CN105802108B - A kind of lathe ground built using foam cement - Google Patents

A kind of lathe ground built using foam cement Download PDF

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Publication number
CN105802108B
CN105802108B CN201610155220.0A CN201610155220A CN105802108B CN 105802108 B CN105802108 B CN 105802108B CN 201610155220 A CN201610155220 A CN 201610155220A CN 105802108 B CN105802108 B CN 105802108B
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CN
China
Prior art keywords
parts
foam cement
phenyl ring
alkene
ore slag
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Expired - Fee Related
Application number
CN201610155220.0A
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Chinese (zh)
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CN105802108A (en
Inventor
马峻
薛松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIAXING CITY ST. LOUIS SANITARY WARE CO., LTD.
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Xinchang Yulin Street Dakang Machinery Factory
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Priority to CN201610155220.0A priority Critical patent/CN105802108B/en
Publication of CN105802108A publication Critical patent/CN105802108A/en
Application granted granted Critical
Publication of CN105802108B publication Critical patent/CN105802108B/en
Expired - Fee Related legal-status Critical Current
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/10Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
    • C08F283/105Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule on to unsaturated polymers containing more than one epoxy radical per molecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2351/08Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter

Abstract

The invention belongs to soft soil foundation field, specially a kind of lathe ground built using foam cement, the foam cement includes each substance of following parts by weight:10 20 parts of double bond epoxy resin, 1,10 20 parts of 4,5,8 naphthalenetetracarbacidic acidic, 5 10 parts of alkene with phenyl ring, 14 parts of age resister, 10 15 parts of Iron-ore Slag, 13 parts of zinc ore slag, 20 30 parts of ethyl alcohol, 3 10 parts of catalyst, wherein the alkene with phenyl ring is containing there are one the C10H10 compounds of two double bonds of phenyl ring.It can be done directly on the foundation that weak soil carries out lathe ground on the ground, reduce construction volume and human cost.

Description

A kind of lathe ground built using foam cement
Technical field
The invention belongs to soft soil foundation field, specially a kind of lathe ground built using foam cement.
Background technology
Heavy machine tool is widely used in fields such as the machinery in China, space flight, national defence, the energy, is China's equipment The representative product of manufacturing industry.But domestic heavy machine tool presently, there are one of main problem precisely due to heavy machine The huge quality of bed volume is very big, and ground is difficult the requirement for meeting lathe load-bearing, and the ground in especially many areas is partially soft, in order to make Obtaining heavy machine tool at work can be steady, generally requires to carry out consolidation process to ground, such as Chinese patent CN103469783A " a kind of soft soil foundation reinforcing method ", the reinforcement means include using weak soil compacting equipment, the weak soil compacting equipment:Nip drum Machine and two sets of rail pressure devices;The reinforcement means includes the following steps:A drafts of soft soil foundation is determined first;Setting Four fixed foundation points;By nip drum machine setting in compacting initial position;Make the front stretching of two sets of rail pressure devices respectively Mechanism and rear telescoping mechanism alternating movement, the nip drum machine accordingly move forward and backward, to be compacted to the soft soil foundation, Until practical drafts meets the requirement of overall reduction.For another example Chinese patent CN1957143A " reinforcement means of soft soil foundation ", In the inside of the ground of consolidated subsoil peripheral portion, vertical drainage part is set, forms vertical row supply passageway, is supplied in the vertical row The inside of access pours into the water with sealing part, and by above-mentioned vertical supply passageway, the water with sealing part is supplied to reinforcing The inside of the ground of ground peripheral portion, the sealing part being circulated into above-mentioned vertical supply passageway are spread in vertical confession with flow To the periphery of access, sealing region is formed, effect is:Consolidated subsoil peripheral portion is hindered by the sealing region that sealing part is formed Ground inside underground water movement, can inhibit the consolidated subsoil periphery of the forced drainage of the underground water with consolidated subsoil The decline of the underground water of the inside of the ground in portion can effectively inhibit the consolidated subsoil peripheral portion of the reinforcing with soft soil foundation The sedimentation of ground.
The above method is to carry out compacting or the firm ground of drain reinforcing method foundation to soft soil foundation, great in constructing amount, Program is complex, and labour cost is higher, and the ground established is unable to antidetonation resistance to compression, and service life is short.
Invention content
In order to solve the above technical problem, the present invention provides a kind of lathe grounds built using foam cement, can be straight It connects and acts on the foundation that weak soil carries out lathe ground on the ground, reduce construction volume and human cost.
To realize the above-mentioned technical purpose, the technical solution that the present invention takes is a kind of lathe built using foam cement Ground, the foam cement include each substance of following parts by weight:
10-20 parts of unsatured epoxy resin,
1,4,5,10-20 parts of 8- naphthalenetetracarbacidic acidics,
5-10 parts of alkene with phenyl ring,
1-4 parts of age resister,
10-15 parts of Iron-ore Slag,
1-3 parts of zinc ore slag,
20-30 parts of ethyl alcohol,
3-10 parts of catalyst,
Wherein, the alkene for carrying phenyl ring is containing there are one the C10H10 compounds of two double bonds of phenyl ring.
As the preferred technical solution of the present invention, the alkene with phenyl ring is preferably:Or
Further include 3-8 parts of dispersant as the preferred technical solution of the present invention.
As the preferred technical solution of the present invention, the catalyst is heteropoly acid, the sodium salt or aluminum phosphate of heteropoly acid Molecular sieve.
As the preferred technical solution of the present invention, the heteropoly acid is preferably phosphorus heteropoly tungstic acid, silicotungstic heteropolyacid or silicon Molybdenum heteropolyacid.
As the preferred technical solution of the present invention, Iron-ore Slag particle size is 3-5mm.
As the preferred technical solution of the present invention, zinc ore solid impurity particle size is 0.1-1mm.
As the preferred technical solution of the present invention, lathe ground be using by unsatured epoxy resin, 1,4,5,8- naphthalenes Tetracarboxylic acid carries the alkene of phenyl ring, and age resister, Iron-ore Slag, zinc ore slag, ethyl alcohol and catalyst mix preparation.
Advantageous effect
Prepared cement is that the Iron-ore Slag of high rigidity is dispersed in polar organic matter so that honeycombed cement has high strong It spends, while in chance 1,4,5,8- naphthalenetetracarbacidic acidics under the action of catalyst again displacement reaction generation hydrogen, realization can occur for Iron-ore Slag Cement self-heating generates gas, so that the even pore distribution of prepared honeycombed cement;And it is equally distributed porous Structure has high intensity and water imbibition;Meanwhile there are the effects of catalyst with the alkene with phenyl ring for unsatured epoxy resin Under can occur sudden reaction, form that the combination chain containing rigid chain and flexible chain, combination chain can be by inorganic solid particles objects simultaneously It is merged;
And in order to avoid in building lot honeycombed cement absorb the corrosion that excessive moisture causes foundation pile, the present invention adds Enter zinc ore slag because zinc ore slag can chemically react under mildly acidic conditions with iron substance, and then can be to cement inside Iron and irony foundation pile carry out corrosion resistance protection, improve the service life of cement and foundation pile.
Specific implementation mode
It is clearer for the purpose and technical solution that make the embodiment of the present invention, below in conjunction with the embodiment of the present invention to this hair Bright technical solution is clearly and completely described.Obviously, described embodiment is a part of the embodiment of the present invention, and The embodiment being not all of.Based on described the embodiment of the present invention, those of ordinary skill in the art are without creative labor The every other embodiment obtained under the premise of dynamic, shall fall within the protection scope of the present invention.
Those skilled in the art of the present technique are appreciated that unless otherwise defined, all terms used herein(Including technology art Language and scientific terminology)With meaning identical with the general understanding of the those of ordinary skill in fields of the present invention.Should also Understand, those terms such as defined in the general dictionary, which should be understood that, to be had and the meaning in the context of the prior art The consistent meaning of justice, and unless defined as here, will not be with idealizing or the meaning of too formal be explained.
The lathe ground built using foam cement, specially by unsatured epoxy resin, 1,4,5,8- naphthalenetetracarbacidic acidics, band There is the alkene of phenyl ring, age resister, Iron-ore Slag, zinc ore slag, ethyl alcohol and catalyst mix preparation.
Embodiment 1
Foam cement includes each substance of following parts by weight:
10 parts of unsatured epoxy resin,
1,4,5,20 parts of 8- naphthalenetetracarbacidic acidics,
5 parts of alkene with phenyl ring,
4 parts of age resister,
10 parts of Iron-ore Slag,
3 parts of zinc ore slag,
20 parts of ethyl alcohol,
10 parts of catalyst,
8 parts of dispersant.
Wherein, the alkene for carrying phenyl ring is containing there are one the C10H10 compounds of two double bonds of phenyl ring.
The alkene with phenyl ring is in the present embodiment:
The catalyst is phosphorus heteropoly tungstic acid.
Iron-ore Slag particle size is 3mm.
Zinc ore solid impurity particle size is 0.1mm.
Implementation result
The compression strength that the foam cement ground built up can bear is 289kpa.
Embodiment 2
Foam cement includes each substance of following parts by weight:
20 parts of unsatured epoxy resin,
1,4,5,10 parts of 8- naphthalenetetracarbacidic acidics,
10 parts of alkene with phenyl ring,
1 part of age resister,
15 parts of Iron-ore Slag,
1 part of zinc ore slag,
30 parts of ethyl alcohol,
Heteropoly acid, 3 parts of the sodium salt or aluminium phosphate molecular sieve of heteropoly acid,
3-8 parts of dispersant.
Wherein, the alkene for carrying phenyl ring is containing there are one the C10H10 compounds of two double bonds of phenyl ring.
In the present embodiment, the alkene with phenyl ring is:
The heteropoly acid is silicotungstic heteropolyacid.
Iron-ore Slag particle size is 5mm.
Zinc ore solid impurity particle size is 01mm.
Implementation result
The compression strength that the foam cement ground built up can bear is 180kpa.
Embodiment 3
Foam cement includes each substance of following parts by weight:
15 parts of unsatured epoxy resin,
1,4,5,15 parts of 8- naphthalenetetracarbacidic acidics,
6 parts of alkene with phenyl ring,
2 parts of age resister,
12 parts of Iron-ore Slag,
2 parts of zinc ore slag,
25 parts of ethyl alcohol,
5 parts of catalyst,
Heteropoly acid, 3-8 parts of the sodium salt or aluminium phosphate molecular sieve of heteropoly acid.
Wherein, the alkene for carrying phenyl ring is containing there are one the C10H10 compounds of two double bonds of phenyl ring.
In the present embodiment, the alkene with phenyl ring is:
The catalyst is silicon-molybdenum heteropoly acid.
Iron-ore Slag particle size is 4mm.
Zinc ore solid impurity particle size is 0.7mm.
Implementation result
The compression strength that the foam cement ground built up can bear is 279kpa.
Embodiment 4
Foam cement includes each substance of following parts by weight:
18 parts of unsatured epoxy resin,
1,4,5,18 parts of 8- naphthalenetetracarbacidic acidics,
8 parts of alkene with phenyl ring,
3 parts of age resister,
14 parts of Iron-ore Slag,
2 parts of zinc ore slag,
25 parts of ethyl alcohol,
7 parts of catalyst,
6 parts of dispersant.
Wherein, the alkene for carrying phenyl ring is containing there are one the C10H10 compounds of two double bonds of phenyl ring.
The alkene with phenyl ring is preferably in the present embodiment:
The catalyst is phosphorus heteropoly tungstic acid sodium.
Iron-ore Slag particle size is 4mm.
Zinc ore solid impurity particle size is 0.5mm.
Implementation result
The compression strength that the foam cement ground built up can bear is 267kpa.
Embodiment 5
Foam cement includes each substance of following parts by weight:
15 parts of unsatured epoxy resin,
1,4,5,18 parts of 8- naphthalenetetracarbacidic acidics,
9 parts of alkene with phenyl ring,
2 parts of age resister,
14 parts of Iron-ore Slag,
2 parts of zinc ore slag,
27 parts of ethyl alcohol,
4 parts of catalyst,
8 parts of dispersant.
Wherein, the alkene for carrying phenyl ring is containing there are one the C10H10 compounds of two double bonds of phenyl ring.
In the present embodiment, the alkene with phenyl ring is:
The catalyst is aluminium phosphate molecular sieve.
Iron-ore Slag particle size is 5mm.
Zinc ore solid impurity particle size is 0.9mm.
Implementation result
The compression strength that the foam cement ground built up can bear is 276kpa.
Embodiment 6
Foam cement includes each substance of following parts by weight:
13 parts of unsatured epoxy resin,
1,4,5,13 parts of 8- naphthalenetetracarbacidic acidics,
7 parts of alkene with phenyl ring,
2 parts of age resister,
14 parts of Iron-ore Slag,
2 parts of zinc ore slag,
27 parts of ethyl alcohol,
7 parts of catalyst,
3-8 parts of dispersant.
Wherein, the alkene for carrying phenyl ring is containing there are one the C10H10 compounds of two double bonds of phenyl ring.
In the present embodiment, the alkene with phenyl ring is:
The catalyst is silicotungstic heteropolyacid sodium.
Iron-ore Slag particle size is 3mm.
Zinc ore solid impurity particle size is 0.1mm.
Implementation result
The compression strength that the foam cement ground built up can bear is 290kpa.
Embodiment 7
Foam cement includes each substance of following parts by weight:
11 parts of unsatured epoxy resin,
1,4,5,11 parts of 8- naphthalenetetracarbacidic acidics,
6 parts of alkene with phenyl ring,
2 parts of age resister,
14 parts of Iron-ore Slag,
2 parts of zinc ore slag,
27 parts of ethyl alcohol,
7 parts of catalyst,
3 parts of of dispersant
Wherein, the alkene for carrying phenyl ring is containing there are one the C10H10 compounds of two double bonds of phenyl ring.
In the present embodiment, the alkene with phenyl ring is preferably:
The catalyst is aluminium phosphate molecular sieve.
Iron-ore Slag particle size is 3mm.
Zinc ore solid impurity particle size is 1mm.
Implementation result
The compression strength that the foam cement ground built up can bear is 286kpa.
Embodiment 8
Foam cement includes each substance of following parts by weight:
19 parts of unsatured epoxy resin,
1,4,5,19 parts of 8- naphthalenetetracarbacidic acidics,
9 parts of alkene with phenyl ring,
2 parts of age resister,
14 parts of Iron-ore Slag,
1 part of zinc ore slag,
28 parts of ethyl alcohol,
7 parts of catalyst,
7 parts of dispersant.
Wherein, the alkene for carrying phenyl ring is containing there are one the C10H10 compounds of two double bonds of phenyl ring.
In the present embodiment, the alkene with phenyl ring is:
The catalyst is phosphorus heteropoly tungstic acid potassium.
Iron-ore Slag particle size is 6mm.
Zinc ore solid impurity particle size is 2mm.
Implementation result
The compression strength that the foam cement ground built up can bear is 190kpa.
It these are only embodiments of the present invention, the description thereof is more specific and detailed, but can not therefore be interpreted as pair The limitation of the scope of the claims of the present invention.It should be pointed out that for those of ordinary skill in the art, not departing from the present invention Under the premise of design, various modifications and improvements can be made, these are all belonged to the scope of protection of the present invention.

Claims (8)

1. a kind of lathe ground built using foam cement, it is characterised in that:The foam cement includes following parts by weight Each substance:
10-20 parts of unsatured epoxy resin,
1,4,5,10-20 parts of 8- naphthalenetetracarbacidic acidics,
5-10 parts of alkene with phenyl ring,
1-4 parts of age resister,
10-15 parts of Iron-ore Slag,
1-3 parts of zinc ore slag,
20-30 parts of ethyl alcohol,
3-10 parts of catalyst,
Wherein, the alkene for carrying phenyl ring is containing there are one the C10H10 compounds of two double bonds of phenyl ring.
2. a kind of lathe ground built using foam cement according to claim 1, which is characterized in that with phenyl ring Alkene is:
3. a kind of lathe ground built using foam cement according to claim 1, which is characterized in that further include dispersion 3-8 parts of agent.
4. a kind of lathe ground built using foam cement according to claim 1, which is characterized in that the catalyst For heteropoly acid, the sodium salt or aluminium phosphate molecular sieve of heteropoly acid.
5. a kind of lathe ground built using foam cement according to claim 4, which is characterized in that the heteropoly acid For phosphorus heteropoly tungstic acid, silicotungstic heteropolyacid or silicon-molybdenum heteropoly acid.
6. a kind of lathe ground built using foam cement according to claim 1, which is characterized in that iron ore solid impurity particle Size is 3-5mm.
7. a kind of lathe ground built using foam cement according to claim 1, which is characterized in that zinc ore solid impurity particle Size is 0.1-1mm.
8. a kind of lathe ground built using foam cement according to claim 1, which is characterized in that lathe ground is By unsatured epoxy resin, 1,4,5,8- naphthalenetetracarbacidic acidics, carry the alkene of phenyl ring, age resister, Iron-ore Slag, zinc ore slag, ethyl alcohol And it is prepared after catalyst mixing.
CN201610155220.0A 2016-03-18 2016-03-18 A kind of lathe ground built using foam cement Expired - Fee Related CN105802108B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201610155220.0A CN105802108B (en) 2016-03-18 2016-03-18 A kind of lathe ground built using foam cement

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CN105802108B true CN105802108B (en) 2018-09-07

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101870138A (en) * 2010-06-12 2010-10-27 王�琦 Preparation method for manufacturing building board by utilizing mine tailing residue
CN102745955A (en) * 2011-09-21 2012-10-24 江苏尼高科技有限公司 Preparation process for three-dimensional mesh cloth foaming cement composite material
CN102807385A (en) * 2012-07-19 2012-12-05 江苏科技大学 Cement-based waterborne epoxy resin foam heat insulation material and preparation method thereof
CN103288470A (en) * 2012-02-24 2013-09-11 江苏尼高科技有限公司 Foamed cement composite material with honeycomb structure and preparation method thereof
CN103964792A (en) * 2014-04-16 2014-08-06 徐琪 Preparation method for resin/ cement composite light weight board

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101870138A (en) * 2010-06-12 2010-10-27 王�琦 Preparation method for manufacturing building board by utilizing mine tailing residue
CN102745955A (en) * 2011-09-21 2012-10-24 江苏尼高科技有限公司 Preparation process for three-dimensional mesh cloth foaming cement composite material
CN103288470A (en) * 2012-02-24 2013-09-11 江苏尼高科技有限公司 Foamed cement composite material with honeycomb structure and preparation method thereof
CN102807385A (en) * 2012-07-19 2012-12-05 江苏科技大学 Cement-based waterborne epoxy resin foam heat insulation material and preparation method thereof
CN103964792A (en) * 2014-04-16 2014-08-06 徐琪 Preparation method for resin/ cement composite light weight board

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Address before: The streets of Zhejiang province 312500 Ao Yuan village, Shaoxing city Xinchang County habayashi No. 565

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