports shoe soles and manufacture method, this ice face
Antiskid rubber athletic shoe sole is by butadiene rubber, nitrile rubber, natural rubber, brombutyl, white carbon, stearic acid, oxygen
Change zinc, age resistor, microwax, white smoke active agent, silane coupler, rosin resin, aluminium oxide, glass fibre, sulfur, accelerator
Composition, on the interface, road surface of thin ice, snowfield and frozen soil layer, on-slip is preferable.Patent CN 104292554 A discloses a kind of ice face
Dynamically Anti-skidding rubber sole and production method thereof, the dynamic Anti-skidding rubber sole in this ice face composition includes: natural rubber, neoprene rubber
Glue, brombutyl, nano silicon, plasticiser, age resistor, white smoke active agent, silane coupler, china-hemp fibers, poly-
Ethylene waxes, zinc oxide, sulfur, vulcanization accelerator, the dynamic Anti-skidding rubber sole in ice face prepared, snowfield, frost ice face,
Dry ice face, wet ice face interface, road surface on there is good skidproof effect, combination property is stable, ensure wearer will not be because of ice face
Wet and slippery and slip.The anti-skidding technology in existing ice face is all to use vulcanite, and rubber is a kind of thermosetting polymerization after sulfuration
Thing, owing to it is during sulfidization molding, molecule interchain forms cross-bond, and making whole molecule is spatial network shape structure, is subject to
The effect of molecule interchain cross-bond, strand cannot move, and makes elastomeric material can not be dissolved in relevant solvent, after heating
Also will not melt so that it is after using, be difficult to reclaim molding utilize.And, waste old has the strongest heat resistanceheat resistant, heat
Biological, mechanical resistance, is difficult to degraded, falls all without Lock-out decades.Long-term air storage, does not only take up a large amount of soil,
And easily grow killing propagation disease, and easily initiation fire, it is known as " black pollution ".
Summary of the invention
In order to overcome the defect of existing patented technology, the invention provides a kind of environment-protecting thermoplastic ice face Antiskid sole and
Its preparation method, described environment-protecting thermoplastic ice face Antiskid sole is on snowfield, frost ice face, dry ice face, the road surface circle in wet ice face
Having fine skidproof effect on face, low temperature flexibility is good, and can repeatedly recycle, and economizes on resources；And described environmental protection
The preparation method processing step of type thermoplasticity ice face Antiskid sole is simple, easily operates, and is suitable for production and application quantitatively.
For achieving the above object, the present invention adopts the following technical scheme that a kind of environment-protecting thermoplastic ice face Antiskid sole, bag
Include component material: epoxidized styrene-butadiene-styrene block copolymer (ESBS), SAN
(SAN), chlorinated polyethylene resin, china-hemp fibers, white mineral oil, antioxidant, zinc stearate, nano-calcium carbonate are prepared from.
Further, each component material is expressed as by weight:
Epoxidized styrene-butadiene-styrene block copolymer (ESBS) 40 parts
SAN (SAN) 25-30 parts
Chlorinated polyethylene resin 2-3 parts
China-hemp fibers 8-12 parts
White mineral oil 12-15 parts
0.2-0.3 part of antioxidant
Zinc stearate 0.5-1 part
Nano-calcium carbonate 12-15 parts.
Further, the weight portion of each component material is preferably:
Epoxidized styrene-butadiene-styrene block copolymer (ESBS) 40 parts
SAN (SAN) 28 parts
Chlorinated polyethylene resin 3 parts
China-hemp fibers 10 parts
White mineral oil 15 parts
0.2 part of antioxidant
Zinc stearate 0.5 part
Nano-calcium carbonate 12 parts.
Further, the epoxidation matter of described epoxidized styrene-butadiene-styrene block copolymer (ESBS)
Amount mark is more than 4%.
Further, the melt index of described SAN (SAN) is higher than 20g/10min.
Further, the chlorinty of described chlorinated polyethylene resin is more than 30%.
Further, described antioxidant at least includes the one in antioxidant 1076, antioxidant GM, antioxidant S4P.
A kind of preparation method of environment-protecting thermoplastic ice face Antiskid sole, by component material epoxidized styrene-butadiene-
Styrene block copolymer (ESBS), SAN (SAN), chlorinated polyethylene resin, china-hemp fibers, white mineral oil,
Antioxidant, zinc stearate, nano-calcium carbonate premix 5-7 minute in super mixer, then premix material are squeezed by twin screw
Going out machine, extrusion, pelletize, finally at 173-175 DEG C, injection mo(u)lding obtains described thermoplasticity ice face Antiskid sole.
By taking preceding solution, there is advantages that
1, use the environment-protecting thermoplastic material substitution vulcanite that can repeatedly recycle, retain preferable ice face simultaneously and prevent
Slip energy and comprehensive mechanical property.Leftover pieces in the thermoplasticity ice face Antiskid sole of the present invention, production process can reclaim
Utilizing, the most do not produce garbage in whole process of producing product, material is constantly recycled, it is achieved resource-product
The mode of sustainable development of product-regenerated resources, not only saves resource, protection environment, and reduces production cost, have bigger
Social economic effect.
2, the present invention uses the preferable epoxidized styrene-butadiene-styrene block copolymer of wet-sliding resistant performance to be base
Body glue, by adding polar resin SAN (SAN) and chlorinated polyethylene resin, increases the polarity of material, carries
The hydrophilic of high material, significantly improve material snowfield, frost ice face, dry ice face, wet ice face interface, road surface on skid resistance
Energy.
Detailed description of the invention
In conjunction with specific embodiment, the present invention is further described.
Embodiment 1:
In the present embodiment 1, a kind of environment-protecting thermoplastic ice face Antiskid sole is composed of the following components:
Epoxidized styrene-butadiene-styrene block copolymer (ESBS) 40 parts
SAN (SAN) PN-107 28 parts
Chlorinated polyethylene resin 135B 3 parts
China-hemp fibers 10 parts
White mineral oil 15 parts
Antioxidant GM 0.2 part
Zinc stearate 0.5 part
Nano-calcium carbonate 12 parts.
Above component material is premixed in super mixer 6 minutes, then by premix material by double screw extruder, squeeze
Go out, pelletize, finally at 173 DEG C, injection mo(u)lding obtains thermoplasticity ice face Antiskid sole.
The above-mentioned environment-protecting thermoplastic ice face Antiskid sole prepared, the on-slip coefficient in frost ice face is 0.42,
The on-slip coefficient in dry ice face is 0.42, on-slip coefficient 0.34 in wet ice face.
Embodiment 2:
In the present embodiment 2, the preparation substantially and in embodiment 1 of the preparation method of a kind of environment-protecting thermoplastic ice face Antiskid sole
Method is identical, except that:
SAN (SAN) PN-107 30 parts, china-hemp fibers 8 parts, antioxidant GM 0.3 part, zinc stearate 1
Part；
Premix 7 minutes；Injection temperature 175 DEG C.
The above-mentioned environment-protecting thermoplastic ice face Antiskid sole prepared, the on-slip coefficient in frost ice face is 0.39,
The on-slip coefficient in dry ice face is 0.36, on-slip coefficient 0.30 in wet ice face.
Embodiment 3:
In the present embodiment 3, the preparation substantially and in embodiment 1 of the preparation method of a kind of environment-protecting thermoplastic ice face Antiskid sole
Method is identical, except that:
SAN (SAN) PN-117 25 parts, chlorinated polyethylene 135B 2 parts, china-hemp fibers 12 parts, white mineral oil
12 parts, nano-calcium carbonate 15 parts；
The above-mentioned environment-protecting thermoplastic ice face Antiskid sole prepared, the on-slip coefficient in frost ice face is 0.44, at dry ice
The on-slip coefficient in face is 0.42, on-slip coefficient 0.33 in wet ice face.
After the data compilation of above-described embodiment 1～3, obtain such as following table 1(note: survey according to TM144:2011 method
Examination, uses STM 603 instrument and the ice face instrument of SATRA scientific & technical corporation of Britain, and ice surface temperature-6 to-8 DEG C, after test pattern is
With):
The dynamic on-slip in the ice face test parameter synopsis of anti-slip sole in table 1, embodiment 1-3
| Embodiment | Frost ice face | Dry ice face | Wet ice face |
| 1 | 0.42 | 0.42 | 0.34 |
| 2 | 0.39 | 0.36 | 0.30 |
| 3 | 0.44 | 0.42 | 0.33 |
In sum, a kind of environment-protecting thermoplastic ice face Antiskid sole designing according to the present invention and preparing, preparation method is simple
Easy, it is easy to industrialized production, the thermoplasticity ice face Antiskid sole prepared is in snowfield, frost ice face, dry ice face, wet ice face
Interface, road surface on there is fine skidproof effect, low temperature flexibility is good, and can repeatedly recycle, and material is constantly followed
Ring utilizes, it is achieved the mode of sustainable development of resource-product-regenerated resources, not only saves resource, protection environment, and reduces
Production cost, has bigger social economic effect.
Described above, only utilize the embodiment of this origination techniques content, any those skilled in the art to use this wound
Make modification, the change done, all belong to the scope of the claims that this creation is advocated, and be not limited to those disclosed embodiments.
Claims (8)
1. an environment-protecting thermoplastic ice face Antiskid sole, it is characterised in that include following component material: epoxidation benzene second
Alkene-butadiene-styrene block copolymer (ESBS), SAN (SAN), chlorinated polyethylene resin, Fructus Cannabis are fine
Dimension, white mineral oil, antioxidant, zinc stearate, nano-calcium carbonate are prepared from.
Environment-protecting thermoplastic ice face the most according to claim 1 Antiskid sole, it is characterised in that each component material is by weight
Part is expressed as:
Epoxidized styrene-butadiene-styrene block copolymer (ESBS) 40 parts
SAN (SAN) 25-30 parts
Chlorinated polyethylene resin 2-3 parts
China-hemp fibers 8-12 parts
White mineral oil 12-15 parts
0.2-0.3 part of antioxidant
Zinc stearate 0.5-1 part
Nano-calcium carbonate 12-15 parts.
Environment-protecting thermoplastic ice face the most according to claim 2 Antiskid sole, it is characterised in that each component material is by weight
Part is expressed as:
Epoxidized styrene-butadiene-styrene block copolymer (ESBS) 40 parts
SAN (SAN) 28 parts
Chlorinated polyethylene resin 3 parts
China-hemp fibers 10 parts
White mineral oil 15 parts
0.2 part of antioxidant
Zinc stearate 0.5 part
Nano-calcium carbonate 12 parts.
Environment-protecting thermoplastic ice face the most according to claim 1 and 2 Antiskid sole, it is characterised in that: described epoxidation benzene
The epoxidation mass fraction of ethylene-butadiene-styrene block copolymer (ESBS) is more than 4%.
Environment-protecting thermoplastic ice face the most according to claim 1 and 2 Antiskid sole, it is characterised in that: styrene-acrylonitrile
The melt index of resin (SAN) is higher than 20g/10min.
Environment-protecting thermoplastic ice face the most according to claim 1 and 2 Antiskid sole, it is characterised in that: described chlorination gathers
The chlorinty of vinyl is more than 30%.
Environment-protecting thermoplastic ice face the most according to claim 1 and 2 Antiskid sole, it is characterised in that: described antioxidant
At least include the one in antioxidant 1076, antioxidant GM, antioxidant S4P.
8. the preparation method of an environment-protecting thermoplastic ice face Antiskid sole, it is characterised in that: by component material epoxidation benzene second
Alkene-butadiene-styrene block copolymer (ESBS), SAN (SAN), chlorinated polyethylene resin, Fructus Cannabis are fine
Dimension, white mineral oil, antioxidant, zinc stearate, nano-calcium carbonate premix 5-7 minute in super mixer, then premix material are led to
Crossing double screw extruder, extrusion, pelletize, finally at 173-175 DEG C, injection mo(u)lding obtains described thermoplasticity ice face Antiskid sole.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610264429.0A CN105802113B (en) | 2016-04-26 | 2016-04-26 | A kind of environment-protecting thermoplastic ice face Antiskid sole and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610264429.0A CN105802113B (en) | 2016-04-26 | 2016-04-26 | A kind of environment-protecting thermoplastic ice face Antiskid sole and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105802113A true CN105802113A (en) | 2016-07-27 |
| CN105802113B CN105802113B (en) | 2018-07-03 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292554A (en) * | 2014-08-07 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | Ice-surface dynamic anti-slip rubber sole and production method thereof |
| CN104356581A (en) * | 2014-11-13 | 2015-02-18 | 茂泰(福建)鞋材有限公司 | Anti-slip thermoplastic shoe sole and preparation method thereof |
| CN104829884A (en) * | 2015-04-24 | 2015-08-12 | 茂泰(福建)鞋材有限公司 | Antibacterial mildewproof rubber shoe sole and preparation method thereof |
-
2016
- 2016-04-26 CN CN201610264429.0A patent/CN105802113B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292554A (en) * | 2014-08-07 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | Ice-surface dynamic anti-slip rubber sole and production method thereof |
| CN104356581A (en) * | 2014-11-13 | 2015-02-18 | 茂泰(福建)鞋材有限公司 | Anti-slip thermoplastic shoe sole and preparation method thereof |
| CN104829884A (en) * | 2015-04-24 | 2015-08-12 | 茂泰(福建)鞋材有限公司 | Antibacterial mildewproof rubber shoe sole and preparation method thereof |
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| Publication number | Publication date |
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| CN105802113B (en) | 2018-07-03 |
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Address after: No. 588, Jinxin Road, Jiangtou Village, Chendai Town, Jinjiang City, Quanzhou City, Fujian Province, 362000 Patentee after: Maotai (Fujian) New Material Technology Co.,Ltd. Address before: 362000 Chen Dai Zhen Jiang tou Cun, Jinjiang City, Quanzhou City, Fujian Province Patentee before: Maotai(Fujian) Soles Co.,Ltd. |