CN105802108A - Machine tool foundation built by adopting foaming cement - Google Patents

Machine tool foundation built by adopting foaming cement Download PDF

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Publication number
CN105802108A
CN105802108A CN201610155220.0A CN201610155220A CN105802108A CN 105802108 A CN105802108 A CN 105802108A CN 201610155220 A CN201610155220 A CN 201610155220A CN 105802108 A CN105802108 A CN 105802108A
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China
Prior art keywords
parts
foam cement
phenyl ring
build
alkene
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Granted
Application number
CN201610155220.0A
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Chinese (zh)
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CN105802108B (en
Inventor
马峻
薛松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIAXING CITY ST. LOUIS SANITARY WARE CO., LTD.
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Suzhou Yasike Precision Numerical Control Co Ltd
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Priority to CN201610155220.0A priority Critical patent/CN105802108B/en
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Publication of CN105802108B publication Critical patent/CN105802108B/en
Expired - Fee Related legal-status Critical Current
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/10Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
    • C08F283/105Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule on to unsaturated polymers containing more than one epoxy radical per molecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2351/08Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)

Abstract

The invention belongs to the field of soft soil foundations and particularly provides a machine tool foundation built by adopting foaming cement.The foaming cement is prepared from, by weight, 10-20 parts of double-bond epoxy resin, 10-20 parts of 1,4,5,8-naphthalene tetracarboxylic acid, 5-10 parts of olefin with a benzene ring, 1-4 parts of an anti-aging agent, 10-15 parts of iron ore slag, 1-3 parts of zinc ore slag, 20-30 parts of ethanol and 3-10 parts of a catalyst, wherein the olefin with the benzene ring is a C10H10 compound containing one benzene ring and two double bonds.The machine tool foundation can be directly built on soft soil, and the construction quantity and the manpower costs can be reduced.

Description

A kind of lathe ground using foam cement to build
Technical field
The invention belongs to soft soil foundation field, a kind of lathe ground using foam cement to build.
Background technology
Heavy machine tool is widely used in fields such as the machinery of China, space flight, national defence, the energy, is China's equipment The product that manufacturing industry is representative.But, one of subject matter that domestic heavy machine tool presently, there are is precisely due to heavy machine The huge quality of bed volume is very big, and ground is difficult to meet the requirement of lathe load-bearing, and the ground in especially a lot of areas is the softest, in order to make Obtaining heavy machine tool at work can be steady, generally requires and ground is carried out consolidation process, such as Chinese patent CN103469783A " a kind of soft soil foundation reinforcing method ", described reinforcement means uses weak soil compacting equipment, and described weak soil compacting equipment includes: nip drum Machine and two set rail pressure devices;Described reinforcement means comprises the steps: first to determine a drafts of soft soil foundation;Arrange Four basic points regularly;Described nip drum machine is arranged on compacting initial position;Make the front stretching of described two set rail pressure devices respectively Mechanism and rear telescoping mechanism alternating movement, described nip drum machine seesaws accordingly, thus is compacted described soft soil foundation, Until actual drafts meets the requirement of overall reduction.And for example Chinese patent CN1957143A " reinforcement means of soft soil foundation ", In the inside of the ground of consolidated subsoil periphery, vertical drainage part is set, forms vertical row supply passageway, supply in this vertical row The inside of path, pours into the water with sealing part, by above-mentioned vertical supply passageway, is supplied to the water with sealing part reinforce The inside of the ground of ground periphery, the sealing part being circulated in above-mentioned vertical supply passageway is spread in vertical confession with current To the periphery of path, forming sealing region, its effect is: the sealing region formed by sealing part hinders consolidated subsoil periphery The movement of subsoil water of inside of ground, the consolidated subsoil periphery of the forced drainage of the subsoil water along with consolidated subsoil can be suppressed The decline of the subsoil water of the inside of the ground in portion, can suppress the consolidated subsoil periphery of the reinforcing with soft soil foundation effectively The sedimentation of ground.
Said method is all to be compacted soft soil foundation or the firm ground of drain reinforcing method foundation, and it is great in constructing amount, Program is complex, and labour cost is higher, and the ground set up can not antidetonation resistance to compression, service life is short.
Summary of the invention
In order to solve above-mentioned technical problem, the present invention provides a kind of lathe ground using foam cement to build, and it can be straight Connect and act on weak soil and carry out on the ground the foundation of lathe ground, reduce construction volume and human cost.
For realizing above-mentioned technical purpose, the technical scheme that the present invention takes is, a kind of lathe using foam cement to build Ground, described foam cement includes each material of following weight portion:
Unsatured epoxy resin 10-20 part,
1,4,5,8-naphthalenetetracarbacidic acidic 10-20 part,
With alkene 5-10 part of phenyl ring,
Age resister 1-4 part,
Iron-ore Slag 10-15 part,
Zinc ore slag 1-3 part,
Ethanol 20-30 part,
Catalyst 3-10 part,
Wherein, the alkene with phenyl ring is the C10H10 compound containing two double bonds of a phenyl ring.
As the preferred technical scheme of the present invention, the alkene with phenyl ring is preferably:Or
As the preferred technical scheme of the present invention, also include dispersant 3-8 part.
As the preferred technical scheme of the present invention, described catalyst is heteropoly acid, the sodium salt of heteropoly acid, or aluminum phosphate Molecular sieve.
As the preferred technical scheme of the present invention, described heteropoly acid is preferably phosphorus heteropoly tungstic acid, silicotungstic heteropolyacid or silicon Molybdenum heteropolyacid.
As the preferred technical scheme of the present invention, Iron-ore Slag particle size is 3-5mm.
As the preferred technical scheme of the present invention, zinc ore solid impurity particle a size of 0.1-1mm.
As the preferred technical scheme of the present invention, lathe ground be use by unsatured epoxy resin, 1,4,5,8-naphthalene Tetracarboxylic acid, with the alkene of phenyl ring, age resister, Iron-ore Slag, zinc ore slag, ethanol and catalyst mix preparation.
Beneficial effect
Prepared cement is the Iron-ore Slag being dispersed with high rigidity in polar organic matter so that honeycombed cement has high intensity, Simultaneously Iron-ore Slag meeting 1,4,5,8-naphthalenetetracarbacidic acidic displacement reaction can be occurred to generate hydrogen under the effect of catalyst again, it is achieved cement Self-heating produces gas, and then makes the even pore distribution of prepared honeycombed cement;And equally distributed loose structure There is high intensity and water absorption;Meanwhile, unsatured epoxy resin with there is energy under the effect of catalyst with the alkene of phenyl ring Sudden reaction occurring, forms the combination chain simultaneously containing rigid chain with flexible chain, inorganic solid particles thing can be merged by combination chain Together;
And in order to avoid when building lot honeycombed cement absorb too much moisture and cause the corrosion of foundation pile, the present invention adds zinc Slag because zinc ore slag under mildly acidic conditions can with ferrum class material generation chemical reaction, and then can to the ferrum within cement and Irony foundation pile carries out corrosion resistance protection, improves the service life of cement and foundation pile.
Detailed description of the invention
Purpose and technical scheme for making the embodiment of the present invention are clearer, below in conjunction with the embodiment of the present invention to this Bright technical scheme is clearly and completely described.Obviously, described embodiment is a part of embodiment of the present invention, and It is not all, of embodiment.Based on described embodiments of the invention, those of ordinary skill in the art are without creative labor The every other embodiment obtained on the premise of Dong, broadly falls into the scope of protection of the invention.
Those skilled in the art of the present technique are appreciated that unless otherwise defined, and all terms used herein (include technology art Language and scientific terminology) have with the those of ordinary skill in art of the present invention be commonly understood by identical meaning.Also should Being understood by, those terms defined in such as general dictionary should be understood that the meaning having with the context of prior art The meaning that justice is consistent, and unless defined as here, will not explain by idealization or the most formal implication.
Use foam cement build lathe ground, be specially by unsatured epoxy resin, 1,4,5,8-naphthalenetetracarbacidic acidic, band Having the alkene of phenyl ring, age resister, Iron-ore Slag, zinc ore slag, ethanol and catalyst mix preparation.
Embodiment 1
Foam cement, including each material of following weight portion:
Unsatured epoxy resin 10 parts,
1,4,5,8-naphthalenetetracarbacidic acidic 20 parts,
With 5 parts of the alkene of phenyl ring,
Age resister 4 parts,
Iron-ore Slag 10 parts,
Zinc ore slag 3 parts,
Ethanol 20 parts,
Catalyst 10 parts,
Dispersant 8 parts.
Wherein, the alkene with phenyl ring is the C10H10 compound containing two double bonds of a phenyl ring.
In the present embodiment, the alkene with phenyl ring is:
Described catalyst is phosphorus heteropoly tungstic acid.
Iron-ore Slag particle size is 3mm.
Zinc ore solid impurity particle a size of 0.1mm.
Implementation result
The comprcssive strength that the foam cement ground built up can bear is 289kpa.
Embodiment 2
Foam cement, including each material of following weight portion:
Unsatured epoxy resin 20 parts,
1,4,5,8-naphthalenetetracarbacidic acidic 10 parts,
With 10 parts of the alkene of phenyl ring,
Age resister 1 part,
Iron-ore Slag 15 parts,
Zinc ore slag 1 part,
Ethanol 30 parts,
Heteropoly acid, the sodium salt of heteropoly acid, or aluminium phosphate molecular sieve 3 parts,
Dispersant 3-8 part.
Wherein, the alkene with phenyl ring is the C10H10 compound containing two double bonds of a phenyl ring.
In the present embodiment, the alkene with phenyl ring is:
Described heteropoly acid is silicotungstic heteropolyacid.
Iron-ore Slag particle size is 5mm.
Zinc ore solid impurity particle a size of 01mm.
Implementation result
The comprcssive strength that the foam cement ground built up can bear is 180kpa.
Embodiment 3
Foam cement, including each material of following weight portion:
Unsatured epoxy resin 15 parts,
1,4,5,8-naphthalenetetracarbacidic acidic 15 parts,
With 6 parts of the alkene of phenyl ring,
Age resister 2 parts,
Iron-ore Slag 12 parts,
Zinc ore slag 2 parts,
Ethanol 25 parts,
Catalyst 5 parts,
Heteropoly acid, the sodium salt of heteropoly acid, or aluminium phosphate molecular sieve 3-8 part.
Wherein, the alkene with phenyl ring is the C10H10 compound containing two double bonds of a phenyl ring.
In the present embodiment, the alkene with phenyl ring is:
Described catalyst is silicon-molybdenum heteropoly acid.
Iron-ore Slag particle size is 4mm.
Zinc ore solid impurity particle a size of 0.7mm.
Implementation result
The comprcssive strength that the foam cement ground built up can bear is 279kpa.
Embodiment 4
Foam cement, including each material of following weight portion:
Unsatured epoxy resin 18 parts,
1,4,5,8-naphthalenetetracarbacidic acidic 18 parts,
With 8 parts of the alkene of phenyl ring,
Age resister 3 parts,
Iron-ore Slag 14 parts,
Zinc ore slag 2 parts,
Ethanol 25 parts,
Catalyst 7 parts,
Dispersant 6 parts.
Wherein, the alkene with phenyl ring is the C10H10 compound containing two double bonds of a phenyl ring.
Alkene with phenyl ring is preferably in the present embodiment:
Described catalyst is phosphorus heteropoly tungstic acid sodium.
Iron-ore Slag particle size is 4mm.
Zinc ore solid impurity particle a size of 0.5mm.
Implementation result
The comprcssive strength that the foam cement ground built up can bear is 267kpa.
Embodiment 5
Foam cement, including each material of following weight portion:
Unsatured epoxy resin 15 parts,
1,4,5,8-naphthalenetetracarbacidic acidic 18 parts,
With 9 parts of the alkene of phenyl ring,
Age resister 2 parts,
Iron-ore Slag 14 parts,
Zinc ore slag 2 parts,
Ethanol 27 parts,
Catalyst 4 parts,
Dispersant 8 parts.
Wherein, the alkene with phenyl ring is the C10H10 compound containing two double bonds of a phenyl ring.
In the present embodiment, the alkene with phenyl ring is:
Described catalyst is aluminium phosphate molecular sieve.
Iron-ore Slag particle size is 5mm.
Zinc ore solid impurity particle a size of 0.9mm.
Implementation result
The comprcssive strength that the foam cement ground built up can bear is 276kpa.
Embodiment 6
Foam cement, including each material of following weight portion:
Unsatured epoxy resin 13 parts,
1,4,5,8-naphthalenetetracarbacidic acidic 13 parts,
With 7 parts of the alkene of phenyl ring,
Age resister 2 parts,
Iron-ore Slag 14 parts,
Zinc ore slag 2 parts,
Ethanol 27 parts,
Catalyst 7 parts,
Dispersant 3-8 part.
Wherein, the alkene with phenyl ring is the C10H10 compound containing two double bonds of a phenyl ring.
In the present embodiment, the alkene with phenyl ring is:
Described catalyst is silicotungstic heteropolyacid sodium.
Iron-ore Slag particle size is 3mm.
Zinc ore solid impurity particle a size of 0.1mm.
Implementation result
The comprcssive strength that the foam cement ground built up can bear is 290kpa.
Embodiment 7
Foam cement, including each material of following weight portion:
Unsatured epoxy resin 11 parts,
1,4,5,8-naphthalenetetracarbacidic acidic 11 parts,
With 6 parts of the alkene of phenyl ring,
Age resister 2 parts,
Iron-ore Slag 14 parts,
Zinc ore slag 2 parts,
Ethanol 27 parts,
Catalyst 7 parts,
Dispersant 3 parts.
Wherein, the alkene with phenyl ring is the C10H10 compound containing two double bonds of a phenyl ring.
In the present embodiment, the alkene with phenyl ring is preferably:
Described catalyst is aluminium phosphate molecular sieve.
Iron-ore Slag particle size is 3mm.
Zinc ore solid impurity particle a size of 1mm.
Implementation result
The comprcssive strength that the foam cement ground built up can bear is 286kpa.
Embodiment 8
Foam cement, including each material of following weight portion:
Unsatured epoxy resin 19 parts,
1,4,5,8-naphthalenetetracarbacidic acidic 19 parts,
With 9 parts of the alkene of phenyl ring,
Age resister 2 parts,
Iron-ore Slag 14 parts,
Zinc ore slag 1 part,
Ethanol 28 parts,
Catalyst 7 parts,
Dispersant 7 parts.
Wherein, the alkene with phenyl ring is the C10H10 compound containing two double bonds of a phenyl ring.
In the present embodiment, the alkene with phenyl ring is:
Described catalyst is phosphorus heteropoly tungstic acid potassium.
Iron-ore Slag particle size is 6mm.
Zinc ore solid impurity particle a size of 2mm.
Implementation result
The comprcssive strength that the foam cement ground built up can bear is 190kpa.
These are only embodiments of the present invention, it describes more concrete and in detail, but can not therefore and be interpreted as right The restriction of the scope of the claims of the present invention.It should be pointed out that, for the person of ordinary skill of the art, without departing from the present invention On the premise of design, it is also possible to make some deformation and improvement, these belong to protection scope of the present invention.

Claims (8)

1. the lathe ground that a kind uses foam cement to build, it is characterised in that: described foam cement includes following weight portion Each material:
Unsatured epoxy resin 10-20 part,
1,4,5,8-naphthalenetetracarbacidic acidic 10-20 part,
With alkene 5-10 part of phenyl ring,
Age resister 1-4 part,
Iron-ore Slag 10-15 part,
Zinc ore slag 1-3 part,
Ethanol 20-30 part,
Catalyst 3-10 part,
Wherein, the alkene with phenyl ring is the C10H10 compound containing two double bonds of a phenyl ring.
A kind of lathe ground using foam cement to build the most according to claim 1, it is characterised in that with the alkene of phenyl ring It is preferably:Or
A kind of lathe ground using foam cement to build the most according to claim 1, it is characterised in that also include dispersion Agent 3-8 part.
A kind of lathe ground using foam cement to build the most according to claim 1, it is characterised in that described catalyst For heteropoly acid, the sodium salt of heteropoly acid, or aluminium phosphate molecular sieve.
A kind of lathe ground using foam cement to build the most according to claim 1, it is characterised in that described heteropoly acid It is preferably phosphorus heteropoly tungstic acid, silicotungstic heteropolyacid or silicon-molybdenum heteropoly acid.
A kind of lathe ground using foam cement to build the most according to claim 1, it is characterised in that Iron-ore Slag granule A size of 3-5mm.
A kind of lathe ground using foam cement to build the most according to claim 1, it is characterised in that zinc ore solid impurity particle A size of 0.1-1mm.
A kind of lathe ground using foam cement to build the most according to claim 1, it is characterised in that lathe ground is Use unsatured epoxy resin, 1,4,5,8-naphthalenetetracarbacidic acidic, with the alkene of phenyl ring, age resister, Iron-ore Slag, zinc ore slag, Ethanol and catalyst mix preparation.
CN201610155220.0A 2016-03-18 2016-03-18 A kind of lathe ground built using foam cement Expired - Fee Related CN105802108B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101870138A (en) * 2010-06-12 2010-10-27 王�琦 Preparation method for manufacturing building board by utilizing mine tailing residue
CN102745955A (en) * 2011-09-21 2012-10-24 江苏尼高科技有限公司 Preparation process for three-dimensional mesh cloth foaming cement composite material
CN102807385A (en) * 2012-07-19 2012-12-05 江苏科技大学 Cement-based waterborne epoxy resin foam heat insulation material and preparation method thereof
CN103288470A (en) * 2012-02-24 2013-09-11 江苏尼高科技有限公司 Foamed cement composite material with honeycomb structure and preparation method thereof
CN103964792A (en) * 2014-04-16 2014-08-06 徐琪 Preparation method for resin/ cement composite light weight board

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101870138A (en) * 2010-06-12 2010-10-27 王�琦 Preparation method for manufacturing building board by utilizing mine tailing residue
CN102745955A (en) * 2011-09-21 2012-10-24 江苏尼高科技有限公司 Preparation process for three-dimensional mesh cloth foaming cement composite material
CN103288470A (en) * 2012-02-24 2013-09-11 江苏尼高科技有限公司 Foamed cement composite material with honeycomb structure and preparation method thereof
CN102807385A (en) * 2012-07-19 2012-12-05 江苏科技大学 Cement-based waterborne epoxy resin foam heat insulation material and preparation method thereof
CN103964792A (en) * 2014-04-16 2014-08-06 徐琪 Preparation method for resin/ cement composite light weight board

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