CN105798323B - 球磨辅助界面制备大比表面积过渡金属‑硼合金材料的方法 - Google Patents
球磨辅助界面制备大比表面积过渡金属‑硼合金材料的方法 Download PDFInfo
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- CN105798323B CN105798323B CN201610155526.6A CN201610155526A CN105798323B CN 105798323 B CN105798323 B CN 105798323B CN 201610155526 A CN201610155526 A CN 201610155526A CN 105798323 B CN105798323 B CN 105798323B
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- 238000000498 ball milling Methods 0.000 title claims abstract description 47
- 229910000521 B alloy Inorganic materials 0.000 title claims abstract description 37
- 239000000956 alloy Substances 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 19
- 229910052723 transition metal Inorganic materials 0.000 title claims abstract description 14
- 150000003624 transition metals Chemical class 0.000 title abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003960 organic solvent Substances 0.000 claims abstract description 10
- -1 transition metal salt Chemical class 0.000 claims abstract description 8
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 5
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 4
- 239000012153 distilled water Substances 0.000 claims abstract description 3
- 239000012279 sodium borohydride Substances 0.000 claims description 29
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 29
- 230000007704 transition Effects 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
- 238000001291 vacuum drying Methods 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 45
- 239000001257 hydrogen Substances 0.000 abstract description 45
- 239000003054 catalyst Substances 0.000 abstract description 34
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 25
- 238000004519 manufacturing process Methods 0.000 abstract description 22
- 238000002360 preparation method Methods 0.000 abstract description 13
- 230000003197 catalytic effect Effects 0.000 abstract description 7
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 230000007062 hydrolysis Effects 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 238000006555 catalytic reaction Methods 0.000 abstract description 3
- 150000003839 salts Chemical class 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000002131 composite material Substances 0.000 abstract description 2
- 239000000446 fuel Substances 0.000 abstract description 2
- 239000000779 smoke Substances 0.000 abstract description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 43
- 229910045601 alloy Inorganic materials 0.000 description 16
- 238000005406 washing Methods 0.000 description 11
- 239000011049 pearl Substances 0.000 description 10
- 239000012071 phase Substances 0.000 description 9
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- 238000004821 distillation Methods 0.000 description 8
- 238000001035 drying Methods 0.000 description 8
- 239000012074 organic phase Substances 0.000 description 8
- 206010013786 Dry skin Diseases 0.000 description 7
- 238000011946 reduction process Methods 0.000 description 7
- 238000003860 storage Methods 0.000 description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 230000003301 hydrolyzing effect Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 2
- 238000010406 interfacial reaction Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000002336 sorption--desorption measurement Methods 0.000 description 2
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 description 1
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt(II) nitrate Inorganic materials [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000002003 electron diffraction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(III) nitrate Inorganic materials [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
Abstract
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Priority Applications (1)
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CN201610155526.6A CN105798323B (zh) | 2016-03-18 | 2016-03-18 | 球磨辅助界面制备大比表面积过渡金属‑硼合金材料的方法 |
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CN201610155526.6A CN105798323B (zh) | 2016-03-18 | 2016-03-18 | 球磨辅助界面制备大比表面积过渡金属‑硼合金材料的方法 |
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CN105798323A CN105798323A (zh) | 2016-07-27 |
CN105798323B true CN105798323B (zh) | 2018-04-06 |
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CN201610155526.6A Active CN105798323B (zh) | 2016-03-18 | 2016-03-18 | 球磨辅助界面制备大比表面积过渡金属‑硼合金材料的方法 |
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1179358A (zh) * | 1996-10-15 | 1998-04-22 | 中国石油化工总公司 | 一种Ni-B非晶态合金催化剂、其制备方法及应用 |
CN1196975A (zh) * | 1997-04-24 | 1998-10-28 | 中国石油化工总公司 | 含镍和硼的非晶态合金催化剂、其制备方法及应用 |
JP2005317373A (ja) * | 2004-04-28 | 2005-11-10 | Nissan Motor Co Ltd | 燃料電池用触媒、および白金−イリジウム合金粒子の製造方法 |
CN1820850A (zh) * | 2006-03-16 | 2006-08-23 | 上海师范大学 | 粒径尺寸均匀的非晶态合金催化剂及其制备方法 |
CN101157034A (zh) * | 2007-11-13 | 2008-04-09 | 上海师范大学 | 一种非晶态合金催化剂及其制备方法和用途 |
CN102886527A (zh) * | 2012-10-12 | 2013-01-23 | 东华大学 | 一种以油酸银为原料的油水界面法制备立方晶型纳米银材料的方法 |
CN103127936A (zh) * | 2013-02-04 | 2013-06-05 | 中国科学院过程工程研究所 | 一种液相球磨部分还原法制备催化剂的方法及三元铜催化剂 |
CN103172124A (zh) * | 2013-04-17 | 2013-06-26 | 新疆大学 | 一种固相化学反应制备氧化铁三维纳米结构的方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5751516B2 (ja) * | 2011-09-07 | 2015-07-22 | 国立研究開発法人産業技術総合研究所 | 水素発生用触媒及び水素発生方法 |
-
2016
- 2016-03-18 CN CN201610155526.6A patent/CN105798323B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1179358A (zh) * | 1996-10-15 | 1998-04-22 | 中国石油化工总公司 | 一种Ni-B非晶态合金催化剂、其制备方法及应用 |
CN1196975A (zh) * | 1997-04-24 | 1998-10-28 | 中国石油化工总公司 | 含镍和硼的非晶态合金催化剂、其制备方法及应用 |
JP2005317373A (ja) * | 2004-04-28 | 2005-11-10 | Nissan Motor Co Ltd | 燃料電池用触媒、および白金−イリジウム合金粒子の製造方法 |
CN1820850A (zh) * | 2006-03-16 | 2006-08-23 | 上海师范大学 | 粒径尺寸均匀的非晶态合金催化剂及其制备方法 |
CN101157034A (zh) * | 2007-11-13 | 2008-04-09 | 上海师范大学 | 一种非晶态合金催化剂及其制备方法和用途 |
CN102886527A (zh) * | 2012-10-12 | 2013-01-23 | 东华大学 | 一种以油酸银为原料的油水界面法制备立方晶型纳米银材料的方法 |
CN103127936A (zh) * | 2013-02-04 | 2013-06-05 | 中国科学院过程工程研究所 | 一种液相球磨部分还原法制备催化剂的方法及三元铜催化剂 |
CN103172124A (zh) * | 2013-04-17 | 2013-06-26 | 新疆大学 | 一种固相化学反应制备氧化铁三维纳米结构的方法 |
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Effective date of registration: 20191225 Address after: No.58 Xinfu Road, Xinjie community, yonganzhou Town, Gaogang District, Taizhou City, Jiangsu Province Patentee after: Chen Weidi Address before: 730070 Anning Road, Anning District, Gansu, Lanzhou, China, No. 967 Patentee before: Northwest Normal University |
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Effective date of registration: 20201104 Address after: Room 706, building 6, No. 999, Wanshou South Road, Chengnan street, Rugao City, Nantong City, Jiangsu Province Patentee after: Nantong Nuolin metal new material technology Co.,Ltd. Address before: No.58 Xinfu Road, Xinjie community, yonganzhou Town, Gaogang District, Taizhou City, Jiangsu Province Patentee before: Chen Weidi |
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TR01 | Transfer of patent right | ||
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Address after: Room 706, building 6, 999 Wanshou South Road, Chengnan street, Rugao City, Nantong City, Jiangsu Province, 226500 Patentee after: Nantong Nuolin New Technology Co.,Ltd. Address before: Room 706, building 6, 999 Wanshou South Road, Chengnan street, Rugao City, Nantong City, Jiangsu Province, 226500 Patentee before: Nantong Nuolin metal new material technology Co.,Ltd. |
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CP01 | Change in the name or title of a patent holder |